EP0203660A1 - Flüssige, weichmachende Reinigungsmittel - Google Patents
Flüssige, weichmachende Reinigungsmittel Download PDFInfo
- Publication number
- EP0203660A1 EP0203660A1 EP86200858A EP86200858A EP0203660A1 EP 0203660 A1 EP0203660 A1 EP 0203660A1 EP 86200858 A EP86200858 A EP 86200858A EP 86200858 A EP86200858 A EP 86200858A EP 0203660 A1 EP0203660 A1 EP 0203660A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- amine
- composition according
- composition
- component
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 50
- 239000007788 liquid Substances 0.000 title claims abstract description 10
- 238000004140 cleaning Methods 0.000 title claims abstract description 8
- 150000001412 amines Chemical class 0.000 claims abstract description 29
- 239000003599 detergent Substances 0.000 claims abstract description 20
- 239000004744 fabric Substances 0.000 claims abstract description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 239000003792 electrolyte Substances 0.000 claims description 13
- 125000000129 anionic group Chemical group 0.000 claims description 11
- 238000005185 salting out Methods 0.000 claims description 9
- 239000011149 active material Substances 0.000 claims description 8
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 102000004190 Enzymes Human genes 0.000 claims description 4
- 108090000790 Enzymes Proteins 0.000 claims description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 claims description 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000004902 Softening Agent Substances 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 21
- -1 aliphatic alcohols Chemical group 0.000 description 19
- 229910052783 alkali metal Inorganic materials 0.000 description 11
- 239000000344 soap Substances 0.000 description 8
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- 150000001340 alkali metals Chemical class 0.000 description 6
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000037230 mobility Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000004711 α-olefin Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 150000001335 aliphatic alkanes Chemical group 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 125000006701 (C1-C7) alkyl group Chemical group 0.000 description 1
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 229910001513 alkali metal bromide Inorganic materials 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 229910001516 alkali metal iodide Inorganic materials 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 230000003625 amylolytic effect Effects 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000004665 cationic fabric softener Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- XXUJMEYKYHETBZ-UHFFFAOYSA-N ethyl 4-nitrophenyl ethylphosphonate Chemical compound CCOP(=O)(CC)OC1=CC=C([N+]([O-])=O)C=C1 XXUJMEYKYHETBZ-UHFFFAOYSA-N 0.000 description 1
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 229940082005 hydrogenated tallow acid Drugs 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- UWHRNIXHZAWBMF-UHFFFAOYSA-N n-dodecyl-n-methyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)CCCCCCCCCCCC UWHRNIXHZAWBMF-UHFFFAOYSA-N 0.000 description 1
- KCMTVIZYKDBFFS-UHFFFAOYSA-N n-hexadecyl-n-methylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCC KCMTVIZYKDBFFS-UHFFFAOYSA-N 0.000 description 1
- VFLWKHBYVIUAMP-UHFFFAOYSA-N n-methyl-n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCCCCCC VFLWKHBYVIUAMP-UHFFFAOYSA-N 0.000 description 1
- KUFYUMSBZMUWAN-UHFFFAOYSA-N n-methyl-n-tetradecyltetradecan-1-amine Chemical compound CCCCCCCCCCCCCCN(C)CCCCCCCCCCCCCC KUFYUMSBZMUWAN-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- IFIDXBCRSWOUSB-UHFFFAOYSA-M potassium;1,5-dichloro-4,6-dioxo-1,3,5-triazin-2-olate Chemical compound [K+].ClN1C(=O)[N-]C(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-M 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 230000002797 proteolythic effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000013042 solid detergent Substances 0.000 description 1
- 150000008053 sultones Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
Definitions
- the present invention relates to aqueous liquid detergent compositions of the suspending type, i.e. compositions in which particles of a different density can be stably suspended.
- the invention relates to aqueous liquid detergent compositions of the suspending type which exhibit good cleaning performance and simultaneously impart a softening quality to the fabrics being laundered.
- Simultaneous cleaning and softening is desirable, as it provides the user with increased convenience in the laundering operation, rendering redundant the after-wash softening/rinse cycle and the separate dosing of special-purpose softening compositions.
- long-chain fatty amines which are suitable to impart through-the- wash softening, can be stably incorporated in aqueous liquid detergent compositions of the suspending type, provided the compositions are formulated to have a pH value above the isoelectric point of the fatty amine.
- an aqueous suspending liquid detergent composition for the cleaning and softening of fabrics which comprises:
- composition also comprises one or more electrolytes as part of the active system, thereby providing the structure necessary for the suspending properties of the composition.
