EP0123794A2 - Method of making a non woven stretch filler fabric - Google Patents

Method of making a non woven stretch filler fabric Download PDF

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Publication number
EP0123794A2
EP0123794A2 EP84101053A EP84101053A EP0123794A2 EP 0123794 A2 EP0123794 A2 EP 0123794A2 EP 84101053 A EP84101053 A EP 84101053A EP 84101053 A EP84101053 A EP 84101053A EP 0123794 A2 EP0123794 A2 EP 0123794A2
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EP
European Patent Office
Prior art keywords
fibers
filler
producing
material according
upholstery material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP84101053A
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German (de)
French (fr)
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EP0123794A3 (en
Inventor
Kiyoto Nakai
Kanji Hosokawa
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Carl Freudenberg KG
Original Assignee
Carl Freudenberg KG
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Filing date
Publication date
Application filed by Carl Freudenberg KG filed Critical Carl Freudenberg KG
Publication of EP0123794A2 publication Critical patent/EP0123794A2/en
Publication of EP0123794A3 publication Critical patent/EP0123794A3/en
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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4282—Addition polymers
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43825—Composite fibres
    • D04H1/43832—Composite fibres side-by-side
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4382—Stretched reticular film fibres; Composite fibres; Mixed fibres; Ultrafine fibres; Fibres for artificial leather
    • D04H1/43835—Mixed fibres, e.g. at least two chemically different fibres or fibre blends
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4391—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres
    • D04H1/43918—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece characterised by the shape of the fibres nonlinear fibres, e.g. crimped or coiled fibres

Definitions

  • the invention relates to a method for producing an elastic, non-woven filler or cushioning material with a density of 0.005 to 0.05 g / cm 3 according to the preamble of claim 1.
  • a method of this type is known from EP-OS 42 150.
  • a nonwoven made of a fiber mixture with low-melting, shrinkable and higher-melting, crimpable fibers is subjected to a heat treatment such that the temperature lies between the softening temperatures of the two types of fibers.
  • the low-melting component shrinks, the higher-melting component ripples and a bulky padding material is created by these processes.
  • the softening of the low-melting fibers leads to an adhesive binding at the fiber crossing points.
  • the method mentioned requires an exact temperature control with respect to each point of the nonwoven, since even slight deviations negatively influence the melting, shrinking and crimping behavior of the fiber components. Furthermore, the simultaneous laying down of two types of fibers in a defined spatial and quantitative relationship to one another can only be achieved with a high outlay in process control during spinning and during the formation of nonwovens.
  • a method using only one shrinkable type of fiber is described in EP-OS 38 887.
  • the bonding of the fibers in the nonwoven is achieved in that shrinked and crimped fibers are sprayed with a hot melt adhesive before being deposited into a nonwoven.
  • the surface of the filler nonwoven thus formed is sprayed again with binder in a further process step.
  • Subsequent thermal softening of the binder creates a bond between the fibers at their crossing points and on the nonwoven surface.
  • the crimping of the fibers by heating fixed and the binder stabilized at the same time.
  • a disadvantage here is the fact that the individual fibers remain stiff despite their crimping, since the binder is located on the entire outer surface of the fibers after shrinkage and thus blocks a resilient movement. This has a negative effect on the stretchability of the filler nonwoven. Furthermore, the relatively high amount of binder causes sticking at too many places in the fiber fabric, which leads to stiffening and irregularities in the filler; this limits its possible use, for example in sports clothing, where high flexibility is required.
  • DE-AS 12 20 141 contains a method in which a nonwoven fabric made of latent shrinkable or crimpable fibers is solidified solely by needle treatment and then shrunk.
  • this method is only suitable for the production of compact felt materials and would in no way guarantee the required cohesion of the fibers when applied to bulky fillers.
  • the invention has for its object to develop a method of the type mentioned in such a way that the disadvantages mentioned are avoided.
  • the method is intended in particular to provide a filler or upholstery material whose softness, bulk and extensibility outperforms the products previously manufactured using similar methods. These properties should go hand in hand with such a strength that the fillers, even as wadding in sports clothing, can withstand high loads with regard to tensile, compressive and crushable properties. Furthermore, the thermal insulation qualities important for this area of application are to be improved at the same time.
  • a non-woven filler or upholstery material with a density of 0.005 to 0.05 g / cm 3 is obtained by forming a nonwoven scrim with a proportion of at least 30% by weight of latently crimpable fibers and a binder on both sides this fleece sprays, the fleece dries at a temperature below which there is no crimping of the fibers, and then the shrinkage of the fleece is initiated by subjecting the fibers to a crimping process.
  • All synthetic organic continuous threads and / or staple fibers can be used as latent crimpable fibers, provided that they can be shortened to a substantial extent by at least 15%.
  • the shortening should preferably be done by crimping.
  • thermoplastic fibers are those which are heat-set in their manufacture in a highly twisted state and are then untwisted at a lower temperature.
  • a third preferred type of fiber consists of edge-shrunk yarn. These are fibers whose crimpability is based on one-sided molecular orientation disorders.
  • the fleece is produced by carding or carding.
  • the fiber structure should consist of at least 30% by weight, preferably more than 50% by weight, of latent crimpable fibers. Falling below the value of 30% by weight leads to products with insufficient stretchability.
  • a fleece will be used that consists entirely of latent crimpable fibers. Otherwise, the crimpable fibers in a fiber mixture should contain as many crimps as possible, provided that the carding process or the uniformity of the fleece are not impaired thereby. Fibers with a low number of crimps negatively influence the elasticity of the filler.
  • a preferred process variant includes a needling process after the fleece has been laid.
  • a binder for example acrylic resin emulsion
  • a binder for example acrylic resin emulsion
  • good values for stretchability, thickness elasticity and bulk are only achieved if the adhesive dots are distributed three-dimensionally; therefore a spraying process is necessary.
  • hot melt adhesive fibers can also be used the fleece must be mixed in to achieve a three-dimensional adhesive dot distribution.
  • the three-dimensional distribution of the adhesive dots can preferably also be ensured by spraying the fleece on both sides with adhesive.
  • the nonwoven fabric After the adhesive treatment, the nonwoven fabric is subjected to drying in order to achieve the necessary fiber-fiber bond.
  • the temperature must in no case reach the values which initiate crimping, since otherwise uneven shrinkage would result in the fiber composite as a result of simultaneous gluing and crimping, which would result in undesired deformation and / or inadequate elongation properties of the end product.
  • the crimping process of the fibers is initiated. This can be done, for example, by the action of heat below the melting point. In order to maintain the stretching behavior and bulkiness of the product, no tension should be exerted on the nonwoven that would hinder its shrinking in one direction.
  • the fiber density of the resulting filler or upholstery material should be 0.005 to 0.05 g / cm 3 , preferably 0.1 to 0.03 g / cm 3 in view of thermal insulation properties and tensile strength,
  • the nonwoven filling and cushioning nonwovens produced according to the above procedure are characterized by high values for bulk and elasticity. Furthermore, the fact that, according to the invention, a large number of fiber crimps remain unbound, the stretching behavior is uniform and satisfactory on all sides.
  • a further advantage consists in the agreement that by the binder-spraying high Waschbeuri g ness of the product, which is particularly for use in sports and winter clothing beneficial. Due to the excellent thermal insulation properties, such fillers are also well suited for bedding, sleeping bags and gloves.
  • the "percent permanent set" is used as a measure of the stretchability. It is based on measurement data according to the Japanese standard JIS L-1080. Here, the sample is stretched to 40 degrees and then allowed to reform. After repeating this process ten times, the quotient is formed from the remaining length to the initial length of the sample and converted into percent.
  • the fibers had a crimp of 13 crimps / cm (34 / inch) and the degree of shrinkage of the nonwoven was 17% in the longitudinal direction and 23% in the transverse direction.
  • the resulting upholstery fabric had a specific weight of 70 g / m 2 , a thickness of 7 mm and an apparent density of 0.01 g / cm 3 .
  • the permanent deformation which is a measure of the stretchability of the upholstery material, was 25% in the longitudinal and 15% in the transverse direction. These values show a very good stretchability.
  • the filler showed good stretchability after dry cleaning, with values for the permanent deformation of 3.5% in the longitudinal direction and 2.0% in the transverse direction. So there was a high resistance to dry cleaning.
  • the filler obtained in this way could not be measured for its longitudinal stretchability, since it did not withstand a 40% change in length and broke. In the transverse direction, too, there were poor tensile qualities with a residual deformation of 15%.
  • the cushion or filler thus obtained had a specific weight of 130 g / m 2 , a thickness of 6 mm and an apparent density of 0.022 g / cm 3 .
  • the percentage permanent deformation was 1.5 110 in the longitudinal direction and 1.0% in the transverse direction; the product therefore had better values than that in Example 1.
  • This improvement in strength through needle treatment makes the fillers produced according to the invention particularly suitable for use in sports clothing.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nonwoven Fabrics (AREA)

