EP0151936A2 - Agent de lavage ayant des qualités adoucissant le linge et procédé pour sa production - Google Patents

Agent de lavage ayant des qualités adoucissant le linge et procédé pour sa production Download PDF

Info

Publication number: EP0151936A2
Authority: EP; European Patent Office
Prior art keywords: atoms; fabric softener; weight; alkyl radical; component
Prior art date: 1984-01-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP85100278A

Other languages

German (de)

English (en)

Other versions

EP0151936A3 (en

EP0151936B1 (fr

Inventor

Helmut Dr. Dipl.-Chem. Hein

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rewo Chemische Werke GmbH

Original Assignee

Rewo Chemische Werke GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-01-25

Filing date

1985-01-12

Publication date

1985-08-21

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6225822&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0151936(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1985-01-12 Application filed by Rewo Chemische Werke GmbH filed Critical Rewo Chemische Werke GmbH

1985-01-12 Priority to AT85100278T priority Critical patent/ATE42763T1/de

1985-08-21 Publication of EP0151936A2 publication Critical patent/EP0151936A2/fr

1986-11-20 Publication of EP0151936A3 publication Critical patent/EP0151936A3/de

1989-05-03 Application granted granted Critical

1989-05-03 Publication of EP0151936B1 publication Critical patent/EP0151936B1/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims description 10
238000004519 manufacturing process Methods 0.000 title claims description 8
238000005406 washing Methods 0.000 title description 20
239000002979 fabric softener Substances 0.000 claims abstract description 38
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 37
239000003599 detergent Substances 0.000 claims abstract description 19
150000001450 anions Chemical class 0.000 claims abstract description 16
239000013543 active substance Substances 0.000 claims abstract description 13
239000000654 additive Substances 0.000 claims abstract description 10
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 10
150000003856 quaternary ammonium compounds Chemical class 0.000 claims abstract description 10
150000001875 compounds Chemical class 0.000 claims abstract description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 8
125000001183 hydrocarbyl group Chemical group 0.000 claims abstract description 8
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 8
239000001257 hydrogen Substances 0.000 claims abstract description 8
239000004902 Softening Agent Substances 0.000 claims abstract description 7
239000000194 fatty acid Substances 0.000 claims abstract description 7
125000004433 nitrogen atom Chemical group N* 0.000 claims abstract description 7
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 6
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 5
229930195729 fatty acid Natural products 0.000 claims abstract description 5
150000004665 fatty acids Chemical class 0.000 claims abstract description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 46
239000000843 powder Substances 0.000 claims description 29
239000000377 silicon dioxide Substances 0.000 claims description 23
239000002250 absorbent Substances 0.000 claims description 12
230000002745 absorbent Effects 0.000 claims description 12
230000000694 effects Effects 0.000 claims description 11
239000004744 fabric Substances 0.000 claims description 9
230000000087 stabilizing effect Effects 0.000 claims description 8
QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 claims description 7
238000009736 wetting Methods 0.000 claims description 7
239000003205 fragrance Substances 0.000 claims description 5
239000003995 emulsifying agent Substances 0.000 claims description 4
239000004094 surface-active agent Substances 0.000 claims description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
239000003945 anionic surfactant Substances 0.000 abstract description 7
239000002736 nonionic surfactant Substances 0.000 abstract description 5
125000000129 anionic group Chemical group 0.000 abstract description 2
239000003463 adsorbent Substances 0.000 abstract 2
150000002431 hydrogen Chemical group 0.000 abstract 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 1
235000012239 silicon dioxide Nutrition 0.000 abstract 1
239000004014 plasticizer Substances 0.000 description 16
239000000203 mixture Substances 0.000 description 9
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
125000002091 cationic group Chemical group 0.000 description 7
238000009472 formulation Methods 0.000 description 5
238000002156 mixing Methods 0.000 description 5
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
229920000151 polyglycol Polymers 0.000 description 4
239000010695 polyglycol Substances 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
239000004665 cationic fabric softener Substances 0.000 description 3
REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 3
239000003112 inhibitor Substances 0.000 description 3
-1 isopropanol oleic acid ester Chemical class 0.000 description 3
239000000155 melt Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 2
239000007844 bleaching agent Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
230000003111 delayed effect Effects 0.000 description 2
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
239000000975 dye Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
239000007788 liquid Substances 0.000 description 2
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
239000000047 product Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000003760 tallow Substances 0.000 description 2
238000011282 treatment Methods 0.000 description 2
ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
101500021084 Locusta migratoria 5 kDa peptide Proteins 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
239000012190 activator Substances 0.000 description 1
230000006978 adaptation Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000003868 ammonium compounds Chemical group 0.000 description 1
IPTLKMXBROVJJF-UHFFFAOYSA-N azanium;methyl sulfate Chemical compound N.COS(O)(=O)=O IPTLKMXBROVJJF-UHFFFAOYSA-N 0.000 description 1
VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
229940051250 hexylene glycol Drugs 0.000 description 1
MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical group C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
229940055577 oleyl alcohol Drugs 0.000 description 1
XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000005204 segregation Methods 0.000 description 1
238000005029 sieve analysis Methods 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads

