EP0162108A4 - Verre modifie par de l'oxyde de bore et resistant aux substances alcalines. - Google Patents

Verre modifie par de l'oxyde de bore et resistant aux substances alcalines.

Info

Publication number
EP0162108A4
EP0162108A4 EP19850900315 EP85900315A EP0162108A4 EP 0162108 A4 EP0162108 A4 EP 0162108A4 EP 19850900315 EP19850900315 EP 19850900315 EP 85900315 A EP85900315 A EP 85900315A EP 0162108 A4 EP0162108 A4 EP 0162108A4
Authority
EP
European Patent Office
Prior art keywords
weight
glass
composition
calcia
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19850900315
Other languages
German (de)
English (en)
Other versions
EP0162108A1 (fr
Inventor
Durai N Raghavan
Tetsuro Horiuchi
William S Britt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Atlantic Richfield Co
Original Assignee
Atlantic Richfield Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atlantic Richfield Co filed Critical Atlantic Richfield Co
Publication of EP0162108A1 publication Critical patent/EP0162108A1/fr
Publication of EP0162108A4 publication Critical patent/EP0162108A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00—Fibre or filament compositions
    • C03C13/001—Alkali-resistant fibres

Definitions

  • the invention herein relates to alkaline- resistant glasses. While it pertains to glass bodies generally, it has particular pertinence to glasses which are fiberizable.
  • the natural mineral zeolites are a group of hydrous alkali and/or alkaline earth aluminosilicates which have an open three-dimensional crystalline framework. While a large number of individual mineral zeolites are known and have been described in the literature, eleven (11) minerals make up the major group of mineral zeolites: analcime, chabazite, clinoptilolite, erionite, ferrierite, heulandite, laumontite, mordenite, natrolite, phillipsite and wairakite.
  • Glasses are vitreous materials composed largely of silica. Because silica is a highly refractory material, however, substantial quantities of soda ash, lime or other fluxing materials are added to the silica to permit the glass-forming composition to be melted at reasonable temperatures. Small quantities of other materials, usually elemental materials or oxides, are commonly added to glass melts to provide particular properties such as color or chemical resistance to the finished glass.
  • soda ash, lime or other fluxing materials are added to the silica to permit the glass-forming composition to be melted at reasonable temperatures.
  • Small quantities of other materials, usually elemental materials or oxides, are commonly added to glass melts to provide particular properties such as color or chemical resistance to the finished glass.
  • One experiment has been reported in which a clinoptilolite and glass mixture was fired at 800°C (well below the melting point of either) to produce what was described as a porous low density glass composition; see Mumpton, supra, p. 197, referring to Tamura Japanese published application 74/098,817 (1974
  • Alkaline resistance is provided in some glasses by the inclusion of substantial quantities of zirconia and/or titania, such as in AR glasses of Pilkington. Although these materials enhance the alkaline resistance of glass bodies, these are refractory materials which increase the melting point of such glasses. Also, zir ⁇ onia and titania tend to add cost to the glass inasmuch as these are much more expensive materials than silica, soda, calcia and the usual components of soda lime silica glasses.
  • Objects of the Invention It is an object of the invention to produce alkaline-resistant glasses from modified, naturally occurring zeolite materials.
  • Another object of the invention is to modify naturally occurring zeolite materials with readily available boron, aluminum and alkaline earth metal compounds.
  • a further object of the invention is to form glass bodies from modified naturally occurring zeolites at relatively low temperatures.
  • a still further object of the invention is to form glass compositions having improved properties, in particular, fiberizability and/or alkaline resistance.
  • the invention herein comprises glass compositions which have good working and forming properties and which have outstanding resistance to alkaline environments.
  • Such glass compositions are characterized by a low boria content, a relatively high calcia content, a relatively low silica content and a moderate alumina content.
  • these glass compositions are derived from a naturally occurring zeolite to which a boron containing material and at least one alkaline earth metal compound, especially calcium compound or calcium and magnesium compounds, are added to yield a low-silica, high-alkaline earth metal oxide, especially calcia, boria containing glass composition.
  • Alumina or an aluminum compound may be added to the glass-forming materials.
  • glass bodies, particularly fibers, formed from the aforesaid glass composition are included within the scope of the present invention.
  • the present invention relates to boria-modified, alkaline-resistant glasses containing relatively high quantities of one or more alkaline earth oxides and particularly to glasses comprising boria, silica, alumina, calcia and combinations of calcia and magnesia.
  • a particularly useful alkaline-resistant glass has the following composition:
  • the invention relates to glasses formed from naturally occurring zeolites and especially to glasses wherein such zeolites are present in at least substantial quantities in the glass-forming mixture, often providing the predominance of the glass-formers, in particular, the silica present in such mixtures.
  • glasses may be easily and inexpensivelly formed by melting a boria-forming material and an alkaline earth metal material, especially a calcium compound, in the form of limestone, for example, or a calcium compound and a magnesium compound, such as found in dolomite, with one or more naturally occurring zeolites.
  • glasses of excellent resistance to alkaline attack may be formed by starting with conventional materials such as silica, soda ash, an aluminaforming material, limestone and/or dolomite, and a boria-forming material.
  • Such glasses may be described as low-boria, moderate-alumina, calcium silicate glasses inasmuch as the calcium is generally present in greater quantities than alumina.
  • the alkaline-resistant glass composition may be readily formed by mixing calcium carbonate with a naturally occurring zeolite material.
  • Many naturally occurring zeolite materials may be formed into glasses under appropriate conditions.
  • Naturally occurring zeolites, as a glass-forming material have many advantages.
  • Naturally occurring zeolites have already undergone reaction and the various elements are intimately mixed and reacted with one another.
  • the zeolite materials are particularly useful inasmuch as they have a very low sulphur content.
  • very useful glass bodies may be formed by combining various quanti ⁇ ties of boria and calcia or calcia and magnesia combinations with a zeolite of the following compositional range:
  • zeolites with a relatively low alumina content, for example less than about 10% to about 15% by weight of zeolite material, it is preferable to include additional alumina-forming material in the glass-forming mixture to enhance the fiberizability of the resulting glass.
  • a glass-forming composition may be readily prepared by mixing finely ground boron-containing material and limestone with a finely ground zeolite material, such as the composition identified above.
  • the zeolite material inasmuch as it is a pre-reacted crystalline material, for example, calcium aluminum silicates, reacts readily and efficiently with the boron-containing material, such as borax, colemanite and the like, and calcium carbonate of the limestone to form a glass composition having a minor boria and relatively high calcia loading.
  • the boron-containing material appears to provide the glass with improved working and forming properties and especially enhances the fiberiz ability of the glass, particularly in conjunction with the presence of a moderate alumina content.
  • the boria-containing glass material upon cooling, exhibits good physical properties, having strengths and other qualities substantially equivalent to a typical silicate fiber glass and having resistance to alkaline solutions from about ten-fold to about twenty- fold better than a typical soda-lime silicate window glass. Also, the resistance to alkaline materials tends to increase as the calcia content increases from about
  • glasses containing low boria and moderate to relatively high calcia loadings have other advantages as well.
  • Zeolites are naturally occurring materials and are not homogenous or uniform in their composition.
  • the zeolites contain relatively substantial quantities of water, that is, hydrated materials. Hydrated crystalline materials generally tend to melt at a lower temperature. Thus, there are further advantages to beginning the glass-forming operation with a prereacted zeolite, rather than initiating it with silica.
  • the melting temperatures of the boria-modified alumina alkaline earth metal silicate glasses of this invention come within a range, i.e. about 1250°C to about 1500°C, and especially about 1300°C to about 1400°C, which permits the drawing of glass fibers through platinum dies.
  • glass fibers may be drawn through a platinum or platinum-rhodium die at temperatures of about 1100oC to about 1350°C.
  • the glass fibers could also be formed by spinning or other techniques. However, formation of continuous strands is best accomplished by drawing through an orifice in a platinum or platinum-rhodium body.
  • a particular advantage of the boria-modified glasses described herein resides in their excellent working and fiber-forming properties, their resistance to crystallization and uniform viscosity across a broad temperature range at fiber-forming temperatures.
  • Fibers of the glass compositions of this invention are particularly useful inasmuch as they may be used to strengthen bodies which are highly alkaline in nature, for example, cement and plaster. Such fibers may also be used to strengthen organic matrices of various types. Reinforcement of cement with such fibers, however, provides a particularly advantageous use inasmuch as asbestos has been frequently used heretofore for that purpose. Because of various health and/or environmental concerns, the use of asbestos is being discontinued. Continuous strands or mats of glass fibers having the glass compositions described herein effectively reinforce concrete bodies.