Abstract

The fabric with a density of 0.005 to 0.05 g/cm<3> is produced by processing the latent crimp fibres into a fibre web with or without needling, spraying with a binder and then drying at a temperature at which no crimping of the fibres occurs, then initiating the crimping of the fibres and thus causing the web assembly to shrink, with the proviso that the web comprises at least 30 % by weight of latent crimp fibres or fibre blends and, if desired, less than 30 % of thermal binding fibres.

Description

Die Erfindung betrifft ein Verfahren zur Herstellung eines elastischen, nicht gewebten Füll- oder Polsterstoffes mit einer Dichte von 0,005 bis 0,05 g/cm3 gemäß dem Oberbegriff des Anspruchs 1.The invention relates to a method for producing an elastic, non-woven filler or cushioning material with a density of 0.005 to 0.05 g / cm 3 according to the preamble of claim 1.

Ein Verfahren dieser Art ist aus EP-OS 42 150 bekannt. Dabei wird ein Vlies aus einer Fasermischung mit niedrigschmelzenden, schrumpffähigen und höherschmelzenden, kräuselfähigen Fasern einer Wärmebehandlung unterworfen derart, daß die Temperatur zwischen den Erweichungstemperaturen der beiden Faserarten liegt. Dies hat zur Folge, daß die niedrigschmelzende-Komponente schrumpft, die höherschmelzende Komponente sich kräuselt und durch diese Vorgänge ein bauschiger Wattierungsstoff entsteht. Das Erweichen der niedrigschmelzenden Fasern führt zu einer Klebebindung an den Faserkreuzungsstellen.A method of this type is known from EP-OS 42 150. In this case, a nonwoven made of a fiber mixture with low-melting, shrinkable and higher-melting, crimpable fibers is subjected to a heat treatment such that the temperature lies between the softening temperatures of the two types of fibers. As a result, the low-melting component shrinks, the higher-melting component ripples and a bulky padding material is created by these processes. The softening of the low-melting fibers leads to an adhesive binding at the fiber crossing points.