- Suitable nonionic detergent-actives for use in the present invention may be found in the following classes: fatty acid alkylolamides, alkylene oxide condensates of alkylphenols or primary and secondary aliphatic alcohols, alkylamines, alkyl mercaptans and amine oxides.
- ethylene oxide condensates and mixtures of ethylene oxide condensates with fatty acid alkylolamides are preferred. Particularly suitable have been found ethylene oxides having a hydrophilic-lipophilic balance of between 11 and 15, such as C"C,5 alcohols condensed with 6-8 ethylene oxides.
- anionic derivatives of, in particular, polyalkoxylated nonionic detergent materials which have retained to a large extent a nonionic character can be used instead of or in combination with nonionic detergent-actives.
- Suitable examples are the sulphated, phosphated or carboxylated polyalkoxylated nonionic detergent-actives, such as the alkyl and alkylaryl polyethoxy ether sulphates.
- Suitable alkyl polyethoxy ether sulphates have about 10 to about 18 carbon atoms in the alkyl chain and have an average of 1 to 12, preferably 1 to 6 ethylene oxide units.
- anionic surfactants can be used in the compositions of the present invention.
- Suitable anionic non-soap surfactants are water-soluble salts of alkyl benzene sulphonates, alkyl sulphates, paraffin sulphonates, alpha-olefin sulphonates, alpha-sulphocarboxylates and their esters, alkyl glyceryl ether sulphonates, fatty acid monoglyceride sulphates and sulphonates, 2- acyloxy-alkane-1-sulphonates, and beta-alkoxy alkane sulphonates. Soaps are also suitable anionic surfactants.
- Especially preferred alkyl benzene sulphonates have about 9 to about 15 carbon atoms in a linear or branched alkyl chain, more especially about 11 to about 13 carbon atoms.
- Suitable alkyl sulphates have about 10 to about 22 carbon atoms in the alkyl chain, more especially from about 12 to about 18 carbon atoms.
- Suitable paraffin sulphonates are essentially linear and contain from about 8 to about 24 carbon atoms, more especially from about 14 to about 18 carbon atoms.
- Suitable alpha-olefin sulphonates have about 10 to about 24 carbon atoms, more especially about 14 to about 16 carbon atoms; alpha-olefin sulphonates can be made by reaction with sulphur trioxide, followed by neutralization under conditions such that any sultones present are hydrolyzed to the corresponding hydroxy alkane sulphonates.
- Suitable alpha-sulphocarboxylates contain from about 6 to about 20 carbon atoms; included herein are not only the salts of alpha-sulphonated fatty acids, but also their esters made from alcohols containing about 1 to about 14 carbon atoms.
- Suitable alkyl glyceryl ether sulphates are ethers of alcohols having about 10 to about 18 carbon atoms, more especially those derived from coconut oil and tallow.
- Suitable alkyl phenol polyethoxy ether sulphates have about 8 to about 12 carbon atoms in the alkyl chain and an average of about 1 to about 6 ethylene oxide units per molecule.
- Suitable 2-acyloxy-alkane-1-sulphonates contain from about 2 to about 9 carbon atoms in the acyl group and about 9 to about 23 carbon atoms in the alkane moiety.
- Suitable beta-alkyloxy alkane sulphonates contain about 1 to about 3 carbon atoms in the alkyl group and about 8 to about 20 carbon atoms in the alkane moiety.
- the alkyl chains of the foregoing non-soap anionic surfactants can be derived from natural sources such as coconut oil or tallow, or can be made synthetically, as for example by using the Ziegler or Oxo processes. Water-solubility can be achieved by using alkali metal, ammonium, or alkanolammonium cations; sodium is preferred. Mixtures of anionic surfactants are contemplated by this invention; a satisfactory mixture contains alkyl benzene sulphonate having 11-13 carbon atoms in the alkyl group and alkyl sulphate having 12 to 18 carbon atoms in the alkyl group.
- Suitable soaps contain about 8 to about 18 carbon atoms, more especially about 12 to about 18 carbon atoms.
- Soaps can be made by direct saponification of natural fats and oils such as coconut oil, tallow and palm oil, or by neutralization of free fatty acids obtained from either natural or synthetic sources.
- the soap cation can be alkali metal, ammonium or alkanolammonium; sodium is preferred.
- the amount of the active detergent material may vary from 1 to 60%, preferably from 2-40% and especially preferably from 5-25%; when mixtures of e.g. anionics and nonionics are used, the relative weight ratio varies from 10:1 to 1:10, preferably from 6:1 to 1:6. When a soap is also incorporated, the amount thereof is from 1-40% by weight.
