EP0234334A2 - Agent de lavage et de nettoyage pour matières textiles - Google Patents

Agent de lavage et de nettoyage pour matières textiles Download PDF

Info

Publication number: EP0234334A2
Authority: EP; European Patent Office
Prior art keywords: percent; embodiment according; weight; detergent; amounts
Prior art date: 1986-02-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP87101333A

Other languages

German (de)

English (en)

Other versions

EP0234334A3 (fr

Inventor

Alfred Dr. Meffert

Brigitte Giesen

Andreas Dr. Syldatk

Ingo Wegener

Horst Dr. Upadek

Johann Friedrich Dr. Fues

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-02-08

Filing date

1987-01-31

Publication date

1987-09-02

1987-01-31 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

1987-09-02 Publication of EP0234334A2 publication Critical patent/EP0234334A2/fr

1989-06-28 Publication of EP0234334A3 publication Critical patent/EP0234334A3/fr

Status Withdrawn legal-status Critical Current

Links

239000004753 textile Substances 0.000 title claims abstract description 21
238000005406 washing Methods 0.000 title claims description 13
239000012459 cleaning agent Substances 0.000 title claims description 5
239000003599 detergent Substances 0.000 claims abstract description 38
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 26
239000000194 fatty acid Substances 0.000 claims abstract description 26
229930195729 fatty acid Natural products 0.000 claims abstract description 26
150000004665 fatty acids Chemical class 0.000 claims abstract description 25
-1 fatty alcohol sulfate Chemical class 0.000 claims abstract description 23
239000004094 surface-active agent Substances 0.000 claims abstract description 20
150000004760 silicates Chemical class 0.000 claims abstract description 8
229930182470 glycoside Natural products 0.000 claims abstract description 7
230000000694 effects Effects 0.000 claims description 16
125000004432 carbon atom Chemical group C* 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 9
150000003839 salts Chemical class 0.000 claims description 7
150000002191 fatty alcohols Chemical class 0.000 claims description 4
229910021647 smectite Inorganic materials 0.000 claims description 4
102000004190 Enzymes Human genes 0.000 claims description 3
108090000790 Enzymes Proteins 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 3
238000004140 cleaning Methods 0.000 claims description 3
229910052901 montmorillonite Inorganic materials 0.000 claims description 3
125000003277 amino group Chemical group 0.000 claims description 2
239000000975 dye Substances 0.000 claims description 2
125000001033 ether group Chemical group 0.000 claims description 2
239000003205 fragrance Substances 0.000 claims description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
125000003563 glycoside group Chemical group 0.000 claims 2
239000003513 alkali Substances 0.000 claims 1
150000001412 amines Chemical class 0.000 claims 1
239000007859 condensation product Substances 0.000 claims 1
229910052615 phyllosilicate Inorganic materials 0.000 claims 1
229920000233 poly(alkylene oxides) Polymers 0.000 claims 1
239000000126 substance Substances 0.000 claims 1
239000002736 nonionic surfactant Substances 0.000 abstract description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 2
239000000203 mixture Substances 0.000 description 16
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
238000009472 formulation Methods 0.000 description 5
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 5
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
229910021536 Zeolite Inorganic materials 0.000 description 3
239000000654 additive Substances 0.000 description 3
230000003712 anti-aging effect Effects 0.000 description 3
229940094522 laponite Drugs 0.000 description 3
XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 3
239000000463 material Substances 0.000 description 3
238000006384 oligomerization reaction Methods 0.000 description 3
235000019353 potassium silicate Nutrition 0.000 description 3
229960001922 sodium perborate Drugs 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
239000003760 tallow Substances 0.000 description 3
239000010457 zeolite Substances 0.000 description 3
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000013543 active substance Substances 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
239000000470 constituent Substances 0.000 description 2
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
239000002979 fabric softener Substances 0.000 description 2
239000008103 glucose Substances 0.000 description 2
229910000271 hectorite Inorganic materials 0.000 description 2
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 2
239000000843 powder Substances 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
229910000275 saponite Inorganic materials 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
VNSBYDPZHCQWNB-UHFFFAOYSA-N calcium;aluminum;dioxido(oxo)silane;sodium;hydrate Chemical compound O.[Na].[Al].[Ca+2].[O-][Si]([O-])=O VNSBYDPZHCQWNB-UHFFFAOYSA-N 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
229940096386 coconut alcohol Drugs 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000008021 deposition Effects 0.000 description 1
238000001035 drying Methods 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
229930182478 glucoside Natural products 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000000034 method Methods 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
229920001542 oligosaccharide Polymers 0.000 description 1
150000002482 oligosaccharides Chemical class 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
150000003141 primary amines Chemical class 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
150000003335 secondary amines Chemical class 0.000 description 1
229910000269 smectite group Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
238000006277 sulfonation reaction Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
230000003655 tactile properties Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives

Definitions

Granular detergent compositions containing builders which - in addition to the usual textile detergent components, in particular based on wash-active surfactants and builder systems therefor - contain highly swellable, water-insoluble, finely divided smectite clays, have been described in numerous numbers in the literature. Reference is made, for example, to DE-AS 23 34 899, DE-OSes 32 06 265, 32 06 379, 33 11 368, 33 11 782, 33 12 774 and 33 44 099.
the use of the insoluble, finely divided smectite clays, in particular corresponding montmorillonites , Hectorite and / or Saponite is said to give the textile detergent, in addition to its cleaning action, the ability to soften the washed textile, so that washing and softening can be combined in one operation.
the options for softening that have so far been adjustable in practice are extremely limited. At best, hardly noticeable softening effects are achieved in the washed and dried textile.
the subsequent treatment of the washed textiles in the rinsing bath or in a subsequent treatment step with the known fabric softeners based on quaternary ammonium compounds has so far been indispensable if really noticeable effects are to be achieved with regard to the fabric softening.
the present invention is based on the finding that surprisingly strong washing bath vivage effects can be obtained if the known, highly swellable, insoluble, finely divided layered silicates with an anti-aging effect in combination with disalts alpha-sulfonated fatty acids and / or in combinations. tion with certain selected surfactants are used.
an increased anti-aging effect can also be achieved according to the invention by selecting very specific surfactant components.
these selected surfactants are used together with the swellable layered silicates (component a) and the disalts (component b), optimal results are achieved both in the direction of a high-quality washing result and in the direction of a high-quality finishing result.
the selected surfactants (components c) are used in total in amounts of up to about 25 percent by weight, preferably in the range of about 4 to 20 percent by weight, in each case based on the total dry detergent. 5 to 15 percent by weight of these surfactants can be a particularly useful range.
the selected surfactant components are fatty alcohol sulfates (c 1), possibly in a mixture with alkyl glycosides (c 2), as the main surfactant components.
the fatty acid alkanolamides (c 3) and / or ether amines (c 4) are present in smaller amounts.
about 50 to 80 percent by weight of the selected surfactant components can be formed by compounds of classes c 1 and / or c 2, while the rest are washing-strengthening components of groups c 3 and / or c 4.
washing-active nonionic surfactant components which are formed by polyalkoxylation of fatty alcohols and / or alkylphenols, are not used. It turns out that by using at least considerable amounts of such in detergents per se. usual nonionics, the aviva effect can be substantially impaired.
Bleaching components especially peroxide compounds such as sodium perborate.
the sum of components a to c essential to the invention can make up, for example, 20 to 80 percent by weight, preferably 25 to 65 percent by weight, in each case based on the total dry detergent mixture, in the detergent mixtures according to the invention.
the rest is formed by the usual detergent ingredients listed above.
Test rags made of terry towels, molton and knitwear are subjected to a 60 ° C wash 3 times in household drum machines together with the usual standard household laundry items. After each wash, the test rags are dried hanging under the conditions of a normal linen drying. The dried test rags are tactile evaluated after the 1st and 3rd wash in a test panel consisting of 5 selected people.
the test subjects have the task of assigning the tactile properties of each flap to a range of grades from -6 to +6, whereby only half or full grades are assigned.
the grades obtained for each rag are averaged and the differences in the mean values are checked for statistical significance.
the unit of averaged grip grade and ranking is used to evaluate the individual recipes.
a high-quality standard detergent without additives is used in the parallel test with a grade of 0.0.
a common standard detergent with the addition of wash bath leveling reaches a value of 0.22 after the 1st wash and 0.24 after the 3rd wash.

