EP0157332A2 - Modificateur de gaz de pyrolyse de déchets - Google Patents

Modificateur de gaz de pyrolyse de déchets Download PDF

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Publication number
EP0157332A2
EP0157332A2 EP85103523A EP85103523A EP0157332A2 EP 0157332 A2 EP0157332 A2 EP 0157332A2 EP 85103523 A EP85103523 A EP 85103523A EP 85103523 A EP85103523 A EP 85103523A EP 0157332 A2 EP0157332 A2 EP 0157332A2
Authority
EP
European Patent Office
Prior art keywords
chamber
gas
bed
gases
vertical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP85103523A
Other languages
German (de)
English (en)
Other versions
EP0157332B1 (fr
EP0157332A3 (en
Inventor
Horst Jelinek
Egon Teuner
Helmut Werdinig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KRAFTWERK UNION-UMWELTTECHNIK GmbH
Original Assignee
Kraftwerk Union-Umwelttechnik GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kraftwerk Union-Umwelttechnik GmbH filed Critical Kraftwerk Union-Umwelttechnik GmbH
Priority to AT85103523T priority Critical patent/ATE34764T1/de
Publication of EP0157332A2 publication Critical patent/EP0157332A2/fr
Publication of EP0157332A3 publication Critical patent/EP0157332A3/de
Application granted granted Critical
Publication of EP0157332B1 publication Critical patent/EP0157332B1/fr
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/50Fuel charging devices
    • C10J3/506Fuel charging devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/52Ash-removing devices
    • C10J3/526Ash-removing devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60Processes
    • C10J3/64Processes with decomposition of the distillation products
    • C10J3/66Processes with decomposition of the distillation products by introducing them into the gasification zone
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • C10J3/845Quench rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0943Coke
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0956Air or oxygen enriched air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen

Definitions

  • the invention relates to a gas converter for carbonization gases from a pyrolysis of waste materials, consisting of a combustion chamber for a substoichiometric combustion of the carbonization gases with the supply of oxygen-containing gases, a vertical chamber with a bed of glowing solid bodies, a feed line for the hot, substoichiometrically burned carbonization gases Chamber, a discharge for the gases from the chamber after passing through the bed of the solid body, an addition device for the solids into the chamber and an outlet device for solids from the chamber.
  • One method is that carbonization of the waste materials at temperatures of approximately 300-800 ° C. produces carbonization gases and a solid carbonization residue.
  • the smoldering gases are then cracked at higher temperatures of around 850 - 1 200 ° C. This is done by sub-stoichiometric partial combustion with the supply of oxygen-containing gases and passage of the gases through a glowing bed of solids. After cleaning, the cracked gases are used as fuel gases.
  • EP-A-0 026 450 also refers to such a gas converter.
  • carbon dioxide gas entering the gas converter even if it is first passed through a mechanical gas cleaner, for example a cyclone separator, contains even larger amounts of dust particles. These are deposited in the bed of F eststoff emotionsn, and thread as a result of higher temperatures in the gas converter to caking and clumping. This prevents even and optimal gas passage.
  • a mechanical gas cleaner for example a cyclone separator
  • the invention has for its object to provide a gas converter which enables the most uniform and optimal gas passage through the bed of solids with the least possible effort.
  • the combustion chamber for the substoichiometric combustion of the carbonization gas is arranged horizontally, the feed line from the combustion chamber opens laterally into the upper part of the vertical chamber, the vertical chamber is tapered downwards, the discharge for the gases after the passage through the upper part of the bed of glowing solid bodies is arranged in the upper part of the chamber, solid bodies are continuously withdrawn from the outlet device of the chamber and fresh solid bodies are constantly introduced into the addition device of the chamber.
  • the upper part of the bed of solid bodies through which the hot, partially burned smoldering gases flow is selected so that the desired conversion of the gases is achieved. The size required for this depends on the composition of the carbonization gases gig and can be determined empirically.
  • solid bodies are to be understood as meaning both removed and cleaned solid bodies and new solid bodies. New solid bodies are preferably only added in an amount which corresponds to the consumption by abrasion and undersize removed.
  • the solid bodies are heated by the hot, partially burned carbonization gases. Even when coke or other carbon-containing materials are used as solid bodies, there is practically no combustion, especially because the partially burned carbonization gases do not contain any free oxygen.
  • a preferred embodiment is that the vertical chamber is designed with a round cross section. This ensures that the bed drops automatically and evenly.
  • a preferred embodiment is that the mouth of the feed line of the combustion chamber in the upper part of the vertical chamber is designed as an annular channel and the discharge for the gas is arranged in the ceiling of the vertical chamber after passing through the upper part of the bed of the glowing solid body .
  • the outlet opening of the ring channel is arranged at a height of the chamber such that the bed of solid bodies above it has a sufficient height.
  • a preferred embodiment is that the mouth of the feed of the combustion chamber in the upper part of the vertical chamber on one side of the chamber and the discharge for the gas on the opposite side of the chamber are arranged, the solid body in the upper part of the chamber between two vertical gas-permeable walls are arranged, the gas-permeable vapors at a distance from each other are arranged, which is smaller than the diameter of the bed of the solid body in the adjoining part of the chamber and the gas-permeable walls extend over the cross section of the upper part of the chamber.
  • the height and thickness of the bed of the solid body between the two gas-permeable walls is chosen so that it is sufficient to convert the gas.
  • a preferred embodiment consists in that the outlet opening for the solid bodies is arranged in a water bath at the lower end of the vertical chamber. This results in a simple discharge with immediate cooling of the solid bodies.
  • the horizontal combustion chamber consists of the burner 1 and the combustion chamber 2. Preheated air 3 and carbonization gas 3a are passed into the burner 1 and partially burned under-stoichiometrically in the combustion chamber 2.
  • the supply line to the combustion chamber is designed as an annular channel 4 with nozzle stones 5.
  • the feed line is formed through the outlet opening of the combustion chamber 2.
  • the supply line 4, 4a opens into the upper part of the vertical chamber 6.
  • the chamber 6 has a round cross section and is designed to taper conically below the supply line 4, 4a.
  • the discharge 8 for gases after passage through the upper part of the bed 7 the solid body is arranged in Figure 1 in the ceiling of the chamber 6 and in Figure 2 opposite the feed line 4a.
  • the upper part of the bed 7 consists of the part which is located above the nozzle stones 5.
  • two gas-permeable walls 9, 9a are arranged in the upper part of the chamber 6, which extend over the entire cross section of the chamber 6.
  • the walls 9, 9a consist of grate bars which are attached to air-cooled tubes 10.
  • the space between the walls 9, 9a is filled by a bed 7a of the solid body, which is supported on the lower bed 7.
  • Solid bodies are continuously discharged from the outlet opening 11 of the chamber 6 via a water bath 12. Fresh solid bodies are fed through the addition device 13.
  • a support burner 14 is arranged in the combustion chamber 2 and is used to heat the solid bodies during commissioning, at standstill and when the composition of the carbonization gas fluctuates.
  • the advantages of the invention are that the structural design of the gas converter achieves considerable weight savings, the wear caused by the moving bed is kept low, the exchange of the solid bodies is carried out in a simple manner and the smoldering gases nevertheless constantly meet a bed of fresh solid bodies .