Das genannte Verfahren erfordert eine exakte Temperaturführung bezüglich eines jeden Punktes des Vliesstoffes, da schon geringe Abweichungen das Schmelz-, Schrumpf- und Kräuselverhalten der Faserkomponenten negativ beeinflussen. Ferner ist das simultane Ablegen zweier Faserarten in einem definierten räumlichen und mengenmäßigen Verhältnis zueinander nur mit einem hohen Aufwand in der Prozeßsteuerung während des Spinnens und während der Vliesbildung zu realisieren.The method mentioned requires an exact temperature control with respect to each point of the nonwoven, since even slight deviations negatively influence the melting, shrinking and crimping behavior of the fiber components. Furthermore, the simultaneous laying down of two types of fibers in a defined spatial and quantitative relationship to one another can only be achieved with a high outlay in process control during spinning and during the formation of nonwovens.

Ein Verfahren unter Verwendung von nur einer schrumpffähigen Fasersorte wird in EP-OS 38 887 beschrieben. Die Verklebung der Fasern im Vlies wird dadurch erreicht, daß bereits geschrumpfte und gekräuselte Fasern noch vor dem Ablegen zu einem Vlies mit einem Schmelzkleber besprüht werden. Nach der Ablage wird in einem weiteren Verfahrensschritt die Oberfläche des so gebildeten Füllvliesstoffes nochmals mit Bindemittel besprüht. Durch anschließendes thermisches Erweichen des Bindemittels entsteht eine Verklebung der Fasern an ihren Kreuzungspunkten und an der Vliesoberfläche. Anschließend wird die Kräuselung der Fasern durch Erhitzen fixiert und gleichzeitig das Bindemittel stabilisiert. Von Nachteil ist hier die Tatsache, daß die Einzelfasern trotz ihrer Kräuselung steif bleiben, da das Bindemittel nach der Schrumpfung sich auf der gesamten Mantelfläche der Fasern befindet und so eine federnde Bewegung blockiert. Dieser Umstand wirkt sich negativ auf die Dehnbarkeit des Füllvliesstoffes aus. Ferner verursacht die relativ hohe Menge an Bindemittel ein Verkleben an zu vielen Stellen im Fasergelege, was zu Versteifungen und Unregelmäßigkeiten im Füllstoff führt; dadurch ist dessen Verwendungsmöglichkeit beispielsweise in Sportbekleidung, wo hohe Flexibilität gefordert wird, eingeschränkt.A method using only one shrinkable type of fiber is described in EP-OS 38 887. The bonding of the fibers in the nonwoven is achieved in that shrinked and crimped fibers are sprayed with a hot melt adhesive before being deposited into a nonwoven. After storage, the surface of the filler nonwoven thus formed is sprayed again with binder in a further process step. Subsequent thermal softening of the binder creates a bond between the fibers at their crossing points and on the nonwoven surface. Then the crimping of the fibers by heating fixed and the binder stabilized at the same time. A disadvantage here is the fact that the individual fibers remain stiff despite their crimping, since the binder is located on the entire outer surface of the fibers after shrinkage and thus blocks a resilient movement. This has a negative effect on the stretchability of the filler nonwoven. Furthermore, the relatively high amount of binder causes sticking at too many places in the fiber fabric, which leads to stiffening and irregularities in the filler; this limits its possible use, for example in sports clothing, where high flexibility is required.

Die DE-AS 12 20 141 enthält ein Verfahren, bei dem ein Faservlies aus latent schrumpf- bzw. kräuselfähigen Fasern allein durch Nadelbehandlung verfestigt und danach geschrumpft wird. Dieses Verfahren eignet sich jedoch ausschließlich zur Herstellung kompakter Filzstoffe und würde bei Anwendung auf bauschige Füllstoffe den erforderlichen Zusammenhalt der Fasern in keiner Weise gewährleisten.DE-AS 12 20 141 contains a method in which a nonwoven fabric made of latent shrinkable or crimpable fibers is solidified solely by needle treatment and then shrunk. However, this method is only suitable for the production of compact felt materials and would in no way guarantee the required cohesion of the fibers when applied to bulky fillers.

Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren der eingangs genannten Art derart weiter zu entwickeln, daß die angesprochenen Nachteile vermieden werden. Das Verfahren soll neben einer Vereinfachung des Herstellungsprozesses insbesondere ermöglichen, einen Füll- bzw. Polsterstoff zu schaffen, dessen Weichheit, Bausch und allseitige Dehnbarkeit die bisher nach ähnlichen Methoden hergestellten Produkte übertrifft. Diese Eigenschaften sollen mit einer solchen Festigkeit einhergehen, daß die Füllstoffe auch als Wattierungen in Sportbekleidung bezüglich Zug-, Druck- und Knautschfähigkeit hohen Beanspruchungen gewachsen sind. Ferner sollen gleichzeitig die für diesen Anwendungsbereich wichtige Wärmedämmqualitäten verbessert werden.The invention has for its object to develop a method of the type mentioned in such a way that the disadvantages mentioned are avoided. In addition to simplifying the manufacturing process, the method is intended in particular to provide a filler or upholstery material whose softness, bulk and extensibility outperforms the products previously manufactured using similar methods. These properties should go hand in hand with such a strength that the fillers, even as wadding in sports clothing, can withstand high loads with regard to tensile, compressive and crushable properties. Furthermore, the thermal insulation qualities important for this area of application are to be improved at the same time.