- a particularly preferred active detergent mixture is that of a water-soluble anionic sulphonate or sulphate detergent and a nonionic detergent in a weight ratio of from about 6:1 to 1:1, with or without a soap in a ratio of up to 2:1 with respect to the nonionic detergent constituent.
- the inclusion of one or more electrolytes, in particular of the salting-out type, is often essential.
- the composition may contain from 1 to 60% by weight, and preferably from 3 to 50% by weight, and particularly preferably from 10 to 35% by weight of the salting-out electrolytes.
- Typical examples of such salting-out electrolytes are water-soluble builder salts, such as the alkali metal ortho-and pyrophosphates, the alkali metal tripolyphosphates, such as sodium tripolyphosphate, the alkali metal silicates, alkali metal borates, alkali metal carbonates, alkali metal sulphates, alkali metal citrates; alkali metal salts of nitrilotriacetate; alkali metal salts of carbox- ymethyloxy succinate.
- the alkali metal salts the ammonium and ethanol-substituted ammonium salts can be used.
- ⁇ may be advantageous to include also a certain level of a non-salting-out electrolyte. This can be determined by routine experimentation, using the general indications below as to level and type of auxiliary electrolytes.
- auxiliary electrolytes are alkali metal iodides, alkali metal (per)-chlorates, alkali metal rhodanides, and alkali metal nitrates, and alkali metal bromides and alkali metal chlorides.
- the corresponding ammonium and ethanol-substituted ammonium salts can also be used.
- the auxiliary electrolyte is generally used in the composition in an amount of 0.5 to 35% by weight, preferably 1 to 30% by weight, and particularly preferably 2 to 25% by weight.
- Long-chain fatty amines suitable for the purpose of the invention are substantially water-insoluble compounds that have the general formula: wherein: R, is a C 10 -C 25 alkyl or alkenyl group,
- R 3 is methyl or ethyl.
- Suitable amines include:
- compositions should contain from 0.5% to 15% by weight of the amine, preferably from 1% to 10% by weight and most preferably from 2% to 5% by weight.
- the pH of the composition is essential to obtain physically stable formulations, and should be above the isoelectric point of the amine used.
- the compositional pH is at least one pH unit above said isoelectric point.
- amines in the lower range of isoelectric points Preferably amines having an isoelectric point in the range of 7 to 8.5 are used in combination with enzymes.
- the isoelectric point of any given amine can be determined by measuring the electrophoretic mobility of an aqueous dispersion of the amine under standard conditions of concentration and temperature at a series of pHs, with plotting of the mobilities against pH to determine the pH of zero mobility.
- T and Co represent the mixed alkyl radical derived from hydrogenated tallow acid and coconut oil acid, respectively.
- the liquid detergent composition of the invention may further contain any of the adjuncts normally used in fabric-washing detergent compositions, e.g. sequestering agents such as ethylene diamine tetraacetate; alkali silicates for adjusting the pH; soil-suspending and anti-redeposition agents such as sodium carboxymethylcellulose, polyvinylpyrrolidone, etc.; fluorescent agents; perfumes, germicides and colourants.
- adjuncts normally used in fabric-washing detergent compositions e.g. sequestering agents such as ethylene diamine tetraacetate; alkali silicates for adjusting the pH; soil-suspending and anti-redeposition agents such as sodium carboxymethylcellulose, polyvinylpyrrolidone, etc.; fluorescent agents; perfumes, germicides and colourants.
- lather depressors such as silicones; and enzymes, particularly proteolytic and amylolytic enzymes; and peroxygen or chlorine bleaches, such as sodium perborate and potassium dichlorocyanurate, including bleach activators, such as N,N,N',N'-tetraacetylethylenediamine, may be necessary to formulate a complete heavy duty detergent composition suitable for use in washing machine operations.