Definitions

Drum washing machines as are common in European households, usually wash in two steps. In the main wash cycle, the laundry is first cleaned using a washing powder. This is followed by several rinses. A fabric softener is added to the last rinsing bath for post-treatment. This is intended to give the laundry a soft, fluffy feel and impart pleasant wearing properties, even if the laundry has to be dried under unfavorable conditions.
the desired delayed effectiveness can therefore only be achieved if the cationic plasticizer is in powder form and is subsequently added to the washing powder.
the cationic plasticizers have a lower tendency to crystallize, the spray drying process cannot be used.
the roller drying process also presents considerable difficulties because of the slow crystallization and solidification of the products. Significant heat of crystallization is also released, which leads to the fact that the finished powders cake again.
quaternary ammonium compounds and alkylimidazolinium compounds containing lipophilic radicals known as laundry softeners and having surface-active properties can be used as cationic surface-active substances.
Such connections are e.g. B. in Chemistry and Industry, 1969, pp. 893 u. 894.
R 1 , R 2 , R 6 , R 8 , R 9 and R 10 are usually fatty alkyl residues, preferably with a C chain length of C 16 to C 18.
Suitable auxiliaries are, in particular, nonionic surfactants, such as, for. B. are described in DE-A-30 25 369, in particular reaction products of fatty acid ethanol amide or fatty amines with ethylene oxide and / or propylene oxide, which act as dispersants or emulsifiers and may optionally have an additional plasticizing effect.
nonionic emulsifiers are those based on oxyalkylates, e.g. B. reaction products of ethylene oxide with alkylphenols or fatty alcohols.
auxiliaries are: oleyl alcohol polyglycol ether, nonylphenol polyglycol ether or stearic acid monoglyceride polyglycol ether.
Common additives are in particular fragrances, dyes and optical brighteners.
a highly absorbent silica in particular one with 250 to 600 m 2 / g, preferably 350 to 500 m 2 / g (BET), is used as component B).
Suitable fine-particle highly absorbent carrier silicas with a large specific surface area as possible are produced by precipitation and spray drying and are commercially available.
a process according to the invention for the production of powdered fabric softening agents is characterized in that 60-80 parts by weight of a fabric softener based on one or more nitrogen-containing cationic surface-active substances with at least one hydrocarbon group with at least 8 carbon atoms bonded to the nitrogen atom, which optionally usual auxiliaries with stabilizing or back contains wetting action and / or additives, in a powder mixer, optionally together with auxiliaries and / or fragrances, to 20-40 parts by weight of highly absorbent silica.
Suitable mixers are, for example, commercially available ploughshare mixers.
the silica is admixed with the cationic plasticizer, whereby any of the above-mentioned quaternary imidazolinium and ammonium compounds can be used, regardless of which structure is present. Furthermore, properties of the plasticizer are not influenced by the type of anion. It is also immaterial whether the plasticizer is in liquid form or must first be melted in order to be admixed with the silica as a melt. Commercial quaternary plasticizers also often contain solvents, especially lower alcohols and glycols, such as. B. isopropanol, 1,2-propylene glycol or hexylene glycol. These solvents generally do not interfere, i. that is, a plasticizer can be mixed with up to 25% isopropanol, for example with silica, to form a fine powder.
laundry softeners which are dissolved in the abovementioned nonionic surfactants can be applied to the silica as such solutions.
the nonionic surfactants applied together with the cationic fabric softener naturally do not interfere with the washing process.
the powdered fabric softener can be mixed with the usual household detergents for full laundry and 60 ° laundry without any problems.