Diese Aufgabe wird erfindungsgemäß durch die angegebenen Patentansprüche gelöst.This object is achieved according to the invention by the specified claims.

Nach dem vorgeschlagenen Verfahren wird ein nicht gewebter Füll- oder Polsterstoff mit einer Dichte von 0,005 bis 0,05 g/cm3 dadurch erhalten, daß man ein Vliesgelege mit einem Anteil von mindestens 30 Gew.% latent kräuselfähigen Fasern bildet, ein Bindemittel beidseitig auf dieses Vlies sprüht, das Vlies trocknet bei einer Temperatur, unter der keine Kräuselung der Fasern erfolgt, und daß man anschließend die Schrumpfung des Vlieses einleitet, indem die Fasern einem Kräuselungsprozeß unterzogen werden.According to the proposed method, a non-woven filler or upholstery material with a density of 0.005 to 0.05 g / cm 3 is obtained by forming a nonwoven scrim with a proportion of at least 30% by weight of latently crimpable fibers and a binder on both sides this fleece sprays, the fleece dries at a temperature below which there is no crimping of the fibers, and then the shrinkage of the fleece is initiated by subjecting the fibers to a crimping process.

Als latent kräuselfähige Fasern können alle synthetischen organischen Endlosfäden und/oder Stapelfasern Verwendung finden, sofern sie zu einem wesentlichen Anteil um mindestens 15 % verkürzbar sind. Die Verkürzung sollte bevorzugt durch eine Kräuselung erfolgen.All synthetic organic continuous threads and / or staple fibers can be used as latent crimpable fibers, provided that they can be shortened to a substantial extent by at least 15%. The shortening should preferably be done by crimping.

Unter den verschiedenen, für das vorliegende Verfahren einsetzbaren, kräuselfähigen Fasertypen können bevorzugt Seite-an-Seite-Bikomponentenfasern verwendet werden, deren Polymerbestandteile in ihrem thermischen Verhalten voneinander abweichen.Side-by-side bicomponent fibers whose polymer components differ from one another in their thermal behavior can preferably be used among the various types of crimpable fibers that can be used for the present method.

Andere bevorzugte thermoplastische Fasern sind solche, die bei ihrer Herstellung in stark verdrehtem Zustand wärmefixiert und anschließend bei einer niedrigeren Temperatur aufdreht werden.Other preferred thermoplastic fibers are those which are heat-set in their manufacture in a highly twisted state and are then untwisted at a lower temperature.

Eine dritte bevorzugte Faserart besteht aus kantengeschrumpftem Garn. Das sind Fasern, deren Kräuselfähigkeit auf Störungen bezüglich der einseitigen molekularen Ausrichtung beruht.A third preferred type of fiber consists of edge-shrunk yarn. These are fibers whose crimpability is based on one-sided molecular orientation disorders.

Da die Dehnbarkeit eines jeden Polsterstoffes durch die Kräuselung der in ihm enthaltenen Fasern erzeugt wird, muß eine Erhöhung der Anzahl von Faserkräuseln zu einer Verbesserung der erzielbaren Verstreckeigenschaften des Füllstoffes führen. Infolgedessen werden jene Faserarten ein besonders wertvolles Produkt bilden, deren Kräuselungsrate pro Längeneinheit hoch ist.Since the extensibility of each upholstery material is generated by the crimping of the fibers contained in it, an increase in the number of crimped fibers must lead to an improvement in the achievable stretching properties of the filler. As a result, those types of fibers will form a particularly valuable product whose crimp rate per unit length is high.

Erfindungsgemäß wird das Vlies durch Kardieren oder Krempeln erzeugt. Der Faseraufbau soll zu mindestens 30 Gew.%, vorzugsweise zu mehr als 50 Gew.%, aus latent kräuselfähigen Fasern bestehen. Ein Unterschreiten des Wertes von 30 Gew.% führt zu Produkten mit ungenügender Dehnbarkeit. Je größer der Anteil an latent kräuselfähigen Fasern ist, desto besser verhält sich der Polsterstoff in bezug auf seine Streckbarkeit. Um daher besonders gute Dehnwerte zu erhalten, wird man ein Vlies verwenden, das zur Gänze aus latent kräuselfähigen Fasern besteht. Andernfalls sollten die kräuselfähigen Fasern in einer Fasermischung möglichst viele Kräusel enthalten, sofern der Kardiervorgang oder die Gleichförmigkeit des Vlieses hierdurch nicht beeinträchtigt werden. Fasern mit niederer Kräuselzahl beeinflussen die Dehnbarkeit des Füllstoffes negativ.According to the invention, the fleece is produced by carding or carding. The fiber structure should consist of at least 30% by weight, preferably more than 50% by weight, of latent crimpable fibers. Falling below the value of 30% by weight leads to products with insufficient stretchability. The greater the proportion of latent crimpable fibers, the better the upholstery fabric behaves in terms of its stretchability. In order to obtain particularly good elongation values, a fleece will be used that consists entirely of latent crimpable fibers. Otherwise, the crimpable fibers in a fiber mixture should contain as many crimps as possible, provided that the carding process or the uniformity of the fleece are not impaired thereby. Fibers with a low number of crimps negatively influence the elasticity of the filler.