- lather depressors such as silicones
- enzymes particularly proteolytic and amylolytic enzymes
- peroxygen or chlorine bleaches such as sodium perborate and potassium dichlorocyanurate
- bleach activators such as N,N,N',N'-tetraacetylethylenediamine
- the composition of the invention has a viscosity of up to 1.2 Pas, and most preferably from 0.4 to 1.0 Pas as measured at 20°C and at a shear rate of 21 seconds-'.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB858513420A GB8513420D0 (en) | 1985-05-28 | 1985-05-28 | Liquid cleaning & softening compositions |
| GB8513420 | 1985-06-10 | ||
| GB8514582 | 1985-06-10 | ||
| GB858514582A GB8514582D0 (en) | 1985-06-10 | 1985-06-10 | Liquid cleaning & softening compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0203660A1 true EP0203660A1 (de) | 1986-12-03 |
| EP0203660B1 EP0203660B1 (de) | 1989-01-04 |
Family
ID=26289294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19860200858 Expired EP0203660B1 (de) | 1985-05-28 | 1986-05-20 | Flüssige, weichmachende Reinigungsmittel |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0203660B1 (de) |
| JP (1) | JPH0637635B2 (de) |
| AU (1) | AU572024B2 (de) |
| DE (1) | DE3661640D1 (de) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0309264A3 (de) * | 1987-09-24 | 1989-12-06 | Unilever Plc | Zusammensetzung zum Weichspülen von Wäsche |
| GB2245000A (en) * | 1987-09-17 | 1991-12-18 | Colgate Palmolive Co | Fabric softening detersive article |
| US5445756A (en) * | 1990-10-22 | 1995-08-29 | The Procter & Gamble Company | Stable liquid detergent compositions containing peroxygen bleach suspended by a hydropholic silica |
| WO1996012000A1 (en) * | 1994-10-13 | 1996-04-25 | The Procter & Gamble Company | Detergent compositions containing amines and anionic surfactants |
| WO1997000929A1 (en) * | 1994-10-13 | 1997-01-09 | The Procter & Gamble Company | Detergent compositions containing amines and anionic surfactants |
| WO1997012021A1 (en) * | 1995-09-29 | 1997-04-03 | The Procter & Gamble Company | Detergent compositions containing amines, alkyl sulfates, and other anionic surfactants |
| US5981466A (en) * | 1994-10-13 | 1999-11-09 | The Procter & Gamble Company | Detergent compositions containing amines and anionic surfactants |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2328792A1 (fr) * | 1975-10-22 | 1977-05-20 | Unilever Nv | Compositions pour l'assouplissement des etoffes |
| FR2329746A1 (fr) * | 1975-10-31 | 1977-05-27 | Procter & Gamble Europ | Composition detergente liquide pour la vaisselle |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0011340B1 (de) * | 1978-11-20 | 1982-11-24 | THE PROCTER & GAMBLE COMPANY | Reinigungsmittelzusammensetzung mit Textil-Weichmachereigenschaften |
| US4554098A (en) * | 1982-02-19 | 1985-11-19 | Colgate-Palmolive Company | Mild liquid detergent compositions |
| GB2172910B (en) * | 1985-03-28 | 1989-06-21 | Procter & Gamble | Detergent containing a fabric conditioner |
| GB8513421D0 (en) * | 1985-05-28 | 1985-07-03 | Unilever Plc | Liquid cleaning & softening compositions |
-
1986
- 1986-05-20 DE DE8686200858T patent/DE3661640D1/de not_active Expired
- 1986-05-20 EP EP19860200858 patent/EP0203660B1/de not_active Expired
- 1986-05-26 JP JP61120928A patent/JPH0637635B2/ja not_active Expired - Lifetime
- 1986-05-27 AU AU57973/86A patent/AU572024B2/en not_active Expired
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2328792A1 (fr) * | 1975-10-22 | 1977-05-20 | Unilever Nv | Compositions pour l'assouplissement des etoffes |
| FR2329746A1 (fr) * | 1975-10-31 | 1977-05-27 | Procter & Gamble Europ | Composition detergente liquide pour la vaisselle |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2245000A (en) * | 1987-09-17 | 1991-12-18 | Colgate Palmolive Co | Fabric softening detersive article |
| GB2245000B (en) * | 1987-09-17 | 1992-06-03 | Colgate Palmolive Co | Liquid detergent composition |
| EP0309264A3 (de) * | 1987-09-24 | 1989-12-06 | Unilever Plc | Zusammensetzung zum Weichspülen von Wäsche |
| US4970028A (en) * | 1987-09-24 | 1990-11-13 | Lever Brothers Company | Composition for softening fabrics |
| AU616204B2 (en) * | 1987-09-24 | 1991-10-24 | Unilever Plc | A composition for softening fabrics |
| US5445756A (en) * | 1990-10-22 | 1995-08-29 | The Procter & Gamble Company | Stable liquid detergent compositions containing peroxygen bleach suspended by a hydropholic silica |
| WO1996012000A1 (en) * | 1994-10-13 | 1996-04-25 | The Procter & Gamble Company | Detergent compositions containing amines and anionic surfactants |
| WO1997000929A1 (en) * | 1994-10-13 | 1997-01-09 | The Procter & Gamble Company | Detergent compositions containing amines and anionic surfactants |