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

EP87101333A 1986-02-08 1987-01-31 Agent de lavage et de nettoyage pour matières textiles Withdrawn EP0234334A3 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE3604039		1986-02-08
DE19863604039 DE3604039A1 (de)	1986-02-08	1986-02-08	Textil-wasch- und reinigungsmittel

Publications (2)

Publication Number	Publication Date
EP0234334A2 true EP0234334A2 (fr)	1987-09-02
EP0234334A3 EP0234334A3 (fr)	1989-06-28

Family

ID=6293729

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP87101333A Withdrawn EP0234334A3 (fr)	1986-02-08	1987-01-31	Agent de lavage et de nettoyage pour matières textiles

Country Status (4)

Country	Link
EP (1)	EP0234334A3 (fr)
JP (1)	JPS62185799A (fr)
DE (1)	DE3604039A1 (fr)
PH (1)	PH24006A (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0302402A3 (fr) *	1987-08-07	1989-11-29	Henkel Kommanditgesellschaft auf Aktien	Agents de lavage et de nettoyage pour le linge
EP0302403A3 (fr) *	1987-08-07	1989-11-29	Henkel Kommanditgesellschaft auf Aktien	Agents de lavage et de nettoyage pour le linge
WO2015104162A1 (fr) *	2014-01-07	2015-07-16	Henkel Ag & Co. Kgaa	Détergents contenant un alcanolamide

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3812555A1 (de) *	1988-04-15	1989-10-26	Hoechst Ag	Lagerstabilisiertes waschmittel mit verstaerkter bleichwirkung
DE3812556A1 (de) *	1988-04-15	1989-10-26	Hoechst Ag	Waschmittel mit lagerstabilisiertem bleichsystem
DE4021694A1 (de) *	1990-07-07	1992-01-09	Henkel Kgaa	Neue thiodiglykolalkxylat-derivate, verfahren zu ihrer herstellung und ihre verwendung als weichmacher fuer textilien
DE4204885A1 (de) *	1992-02-19	1993-08-26	Henkel Kgaa	Thiodiglykol-derivate, verfahren zu ihrer herstellung und deren verwendung zum weichmachen von textilien
US5871590A (en) *	1997-02-25	1999-02-16	Ecolab Inc.	Vehicle cleaning and drying compositions

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3069588D1 (en) *	1979-07-05	1984-12-13	Procter & Gamble	Detergent composition having textile softening property
GB8331823D0 (en) *	1983-11-29	1984-01-04	Procter & Gamble	Laundry compositions
GB8333816D0 (en) *	1983-12-20	1984-02-01	Procter & Gamble	Fabric softening compositions

1986
- 1986-02-08 DE DE19863604039 patent/DE3604039A1/de not_active Withdrawn
1987
- 1987-01-31 EP EP87101333A patent/EP0234334A3/fr not_active Withdrawn
- 1987-02-05 PH PH34817A patent/PH24006A/en unknown
- 1987-02-09 JP JP2798387A patent/JPS62185799A/ja active Pending

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0302402A3 (fr) *	1987-08-07	1989-11-29	Henkel Kommanditgesellschaft auf Aktien	Agents de lavage et de nettoyage pour le linge
EP0302403A3 (fr) *	1987-08-07	1989-11-29	Henkel Kommanditgesellschaft auf Aktien	Agents de lavage et de nettoyage pour le linge
WO2015104162A1 (fr) *	2014-01-07	2015-07-16	Henkel Ag & Co. Kgaa	Détergents contenant un alcanolamide

Also Published As

Publication number	Publication date
EP0234334A3 (fr)	1989-06-28
DE3604039A1 (de)	1987-08-20
PH24006A (en)	1990-02-09
JPS62185799A (ja)	1987-08-14

