Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/37—Mixtures of compounds all of which are anionic
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
  • C11D11/02—Preparation in the form of powder by spray drying
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
  • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
  • C11D17/065—High-density particulate detergent compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/02—Inorganic compounds ; Elemental compounds
  • C11D3/04—Water-soluble compounds
  • C11D3/08—Silicates
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
  • C11D1/02—Anionic compounds
  • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
  • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds

Definitions

• the present invention relates to granular detergent compositions containing a specific mixture of alkylben­zene sulfonate surfactant, alkyl sulfate surfactant, alkali metal silicate and water-soluble sulfate.
• the compositions are prepared by drying, preferably by spray-drying, an aqueous slurry comprising the above components. While the compositions preferably also contain detergent builder materials, there should be relatively little or no pyrophosphate or anhydrous Form 1 tripolyphosphate builder in that portion of the composition prepared by drying the slurry comprising the sulfonate and sulfate surfactants, silicate and sulfate.
• alkylbenzene sulfonate and alkyl sulfate surfactants are desired for optimum detergency perform­ance. However, such mixtures tend to gel on contact with water. This can result in poor solubility of granules having high levels of alkylbenzene sulfonate and alkyl sulfate surfactants, particularly when such granules are incorporated in dense detergent compositions.
• soluble granular detergent compositions containing high levels of alkyl­benzene sulfonate and alkyl sulfate surfactants can be obtained by drying an aqueous slurry comprising the surfactants, silicate in a weight ratio of surfactant to silicate within the range of from 1.5:1 to 6:1, sulfate and relatively little or no pyrophosphate or anhydrous Form 1 tripolyphosphate detergent builder material.
• these soluble detergent granules are admixed or agglomerated with builders and other optional detergent ingredients.
• compositions are obtained by admixing the soluble granules with builders, compacting the admix at relatively low pressures (e.g., 137.9 kPa to 1379 kPa and optionally admixing additional builders and other ingredients to provide finished granular detergent compositions.
• the compositions can also contain 0-20% of other surfactants such as alkylbenzene sulfonates.
• Spray-dried detergents containing mixtures of alkylbenzene sulfonate and alkyl ethoxy sulfate surfactants, silicate and builders are exemplified.
• the particles are mixed with spray-dried base granule containing about 27% of a mixture of alkylbenzene sulfonate and alkyl ethoxy sulfate surfactants, 18% silicate and about 22% sodium tripolyphosphate.
• Japanese OPI 106509 published August 21, 1979, discloses spray-dried granular detergents containing 15-40% surfactant, 5-20% silicate and no more than 12% phosphate.
• the compositions are said to have good physical properties and to cause less deposition of insolubles on clothes.
• Japanese OPI 72998 and 72999 published April 25, 1985, disclose dense granular detergents formed by high shear mixing of alkylbenzene sulfuric acid and alkyl sulfuric acid with sodium carbonate and water to cause neutralization, admixing other ingredients such as builders, and then crushing and granulating the mixture.
• This invention relates to a granular detergent composition prepared by:
• the granular detergent compositions of the present invention contain from 30% to 85%, preferably from 35% to 60%, more preferably from 40% to 50%, by weight of a mixture of C11-C13 alkylbenzene sulfonate surfactant and C12-C16 alkyl sulfate surfactant in a weight ratio of sulfonate sur­factant to sulfate surfactant of from 4:1 to 1:4, preferably from 3:1 to 1:3, more preferively from 2:1 to 1:2.
• Sulfonate surfactants useful herein are the water-­soluble salts, particularly the alkali metal, ammonium and alkanolammonium (e.g., monoethanolammonium or triethanolammonium) salts of alkylbenzene sulfonates in which the alkyl group contains from 11 to 13 carbon atoms, in straight chain or branched chain configuration, e.g., those of the type described in U.S. Patents 2,220,099 and 2,477,383.