  • Glass-forming materials were finely comminuted, admixed with particulate additives as identified in the following tables (expressed in percent by weight) and melted to form glass bodies and fibers.
  • the melting was conducted batch-wise in small crucibles at temperatures of about 1250°C to about 1500°C depending upon batch composition and quantity of additives.
  • the glasses set forth in Table I were prepared from silica, alumina, calcium carbonate, boria and magnesium carbonate. A zeolite material was not present in the batch. These glasses were prepared from traditional glass-forming materials in order to examine the fiber-forming, alkaline resistance and other properties of the resulting glasses.
  • Glass Ic exhibited very good properties. Its melting point was reasonably low while its alkaline resistance was very good. Fibers were formed without difficulty.
  • Glasses IIa and lIb exhibited excellent alkaline resistance; however, fiberizability and working range were not within preferred parameters.
  • Glass lIc exhibited an improved working range over Glasses Ila and lIb, although the alkaline resistance was lower.
  • Glasses IlIa through IIIe exhibited excellent alkaline resistance and metling temperatures. GlassesIIId and IIIe exhibited excellent fiberizability and working temperature range although their alkaline resistance was slightly less than Glasses IlIa through
  • Glass fibers formed from glasses Illb, IIIc and IIId are excellent reinforcement materials for concrete. Fiber loadings in cement and concrete of from about 1% to about 10% by weight, and in particular around 5% by weight, enhance the strength of the concrete without significant degradation of the fiber.
  • the glasses identified in Table II and III throughout the present Example were prepared from a zeolite having the following composition:
  • Minor variations in the composition may occur from batch to batch of the zeolite.
  • Very minor quantities of other elements for example boron, manganese, zirconium, titanium, vanadium, antimony, barium, in combined form, may be present in such a naturally occurring zeolite.
  • the quantities of such materials generally are individually below about 0.1% by weight and are usually less than 0.01% by weight and frequently present in amounts less than 0.005% by weight.
  • Various other materials, especially those having metallic elements may be found in trace amounts in the zeolite material.
  • the glass fibers of the above example were continuously drawn through a platinum bushing at bushing temperatures of about 1200°C from molten glasses formed from calcium-carbonate-modified naturally occurring zeolites wherein the modifications included various additions of an aluminum component, a boron component, an alkaline earth metal component and, optionally, a zirconium component.
  • glass compositions are fiber-forming and have excellent mechanical properties, such as tensile strength, comparable to commercial glass fibers while possessing outstanding alkaline resistance.
  • modified zeolite glasses are relatively low in iron content and possess an unobjectionable light green color.
  • the alkaline-resistant boria-containing glasses of this invention it is preferred, if starting with a zeolite material, to have such zeolite material present at least about 35% by weight of the glass batch mixture. If the zeolite provides substantially all the silica component for the resulting glass, then quantities of 40% to 50% by weight or more of the zeolite may be utilized in the glass batch mixture.
  • the glass batch mixture contains a significant quantity of a boria-forming ingredient, such as borax, colemanite, sassolite, ulexite and the like.
  • a boria-forming ingredient such as borax, colemanite, sassolite, ulexite and the like.
  • Various naturally occurring borosilicate materials or borosilicate or boroaluminosilicate glass cullet may be utilized to provide the boron component in the glass batch.
  • the boron-containing component is usually present in the glass batch in quantities of up to about 6% by weight and is typically present in sufficient quantities to provide a boria content in the resultant glass of from about 0.1% to about 6% by weight and preferably from about 1% to about 5% by weight and especially preferred from about 1% to about 4% by weight.
  • the instant invention relates particularly to the preparation of alkaline resistant fiber glasses from glass batches containing substantial quantities of a zeolite material and especially to a mixture of a zeolite material and additional aluminum and alkaline earth metal components to which a boron component is additionally included
  • certain unique glass compositions disclosed herein may be formulated from glass batches containing no zeolite.
  • Such glass compositions have unique properties, including fiberizability and alkaline resistance.
  • One such glass composition is as follows, expressed to the least significant number as percent by weight.
  • a preferred composition is as follows, expressed to the least significant number as percent by weight:
  • One particularly preferred composition contains about 26-30% by weight calcia wherein CaO + MgO is about 26-34% by weight.
  • An especially useful composition has the following oxide content, expressed to the least significant number as percent by weight:
  • the alkaline- resistance of such glasses varies with the quantity of boria present. Generally, glasses having less boria have better alkaline resistance. Thus, in glasses having a lower calcia content, the boria content should be low in order to maintain excellent alkaline resistance. While glasses containing about 30% by weight calcia can have up to about 6% by weight boria, glasses containing about 22% by weight calcia should contain less than about 2% by weight boria to exhibit good alkaline resistance. (Good alkaline resistance, for the purposes of this invention, is a loss of less than about 3.3% by weight of a glass sample in 5% NaOH at 90°C for 72 hours.)
  • compositions minor quantities of zir ⁇ onia and titania , for example up to about 2% by weight, may be present.
  • the above stated compositions may be formed, of course, from modified zeolites without loss of any outstanding properties.
  • Industrial Applicability The outstanding tolerance to alkaline environments render these glasses, especially in fiber or flake form, as excellent reinforcement materials for concrete, piaster: and other inorganic matrices of an alkaline nature. This is especially significant inasmuch as asbestos, which has been a standard extender as reinforcement material in cement and concrete bodies, is considered undesirable because of the health hazard it may present.
  • Glass fibers formed from glasses of this invention have particular utility as a reinforcement material for cementatious bodies, e.g. cement and concrete.
  • Cementatious bodies exhibit enhanced strength when such bodies are reinforced with a minor amount of glass fiber, preferably from about 1% to about 10% by weight, and more preferably about 1.5% to about 7.5% by weight glass fibers of the type described herein.
  • the fibers are included in cementatious bodies in sufficient amount to enhance the strength of such bodies.
  • the glasses of this invention have excellent resistance to moisture degradation and do not degrade or deteriorate during normal or extended storage periods.
  • the low sulfate content of naturally occurring zeolites is important in their utilization as ingredients in glass-forming processes. Sulfates tend to degrade during glass melting conditions, yielding sulfur dioxide and other objectionable sulfur compounds. Environmental concerns militate against use in glass-making processes of any raw material containing sulfates, sulfites and other sulfur compounds.
  • the instant invention has been described as boria-containing glasses having relatively high loadings of calcia, it is to be recognized that at least minor substitutions of other alkaline earth metal oxides in lieu of calcia may be made.
  • magnesium compounds particularly magnesium carbonate may be substituted for at least some of the calcium carbonate in preparing a batch tor melting into an alkaline- resistant glass.
  • barium and strontium compounds may be substituted as well as beryllium compounds, many of which are naturally occurring materials found in the same geographic regions as zeolites.
  • the oxides of alkaline earth metal elements are not considered glass formers, which is a terra applied to elements having a valence greater than three, e.g.
  • Alkaline earth metal elements being divalent, are more tightly bound in a glass than are alkali metal elements.
  • Sources of alkaline earth metals to form oxides in the glasses of this invention are as follows: Alkaline Earth Metal Compound Source
  • Sources of calcium and magnesium carbonates are generally more plentiful and cheaper than sources of barium, strontium or beryllium compounds.
  • beryllium metal is considered toxic, although beryllium oxides bound within a glass body are not hazardous.
  • Aluminum may be included in the glass batch as alumina, aluminosilicates, e.g. from aluminosilicate glass cullet or as naturally occurring materials such as various clays includ kaolin, montmorillonite and the like.
  • Zirconia may optionally, be present in the fiber glass composit; of this invention. Minor quantities of zirconi may occur in some compositions trom melting the glass batch mixture in zirconia-containing crucibles. Also, a zirconium-containing component may be added in the form ot zircon, various zirconium silicates and as zirconia-containing cullet.
  • the boron-modified, zeolite-derived glasses of this invention have good working properties and strength in addition to outstanding alkaline resistance.
  • These glasses may be used in any form, e.g. containers, sheets, fibers and the like, and especially for any use in which transparency or colorlessness are not required.
  • the glasses may be used as flakes, bubbles Cmicrospheres), fibers and the like to reinforce organic or inorganic matrices, especially cement, plaster and the like.
  • the characteristics of the glasses of this invention are particularly adapted to the formation of alkaline resistant fibers.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)
  • Glass Melting And Manufacturing (AREA)
EP19850900315 1983-11-23 1984-11-19 Verre modifie par de l'oxyde de bore et resistant aux substances alcalines. Withdrawn EP0162108A4 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55460283A 1983-11-23 1983-11-23
US554602 1983-11-23

