EP0131257A2 - Procédé pour revêtir des substrats métalliques - Google Patents

Procédé pour revêtir des substrats métalliques Download PDF

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Publication number
EP0131257A2
EP0131257A2 EP19840107832 EP84107832A EP0131257A2 EP 0131257 A2 EP0131257 A2 EP 0131257A2 EP 19840107832 EP19840107832 EP 19840107832 EP 84107832 A EP84107832 A EP 84107832A EP 0131257 A2 EP0131257 A2 EP 0131257A2
Authority
EP
European Patent Office
Prior art keywords
component
layer
ethylene
stage
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19840107832
Other languages
German (de)
English (en)
Inventor
Günter Eckner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of EP0131257A2 publication Critical patent/EP0131257A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C08J5/128—Adhesives without diluent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor

Definitions

  • the present invention relates to a method for coating metallic substrates of the type defined in the claims.
  • the method according to the invention makes it e.g. possible to produce coated pipes that also meet difficult installation conditions, e.g. withstand transport over heavy or stony soils without damaging the pipe coating.
  • difficult installation conditions e.g. withstand transport over heavy or stony soils without damaging the pipe coating.
  • better, at least equally good adhesion of the coating is achieved.
  • the process is considerably simplified. It is particularly advantageous that the previously required two-stage, separate structure of the two layers-curable resin and adhesion promoter- or the one-stage structure from a mixture of two components can now be carried out in one operation using the prefabricated, easy-to-use film tape and that all the favorable properties are nevertheless obtained the coating can be achieved.
  • the film tape can be conveniently stored and handled. With suitable application methods, for example, repair or welding points, e.g. Pipe connections are coated properly.
  • the final polyethylene layer which is firmly connected to the film strip layer, only serves for external protection.
  • the film strip can be brought into any shape, for example by cutting, punching and the like, which can then be connected to metal substrates in suitable devices.
  • the side of the film consisting of component A) can also be used thermoplastic materials such as polyolefins.
  • the film tape can thus also be used as a sealing material, the material being used in the food industry, inter alia, when polyolefins are used as the final layer.
  • the film tape can be produced in various ways. For example, it is possible to first produce a film from component A ) in the extrusion process and then to coat it on one side with component B) in powder form at temperatures of the film from 100 to 140 ° C.
  • Component A) can also be applied in solid form to a heated substrate in the form of a tape or plate coated with, for example, polytetrafluoroethylene, where it melts and forms a layer which, after cooling to 100 to 140 ° C. with component B) in Coated in powder form and after cooling to 70 to 80 ° C is removed from the metal base.
  • the metal base is generally heated to temperatures which are above the application temperature, ie the temperature of component A ) during the application of component B ).
  • the layer formation from component A) can, however, also take place at the same temperature as the coating with B), so that cooling between the two process steps is not necessary. In all cases, the two components melt together, forming a film strip consisting of a base layer of component A) and a cover layer of component B).
  • the temperature of component layer A) when applying component B) in powder form is preferably 110 to 140, in particular 120 to 135 ° C.
  • the thickness of the base layer formed from component A), ie the film thickness is generally from 45 to 250, preferably from 80 to 200, ⁇ m
  • Application from component B) of 45 to 250, preferably * 150 to 250 ⁇ m is carried out.
  • the film strip is expediently provided with perforation holes over the entire surface, which have a diameter of at most 1 mm. These serve to dissipate any gas formation that may occur during the coating.
  • components A) and B) are in the form of powders, sprinkling, scattering or blowing processes, but preferably the electrostatic coating process, can be used to form the layer.
  • the film strip or its sections is applied with the epoxy resin side onto the preheated metallic substrate, which expediently has a temperature of 200 to 360, preferably 240 to 310 ° C.
