EP0252386A1 - Procédé pour améliorer la solidité à la lumière de teinture de polyamide - Google Patents
Procédé pour améliorer la solidité à la lumière de teinture de polyamide Download PDFInfo
- Publication number
- EP0252386A1 EP0252386A1 EP87109228A EP87109228A EP0252386A1 EP 0252386 A1 EP0252386 A1 EP 0252386A1 EP 87109228 A EP87109228 A EP 87109228A EP 87109228 A EP87109228 A EP 87109228A EP 0252386 A1 EP0252386 A1 EP 0252386A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- copper
- compounds
- improving
- dyeings
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004043 dyeing Methods 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 15
- 239000004952 Polyamide Substances 0.000 title claims abstract description 10
- 229920002647 polyamide Polymers 0.000 title claims abstract description 10
- 239000005749 Copper compound Substances 0.000 claims abstract description 15
- 150000001880 copper compounds Chemical class 0.000 claims abstract description 15
- 239000000835 fiber Substances 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 6
- -1 aromatic hydroxycarbonyl compounds Chemical class 0.000 claims abstract description 5
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 claims abstract description 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 3
- 150000002367 halogens Chemical class 0.000 claims abstract description 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims abstract description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 3
- 125000001424 substituent group Chemical group 0.000 claims abstract description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 10
- SMQUZDBALVYZAC-UHFFFAOYSA-N salicylaldehyde Chemical compound OC1=CC=CC=C1C=O SMQUZDBALVYZAC-UHFFFAOYSA-N 0.000 claims description 7
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 5
- 229960004889 salicylic acid Drugs 0.000 claims description 5
- FUGKCSRLAQKUHG-UHFFFAOYSA-N 5-chloro-2-hydroxybenzaldehyde Chemical compound OC1=CC=C(Cl)C=C1C=O FUGKCSRLAQKUHG-UHFFFAOYSA-N 0.000 claims description 3
- NKBASRXWGAGQDP-UHFFFAOYSA-N 5-chlorosalicylic acid Chemical compound OC(=O)C1=CC(Cl)=CC=C1O NKBASRXWGAGQDP-UHFFFAOYSA-N 0.000 claims description 3
- XAICWTLLSRXZPB-UHFFFAOYSA-N 5-tert-butyl-2-hydroxybenzoic acid Chemical compound CC(C)(C)C1=CC=C(O)C(C(O)=O)=C1 XAICWTLLSRXZPB-UHFFFAOYSA-N 0.000 claims description 3
- 238000004040 coloring Methods 0.000 claims description 3
- 239000000434 metal complex dye Substances 0.000 claims description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 3
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 2
- DLGBEGBHXSAQOC-UHFFFAOYSA-N 2-hydroxy-5-methylbenzoic acid Chemical compound CC1=CC=C(O)C(C(O)=O)=C1 DLGBEGBHXSAQOC-UHFFFAOYSA-N 0.000 claims description 2
- 229910006069 SO3H Inorganic materials 0.000 claims description 2
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 2
- IHIZFBWFXODXJS-UHFFFAOYSA-N n-tert-butyl-2-[4-[(5,5-dioxo-2-phenyl-7,8-dihydro-6h-thiopyrano[3,2-d]pyrimidin-4-yl)amino]phenyl]acetamide Chemical compound C1=CC(CC(=O)NC(C)(C)C)=CC=C1NC1=NC(C=2C=CC=CC=2)=NC2=C1S(=O)(=O)CCC2 IHIZFBWFXODXJS-UHFFFAOYSA-N 0.000 claims description 2
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 239000000975 dye Substances 0.000 description 12
- 239000010949 copper Substances 0.000 description 11
- 150000004699 copper complex Chemical class 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000001879 copper Chemical class 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000002657 fibrous material Substances 0.000 description 3
- JJVNINGBHGBWJH-UHFFFAOYSA-N ortho-vanillin Chemical compound COC1=CC=CC(C=O)=C1O JJVNINGBHGBWJH-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical class [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 2
- 235000019799 monosodium phosphate Nutrition 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 150000003839 salts Chemical group 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- MFSJUURIAOOSJR-UHFFFAOYSA-N 2-hydroxy-5-(2,4,4-trimethylpentan-2-yl)benzoic acid Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(C(O)=O)=C1 MFSJUURIAOOSJR-UHFFFAOYSA-N 0.000 description 1