Publications (2)

Publication Number Publication Date
EP0162108A1 EP0162108A1 (fr) 1985-11-27
EP0162108A4 true EP0162108A4 (fr) 1985-12-05

Family

ID=24213977

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19850900315 Withdrawn EP0162108A4 (fr) 1983-11-23 1984-11-19 Verre modifie par de l'oxyde de bore et resistant aux substances alcalines.

Country Status (3)

Country Link
EP (1) EP0162108A4 (fr)
JP (1) JPS61500491A (fr)
WO (1) WO1985002395A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0162917A4 (fr) * 1983-11-23 1986-08-21 Atlantic Richfield Co Verres a base d'aluminosilicate-oxyde de calcium, melanges produisant du verre et procedes de production.
DE4324492C2 (de) * 1993-07-21 1995-11-16 Swarovski & Co Verwendung einer Glaszusammensetzung auf der Basis von Siliciumdioxid und Calciumoxid zur Herstellung von Schmucksteinen
FR2768144B1 (fr) * 1997-09-10 1999-10-01 Vetrotex France Sa Fils de verre aptes a renforcer des matieres organiques et/ou inorganiques
FR2800730B1 (fr) * 1999-11-04 2001-12-07 Vetrotex France Sa Fils de verre aptes a renforcer des matieres organiques et/ ou inorganiques, procede de fabrication de fils de verre, composition utilisee
CN114349354B (zh) * 2018-06-22 2024-01-12 巨石集团有限公司 一种玻璃纤维组合物及其玻璃纤维和复合材料
FR3122417B3 (fr) 2021-04-28 2023-09-08 Saint Gobain Isover Procede de fabrication de fibres de verre a partir de matieres minerales non transformees
FR3122418B3 (fr) * 2021-04-28 2023-09-08 Saint Gobain Adfors Procede de fabrication de fibres de verre-e a partir de matieres minerales non transformees
CN115093116A (zh) * 2022-07-07 2022-09-23 湖南洪康新材料科技有限公司 一种中性药用硼硅玻璃及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4074990A (en) * 1976-11-08 1978-02-21 Ppg Industries, Inc. Method of preparing colemanite-containing glass batch
WO1984001365A1 (fr) * 1982-09-30 1984-04-12 Atlantic Richfield Co Compositions de formation de verre contenant de la zeolite naturelle ayant prealablement reagi et procede de production d'un verre a partir de celle-ci
WO1985001498A1 (fr) * 1983-09-28 1985-04-11 Atlantic Richfield Company Composition de verres de zeolites modifiees avec de l'alumine et un oxyde de metal alcalino-terreux
WO1985002393A1 (fr) * 1983-11-23 1985-06-06 Atlantic Richfield Company Verres a base d'aluminosilicate-oxyde de calcium, melanges produisant du verre et procedes de production
WO1985002394A1 (fr) * 1983-11-23 1985-06-06 Atlantic Richfield Company Compositions de fibres de verre possedant une faible teneur en oxyde de fer