washing powder is usually in a grain size range of 450 - 500 ⁇ .
a typical plasticizer powder according to Example 2 has a particle size distribution according to the following sieve analysis: This distribution is usually suitable.
the Weichnacher powder can be granulated by suitable control of the speed and temperature of the ploughshare mixer. The grain size increases two to three times.
Such detergents are usually based on anionic and nonionic surfactants and optionally foam inhibitors and usually contain complexing agents, ion exchangers, bleaching agents, bleach activators, stabilizers, graying inhibitors, enzymes, optical brighteners, corrosion inhibitors, fragrances, dyes, adjusting agents.
the fabric softening agents according to the invention do not have the disadvantages mentioned above of the fabric softening agents known to date for adding to the detergents.
the fabric softening agents according to the invention can be produced without any problems and can be added as a powder to the usual detergent powders.
the cationic components of the fabric softener according to the invention are not complexed with anionic surfactants. Rather, the crystalline structure of the fabric softening agent according to the invention ensures a delayed dissolution of the cationic fabric softener portion, so that in the washing process the easily soluble anionic surfactant Dirt is removed in front of the fiber and solubilized in the wash liquor, the anionic surfactant being used accordingly.
the delayed-dissolving cationic plasticizer can then be drawn onto the fiber unhindered.
the carrier silica contained in fabric softeners according to the invention remains in the wash liquor and is no longer detectable on the finished washed textile. Negative influences on the washing process, laundry or washing machine could not be determined.
the following examples show the production of the fabric softener according to the invention.
a commercial heavy-duty detergent with the following composition was used as the washing powder:
silica with a surface area of 500 m 2 / g (Sipernat 50 S, Degussa) are placed in a Loedige mixer. A melt of 70 parts of dimethyldistearylammoniumchloride is slowly run in with constant stirring. The mixer is then set for optimal shear. The mixture is stirred for a further 30 minutes and a free-flowing powder is obtained.
silica with a surface area of 450 m 2 / g (Sipernat 50, Degussa) are placed in a Loedige mixer with slow stirring and 72 parts by weight of a solution of 75% l-methyl-2-tallowalkyl- 3-talgamido Ethylimidazoliniunmethosulfat in 25% isopropanol with the mixer running at a pressure of 3 bar sprayed onto the silica using a suitable nozzle.
the mixer is set for optimal shear. Mixing is continued for about 20 minutes until a uniformly flowing powder free of lumps is obtained.
carrier silica 24 parts by weight of carrier silica are placed in a ploughshare mixer (from Loedige) and 68 parts by weight of 1-methyl-2-oleylalkyl-3-amidoethyl-imidazolinium methosulfate are initially undiluted with continuous mixing at a speed of 120 rpm sprayed. 8 parts by weight of nonylphenol polyglycol ether (prepared with 9 moles of ethylene oxide) are then sprayed on in the same way. The mixer is then set to optimum shear and sheared for 30 minutes until the grain size of the powder has stabilized. The powder is then ready for filling.
carrier silica 4.5 parts by weight of carrier silica are initially introduced into a ploughshare mixer (from Loedige) and 10.5 parts by weight of the melt of a mixture of 75% N, N-bis-talgamidoethyl- N- (2-hydroxyethyl) -N-methylammonium methosulfate and 25% 1,2-propylene glycol are sprayed onto the silica.
the mixing process is then continued for 30 minutes with optimal shear until the grain size is adapted to that of the washing powder to be used.
Both plasticizers contained approximately 25% isopropanol. In each case 70 parts by weight of the plasticizer were adsorbed onto 30 parts by weight of precipitated carrier silica with a special surface area of 450 m 2 / g (according to BET) in a ploughshare mixer.