Eine bevorzugte Verfahrensvariante beinhaltet einen Nadelvorgang nach der Vlieslegung.A preferred process variant includes a needling process after the fleece has been laid.

Nach dem Kardieren oder Krempeln und gegebenenfalls Nadeln wird Bindemittel, z.B. Acrylharz-Emulsion,auf das Vlies mittels einer Sprühvorrichtung aufgebracht. Gute Werte für Dehnbarkeit, Dickenelastizität und Bausch werden nur erzielt, wenn die Klebepunkte dreidimensional verteilt sind; daher ist ein Sprühverfahren notwendig. In Verbindung mit diesem Sprühverfahren können auch Schmelzklebefasern in das Vlies eingemischt sein, um eine dreidimensionale Klebepunktverteilung zu erreichen. Bei Anwendung dieses Verfahrens besteht jedoch die Möglichkeit, daß während des Kräuselvorganges die Schmelzklebefasern erneut erweichen und dadurch bereits geschrumpfte Fasern mit anderen verkleben, was die Dehnbarkeit des Endproduktes beeinträchtigt. Solche Schmelzklebefasern dürfen daher nur in geringer Anzahl zugesetzt werden. Die dreidimensionale Verteilung der Klebepunkte kann vorzugsweise auch durch ein beidseitiges Besprühen des Vlieses mit Klebstoff gewährleistet werden.After carding or carding and optionally needling, a binder, for example acrylic resin emulsion, is applied to the nonwoven by means of a spraying device. Good values for stretchability, thickness elasticity and bulk are only achieved if the adhesive dots are distributed three-dimensionally; therefore a spraying process is necessary. In connection with this spraying process, hot melt adhesive fibers can also be used the fleece must be mixed in to achieve a three-dimensional adhesive dot distribution. When using this method, however, there is the possibility that the hot-melt adhesive fibers soften again during the crimping process and thereby glue already shrunk fibers to others, which impairs the stretchability of the end product. Such hot melt adhesive fibers may therefore only be added in small numbers. The three-dimensional distribution of the adhesive dots can preferably also be ensured by spraying the fleece on both sides with adhesive.

Nach der Klebstoffbehandlung wird der Vliesstoff einer Trocknung unterzogen, um die notwendige Faser-Faser-Bindung zu erzielen. Erfindungsgemäß darf hierbei die Temperatur keinesfalls die eine Kräuselung einleitenden Werte erreichen, da ansonsten infolge gleichzeitiger Verklebung und Kräuselung eine ungleichmäßige Schrumpfung im Faserverbund hervorgerufen würde, was eine unerwünschte Verformung und/oder ungenügende Dehnungseigenschaften des Endproduktes zur Folge hätte.After the adhesive treatment, the nonwoven fabric is subjected to drying in order to achieve the necessary fiber-fiber bond. According to the invention, the temperature must in no case reach the values which initiate crimping, since otherwise uneven shrinkage would result in the fiber composite as a result of simultaneous gluing and crimping, which would result in undesired deformation and / or inadequate elongation properties of the end product.

Nach dem Trocknungsprozeß wird der Kräuselvorgang der Fasern eingeleitet. Dies kann beispielsweise durch Einwirkung von Wärme unterhalb des Schmelzpunktes geschehen. Um Dehnverhalten und Bauschigkeit des Produktes zu erhalten, sollte dabei möglichst keinerlei Zugkraft auf das Vlies ausgeübt werden, die dessen Schrumpfen in einer Richtung behindern würde.After the drying process, the crimping process of the fibers is initiated. This can be done, for example, by the action of heat below the melting point. In order to maintain the stretching behavior and bulkiness of the product, no tension should be exerted on the nonwoven that would hinder its shrinking in one direction.

Die Faserdichte des resultierenden Füll- oder Polsterstoffes soll 0,005 bis 0,05 g/cm3, im Hinblick auf Wärmedämmeigenschaften und Zugfestigkeit vorzugsweise 0,1 bis 0,03 g/cm3 betragen, Die nach der obigen Verfahrensweise hergestellten nicht gewebten Füll- und Polster-Vliese zeichnen sich durch hohe Werte für Bausch und Dickenelastizität aus. Ferner bewirkt der Umstand, daß erfindungsgemäß eine Vielzahl von Faserkräuseln ungebunden bleibt, ein allseitig gleichförmiges und zufriedenstellendes Dehnverhalten. Ein weiterer Vorteil besteht in der durch das Bindemittel-Sprühverfahren erzielten hohen Waschbeständigkeit des Produktes, was insbesondere bei der Verwendung in Sport- und Winterbekleidung von Vorteil ist. Infolge der hervorragenden Wärmedämmeigenschaften sind solche Füllstoffe auch gut geeignet für Bettzeug, Schlafsäcke und Handschuhe.The fiber density of the resulting filler or upholstery material should be 0.005 to 0.05 g / cm 3 , preferably 0.1 to 0.03 g / cm 3 in view of thermal insulation properties and tensile strength, The nonwoven filling and cushioning nonwovens produced according to the above procedure are characterized by high values for bulk and elasticity. Furthermore, the fact that, according to the invention, a large number of fiber crimps remain unbound, the stretching behavior is uniform and satisfactory on all sides. A further advantage consists in the agreement that by the binder-spraying high Waschbeständi g ness of the product, which is particularly for use in sports and winter clothing beneficial. Due to the excellent thermal insulation properties, such fillers are also well suited for bedding, sleeping bags and gloves.

