EP0157332A2 - Modificateur de gaz de pyrolyse de déchets - Google Patents
Modificateur de gaz de pyrolyse de déchets Download PDFInfo
- Publication number
- EP0157332A2 EP0157332A2 EP85103523A EP85103523A EP0157332A2 EP 0157332 A2 EP0157332 A2 EP 0157332A2 EP 85103523 A EP85103523 A EP 85103523A EP 85103523 A EP85103523 A EP 85103523A EP 0157332 A2 EP0157332 A2 EP 0157332A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- chamber
- gas
- bed
- gases
- vertical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007789 gas Substances 0.000 title claims abstract description 74
- 238000000197 pyrolysis Methods 0.000 title claims description 3
- 239000003607 modifier Substances 0.000 title 1
- 239000007787 solid Substances 0.000 claims abstract description 51
- 238000002485 combustion reaction Methods 0.000 claims abstract description 30
- 238000003763 carbonization Methods 0.000 claims abstract description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000428 dust Substances 0.000 abstract description 3
- 239000000571 coke Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000010791 domestic waste Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000010805 inorganic waste Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- -1 old tires Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000013502 plastic waste Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000010801 sewage sludge Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/50—Fuel charging devices
- C10J3/506—Fuel charging devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/52—Ash-removing devices
- C10J3/526—Ash-removing devices for entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/64—Processes with decomposition of the distillation products
- C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/74—Construction of shells or jackets
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
- C10J3/845—Quench rings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
Definitions
- the invention relates to a gas converter for carbonization gases from a pyrolysis of waste materials, consisting of a combustion chamber for a substoichiometric combustion of the carbonization gases with the supply of oxygen-containing gases, a vertical chamber with a bed of glowing solid bodies, a feed line for the hot, substoichiometrically burned carbonization gases Chamber, a discharge for the gases from the chamber after passing through the bed of the solid body, an addition device for the solids into the chamber and an outlet device for solids from the chamber.
- One method is that carbonization of the waste materials at temperatures of approximately 300-800 ° C. produces carbonization gases and a solid carbonization residue.
- the smoldering gases are then cracked at higher temperatures of around 850 - 1 200 ° C. This is done by sub-stoichiometric partial combustion with the supply of oxygen-containing gases and passage of the gases through a glowing bed of solids. After cleaning, the cracked gases are used as fuel gases.
- EP-A-0 026 450 also refers to such a gas converter.
- carbon dioxide gas entering the gas converter even if it is first passed through a mechanical gas cleaner, for example a cyclone separator, contains even larger amounts of dust particles. These are deposited in the bed of F eststoff emotionsn, and thread as a result of higher temperatures in the gas converter to caking and clumping. This prevents even and optimal gas passage.
- a mechanical gas cleaner for example a cyclone separator
- the invention has for its object to provide a gas converter which enables the most uniform and optimal gas passage through the bed of solids with the least possible effort.
- the combustion chamber for the substoichiometric combustion of the carbonization gas is arranged horizontally, the feed line from the combustion chamber opens laterally into the upper part of the vertical chamber, the vertical chamber is tapered downwards, the discharge for the gases after the passage through the upper part of the bed of glowing solid bodies is arranged in the upper part of the chamber, solid bodies are continuously withdrawn from the outlet device of the chamber and fresh solid bodies are constantly introduced into the addition device of the chamber.
- the upper part of the bed of solid bodies through which the hot, partially burned smoldering gases flow is selected so that the desired conversion of the gases is achieved. The size required for this depends on the composition of the carbonization gases gig and can be determined empirically.
- solid bodies are to be understood as meaning both removed and cleaned solid bodies and new solid bodies. New solid bodies are preferably only added in an amount which corresponds to the consumption by abrasion and undersize removed.
- the solid bodies are heated by the hot, partially burned carbonization gases. Even when coke or other carbon-containing materials are used as solid bodies, there is practically no combustion, especially because the partially burned carbonization gases do not contain any free oxygen.
- a preferred embodiment is that the vertical chamber is designed with a round cross section. This ensures that the bed drops automatically and evenly.