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

EP85100278A 1984-01-25 1985-01-12 Agent de lavage ayant des qualités adoucissant le linge et procédé pour sa production Expired EP0151936B1 (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
AT85100278T ATE42763T1 (de)	1984-01-25	1985-01-12	Waschmittel mit weichspueleigenschaften und verfahren zu seiner herstellung.

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE3402437		1984-01-25
DE19843402437 DE3402437A1 (de)	1984-01-25	1984-01-25	Pulverfoermiges waescheweichspuelmittel, verfahren zu seiner herstellung und diese enthaltendes waschmittel

Publications (3)

Publication Number	Publication Date
EP0151936A2 true EP0151936A2 (fr)	1985-08-21
EP0151936A3 EP0151936A3 (en)	1986-11-20
EP0151936B1 EP0151936B1 (fr)	1989-05-03

Family

ID=6225822

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP85100278A Expired EP0151936B1 (fr)	1984-01-25	1985-01-12	Agent de lavage ayant des qualités adoucissant le linge et procédé pour sa production

Country Status (9)

Country	Link
EP (1)	EP0151936B1 (fr)
JP (1)	JPS60221492A (fr)
AT (1)	ATE42763T1 (fr)
AU (1)	AU578261B2 (fr)
CA (1)	CA1230454A (fr)
DE (2)	DE3402437A1 (fr)
DK (1)	DK162657B (fr)
NO (1)	NO850289L (fr)
ZA (1)	ZA85625B (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0175287A3 (en) *	1984-09-21	1987-01-07	Hoechst Aktiengesellschaft	Organophilic modified layered-silicic acid adsorbents
EP0247832A1 (fr) *	1986-05-27	1987-12-02	Shiseido Company Limited	Composition détergente
FR2636342A1 (fr) *	1988-09-13	1990-03-16	Rhone Poulenc Chimie	Constituants liquides supportes et formules detergentes les contenant
US4919846A (en) *	1986-05-27	1990-04-24	Shiseido Company Ltd.	Detergent composition containing a quaternary ammonium cationic surfactant and a carboxylate anionic surfactant
EP0523287A1 (fr) *	1991-07-18	1993-01-20	The Procter & Gamble Company	Additifs de parfums pour compositions d'adoucissants pour tissus
GB2313602A (en) *	1996-05-31	1997-12-03	Procter & Gamble	Detergent compositions
EP0881279A3 (fr) *	1997-05-26	1999-06-16	Henkel Kommanditgesellschaft auf Aktien	Procédé de préparation de granules contenant un tensioactif cationique
WO2002081612A1 (fr) *	2001-04-03	2002-10-17	Ciba Specialty Chemicals Holding Inc.	Compositions adoucissantes
US7288498B1 (en)	1997-03-18	2007-10-30	Selecto, Inc	Transition metal oxide-aluminosilicate purification media
GB2507750A (en) *	2012-11-07	2014-05-14	Intelligent Fabric Technologies Plc	Fabric softener with colloidal silica for imparting stain resistant properties

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3243983C2 (de) *	1982-11-27	1984-11-22	Degussa Ag, 6000 Frankfurt	Wäscheweichmachmittelkonzentrat
DE4301266C2 (de) *	1993-01-19	1996-02-01	Wolfgang Metzger	Neue Parfümkomplex-Zusammensetzung mit verbesserter Substantivität sowie deren Verwendung
JP4884848B2 (ja) *	2006-06-01	2012-02-29	花王株式会社	レオロジー改質剤

