EP0214580A2 - Procédé et produit pour la réoxidation et le savonnage en un seul bain de teintures réalisées avec des colorants de cuve ou des colorants de cuve au soufre - Google Patents
Procédé et produit pour la réoxidation et le savonnage en un seul bain de teintures réalisées avec des colorants de cuve ou des colorants de cuve au soufre Download PDFInfo
- Publication number
- EP0214580A2 EP0214580A2 EP86112030A EP86112030A EP0214580A2 EP 0214580 A2 EP0214580 A2 EP 0214580A2 EP 86112030 A EP86112030 A EP 86112030A EP 86112030 A EP86112030 A EP 86112030A EP 0214580 A2 EP0214580 A2 EP 0214580A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- soaping
- vat
- chloramide
- dyes
- oxidizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 44
- 230000008569 process Effects 0.000 title claims abstract description 30
- 238000010405 reoxidation reaction Methods 0.000 title claims abstract description 25
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 11
- 239000005864 Sulphur Substances 0.000 title 1
- 238000004048 vat dyeing Methods 0.000 title 1
- 239000000975 dye Substances 0.000 claims abstract description 42
- 239000000984 vat dye Substances 0.000 claims abstract description 26
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 19
- 239000011593 sulfur Substances 0.000 claims abstract description 19
- 230000003647 oxidation Effects 0.000 claims abstract description 14
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 14
- SJUGPXBWZCQTKM-UHFFFAOYSA-N n-chloro-4-methylbenzenesulfonamide;sodium Chemical compound [Na].CC1=CC=C(S(=O)(=O)NCl)C=C1 SJUGPXBWZCQTKM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000004043 dyeing Methods 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 24
- 239000007800 oxidant agent Substances 0.000 claims description 15
- 230000001590 oxidative effect Effects 0.000 claims description 14
- GXJQMKFJQFGQKV-KHPPLWFESA-N 2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS(O)(=O)=O GXJQMKFJQFGQKV-KHPPLWFESA-N 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 11
- 239000004753 textile Substances 0.000 claims description 10
- -1 alkylaryl sulfonamides Chemical class 0.000 claims description 8
- 239000000344 soap Substances 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 150000007973 cyanuric acids Chemical class 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 229920000728 polyester Polymers 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 229940124530 sulfonamide Drugs 0.000 claims description 5
- 239000004094 surface-active agent Substances 0.000 claims description 5
- 229920003043 Cellulose fiber Polymers 0.000 claims description 4
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- NXTVQNIVUKXOIL-UHFFFAOYSA-N N-chlorotoluene-p-sulfonamide Chemical class CC1=CC=C(S(=O)(=O)NCl)C=C1 NXTVQNIVUKXOIL-UHFFFAOYSA-N 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims description 3
- ARGDYOIRHYLIMT-UHFFFAOYSA-N n,n-dichloro-4-methylbenzenesulfonamide Chemical compound CC1=CC=C(S(=O)(=O)N(Cl)Cl)C=C1 ARGDYOIRHYLIMT-UHFFFAOYSA-N 0.000 claims description 3
- JNWGYSUVTQLCQP-UHFFFAOYSA-N n-chloro-2-methylbenzenesulfonamide Chemical compound CC1=CC=CC=C1S(=O)(=O)NCl JNWGYSUVTQLCQP-UHFFFAOYSA-N 0.000 claims description 3
- CHVZPRDGLWBEMJ-UHFFFAOYSA-N n-chlorobenzenesulfonamide Chemical class ClNS(=O)(=O)C1=CC=CC=C1 CHVZPRDGLWBEMJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 229940045996 isethionic acid Drugs 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 125000005418 aryl aryl group Chemical group 0.000 claims 2
- 239000006185 dispersion Substances 0.000 claims 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract description 13
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 20
- 239000000986 disperse dye Substances 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- JACPTQMMZGZAOL-KHPPLWFESA-N 2-[methyl-[(z)-octadec-9-enyl]amino]ethanesulfonic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCN(C)CCS(O)(=O)=O JACPTQMMZGZAOL-KHPPLWFESA-N 0.000 description 10
- 239000000988 sulfur dye Substances 0.000 description 9
- 239000000835 fiber Substances 0.000 description 8
- FMKXFJQAVQXMPX-UHFFFAOYSA-N 4-(9h-carbazol-3-ylimino)cyclohexa-2,5-dien-1-one Chemical compound C1=CC(=O)C=CC1=NC1=CC=C(NC=2C3=CC=CC=2)C3=C1 FMKXFJQAVQXMPX-UHFFFAOYSA-N 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000002609 medium Substances 0.000 description 5
- 238000004040 coloring Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000010411 cooking Methods 0.000 description 4
