EP0113180A2 - Katalytische Umwandlung von leichten olefinischen Beschickungen in einer Gasanlage von einem katalytischen fluidisierten Krachverfahren - Google Patents
Katalytische Umwandlung von leichten olefinischen Beschickungen in einer Gasanlage von einem katalytischen fluidisierten Krachverfahren Download PDFInfo
- Publication number
- EP0113180A2 EP0113180A2 EP83307095A EP83307095A EP0113180A2 EP 0113180 A2 EP0113180 A2 EP 0113180A2 EP 83307095 A EP83307095 A EP 83307095A EP 83307095 A EP83307095 A EP 83307095A EP 0113180 A2 EP0113180 A2 EP 0113180A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- feedstock
- zsm
- zeolite
- fuel oil
- gas plant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000006243 chemical reaction Methods 0.000 title claims description 26
- 230000003197 catalytic effect Effects 0.000 title description 7
- 238000004523 catalytic cracking Methods 0.000 title description 2
- 150000001336 alkenes Chemical class 0.000 claims abstract description 31
- 239000003502 gasoline Substances 0.000 claims abstract description 29
- 238000004231 fluid catalytic cracking Methods 0.000 claims abstract description 25
- 239000010457 zeolite Substances 0.000 claims abstract description 24
- 239000000295 fuel oil Substances 0.000 claims abstract description 23
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 15
- 238000000926 separation method Methods 0.000 claims abstract description 9
- 238000011084 recovery Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 22
- 239000006096 absorbing agent Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 8
- 150000001412 amines Chemical class 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- 239000011148 porous material Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 abstract description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 6
- 239000007789 gas Substances 0.000 description 48
- 239000007788 liquid Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 7
- 150000002430 hydrocarbons Chemical class 0.000 description 7
- 230000029936 alkylation Effects 0.000 description 6
- 238000005804 alkylation reaction Methods 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000007792 gaseous phase Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 239000001282 iso-butane Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 238000011027 product recovery Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000005899 aromatization reaction Methods 0.000 description 1
- 238000003442 catalytic alkylation reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000010771 distillate fuel oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Definitions
- This invention relates to the catalytic conversion of olefinic feedstocks in a FCC gas plant to gasoline and fuel oil using a ZSM-5 type zeolite catalyst.
- the need for separate processes for the polymerization or alkylation of the olefins in this stream is obviated or reduced.
- the concept of utilizing a ZSM-5 type zeolite catalyzed conversion instead of the prior art processes for providing C 5 + gasoline and/or fuel oil blending stocks has many advantages. Since the ZSM-5 type zeolites can tolerate the poisoning effects of the impurities normally found in raw FCC product streams, extreme purification procedures often encountered in polymerization and alkylation do not have to be employed.
- the broad concept of contacting olefins, alone or in admixture with each other or other hydrocarbons, over the identified catalyst with which this invention is concerned is not per se novel.
- the key to this invention resides in selecting a C 2 to C 5 olefins-containing gas stream in a FCC gas plant as the feedstock for the desired catalytic conversion and the use of the separation and recovery facilities of the gas plant to process the effluent from the catalytic conversion such that gasoline and/or fuel oil fractions useful in gasoline and fuel oil blending may be produced without the necessity of providing product recovery facilities, thereby minimizing the capital investment and operating costs for the subject process.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44580882A | 1982-12-01 | 1982-12-01 | |
| US445808 | 1982-12-01 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0113180A2 true EP0113180A2 (de) | 1984-07-11 |
| EP0113180A3 EP0113180A3 (en) | 1987-01-14 |
| EP0113180B1 EP0113180B1 (de) | 1989-03-08 |