- a preferred embodiment is that the mouth of the feed line of the combustion chamber in the upper part of the vertical chamber is designed as an annular channel and the discharge for the gas is arranged in the ceiling of the vertical chamber after passing through the upper part of the bed of the glowing solid body .
- the outlet opening of the ring channel is arranged at a height of the chamber such that the bed of solid bodies above it has a sufficient height.
- a preferred embodiment is that the mouth of the feed of the combustion chamber in the upper part of the vertical chamber on one side of the chamber and the discharge for the gas on the opposite side of the chamber are arranged, the solid body in the upper part of the chamber between two vertical gas-permeable walls are arranged, the gas-permeable vapors at a distance from each other are arranged, which is smaller than the diameter of the bed of the solid body in the adjoining part of the chamber and the gas-permeable walls extend over the cross section of the upper part of the chamber.
- the height and thickness of the bed of the solid body between the two gas-permeable walls is chosen so that it is sufficient to convert the gas.
- a preferred embodiment consists in that the outlet opening for the solid bodies is arranged in a water bath at the lower end of the vertical chamber. This results in a simple discharge with immediate cooling of the solid bodies.
- the horizontal combustion chamber consists of the burner 1 and the combustion chamber 2. Preheated air 3 and carbonization gas 3a are passed into the burner 1 and partially burned under-stoichiometrically in the combustion chamber 2.
- the supply line to the combustion chamber is designed as an annular channel 4 with nozzle stones 5.
- the feed line is formed through the outlet opening of the combustion chamber 2.
- the supply line 4, 4a opens into the upper part of the vertical chamber 6.
- the chamber 6 has a round cross section and is designed to taper conically below the supply line 4, 4a.
- the discharge 8 for gases after passage through the upper part of the bed 7 the solid body is arranged in Figure 1 in the ceiling of the chamber 6 and in Figure 2 opposite the feed line 4a.
- the upper part of the bed 7 consists of the part which is located above the nozzle stones 5.
- two gas-permeable walls 9, 9a are arranged in the upper part of the chamber 6, which extend over the entire cross section of the chamber 6.
- the walls 9, 9a consist of grate bars which are attached to air-cooled tubes 10.
- the space between the walls 9, 9a is filled by a bed 7a of the solid body, which is supported on the lower bed 7.
- Solid bodies are continuously discharged from the outlet opening 11 of the chamber 6 via a water bath 12. Fresh solid bodies are fed through the addition device 13.
- a support burner 14 is arranged in the combustion chamber 2 and is used to heat the solid bodies during commissioning, at standstill and when the composition of the carbonization gas fluctuates.
- the advantages of the invention are that the structural design of the gas converter achieves considerable weight savings, the wear caused by the moving bed is kept low, the exchange of the solid bodies is carried out in a simple manner and the smoldering gases nevertheless constantly meet a bed of fresh solid bodies .
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Processing Of Solid Wastes (AREA)
- Incineration Of Waste (AREA)
- Treating Waste Gases (AREA)
- External Artificial Organs (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines Containing Plant Substances (AREA)
- Gasification And Melting Of Waste (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT85103523T ATE34764T1 (de) | 1984-04-04 | 1985-03-25 | Gaswandler fuer schwelgase aus einer pyrolyse von abfallstoffen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19843412582 DE3412582A1 (de) | 1984-04-04 | 1984-04-04 | Gaswandler fuer schwelgase aus einer pyrolyse von abfallstoffen |