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- BMZAOXGPXCPSTH-UHFFFAOYSA-N vatred14 Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13.C1=CC=C2N(C(C3=CC=C4C(N5C6=CC=CC=C6N=C5C=5C=CC6=C3C4=5)=O)=O)C6=NC2=C1 BMZAOXGPXCPSTH-UHFFFAOYSA-N 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 206010013786 Dry skin Diseases 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- QTWZICCBKBYHDM-UHFFFAOYSA-N leucomethylene blue Chemical compound C1=C(N(C)C)C=C2SC3=CC(N(C)C)=CC=C3NC2=C1 QTWZICCBKBYHDM-UHFFFAOYSA-N 0.000 description 2
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001844 chromium Chemical class 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 description 1
- 229960002218 sodium chlorite Drugs 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 238000009970 yarn dyeing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
- D06P1/222—Oxidising agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/30—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using sulfur dyes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/904—Mixed anionic and nonionic emulsifiers for dyeing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/908—Anionic emulsifiers for dyeing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- the present invention relates to a method for single-bath reoxidation and soaping of dyeings with vat and / or sulfur vat dyes (C.I. Vat Dyes), which have previously been applied in reduced form to a textile material containing cellulose fibers and fixed there, from an alkaline medium.
- This invention also relates to an oxidizing and re-soaping agent for carrying out the claimed process.
- N-chlorinated organic sulfonamides such as N-chloro-aryl- or -alkylaryl-sulfonamides or N-chlorinated isocyanuric acids are suitable representatives of such compounds which split off hypochlorite in the heat and are able to give off positively charged chlorine during the oxidation process in question.
- Anionic, hypochlorite-insensitive surfactants such as e.g. Oleyl methyl taurine or oleyl isethionic sodium, among others, optionally mixed with such non-ionic type auxiliaries. According to the invention, these surfactants are used together with the above-mentioned oxidizing agents from the same liquor.
- the amounts of the oxidizing agents mentioned above depend, according to the invention, on whether the process is carried out continuously or batchwise: with continuous process control, it is recommended that 1 to 4 g / 1 of the oxidants and 1 g / 1 soda be used in the batch liquors and 0.5 in the subsequent liquors to use 1% of the oxidant. In discontinuous work 0.5 to 2% of the oxidant (based on the weight of the goods) and 1 g / 1 soda have proven to be useful.
- the pH of the claimed process can vary within wide limits without affecting the quality of the reoxidation of the leuco dyes, as long as it is ensured that an alkaline medium (p H ) 8) predominates in the developing baths.
- the dye development is preferably carried out at pH values in the range between 8 and 12, which are adjusted either by the alkali on the goods, originating from the previous vatting, or better by the separate addition of, for example, soda.
- the claimed process can be carried out either continuously or batchwise. In the case of continuous working technology, residence times of the material to be dyed in the development / soap baths between 5 and 120 seconds are sufficient.
- the temperature of the treatment for reoxidizing and soaping is also relatively uncritical according to the process and, depending on the composition of the dye combination, can vary between 35 ° C and cooking temperature (100 ° C). While in the case of a combination of the sulfur vat dyes with each other temperatures between 35 ° and 50 ° C are used, in the case of combinations of vat and sulfur vat dyes 95 ° C to cooking temperature are preferred.
- the actual oxidation bath is generally followed by further soap baths set at higher temperatures (80 ° C. to cooking temperature). It is not necessary to interpose rinsing baths to remove the unused oxidizing agent.
- the new process is designed for the continuous as well as for the discontinuous oxidation / soaping of dyeings with the dyes mentioned, regardless of the form, for example by padding or printing or using the pull-out technique, these were previously applied to the textile material to be dyed are. They are independent of the type of application after fixation in reduced form on the fiber before and must be reoxidized to the insoluble dye.
- sulfur dyes of other origins are also present, for example linked sulfur dyes (CI Sulfur Dyes), leuco sulfur dyes (CI Leuco Sulfur Dyes) and sulfur dyes solubilized by thiosulfato groups (CI Solubilized Sulfur Dyes), as described in the German published documents DE-A1-33 12 162 and DE-A1-33 38 267 may be mentioned, can be included as a component in the dye mixtures used according to the invention.