Citations (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0004121A1 (fr)	1978-03-13	1979-09-19	THE PROCTER & GAMBLE COMPANY	Compositions détergentes pour le linge à faible teneur en phosphate
EP0008829A1 (fr)	1978-09-09	1980-03-19	THE PROCTER & GAMBLE COMPANY	Compositions détergentes à moussage réglé

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Publication number	Priority date	Publication date	Assignee	Title
ZA755347B (en) *	1974-09-06	1977-04-27	Colgate Palmolive Co	Fabric softening composition containing molecular sieve zeolite
BE12T2 (fr) *	1977-07-06	1980-02-08	Procter & Gamble Europ	Geconcentreerde vloeibare wasverzachter die een gemengd actief systeembevat
US4149977A (en) *	1978-01-10	1979-04-17	Economics Laboratory, Inc.	Treatment of fabrics in machine dryers
US4203851A (en) *	1978-06-16	1980-05-20	Colgate-Palmolive Company	Fabric softening compositions and methods for manufacture thereof
JPS598794A (ja) *	1982-07-05	1984-01-18	ライオン株式会社	粒状洗剤用添加剤の製造方法
DE3243983C2 (de) *	1982-11-27	1984-11-22	Degussa Ag, 6000 Frankfurt	Wäscheweichmachmittelkonzentrat
US4642258A (en) *	1983-07-05	1987-02-10	Economics Laboratory, Inc.	Treatment of fabrics in machine dryers using treating means containing fabric treating composition having resistance to change in viscosity and release rate with temperature change

1984
- 1984-01-25 DE DE19843402437 patent/DE3402437A1/de not_active Withdrawn
1985
- 1985-01-12 EP EP85100278A patent/EP0151936B1/fr not_active Expired
- 1985-01-12 AT AT85100278T patent/ATE42763T1/de not_active IP Right Cessation
- 1985-01-12 DE DE8585100278T patent/DE3569939D1/de not_active Expired
- 1985-01-14 DK DK016885A patent/DK162657B/da not_active Application Discontinuation
- 1985-01-16 CA CA000472217A patent/CA1230454A/fr not_active Expired
- 1985-01-16 AU AU37722/85A patent/AU578261B2/en not_active Ceased
- 1985-01-23 JP JP60009308A patent/JPS60221492A/ja active Pending
- 1985-01-24 NO NO850289A patent/NO850289L/no unknown
- 1985-01-25 ZA ZA85625A patent/ZA85625B/xx unknown

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0175287A3 (en) *	1984-09-21	1987-01-07	Hoechst Aktiengesellschaft	Organophilic modified layered-silicic acid adsorbents
EP0247832A1 (fr) *	1986-05-27	1987-12-02	Shiseido Company Limited	Composition détergente
US4919846A (en) *	1986-05-27	1990-04-24	Shiseido Company Ltd.	Detergent composition containing a quaternary ammonium cationic surfactant and a carboxylate anionic surfactant
FR2636342A1 (fr) *	1988-09-13	1990-03-16	Rhone Poulenc Chimie	Constituants liquides supportes et formules detergentes les contenant
EP0359630A1 (fr) *	1988-09-13	1990-03-21	Rhone-Poulenc Chimie	Constituants liquides supportés et formules détergentes les contenant
EP0523287A1 (fr) *	1991-07-18	1993-01-20	The Procter & Gamble Company	Additifs de parfums pour compositions d'adoucissants pour tissus
GB2313602A (en) *	1996-05-31	1997-12-03	Procter & Gamble	Detergent compositions
US7288498B1 (en)	1997-03-18	2007-10-30	Selecto, Inc	Transition metal oxide-aluminosilicate purification media
EP0881279A3 (fr) *	1997-05-26	1999-06-16	Henkel Kommanditgesellschaft auf Aktien	Procédé de préparation de granules contenant un tensioactif cationique
WO2002081612A1 (fr) *	2001-04-03	2002-10-17	Ciba Specialty Chemicals Holding Inc.	Compositions adoucissantes
GB2507750A (en) *	2012-11-07	2014-05-14	Intelligent Fabric Technologies Plc	Fabric softener with colloidal silica for imparting stain resistant properties