• alkali metal, ammonium and alkanolammonium e.g., monoethanolammonium or triethanolammonium
• Useful alkyl sulfate surfactants are the water-­soluble salts, particularly the alkali metal, ammonium and alkanolammonium (e.g., monoethanolammonium or triethanolammonium) salts of C12-C16 linear or branched alkyl sulfates. Preferred are those containing a C12-C15, especially C14-C15, linear alkyl group.
• compositions herein can also contain minor amounts (generally less than 30%, but preferably less than 15%, by weight of the above sulfonate and sulfate surfactants) of other detergent surfactants known in the art.
• minor amounts can include anionic, nonionic, cationic, ampholytic and zwitterionic surfactants, such as those disclosed in U.S. Patent 3,919,678, Laughlin, et al, issued December 30, 1975.
• compositions of the present invention also contain an alkali metal silicate having a molar ratio of SiO2 to alkali metal oxide of from 1.0 to 3.2, preferably from 1.6 to 2.4.
• the alkali metal silicates can be purchased in either liquid or granular form. Silicate solutions or slurries can conveniently be used to avoid having to dissolve the dried form in the aqueous slurry (e.g., crutcher mix) of the components herein.
• aqueous slurry e.g., crutcher mix
• the weight ratio of the alkylbenzene sulfonate plus alkyl sulfate surfactants herein to the alkali metal silicate should be from 1.5:1 to 6:1, preferably from 2:1 to 4:1, more preferably from 2.5:1 to 3.5:1.
• compositions further contain from 10% to 60%, preferably from about 20% to about 50%, by weight of a water-soluble (preferably sodium) sulfate.
• a water-soluble (preferably sodium) sulfate is usually formed during the sulfation/sulfonation and neutralization steps in the production of the alkylbenzene sulfonate and alkyl sulfate surfactants herein.
• compositions herein are prepared by drying an aqueous slurry comprising the components.
• the slurry generally contains from 25% to 70%, preferably from 40% to 60%, water, whereas the dried granules initially contain from 1% to 10%, preferably from 1% to 3%, water.
• the drying operation can be accomplished by any convenient means, such as by using spray-drying towers, both counter-current and co-current, fluid beds, flash-drying equipment, or industrial microwave or oven-drying equipment. These are more fully described in U.S. Patent 4,019,998, Benson et al, issued April 26, 1977 (particularly from Column 14, line 19 to Column 15, line 9).
• the granular detergents herein are very soluble in the wash water even though they contain high levels of alkylbenzene sulfonate and alkyl sulfate surfactants. Good solubility is obtained when the weight ratio of total sulfonate plus sulfate surfactant to silicate is within the 1.5:1 to 6:1 range specified above. While not intending to be limited by theory, it is believed that this relatively high level of silicate provides structure and helps to maintain integrity of the high surfactant granules and that this minimizes gelling when the surfactants contact the wash water.
• silicate level becomes too high (e.g., a surfactant to silicate ratio of 1:1), overall solubility can suffer due to the formation of silicate insolubles.
• granules having a surfactant to silicate ratio of, for example, 8:1 have insufficient structure and tend to be too mushy at these high surfactant levels.
• the amount of detergent pyrophosphate or anhydrous Form 1 tripolyphosphate builder material in the portion of the granular detergent obtained by drying an aqueous slurry of the essential components herein should also be minimized.
• the compositions can contain from 0% to 20%, preferably from 0% to 15%, more preferably from 0% to 10%, by weight of such detergent builder material or mixtures thereof.
• the compositions are substantially free of such detergent builder (e.g., they contain less than 5%, preferably less than 3%, by weight of such builder).
• compositions can contain up to 60% preferably from 1% to 45% by weight of other detergent builders including any of those described in U.S. Patent 3,925,262, Laughlin et al, issued December 9, 1975.
• Builders are generally selected from the various water-soluble alkali metal, ammonium or substituted ammonium phosphates, polyphosphates, phosphonates, polyphosphonates, carbonates, borates, polyhydroxy sulfonates, polyacetates, carboxylates, and polycarboxylates.