  • the pipe is helical on an oblique roller conveyor, the film strip being wound onto the heated pipe.
  • the bandwidth must be at least equal to the slope of the helical movement of the pipe.
  • the tape is e.g. pressed onto the pipe surface using suitable processes and fuses with it.
  • the tube is then optionally cooled to the application temperature suitable for the olefin polymer.
  • the compounds required for curing are added to the solid, curable resins B); however, commercially available resin-hardener mixtures are sometimes used.
  • the epoxy resins are particularly preferred. Suitable epoxy resins are, for example, solid resins based on diphenylol *, so that the total thickness of the film strip can be 90 to 500 ⁇ m. propane and / or diphenylolmethane and epihalohydrin such as epibromohydrin, but especially epichlorohydrin, with an epoxy equivalent weight of 600 to 2000, preferably 700 to 1500, in particular 875 to 1100, optionally also a mixture of several epoxy resins.
  • epoxy resins come e.g. in question: polycarboxylic acid anhydrides, polyamidoamines, secondary and tertiary amines, dicyandiamide and biguanide and derived compounds derived therefrom, amine resins such as melamine resins, hexamethylenetetramine in combination with phenolic resins of the novolak type, phenolic resins, COOH-functional polyesters and acrylic resins, individually or as a mixture.
  • amine resins such as melamine resins, hexamethylenetetramine in combination with phenolic resins of the novolak type, phenolic resins, COOH-functional polyesters and acrylic resins, individually or as a mixture.
  • Suitable curable polyesters as component B) are, for example, unsaturated polyesters with free OH groups which are cured with polycarboxylic acids, their anhydrides and / or with — optionally blocked — polyisocyanates.
  • component B) there are also curable acrylic resins e.g. self-crosslinking etherified methoxylated resins based on acrylic and / or methacrylamides.
  • Resins made from acrylic and / or methacrylic acid esters of polyhydric alcohols which are cured with amines, especially amine resins or with polyisocyanates, can also be used.
  • Acrylic resins with built-in glycidyl groups which are hardened with polycarboxylic acid components are also suitable.
  • the particle size of the resins B) can vary widely. So epoxy resins with e.g. 0.2 - 250, preferably 1 - 100 ⁇ m particle size are used; the size of the particles of the other resins B) is e.g. between 0.5 and 250, preferably between 1 and 100 ⁇ m.
  • Component A) in which the term "vinyl compounds” includes (meth) acrylic derivatives, contains as essential Ingredient of at least one copolymer based on ethylene and (meth) acrylic acid and optionally at least one further copolymerizable monomer.
  • copolymers which are free from (meth) acrylic acid can also be used.
  • Copolymerizable monomers are, for example, vinyl acetate, (meth) acrylic acid esters with 1 to 18 carbon atoms in the alkyl radical and others, the vinyl acetate radical in the polymer being able to be wholly or partly saponified to vinyl alcohol.
  • Component A) can have a different chemical composition.
  • It can, for example, a) a vinyl acetate-ethylene (meth) acrylic acid (meth) acrylic acid ester copolymer (melt index, for example, about 15 to 30 g / 10 min.), B) a vinyl acetate-ethylene (meth) acrylic acid copolymer ( Melt index e.g. about 20 to 35 g / min.), C) vinyl acetate-ethylene-vinyl alcohol copolymer (melt index e.g.
  • polyolefin preferably up to 5% by weight of polyolefin can also be incorporated into component A).
  • the particle size of the copolymers A) is not important since the component is processed via the molten state.
  • the layer of olefin polymer applied in the second stage which can be approximately up to 6 mm, preferably 1.5 to 4 mm thick, serves to protect the base layer against injuries. It is expediently light-colored and can also be light-stabilized. It can e.g. as a powder or in the case of objects of suitable shape, in particular tubes in the form of a tape with a thickness of 100 to 400 ⁇ m, preferably 150 to 250 ⁇ m, for example 0.2 mm thick.
  • Suitable olefin polymers have e.g. a melt index of 0.3 to 6.0, preferably 0.5 to 2.0 g / 10 min. For example, it is made of polyethylene e.g.
  • a polyethylene powder from the group LLD, LD (low density), MD, HD (high density) or mixtures thereof, polypropylene or ethylene copolymers, e.g. those of the same components as in the copolymers of component A).