| US5981466A (en) * | 1994-10-13 | 1999-11-09 | The Procter & Gamble Company | Detergent compositions containing amines and anionic surfactants |
| WO1997012021A1 (en) * | 1995-09-29 | 1997-04-03 | The Procter & Gamble Company | Detergent compositions containing amines, alkyl sulfates, and other anionic surfactants |
| US6087321A (en) * | 1995-09-29 | 2000-07-11 | The Procter & Gamble Company | Detergent compositions containing amines, alkyl sulfates, and other anionic surfactants |
Also Published As
| Publication number | Publication date |
|---|---|
| AU572024B2 (en) | 1988-04-28 |
| AU5797386A (en) | 1986-12-04 |
| JPS61283698A (ja) | 1986-12-13 |
| EP0203660B1 (de) | 1989-01-04 |
| DE3661640D1 (en) | 1989-02-09 |
| JPH0637635B2 (ja) | 1994-05-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0151678B1 (de) | Stabile flüssige Detergenszusammensetzungen | |
| CA1109759A (en) | Detergent compositions | |
| CA1312419C (en) | Composition for softening fabrics | |
| EP0181041B1 (de) | Äthanolfreie flüssige Wäschereinigungsmittel | |
| EP0095205B1 (de) | Fettsäure enthaltende Detergenszusammensetzungen | |
| GB1514276A (en) | Fabric-softening compositions | |
| EP0342177B1 (de) | Flüssige Universalwaschmittel, welche anionische und nichtionische oberflächenaktive Mittel, Gerüststoffe und proteolytisches Enzym enthalten | |
| EP0008142A1 (de) | Flüssige Reinigungsmittelzusammensetzung, die ein ternäres oberflächenaktives System enthält | |
| JP4063866B2 (ja) | アミンおよびアニオン性界面活性剤を含む洗剤組成物 | |
| EP0348183A2 (de) | Enzymhaltige, flüssige Waschmittel | |
| EP0000225A1 (de) | Festes Waschmittel zur verbesserten Beseitigung von fetthaltigem Schmutz | |
| US4714565A (en) | Homogeneous concentrated liquid detergent compositions containing a monoester of a dicarboxylic acid | |
| EP0206375B1 (de) | Flüssige Reinigungs- und Weichmacher-Zusammensetzungen | |
| EP0241073B2 (de) | Flüssige Reinigungsmittel, welche einen anionischen oberflächenaktiven Stoff, ein Salz der Bernsteinsäure als Gerüststoff und eine Fettsäure enthalten | |
| US4199483A (en) | Detergent compositions containing salicylate corrosion inhibitor | |
| IE61343B1 (en) | Detergent/softening compositions containing hectorite clays | |
| CA1239324A (en) | Detergent composition containing semi-polar nonionic detergent, alkaline earth metal anionic detergent, and amidoalkylbetaine detergent | |
| EP0203660B1 (de) | Flüssige, weichmachende Reinigungsmittel | |
| EP0189225A2 (de) | Verstärktes flüssiges Reinigungsmittel, das anionische, ethoxilierte nichtionische und amidhaltige oberflächenaktive Verbindungen enthält | |
| IE51245B1 (en) | Granular detergent compositions | |
| EP0051986A2 (de) | Reinigungsmittelzusammensetzungen | |
| EP0167205B1 (de) | Stabile flüssige Reinigungsmittel, die ein anionisches Tensid und einen monosulfonierten optischen Aufheller enthalten | |
| US5858950A (en) | Low sudsing liquid detergent compositions | |
| JPH0323120B2 (de) | ||
| EP0103926A1 (de) | Wässrige flüssige Detergenszusammensetzungen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): CH DE FR GB IT LI NL SE |
|
| 17P | Request for examination filed |
Effective date: 19861215 |
|
| 17Q | First examination report despatched |
Effective date: 19870803 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): CH DE FR GB IT LI NL SE |
|
| REF | Corresponds to: |
Ref document number: 3661640 Country of ref document: DE Date of ref document: 19890209 |
|
| ITF | It: translation for a ep patent filed | ||
| ET | Fr: translation filed | ||
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed | ||
| ITTA | It: last paid annual fee | ||
| EAL | Se: european patent in force in sweden |
Ref document number: 86200858.8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19960502 Year of fee payment: 11 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19970531 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19970531 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20050429 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20050511 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20050517 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20050519 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20050528 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20050630 Year of fee payment: 20 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20060519 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20060520 |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: PE20 |
|
| EUG | Se: european patent has lapsed | ||
| NLV7 | Nl: ceased due to reaching the maximum lifetime of a patent |
Effective date: 20060520 |