• alkali metal especially sodium, salts of the above.
• inorganic phosphate builders are sodium and potassium tripolyphosphate, (Form 11 or hydrated Form 1), polymeric metaphosphate having a degree of polymerization of from 6 to 21, and orthophosphate.
• polyphosphonate builders are the sodium and potassium salts of ethylene diphosphonic acid, the sodium and potassium salts of ethane 1-hydroxy-1,1-diphosphonic acid and the sodium and potassium salts of ethane, 1,1,2-­triphosphonic acid.
• Other phosphorus builder compounds are disclosed in U.S. Patents 3,159,581; 3,213,030; 3,422,021; 3,422,137; 3,400,176; and 3,400,148.
• nonphosphorus, inorganic builders are sodium and potassium carbonate, bicarbonate, sesquicarbonate, and tetraborate decahydrate.
• Water-soluble, nonphosphorus organic builders useful herein include the various alkali metal, ammonium and substituted ammonium polyacetates, carboxylates, polycarboxylates and polyhydroxy sulfonates.
• polyacetate and polycarboxylate builders are the sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylene diamine tetraacetic acid, nitrilotriacetic acid, oxydisuccinic acid, mellitic acid, benzene polycarboxylic acids, and citric acid.
• Polymeric polycarboxylate builders are also described in U.S. Patent 3,308,067, Diehl, issued March 7, 1967. Such materials include the water-soluble salts of homo- and copolymers of aliphatic carboxylic acids such as maleic acid, itaconic acid, mesaconic acid, fumaric acid, aconitic acid, citraconic acid and methylenemalonic acid.
• polyacetal carboxylates are the polyacetal carboxylates described in U.S. Patent 4,144,226, issued March 13, 1979 to Crutchfield et al, and U.S. Patent 4,246,495, issued March 27, 1979 to Crutchfield et al.
• These polyacetal carboxylates can be prepared by bringing together under polymerization conditions an ester of glyoxylic acid and a polymerization initiator. The resulting polyacetal carboxylate ester is then attached to chemically stable end groups to stabilize the polyacetal carboxylate against rapid depolymerization in alkaline solution and converted to the corresponding salt.
• a preferred phosphate builder is Form 11 sodium tripolyphosphate preferably anhydrous.
• a preferred builder for use in compositions that are substantially free of phosphate builders is sodium citrate.
• the builders herein should have the same particle size as the remainder of the composition, as described hereinafter.
• the above granular detergent compositions can be used as is as finished detergent compositions or as detergent additive compositions. However, they are preferably used as (and hereinafter referred to as) detergent base granules which are then admixed or agglomerated with builder material and with other optional ingredients to provide finished detergent compositions exhibiting good solubility.
• Such finished compositions can comprise by weight from 5% to 50%, preferably from 10% to 40%, more preferably from 12% to 25%, of the alkylbenzene sulfonate and alkyl sulfate surfactants herein and from 5% to about 95%, preferably from 10% to 85%, more preferably from 15% to 75%, of detergent builder material, such as described above.
• the amount of pyrophosphate and anhydrous Form 1 tripolyphosphate should be minimised i.e. the finished compositions preferably contain from 0% to 20% preferably from 0% to 10% of such material or mixtures thereof.
• compositions can also contain minor amounts, generally less than 30%, preferably less than 20%, by weight of other ingredients usually included in detergent compositions.
• auxiliary detergent surfactants color speckles, bleaching agents, and bleach activators, suds boosters or suds suppressors, antitarnish and anticorrosion agents, soil suspending agents, soil release agents, dyes, fillers, optical brighteners, germicides, pH adjusting agents, nonbuilder alkalinity sources, enzymes, enzyme-stabilizing agents and perfumes.
• Agglomeration can be accomplished by agitating in the presence of a suitable binder (e.g., in a fluidized bed, tumble mixer, or a rotating drum or pan) or by mechanically mixing under pressure (e.g., extruding, pressing, milling, compacting or pelletizing). Final sizing can then be achieved by grinding and screening.
• a suitable binder e.g., in a fluidized bed, tumble mixer, or a rotating drum or pan