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Incineration Of Waste (AREA)
  • Treating Waste Gases (AREA)
  • External Artificial Organs (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Gasification And Melting Of Waste (AREA)
EP85103523A 1984-04-04 1985-03-25 Modificateur de gaz de pyrolyse de déchets Expired EP0157332B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT85103523T ATE34764T1 (de) 1984-04-04 1985-03-25 Gaswandler fuer schwelgase aus einer pyrolyse von abfallstoffen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19843412582 DE3412582A1 (de) 1984-04-04 1984-04-04 Gaswandler fuer schwelgase aus einer pyrolyse von abfallstoffen
DE3412582 1984-04-04

Publications (3)

Publication Number Publication Date
EP0157332A2 true EP0157332A2 (fr) 1985-10-09
EP0157332A3 EP0157332A3 (en) 1986-01-29
EP0157332B1 EP0157332B1 (fr) 1988-06-01

Family

ID=6232607

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85103523A Expired EP0157332B1 (fr) 1984-04-04 1985-03-25 Modificateur de gaz de pyrolyse de déchets

Country Status (5)

Country Link
EP (1) EP0157332B1 (fr)
AT (1) ATE34764T1 (fr)
DE (2) DE3412582A1 (fr)
FI (1) FI76367C (fr)
IL (1) IL74797A (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0263339A1 (fr) * 1986-09-30 1988-04-13 Siemens Aktiengesellschaft Réacteur de reformage pour gaz de carbonisation contenant des hydrocarbures
DE102008027858A1 (de) * 2008-06-11 2009-12-17 Jörg HO Verfahren und Vorrichtung zur Erzeugung eines teerfreien Brenngases
WO2010097286A3 (fr) * 2009-02-27 2011-01-13 Kbi International Ltd. Réacteur et procédé de traitement thermique d'une matière première
EP3508556A1 (fr) * 2018-01-04 2019-07-10 Günter Hirr Procédé de fonctionnement d'une installation de production d'énergie et installation correspondante

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3806365C1 (fr) * 1988-02-27 1989-07-20 Veba Oel Entwicklungs-Gesellschaft Mbh, 4650 Gelsenkirchen, De
DE10033453B4 (de) * 2000-07-10 2006-11-02 Herhof Verwaltungsgesellschaft Mbh Verfahren und Vorrichtung zur Verwertung von Stoffen und Stoffgemischen, die organische Bestandteile enthalten

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2432504B2 (de) * 1974-07-04 1976-12-16 Kiener, Karl, Dipl.-Ing., 7080 Goldshöfe Verfahren und anlage zum herstellen von brenngasen aus stueckigem haus- und industriemuell u.dgl.
DE2526947A1 (de) * 1975-06-16 1976-12-30 Karl Dipl Ing Kiener Verfahren und vorrichtung zum herstellen von brenngas
DE2927240C2 (de) * 1979-07-05 1985-10-31 Kiener-Pyrolyse Gesellschaft für thermische Abfallverwertung mbH, 7000 Stuttgart Verfahren und Vorrichtung zum Vergasen von stückigen Brennstoffen mit Vorschwelung und Cracken der Schwelgase im Gasgenerator

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0263339A1 (fr) * 1986-09-30 1988-04-13 Siemens Aktiengesellschaft Réacteur de reformage pour gaz de carbonisation contenant des hydrocarbures
DE102008027858A1 (de) * 2008-06-11 2009-12-17 Jörg HO Verfahren und Vorrichtung zur Erzeugung eines teerfreien Brenngases
WO2010097286A3 (fr) * 2009-02-27 2011-01-13 Kbi International Ltd. Réacteur et procédé de traitement thermique d'une matière première
EP3508556A1 (fr) * 2018-01-04 2019-07-10 Günter Hirr Procédé de fonctionnement d'une installation de production d'énergie et installation correspondante

Also Published As

Publication number Publication date
ATE34764T1 (de) 1988-06-15
DE3412582A1 (de) 1985-10-24
IL74797A0 (en) 1985-07-31
FI76367B (fi) 1988-06-30
FI850677L (fi) 1985-10-05
DE3563062D1 (en) 1988-07-07
EP0157332B1 (fr) 1988-06-01
EP0157332A3 (en) 1986-01-29
FI76367C (fi) 1988-10-10
IL74797A (en) 1988-08-31
FI850677A0 (fi) 1985-02-19

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