  • the copolymers can also differ from those of the film strip.
  • Additives such as polyvinyl acetate, carbon black and heat stabilizers can also be added to the olefin polymers. The total amount of these additives can be up to 10% by weight, based on the olefin polymers.
  • Suitable light stabilizers for the light-colored polyethylene film are compounds of the benzotriazole type, but also other compounds which are customary for stabilization.
  • a light-colored cover layer has the advantage, for example, that the pipes are well protected against excessive heating when stored outside for long periods under the influence of heat, for example due to sunshine or by laying in strong to cause heated soil layers.
  • the coating from the extruder is also very simple and time-saving without additional equipment.
  • the strip emerging from the extruder advantageously has a melt index of at least 0.4 g / 10 min.
  • the olefin polymer in the powder coating in the second stage has a particle size of 1 to 600 ⁇ m, preferably 100 to 400 gm.
  • a polyethylene film for example in the case of tube coating, is advantageously applied in the form of a self-supporting polyethylene tape. It can be applied to a rotating tube. This has the advantage that the tape can be wound automatically.
  • the bandwidth can be varied as desired. It is e.g. at least 20 mm. A range of up to about 1 m is generally used.
  • light colored olefin polymer material is preferably white. However, one can. other color can be selected, e.g. the warning color yellow, but also light orange, light blue, light green or the like. If necessary, the light-colored tapes can also be used to identify the pipes.
  • the substrate should have a temperature of at most 260 ° C when applying a polyolefin band, while when applying the powder Temperature can be up to 360, preferably up to 300 ° C.
  • the substrate is cooled, for example in air or by water cooling.
  • the olefin polymer applied in the second process stage consists of an ethylene-vinyl acetate-acrylic or methacrylic acid copolymer
  • the speed at which the film tape and olefin polymer are coated can vary within wide limits. It depends on the layer thickness and the metallic substrate. For example, in the case of a pipe with an outer pipe diameter of 50 to 2000 mm, a minimum layer thickness between 1.5 and 4 mm is required for adequate corrosion protection.
  • the requirements regarding minimum layer thickness, freedom from pores, peel strength, impact resistance, indentation resistance, elongation at break, specific coating resistance, heat and light aging according to the regulations of DIN 30 670 and DIN 30 671 are fully met by the coatings produced according to the invention.
  • the average force required to remove the casing according to DIN 30 670 is 35 N / cm strip width.
  • the metallic substrates coated by the process according to the invention are used in a variety of ways.
  • they are pipes because of their surfaces protection especially for pipelines, for example for the extraction of petroleum, but also of other gaseous, liquid or highly viscous substances, for example natural gas, water, sewage sludge, concrete, waste water, slurries or the like are suitable.
  • the pipes coated according to the invention have increased heat resistance, so that material to be conveyed which has an elevated temperature, e.g. up to about 100 ° C, e.g. heated liquids can be pumped over long periods without affecting the coating.
  • the transport of heated liquids is e.g. given when the pipes are arranged behind compressor stations. In these stations, the medium to be funded is e.g. heated to temperatures of about 150 ° C. In the subsequent pipe section there is therefore a thermal load which is between the ambient temperature and 150 ° C.
  • metallic substrates that require particularly resistant surface protection can also be coated using the method according to the invention.
  • metallic moldings of all types and sizes, containers, components, etc. coated the list is not exhaustive and the process is appropriate to the circumstances, e.g. also an inner coating must be adapted.
  • Inner coatings also include seals, e.g. Closure seals in the food industry in the form of lids, crown caps, etc.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
EP19840107832 1983-07-09 1984-07-05 Procédé pour revêtir des substrats métalliques Withdrawn EP0131257A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19833324791 DE3324791A1 (de) 1983-07-09 1983-07-09 Verfahren zur beschichtung von metallischen substraten
DE3324791 1983-07-09