Die Erfindung wird im folgenden anhand von Beispielen, welche jedoch keine Einschränkung der Patentansprüche darstellen sollen, erläutert. In diesen Beispielen wird als Maß für die Verstreckbarkeit die "prozentuale bleibende Verformung" verwendet. Es beruht auf Meßdaten gemäß der japanischen Norm JIS L-1080. Hierbei wird das Probenstück zu 40 ö gestreckt und dann sich zurückformen gelassen. Nach zehnmaliger Wiederholung dieses Vorganges wird der Quotient aus verbleibender Länge zur Ausgangslänge der Probe gebildet und in Prozente umgerechnet.The invention is explained below using examples, which, however, are not intended to restrict the claims. In these examples, the "percent permanent set" is used as a measure of the stretchability. It is based on measurement data according to the Japanese standard JIS L-1080. Here, the sample is stretched to 40 degrees and then allowed to reform. After repeating this process ten times, the quotient is formed from the remaining length to the initial length of the sample and converted into percent.

Beispiel 1example 1

50 Gew.% an 3 den-Polyesterfasern mit einer Faserlänge von 51 mm und 7 Kräuseln/cm (17/inch), welche durch ein Kantenschrumpfverfahren kräuselfähig gemacht wurden, und 50 Gew.% stark kräuselfähiger 3 den-Polyester-Mehrkomponentenfasemmit einer Länge von 51 mm und 7 Kräuseln/cm (17/inch) wurden gemischt und dann durch eine Kreuzlege-Kardierung in ein Vlies mit einem spezifischen Gewicht von 38 g/m2 übergeführt. Beiderseits des Geleges wurde sodann eine Polyacrylester-Emulsion aufgesprüht und anschließend das Ganze in einem Trockner getrocknet bei einer Temperatur unter 100°C. Zu diesem Zeitpunkt hatte das Vlies ein spezifisches Gewicht von 44 g/m2. Nach beendigter Trocknung wurden die latent kräuselfähigen Fasern unter Verwendung eines Trockners bei 170°C einer Kräuselbehandlung unterworfen, wobei kein oder nur wenig Druck auf die Faserschicht ausgeübt wurde. Dabei begann der Vliesstoff zu schrumpfen.50% by weight of 3 den polyester fibers with a fiber length of 51 mm and 7 crimps / cm (17 / inch), which were made crimpable by an edge shrinking process, and 50% by weight of highly crimpable 3 den polyester multicomponent fibers with a length of 51 mm and 7 crimps / cm (17 / inch) were mixed and then cross-laid Carding transferred into a fleece with a specific weight of 38 g / m 2 . A polyacrylic ester emulsion was then sprayed on both sides of the scrim and the whole was then dried in a dryer at a temperature below 100.degree. At this point the fleece had a specific weight of 44 g / m 2 . After drying was complete, the latent crimpable fibers were crimped using a dryer at 170 ° C with little or no pressure being applied to the fiber layer. The nonwoven began to shrink.

Nach diesem Vorgang wiesen die Fasern einen Kräuselgrad von 13 Kräuseln/cm (34/inch) auf, und der Schrumpfungsgrad des Vlieses betrug in Längsrichtung 17 %, in Querrichtung 23 %. Der resultierende Polsterstoff hatte ein spezifisches Gewicht von 70 g/m2, eine Dicke von 7 mm und eine scheinbare Dichte von 0,01 g/cm3.After this process, the fibers had a crimp of 13 crimps / cm (34 / inch) and the degree of shrinkage of the nonwoven was 17% in the longitudinal direction and 23% in the transverse direction. The resulting upholstery fabric had a specific weight of 70 g / m 2 , a thickness of 7 mm and an apparent density of 0.01 g / cm 3 .

Die bleibende Verformung, welche ein Maß für die Verstreckbarkeit des Polsterstoffes darstellt, betrug 25 % in Längs-und 15 % in Querrichtung. Diese Werte zeugen von einer sehr guten Verstreckbarkeit.The permanent deformation, which is a measure of the stretchability of the upholstery material, was 25% in the longitudinal and 15% in the transverse direction. These values show a very good stretchability.

Ferner zeigte der Füllstoff eine gute Verstreckbarkeit nach einer Trockenreinigung, mit Werten für die bleibende Verformung von 3,5 % in Längs- und 2,0 % in Querrichtung. Es ergab sich also eine hohe Widerstandsfähigkeit gegen eine Trockenreinigung.Furthermore, the filler showed good stretchability after dry cleaning, with values for the permanent deformation of 3.5% in the longitudinal direction and 2.0% in the transverse direction. So there was a high resistance to dry cleaning.

VergleichsbeispielComparative example

100 Gew.% einer hoch kräuselfähigen Mehrkomponentenfaser von 3 den, 51 mm Faserlänge und 7 Kräuseln/cm (17/inch) wurden zu einem Vlies von 38 g/m2 durch ein Kreuzlege-Kardierverfahren bearbeitet. Danach wurde, wie in Beispiel 1, eine Polyacryl-Emulsion über beide Oberflächen des Geleges gesprüht und dieses dann mittels eines Trockners bei 150°C getrocknet. Das Vlies wog nach dieser Behandlung 44 g/m2.100% by weight of a highly crimpable multicomponent fiber of 3 den, 51 mm fiber length and 7 crimps / cm (17 / inch) were made into a fleece of 38 g / m 2 by a cross-laying Carding process processed. Thereafter, as in Example 1, a polyacrylic emulsion was sprayed over both surfaces of the scrim and this was then dried at 150 ° C. using a dryer. The fleece weighed 44 g / m 2 after this treatment.