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3687850A (en) * 1970-03-27 1972-08-29 Johns Manville High temperature insulating fiber
US4046948A (en) * 1975-04-09 1977-09-06 Ppg Industries, Inc. Acid resistant glass fibers
JPS537729A (en) * 1976-07-09 1978-01-24 Asahi Glass Co Ltd Screening method of easilyyattacked glass fiber mixed cement type slurry
US4066466A (en) * 1976-07-22 1978-01-03 Ppg Industries, Inc. Low pollution glass fiber compositions
JPS553367A (en) * 1978-06-24 1980-01-11 Nippon Valqua Ind Ltd Glass composition for alkali resistant filament
JPS565352A (en) * 1979-06-22 1981-01-20 Nippon Sheet Glass Co Ltd Glass composition for fiber
JPS5747741A (en) * 1980-09-01 1982-03-18 Nippon Sheet Glass Co Ltd Glass suitable for manufacturing fibrous wollastonite
US4607015A (en) * 1981-03-30 1986-08-19 Atlantic Richfield Company Glass composition, its method of formation and products made therefrom
WO1983001947A1 (fr) * 1981-12-04 1983-06-09 Us Commerce Fibres de verre resistantes aux alkalis

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4074990A (en) * 1976-11-08 1978-02-21 Ppg Industries, Inc. Method of preparing colemanite-containing glass batch
US4074990B1 (en) * 1976-11-08 1983-08-09 Ppg Industries Inc Method of preparing colemanite-containing glass batch
WO1984001365A1 (fr) * 1982-09-30 1984-04-12 Atlantic Richfield Co Compositions de formation de verre contenant de la zeolite naturelle ayant prealablement reagi et procede de production d'un verre a partir de celle-ci
WO1985001498A1 (fr) * 1983-09-28 1985-04-11 Atlantic Richfield Company Composition de verres de zeolites modifiees avec de l'alumine et un oxyde de metal alcalino-terreux
WO1985002393A1 (fr) * 1983-11-23 1985-06-06 Atlantic Richfield Company Verres a base d'aluminosilicate-oxyde de calcium, melanges produisant du verre et procedes de production
WO1985002394A1 (fr) * 1983-11-23 1985-06-06 Atlantic Richfield Company Compositions de fibres de verre possedant une faible teneur en oxyde de fer

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 97, no. 14, 4th October 1982, page 446, abstract 116730v, Columbus, Ohio, US; D.H. SIEMENS et al.: "Three mile island zeolite vitrification demonstration program", & AICHE SYMP. SER. 1982, 78(213), 41-4 *
See also references of WO8502395A1 *

Also Published As

Publication number Publication date
EP0162108A1 (fr) 1985-11-27
WO1985002395A1 (fr) 1985-06-06
JPS61500491A (ja) 1986-03-20

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