Publications (1)

Publication Number Publication Date
EP0131257A2 true EP0131257A2 (fr) 1985-01-16

Family

ID=6203563

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19840107832 Withdrawn EP0131257A2 (fr) 1983-07-09 1984-07-05 Procédé pour revêtir des substrats métalliques

Country Status (2)

Country Link
EP (1) EP0131257A2 (fr)
DE (1) DE3324791A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU578321B2 (en) * 1984-11-09 1988-10-20 Raychem Limited A curable polymeric coating bonding second polymer layer to a substrate
US5051273A (en) * 1990-01-16 1991-09-24 Nippon Oil And Fats Company, Limited Method of preparation of a patterned decorative material
US5164219A (en) * 1990-01-16 1992-11-17 Nippon Oil And Fats Company, Limited Method of preparation of a patterned decorative material
WO1997008253A1 (fr) * 1995-08-28 1997-03-06 Ppg Industries, Inc. Fermeture pour recipient, recouverte de peinture en poudre
KR100911079B1 (ko) * 2007-04-24 2009-08-06 미쓰비시덴키 가부시키가이샤 엘리베이터 장치

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3605401C1 (en) * 1986-02-20 1987-05-27 Hoesch Ag Process for coating a pipe

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1355761A (fr) * 1963-02-07 1964-03-20 Pneumatiques, Caoutchouc Manufacture Et Plastiques Kleber-Colombes Procédé de collage des polymères thermoplastiques sur surfaces métalliques
DE1629530B1 (de) * 1966-03-08 1972-05-25 Mannesmann Ag Verfahren zum Herstellen eines aus einem Stahlrohr mit aeusseren Kunststoffschichten bestehenden Verbundrohres
US3669797A (en) * 1968-07-06 1972-06-13 Mitsubishi Chem Ind Method of manufacturing composite bodies of metals and polyolefins
DE1958526A1 (de) * 1969-11-21 1971-05-27 Kabel Metallwerke Ghh Verfahren zum Herstellen kunststoffummantelter Metallrohre
DE2257135C3 (de) * 1972-11-17 1975-07-31 Mannesmann Ag, 4000 Duesseldorf Verfahren zum Herstellen eines aus einem metallischen Kernohr und einer thermoplastischen Kunststoffummantelung bestehenden Verbundrohres
JPS534880B2 (fr) * 1973-11-22 1978-02-21
JPS51124181A (en) * 1975-04-22 1976-10-29 Toyo Seikan Kaisha Ltd Polyolefin-metal bonded structure
DE2519046C3 (de) * 1975-04-25 1979-08-23 Mannesmann Ag, 4000 Duesseldorf Verfahren zum Aufbringen einer Schicht aus Polyäthylen auf ein Stahlrohr
US4034132A (en) * 1975-09-25 1977-07-05 The Continental Group, Inc. Propylene polymer adhered to enamel coated metal surface
US4012270A (en) * 1975-09-25 1977-03-15 The Continental Group Inc. Method of improving the adhesion of propylene polymers to enamel coated metal surfaces
JPS582825B2 (ja) * 1977-11-17 1983-01-18 日本クラウンコルク株式会社 オレフイン樹脂−金属接着構造物及びその製造方法
US4211595A (en) * 1978-10-10 1980-07-08 The Kendall Company Method of coating pipe
US4213486A (en) * 1978-11-06 1980-07-22 The Kendall Company Coated pipe and process for making same
JPS56152765A (en) * 1980-04-30 1981-11-26 Kansai Paint Co Ltd Formation of olefin resin coating film
DE3046264C2 (de) * 1980-12-09 1982-12-09 Basf Farben + Fasern Ag, 2000 Hamburg Verfahren zum Ummanteln eines Metallrohres
DE3101684A1 (de) * 1981-01-21 1982-08-26 Hoechst Ag, 6000 Frankfurt "verfahren zur beschichtung von metallrohren und verwendung der nach diesem verfahren hergestellten rohre"
DE3247512C1 (de) * 1982-12-20 1987-11-12 Mannesmann AG, 4000 Düsseldorf Verfahren zum Beschichten von metallischen Formkoerpern mit Polyaethylen

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU578321B2 (en) * 1984-11-09 1988-10-20 Raychem Limited A curable polymeric coating bonding second polymer layer to a substrate
US5051273A (en) * 1990-01-16 1991-09-24 Nippon Oil And Fats Company, Limited Method of preparation of a patterned decorative material
EP0451301A1 (fr) * 1990-01-16 1991-10-16 Nippon Oil And Fats Company, Limited Méthode de préparation d'un matériau décoratif comportant un motif
US5164219A (en) * 1990-01-16 1992-11-17 Nippon Oil And Fats Company, Limited Method of preparation of a patterned decorative material
WO1997008253A1 (fr) * 1995-08-28 1997-03-06 Ppg Industries, Inc. Fermeture pour recipient, recouverte de peinture en poudre
KR100911079B1 (ko) * 2007-04-24 2009-08-06 미쓰비시덴키 가부시키가이샤 엘리베이터 장치

Also Published As

Publication number Publication date
DE3324791A1 (de) 1985-01-17

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Inventor name: ECKNER, GUENTER