Der so erhaltene Füllstoff ließ sich bezüglich seiner Längsverstreckbarkeit nicht messen, da er einer 40 %igen Längenänderung nicht stand hielt und brach. Auch in Querrichtung zeigten sich schlechte Zugqualitäten mit einer bleibenden Restverformung von 15 %.The filler obtained in this way could not be measured for its longitudinal stretchability, since it did not withstand a 40% change in length and broke. In the transverse direction, too, there were poor tensile qualities with a residual deformation of 15%.

Beispiel 2Example 2

100 Gew.% an Seite-an-Seite-Bikomponentenfasern mit 4 den und 51 mm Länge, bestehend aus einer Polyesterkomponente mit einem Schmelzpunkt von 210°C und einer Schrumpf-Anfangstemperatur von 160°C sowie einer Polyesterkomponente mit einem Schmelzpunkt von 255°C und einer Schrumpf-Anfangstemperatur von 230°C wurden mittels einer gewöhnlichen Kreuzlege-Karde zu einem Vlies mit 55 g/m2 und einer Dicke von 10 mm verarbeitet. Das Vlies erfuhr danach eine Nadelbehandlung unter Verwendung eines Nadelstuhls. Man erhielt ein filzartiges Produkt mit einer Dicke von 4 mm. Auf seine beiden Seiten wurde eine Polyacrylester-Emulsion aufgesprüht und der Vliesstoff dann bei 120°C getrocknet. Sein spezifisches Gewicht betrug danach 63 g/m2. Nach der Trocknung erfolgte die Kräuselung der Fasern unter Verwendung eines Wärmeschrumpf-Apparates; das Vlies erfuhr dabei eine Schrumpfung von 22 % in Längs- und 38 % in Querrichtung.100% by weight of side-by-side bicomponent fibers with 4 den and 51 mm length, consisting of a polyester component with a melting point of 210 ° C and a shrinkage starting temperature of 160 ° C and a polyester component with a melting point of 255 ° C and an initial shrinking temperature of 230 ° C. were processed into a nonwoven with 55 g / m 2 and a thickness of 10 mm by means of an ordinary cross-laying card. The fleece then underwent needle treatment using a needle chair. A felt-like product with a thickness of 4 mm was obtained. A polyacrylic ester emulsion was sprayed onto both sides and the nonwoven fabric was then dried at 120 ° C. Its specific weight was then 63 g / m 2 . After drying, the fibers were crimped using a heat shrinking apparatus; the fleece shrank 22% in the longitudinal direction and 38% in the transverse direction.

Der so erhaltene Polster- bzw. Füllstoff wies ein spezifisches Gewicht von 130 g/m2, eine Dicke von 6 mm und eine scheinbare Dichte von 0,022 g/cm3 auf. Die prozentuale bleibende Verformung betrug in Längsrichtung 1,5 110, in Querrichtung 1,0 %; das Produkt wies also bessere Werte auf als das in Beispiel 1.The cushion or filler thus obtained had a specific weight of 130 g / m 2 , a thickness of 6 mm and an apparent density of 0.022 g / cm 3 . The percentage permanent deformation was 1.5 110 in the longitudinal direction and 1.0% in the transverse direction; the product therefore had better values than that in Example 1.

Diese Verbesserung der Festigkeit durch Nadelbehandlung macht die erfindungsgemäß hergestellten Füllstoffe besonders für die Anwendung in Sportkleidung geeignet.This improvement in strength through needle treatment makes the fillers produced according to the invention particularly suitable for use in sports clothing.

Claims (9)