Family
ID=23770278
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19830307095 Expired EP0113180B1 (de) | 1982-12-01 | 1983-11-21 | Katalytische Umwandlung von leichten olefinischen Beschickungen in einer Gasanlage von einem katalytischen fluidisierten Krachverfahren |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0113180B1 (de) |
| JP (1) | JPS59108090A (de) |
| AU (1) | AU562524B2 (de) |
| BR (1) | BR8306584A (de) |
| CA (1) | CA1213551A (de) |
| DE (1) | DE3379335D1 (de) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0311375A1 (de) * | 1987-10-08 | 1989-04-12 | Mobil Oil Corporation | Verfahren zur Spaltung von Kohlenwasserstoffeinsätzen für die Herstellung von Benzin und Olefinen und die Aufarbeitung der Olefine für die Verbesserung der totalen Benzinausbeute |
| US4831203A (en) * | 1987-12-16 | 1989-05-16 | Mobil Oil Corporation | Integrated production of gasoline from light olefins in a fluid cracking process plant |
| US4831205A (en) * | 1987-12-16 | 1989-05-16 | Mobil Oil Corporation | Catalytic conversion of light olefinic feedstocks in a FCC plant |
| US4831204A (en) * | 1987-12-16 | 1989-05-16 | Mobile Oil Corporation | Production of gasoline from light olefins with FCC gas plant improvement by olefin upgrading |
| EP0295018A3 (de) * | 1987-06-11 | 1989-10-11 | Mobil Oil Corporation | Integriertes Verfahren zur Erzeugung von Benzin |
| US5000837A (en) * | 1989-04-17 | 1991-03-19 | Mobil Oil Corporation | Multistage integrated process for upgrading olefins |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8301747A (nl) * | 1983-05-17 | 1984-12-17 | Shell Int Research | Werkwijze voor de bereiding van middeldestillaten. |
| US4605493A (en) * | 1984-12-31 | 1986-08-12 | Mobil Oil Corporation | Method for minimizing recycling in an unsaturated gas plant |
| US4746762A (en) * | 1985-01-17 | 1988-05-24 | Mobil Oil Corporation | Upgrading light olefins in a turbulent fluidized catalyst bed reactor |
| US4754100A (en) * | 1986-03-28 | 1988-06-28 | Mobil Oil Corporation | Catalytic conversion of C3 aliphatics to higher hydrocarbons |
| DE3867245D1 (de) * | 1987-01-23 | 1992-02-13 | Mobil Oil Corp | Verbesserung von diolefine enthaltenden kohlenwasserstoffen. |
| CN104276911A (zh) * | 2009-03-31 | 2015-01-14 | 环球油品公司 | 稀乙烯的低聚方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB510155A (en) * | 1937-11-26 | 1939-07-26 | Standard Oil Co Indiana | Improvements relating to the conversion of mineral oils into gasoline |
| US4211640A (en) * | 1979-05-24 | 1980-07-08 | Mobil Oil Corporation | Process for the treatment of olefinic gasoline |
-
1983
- 1983-11-21 EP EP19830307095 patent/EP0113180B1/de not_active Expired
- 1983-11-21 DE DE8383307095T patent/DE3379335D1/de not_active Expired
- 1983-11-24 AU AU21671/83A patent/AU562524B2/en not_active Ceased
- 1983-11-29 CA CA000442216A patent/CA1213551A/en not_active Expired
- 1983-11-30 JP JP22457183A patent/JPS59108090A/ja active Pending
- 1983-11-30 BR BR8306584A patent/BR8306584A/pt unknown
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0295018A3 (de) * | 1987-06-11 | 1989-10-11 | Mobil Oil Corporation | Integriertes Verfahren zur Erzeugung von Benzin |
| EP0311375A1 (de) * | 1987-10-08 | 1989-04-12 | Mobil Oil Corporation | Verfahren zur Spaltung von Kohlenwasserstoffeinsätzen für die Herstellung von Benzin und Olefinen und die Aufarbeitung der Olefine für die Verbesserung der totalen Benzinausbeute |
| US4831203A (en) * | 1987-12-16 | 1989-05-16 | Mobil Oil Corporation | Integrated production of gasoline from light olefins in a fluid cracking process plant |
| US4831205A (en) * | 1987-12-16 | 1989-05-16 | Mobil Oil Corporation | Catalytic conversion of light olefinic feedstocks in a FCC plant |
| US4831204A (en) * | 1987-12-16 | 1989-05-16 | Mobile Oil Corporation | Production of gasoline from light olefins with FCC gas plant improvement by olefin upgrading |
| US5000837A (en) * | 1989-04-17 | 1991-03-19 | Mobil Oil Corporation | Multistage integrated process for upgrading olefins |
Also Published As
| Publication number | Publication date |
|---|---|
| BR8306584A (pt) | 1984-07-10 |
| JPS59108090A (ja) | 1984-06-22 |
| AU562524B2 (en) | 1987-06-11 |
| CA1213551A (en) | 1986-11-04 |
| AU2167183A (en) | 1984-06-07 |
| EP0113180A3 (en) | 1987-01-14 |
| EP0113180B1 (de) | 1989-03-08 |
| DE3379335D1 (en) | 1989-04-13 |
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