| DE3412582 | 1984-04-04 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0157332A2 true EP0157332A2 (fr) | 1985-10-09 |
| EP0157332A3 EP0157332A3 (en) | 1986-01-29 |
| EP0157332B1 EP0157332B1 (fr) | 1988-06-01 |
Family
ID=6232607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP85103523A Expired EP0157332B1 (fr) | 1984-04-04 | 1985-03-25 | Modificateur de gaz de pyrolyse de déchets |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0157332B1 (fr) |
| AT (1) | ATE34764T1 (fr) |
| DE (2) | DE3412582A1 (fr) |
| FI (1) | FI76367C (fr) |
| IL (1) | IL74797A (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263339A1 (fr) * | 1986-09-30 | 1988-04-13 | Siemens Aktiengesellschaft | Réacteur de reformage pour gaz de carbonisation contenant des hydrocarbures |
| DE102008027858A1 (de) * | 2008-06-11 | 2009-12-17 | Jörg HO | Verfahren und Vorrichtung zur Erzeugung eines teerfreien Brenngases |
| WO2010097286A3 (fr) * | 2009-02-27 | 2011-01-13 | Kbi International Ltd. | Réacteur et procédé de traitement thermique d'une matière première |
| EP3508556A1 (fr) * | 2018-01-04 | 2019-07-10 | Günter Hirr | Procédé de fonctionnement d'une installation de production d'énergie et installation correspondante |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3806365C1 (fr) * | 1988-02-27 | 1989-07-20 | Veba Oel Entwicklungs-Gesellschaft Mbh, 4650 Gelsenkirchen, De | |
| DE10033453B4 (de) * | 2000-07-10 | 2006-11-02 | Herhof Verwaltungsgesellschaft Mbh | Verfahren und Vorrichtung zur Verwertung von Stoffen und Stoffgemischen, die organische Bestandteile enthalten |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2432504B2 (de) * | 1974-07-04 | 1976-12-16 | Kiener, Karl, Dipl.-Ing., 7080 Goldshöfe | Verfahren und anlage zum herstellen von brenngasen aus stueckigem haus- und industriemuell u.dgl. |
| DE2526947A1 (de) * | 1975-06-16 | 1976-12-30 | Karl Dipl Ing Kiener | Verfahren und vorrichtung zum herstellen von brenngas |
| DE2927240C2 (de) * | 1979-07-05 | 1985-10-31 | Kiener-Pyrolyse Gesellschaft für thermische Abfallverwertung mbH, 7000 Stuttgart | Verfahren und Vorrichtung zum Vergasen von stückigen Brennstoffen mit Vorschwelung und Cracken der Schwelgase im Gasgenerator |
-
1984
- 1984-04-04 DE DE19843412582 patent/DE3412582A1/de not_active Withdrawn
-
1985
- 1985-02-19 FI FI850677A patent/FI76367C/fi not_active IP Right Cessation
- 1985-03-25 EP EP85103523A patent/EP0157332B1/fr not_active Expired
- 1985-03-25 AT AT85103523T patent/ATE34764T1/de not_active IP Right Cessation
- 1985-03-25 DE DE8585103523T patent/DE3563062D1/de not_active Expired
- 1985-04-03 IL IL74797A patent/IL74797A/xx unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0263339A1 (fr) * | 1986-09-30 | 1988-04-13 | Siemens Aktiengesellschaft | Réacteur de reformage pour gaz de carbonisation contenant des hydrocarbures |
| DE102008027858A1 (de) * | 2008-06-11 | 2009-12-17 | Jörg HO | Verfahren und Vorrichtung zur Erzeugung eines teerfreien Brenngases |
| WO2010097286A3 (fr) * | 2009-02-27 | 2011-01-13 | Kbi International Ltd. | Réacteur et procédé de traitement thermique d'une matière première |
| EP3508556A1 (fr) * | 2018-01-04 | 2019-07-10 | Günter Hirr | Procédé de fonctionnement d'une installation de production d'énergie et installation correspondante |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE34764T1 (de) | 1988-06-15 |
| DE3412582A1 (de) | 1985-10-24 |
| IL74797A0 (en) | 1985-07-31 |
| FI76367B (fi) | 1988-06-30 |
| FI850677L (fi) | 1985-10-05 |
| DE3563062D1 (en) | 1988-07-07 |
| EP0157332B1 (fr) | 1988-06-01 |
| EP0157332A3 (en) | 1986-01-29 |
| FI76367C (fi) | 1988-10-10 |
| IL74797A (en) | 1988-08-31 |
| FI850677A0 (fi) | 1985-02-19 |
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Legal Events
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| RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: KRAFTWERK UNION-UMWELTTECHNIK GMBH |
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| 17P | Request for examination filed |
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