1. Verfahren zur Herstellung eines elastischen, nicht gewebten Füll- oder Polsterstoffes mit einer Dichte von 0,005 bis 0,05 g/cm3, dadurch gekennzeichnet, daß ein kardiertes bzw. gekrempeltes Vliesgelege mit einem Anteil von mindestens 30 Gew.% latent kräuselfähigen Fasern mit Bindemittel besprüht und danach getrocknet wird, wobei die Trockentemperatur so niedrig liegt, daß keinerlei Faserkräuselung erfolgt, und daß anschließend das Vlies einem allseitig ausgerichteten Kräuselungsprozeß unterzogen wird.1. A process for producing an elastic, non-woven filler or cushioning material with a density of 0.005 to 0.05 g / cm 3 , characterized in that a carded or carded nonwoven scrim with a proportion of at least 30% by weight of latently crimpable fibers sprayed with binder and then dried, the drying temperature being so low that there is no fiber crimping, and that the fleece is then subjected to a crimping process oriented on all sides. 2. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach Anspruch 1, dadurch gekennzeichnet, daß als latent kräuselfähige Fasern Bikomponentenfasern des Seite-an-Seite-Typs verwendet werden, deren Komponenten voneinander verschiedene, das Kräuseln auslösende Temperaturen aufweisen.2. A method for producing a filler or upholstery material according to claim 1, characterized in that bicomponent fibers of the side-by-side type are used as latent crimpable fibers, the components of which have different temperatures which trigger the crimping. 3. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach Anspruch l, dadurch gekennzeichnet, daß thermoplastische Fasern mit latenter Verdrehbarkeit verwendet werden.3. A method for producing a filler or upholstery material according to claim l, characterized in that thermoplastic fibers with latent twistability are used. 4. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach Anspruch 1, dadurch gekennzeichnet, daß Fasern verwendet werden, die infolge ihres molekularen Aufbaus entlang einer Längskante latent kräuselfähig sind.4. A method for producing a filler or upholstery material according to claim 1, characterized in that fibers are used which, due to their molecular structure, are latently curable along a longitudinal edge. 5. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach Anspruch 1 bis 4, dadurch gekennzeichnet, daß Mischungen aus Fasern mit unterschiedlicher Kräuseltemperatur verwendet werden.5. A method for producing a filler or upholstery material according to claim 1 to 4, characterized in that mixtures of fibers with different crimping temperature are used. 6. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß der Vliesstoff zu 100 % aus latent kräuselfähigen Fasern besteht.6. A method for producing a filler or upholstery material according to one of claims 1 to 5, characterized in that the nonwoven fabric consists of 100% latent crimpable fibers. 7. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß das Vliesgelege weniger als 30 Gew.% thermoplastische Bindefasern enthält.7. A method for producing a filler or upholstery material according to one of claims 1 to 5, characterized in that the nonwoven fabric contains less than 30% by weight of thermoplastic binding fibers. 8. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das Vliesgelege vor dem Auftragen des Bindemittels genadelt wird.8. A method for producing a filler or upholstery material according to one of the preceding claims, characterized in that the nonwoven scrim is needled before the application of the binder. 9. Verfahren zur Herstellung eines Füll- oder Polsterstoffes nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das Bindemittel ober- und unterseitig auf das Vlies aufgesprüht wird.9. A method for producing a filler or upholstery material according to one of the preceding claims, characterized in that the binder is sprayed onto the fleece on the top and bottom.
EP84101053A 1983-03-31 1984-02-02 Method of making a non woven stretch filler fabric Withdrawn EP0123794A3 (en)

Applications Claiming Priority (2)

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JP58057650A JPS59207182A (en) 1983-03-31 1983-03-31 Production of extensible padding
JP57650/83 1983-03-31

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EP0123794A3 EP0123794A3 (en) 1988-08-31

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3601144A1 (en) * 1985-01-16 1986-08-21 Kimberly-Clark Corp., Neenah, Wis. ELASTOMERIC, FIBROUS NON-WOVEN FLEECE AND METHOD FOR THE PRODUCTION THEREOF
FR2592403A1 (en) * 1985-12-31 1987-07-03 Huet Andre Ets PROCESS FOR THE MANUFACTURE OF A SYNTHETIC FIBER MATERIAL, AND THE MATERIAL OBTAINED.
EP0314433A3 (en) * 1987-10-26 1990-05-16 E.I. Du Pont De Nemours And Company Improved bonded polyester fiberfill batts
WO2007000206A1 (en) * 2005-06-28 2007-01-04 Carl Freudenberg Kg Elastic, soft and punctiformly bound non-woven fabric provided with filler particles and method for ptoduction and the use thereof
US8449947B2 (en) 2000-08-05 2013-05-28 Carl Freudenberg Kg Thermal control nonwoven material
CN112789374A (en) * 2018-09-28 2021-05-11 贝里国际公司 Self-crimping multicomponent fiber and method of making same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT201700099945A1 (en) * 2017-09-06 2019-03-06 Fisi Fibre Sintetiche Spa FIBER STRUCTURE FREE FOR PADDING.

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6707701A (en) * 1966-06-06 1967-12-07
NL6803291A (en) * 1968-03-07 1968-05-27
JPS5063276A (en) * 1973-10-06 1975-05-29
JPS57193566A (en) * 1981-05-13 1982-11-27 Teijin Ltd Padding

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3601144A1 (en) * 1985-01-16 1986-08-21 Kimberly-Clark Corp., Neenah, Wis. ELASTOMERIC, FIBROUS NON-WOVEN FLEECE AND METHOD FOR THE PRODUCTION THEREOF
FR2592403A1 (en) * 1985-12-31 1987-07-03 Huet Andre Ets PROCESS FOR THE MANUFACTURE OF A SYNTHETIC FIBER MATERIAL, AND THE MATERIAL OBTAINED.
EP0233433A1 (en) * 1985-12-31 1987-08-26 Société dite: Etablissements Andre Huet Method for making a material from synthetic fibres, and material so obtained
EP0314433A3 (en) * 1987-10-26 1990-05-16 E.I. Du Pont De Nemours And Company Improved bonded polyester fiberfill batts
US8449947B2 (en) 2000-08-05 2013-05-28 Carl Freudenberg Kg Thermal control nonwoven material
WO2007000206A1 (en) * 2005-06-28 2007-01-04 Carl Freudenberg Kg Elastic, soft and punctiformly bound non-woven fabric provided with filler particles and method for ptoduction and the use thereof
US8114794B2 (en) 2005-06-28 2012-02-14 Carl Freudenberg Kg Elastic, soft and punctiformly bound non-woven fabric provided with filler particles and method for production and the use thereof
CN112789374A (en) * 2018-09-28 2021-05-11 贝里国际公司 Self-crimping multicomponent fiber and method of making same

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JPS59207182A (en) 1984-11-24
EP0123794A3 (en) 1988-08-31

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