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Publication number	Publication date
CA1230454A (fr)	1987-12-22
JPS60221492A (ja)	1985-11-06
DE3402437A1 (de)	1985-07-25
AU578261B2 (en)	1988-10-20
NO850289L (no)	1985-07-26
EP0151936A3 (en)	1986-11-20
DK162657B (da)	1991-11-25
DK16885D0 (da)	1985-01-14
ZA85625B (en)	1985-09-25
DK16885A (da)	1985-07-26
ATE42763T1 (de)	1989-05-15
AU3772285A (en)	1985-08-01
DE3569939D1 (en)	1989-06-08
EP0151936B1 (fr)	1989-05-03

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Publication	Publication Date	Title
DE2021561C2 (de)	1985-02-21	Verfahren zum Weichmachen von Textilien im Heißlufttextiltrockner und Mittel zu seiner Durchführung
DE2334899C2 (de)	1983-12-22	Körniges, gerüststoffhaltiges Waschmittel zum gleichzeitigen Waschen und Weichmachen von Textilien
DE2406553C2 (de)	1985-07-18	Gewebeweichmachende Mittel und diese enthaltende Detergensgemische
DE2631114C3 (de)	1981-11-26	Weichmachungsmittel für Gewebe
DE69330446T2 (de)	2002-05-16	Teilchenförmige Wäscheweichmacher und Reinigungsmittel
EP0151936B1 (fr)	1989-05-03	Agent de lavage ayant des qualités adoucissant le linge et procédé pour sa production
CH623077A5 (fr)	1981-05-15
DE2646995A1 (de)	1977-04-28	Weichmacher fuer textilerzeugnisse
DE2702162A1 (de)	1977-08-18	Teilchenfoermiges textilkonditionierungsmittel und dieses enthaltende waschmittel
DE2446589C2 (de)	1982-04-22	Mittel zum Weich- und Antistatischmachen von Geweben
DE3518100A1 (de)	1985-12-05	Gewebeweichmachendes builderhaltiges waschmittel
EP0086423B1 (fr)	1987-11-25	Moyen et procédé pour le posttraitement du linge lavé
EP0184099B1 (fr)	1991-01-02	Moyen et procédé pour le post-traitement du linge lavé
DE3601431A1 (de)	1986-07-31	Teilchenfoermige, textilweichmachende, antistatisch wirkende waschmittelzusammensetzung und teilchenfoermiges produkt zur herstellung derselben
DE2812118A1 (de)	1978-10-12	Gewebeweichmach-zusammensetzung mit antistatischer wirkung
DE2300658C2 (de)	1983-10-06	Weichmachungsmittel für Textilien mit gleichzeitiger schmutzfreisetzender und antistatischer Wirkung
DE1901194B2 (de)	1978-08-03	Detergens-verträgliches wäßriges Weichmachungsmittel und dessen Verwendung zum Weichmachen von Geweben während des Waschens oder während des Spülens
DE3601925A1 (de)	1986-07-31	Textilweichmachende und antistatische fluessige waschmittelzusammensetzung und fluessiges textilweichmachendes und antistatisches produkt
EP0881279B1 (fr)	2003-01-02	Procédé de préparation de granules contenant un tensioactif cationique
DE2732985C2 (fr)	1990-11-29
DE1619182C3 (de)	1978-03-02	Verfahren zum Weichmachen von Textilien
AT396479B (de)	1993-09-27	Teilchenförmiges wasch- und weichmachungsmittel
EP0018630A1 (fr)	1980-11-12	Agent de lavage pour textiles
DE1093033B (de)	1960-11-17	Fluessiges Grobwaschmittel
DE2424855C2 (de)	1986-01-09	Vergilbungshinderndes Textilweichmachungsmittel