- linked sulfur dyes CI Sulfur Dyes
- leuco sulfur dyes CI Leuco Sulfur Dyes
- sulfur dyes solubilized by thiosulfato groups CI Solubilized Sulfur Dyes
- the present invention is in principle applicable to textile material which consists of polyester / cellulose fiber mixtures, in which case alkali-stable disperse dyes are then present in the dye preparations containing vat and / or sulfur vat dyes and thus for the coloring of the polyester fiber component in the patterning process according to the invention can actively participate.
- the disperse dyes which are essentially different from the other two dye types, are fixed before the vat and / or sulfur vat dyes are converted into their reduced form (vatting) and the subsequent measures for reoxidizing and soaping under alkaline conditions; it can take place by thermosoling or in the HT pull-out process.
- the new process is significantly enriched because it offers commercially available ranges of dye mixtures on the basis mentioned above, in which combinations of both disperse and vat dyes as well as disperse and Sulfur vat dyes are present next to each other, then oxidized together and can thus be used for coloring both types of fibers at the same time without dyeing difficulties.
- a 100% cotton fabric is made according to the so-called pad-steaming process for vat dyes using 10 g / 1 of the Vat Red 14 dye with the C.I. 71110 treated by padding the web from 25 ° C warm, aqueous medium with a pH of about 5.5 and in the presence of an anionic surfactant with a pigment suspension of the insoluble colorant with a liquor absorption of 45% and then at about 115 ° C dries.
- This impregnation is now padded over with an aqueous bonding liquor based on hydrosulphite / sodium hydroxide solution with a 60% liquor application and steamed for a short time with air-free saturated steam at 105 ° C. with conversion to the leuco form, including fixation thereof, on the fiber.
- a level navy blue dyeing of the mixed yarn on the two fiber components is obtained.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19853532341 DE3532341A1 (de) | 1985-09-11 | 1985-09-11 | Verfahren und mittel zum einbadigen reoxidieren und seifen von faerbungen mit kuepen- oder schwefelkuepenfarbstoffen |
| DE3532341 | 1985-09-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0214580A2 true EP0214580A2 (fr) | 1987-03-18 |
| EP0214580A3 EP0214580A3 (fr) | 1990-03-07 |
Family
ID=6280624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP86112030A Withdrawn EP0214580A3 (fr) | 1985-09-11 | 1986-08-30 | Procédé et produit pour la réoxidation et le savonnage en un seul bain de teintures réalisées avec des colorants de cuve ou des colorants de cuve au soufre |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4723961A (fr) |
| EP (1) | EP0214580A3 (fr) |
| JP (1) | JPS6278284A (fr) |
| DE (1) | DE3532341A1 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105155300A (zh) * | 2015-09-23 | 2015-12-16 | 泉州市新宏化工贸易有限公司 | 一种涤纶或涤纶混纺织物的中性条件染色工艺及涤舒宝 |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4215678A1 (de) * | 1991-05-23 | 1992-11-26 | Sandoz Ag | Trockene leukoschwefelfarbstoffe |
| US7513915B2 (en) * | 2002-11-22 | 2009-04-07 | Schneider Advanced Technologies, Inc. | Process for stain removal |
| US7824448B2 (en) | 2002-11-22 | 2010-11-02 | Schneider David J | Process for stain removal |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL95122C (fr) * | 1954-11-22 | |||
| DE2702710A1 (de) * | 1976-03-24 | 1977-09-29 | Sandoz Ag | Faerbeverfahren |
| US4198204A (en) * | 1976-11-27 | 1980-04-15 | Hoechst Aktiengesellschaft | Short liquor dyeing process for piece goods, made from cellulose fibers, in rope form |
| EP0121227B1 (fr) * | 1983-04-02 | 1987-01-07 | Hoechst Aktiengesellschaft | Procédé de réoxydation de teintures avec des colorants au soufre |
-
1985
- 1985-09-11 DE DE19853532341 patent/DE3532341A1/de not_active Withdrawn
-
1986
- 1986-08-30 EP EP86112030A patent/EP0214580A3/fr not_active Withdrawn
- 1986-09-09 US US06/905,632 patent/US4723961A/en not_active Expired - Fee Related
- 1986-09-10 JP JP61211796A patent/JPS6278284A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105155300A (zh) * | 2015-09-23 | 2015-12-16 | 泉州市新宏化工贸易有限公司 | 一种涤纶或涤纶混纺织物的中性条件染色工艺及涤舒宝 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0214580A3 (fr) | 1990-03-07 |
| JPS6278284A (ja) | 1987-04-10 |
| DE3532341A1 (de) | 1987-03-19 |
| US4723961A (en) | 1988-02-09 |
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