• pressure e.g., extruding, pressing, milling, compacting or pelletizing
• the detergent base granules are admixed with from 0% to 300%, preferably from 25% to 200%, more preferably from 50% to 150%, by weight of the base granules, of a detergent builder material such as described above.
• the resulting admix is then preferably compacted at a relatively low pressure of from 137.9 to 1379 preferably from 275.8 to 1034 more preferably from 344.8 to 689.4 kilo Pascals (kPa).
• the composition is then preferably admixed with an additional 0% to 300%, preferably from 25% to 200%, more preferably from 50% to 150%, by weight of the base granules, of a detergent builder material.
• the above levels and types of builder material and compaction pressure are preferably selected so that the final detergent composition has a bulk density of from 0.55 to 1.2, preferably from 0.65 to 1.1, more preferably from 0.70 to 0.9 g/cc and an average particle size of from 20 to 1500 microns, preferably from 50 to 1200 microns, more preferably from 100 to 800 microns.
• the above compaction step is preferably accomplished by using equipment that applies a relatively uniform compaction pressure, for example, by using compaction rollers with smooth (i.e., noncorrugated) surfaces.
• the composition is preferably granulated and screened to provide an average particle size similar to that desired for the final composition.
• the following granular detergent composition was prepared.
• the base granules were produced by spray-drying an aqueous crutcher mix of the components on a 305 cm tower using a crutcher temperature of 93°C a size 3-1/2 nozzle to make fine granules, and silicone deaeratants. If the base granules contained more than 2% moisture, a second drying stage on a continuous fluid bed was performed to reduce moisture to 2%.
• the base granules were then admixed with powdered STP hexahydrate to form the preblend.
• the preblend was compacted at 344.8 kPa roll pressure on a 10 cm by 25 cm chilsonator, and screened to select a -14(1168 microns)/+65(208 microns) particle size cut (Tyler mesh).
• Oversized particles were collected and granulated on a Fitzmill using a 1168 microns screen and low rpm's. This was screened to select a -20(833 microns)/+48(295 microns) particle size cut. Both materials were dedusted by blowing off fines in a fluid bed dryer using ambient air.
• the admix was prepared at 181.5 kg per batch in a drum mixer. Carbonate, granular STP (with dye sprayed-on), brightener, enzymes, and suds supressor prills were blended with the compacted mainstream product cut and regranulated overs. The ratio of mainstream product cut to overs was 7 to 1. Mineral oil was sprayed on the final admix in 13.6 to 18.1 kg batches at a 1% level using a Forberg Mixer.
• Example 1 is preferably incorporated into a laminated laundry product formed from two plies of water insoluble tissues, at least one of which is water permeable, which are laminated together. At least one of the plies has cup like depressions, surrounded by rims and the other ply being attached to the first ply at the rim to physically separate the cups.
• the laminate is made with plies of the tissue paper described by Trokhan in U.S. Patent 4,529,480, issued July 16, 1985.
• the tissue had good air permeability as set forth in U.S. Patent 4,170,565, Flesher et al, issued October 9, 1979.
• Example 1 When the composition of Example 1 is incorporated in said laminated laundry product, it exhibits superior solubility.
• the following granular detergent composition can be prepared and used according to Example I.

Landscapes

• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Detergent Compositions (AREA)

Applications Claiming Priority (2)

Publications (3)

Family

ID=25137072

Family Applications (1)

Country Status (6)

Cited By (28)

Families Citing this family (4)

Family Cites Families (6)

• 1986
  • 1986-10-08 CA CA000520140A patent/CA1275019A/fr not_active Expired
  • 1986-10-08 AU AU63597/86A patent/AU582519B2/en not_active Ceased
  • 1986-10-09 NZ NZ21787786A patent/NZ217877A/xx unknown
  • 1986-10-09 JP JP61241128A patent/JPH07116476B2/ja not_active Expired - Lifetime
  • 1986-10-09 DE DE19863688821 patent/DE3688821T2/de not_active Expired - Fee Related
  • 1986-10-09 EP EP19860307798 patent/EP0220024B1/fr not_active Expired - Lifetime

Also Published As

Similar Documents

Legal Events