Legal Events

Date	Code	Title	Description
1987-07-18	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
1987-09-02	AK	Designated contracting states	Kind code of ref document: A2 Designated state(s): AT BE CH DE ES FR GB IT LI NL SE
1989-05-11	PUAL	Search report despatched	Free format text: ORIGINAL CODE: 0009013
1989-06-28	AK	Designated contracting states	Kind code of ref document: A3 Designated state(s): AT BE CH DE ES FR GB IT LI NL SE
1990-01-17	17P	Request for examination filed	Effective date: 19891123
1990-03-21	17Q	First examination report despatched	Effective date: 19900201
1991-01-14	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN
1991-02-20	18W	Application withdrawn	Withdrawal date: 19901219
1991-03-06	R18W	Application withdrawn (corrected)	Effective date: 19901219
2007-08-08	RIN1	Information on inventor provided before grant (corrected)	Inventor name: GIESEN, BRIGITTE Inventor name: SYLDATK, ANDREAS, DR. Inventor name: MEFFERT, ALFRED, DR. Inventor name: WEGENER, INGO Inventor name: UPADEK, HORST, DR. Inventor name: FUES, JOHANN FRIEDRICH, DR.

Publication	Publication Date	Title
DE2857292C2 (fr)	1992-07-02
DE2334899C2 (de)	1983-12-22	Körniges, gerüststoffhaltiges Waschmittel zum gleichzeitigen Waschen und Weichmachen von Textilien
DE2215371A1 (de)	1972-10-19	Waschmittel
EP0554287B1 (fr)	1995-08-02	Adjuvant pour produit de lavage
DE2636673A1 (de)	1977-02-24	Gewebeweichmacher
DE3842007A1 (de)	1990-06-21	Fluessiges bis pastoeses, bleichmittelhaltiges waschmittel
DE2337266C2 (de)	1984-06-28	Weichspülendes teilchenförmiges Grobwaschmittel
EP0364739A2 (fr)	1990-04-25	Détergent pour basses températures
DE69229301T2 (de)	1999-12-09	Zeolitharmes oder zeolithfreies Waschmittel
DE2211576C3 (de)	1982-01-28	Verwendung von quaternären Benzimidazolen als Textilweichmacher mit gleichzeitiger schmutzfreisetzender Wirkung
DE2638901C2 (de)	1987-02-26	Reinigungsmittelmischung
WO1993011214A1 (fr)	1993-06-10	Produits de lavage et detergents
DE68919601T3 (de)	1998-02-26	Waschmittelzusammensetzungen.
DE69032814T2 (de)	1999-04-29	Reinigungsverstärkeradditiv und dies enthaltendes Detergentsystem
EP0234334A2 (fr)	1987-09-02	Agent de lavage et de nettoyage pour matières textiles
DE69628239T2 (de)	2004-04-01	Waschzusammensetzung und Verwendung von Polymer zur Reinigung und Schmutzwiderstand von einem Artikel
DE2300658C2 (de)	1983-10-06	Weichmachungsmittel für Textilien mit gleichzeitiger schmutzfreisetzender und antistatischer Wirkung
DE3486155T2 (de)	1993-12-16	Wäschewaschmittel.
DE1939973C3 (de)	1978-03-23	Wasch- und Reinigungsmittel
EP0758678A2 (fr)	1997-02-19	Agent de nettoyage pour le vêtement protecteur de travail
DE3644808A1 (de)	1988-07-14	Phosphatfreies waschmittel mit verringerter schaumneigung
DE2911585C2 (fr)	1987-12-10
EP0302402A2 (fr)	1989-02-08	Agents de lavage et de nettoyage pour le linge
DE3643334A1 (de)	1987-07-09	Zusatz fuer ein koerniges wasch- und reinigungsmittel
DE3931871A1 (de)	1991-04-04	Granulares, phosphatfreies wasserenthaertungsmittel

EP0234334A2 - Agent de lavage et de nettoyage pour matières textiles - Google Patents

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ID=6293729

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Cited By (3)

Families Citing this family (5)

Family Cites Families (3)

Cited By (3)

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