- UXMQLRNDJOZAPS-UHFFFAOYSA-N 2-hydroxy-5-methylbenzoic acid Chemical compound CC1=CC=C(O)C(C(O)=O)=C1.CC1=CC=C(O)C(C(O)=O)=C1 UXMQLRNDJOZAPS-UHFFFAOYSA-N 0.000 description 1
- HLOISCHRUFNEBE-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carboxylic acid Chemical compound OC1=C(C2=CC=CC=C2C=C1)C(=O)O.OC1=C(C2=CC=CC=C2C=C1)C(=O)O HLOISCHRUFNEBE-UHFFFAOYSA-N 0.000 description 1
- UJYZTZFCXKRHCX-UHFFFAOYSA-N 4-hydroxybenzene-1,3-dicarboxylic acid Chemical compound OC1=C(C=C(C(=O)O)C=C1)C(=O)O.OC1=C(C=C(C(=O)O)C=C1)C(=O)O UJYZTZFCXKRHCX-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000002262 Schiff base Substances 0.000 description 1
- 150000004753 Schiff bases Chemical class 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- OVFCVRIJCCDFNQ-UHFFFAOYSA-N carbonic acid;copper Chemical compound [Cu].OC(O)=O OVFCVRIJCCDFNQ-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003426 co-catalyst Substances 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- 229910000009 copper(II) carbonate Inorganic materials 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- CMRVDFLZXRTMTH-UHFFFAOYSA-L copper;2-carboxyphenolate Chemical compound [Cu+2].OC1=CC=CC=C1C([O-])=O.OC1=CC=CC=C1C([O-])=O CMRVDFLZXRTMTH-UHFFFAOYSA-L 0.000 description 1
- 239000011646 cupric carbonate Substances 0.000 description 1
- 235000019854 cupric carbonate Nutrition 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- FPVGTPBMTFTMRT-UHFFFAOYSA-L disodium;2-amino-5-[(4-sulfonatophenyl)diazenyl]benzenesulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005580 one pot reaction Methods 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 229940058287 salicylic acid derivative anticestodals Drugs 0.000 description 1
- 150000003872 salicylic acid derivatives Chemical class 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229960004025 sodium salicylate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000004584 weight gain Effects 0.000 description 1
- 235000019786 weight gain Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6536—Aromatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/503—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms without bond between a carbon atom and a metal or a boron, silicon, selenium or tellurium atom
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65112—Compounds containing aldehyde or ketone groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65125—Compounds containing ester groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/241—Polyamides; Polyurethanes using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
Definitions
- auxiliaries have so far not been able to fully meet the high demands of automobile manufacturers, since the effects achieved were not quite sufficient.
- Some of the auxiliaries also have an undesirable inherent color and / or are relatively expensive because of their complex production method.
- the copper compounds normally produced separately are used in finely divided form, as is obtained by grinding in the presence of customary dispersants.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3622864 | 1986-07-08 | ||
| DE19863622864 DE3622864A1 (de) | 1986-07-08 | 1986-07-08 | Verfahren zur verbesserung der lichtechtheit von polyamidfaerbungen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0252386A1 true EP0252386A1 (fr) | 1988-01-13 |
| EP0252386B1 EP0252386B1 (fr) | 1989-12-13 |
Family
ID=6304625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP87109228A Expired EP0252386B1 (fr) | 1986-07-08 | 1987-06-26 | Procédé pour améliorer la solidité à la lumière de teinture de polyamide |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0252386B1 (fr) |
| JP (1) | JPS6321986A (fr) |
| DE (2) | DE3622864A1 (fr) |
| ES (1) | ES2012074B3 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4775386A (en) * | 1986-05-05 | 1988-10-04 | Ciba-Geigy Corporation | Process for photochemical stabilization of undyed and dyed polyamide fibre material and blends thereof with other fibres: copper complex and light stabilizer treatment |
| EP0413146A1 (fr) * | 1989-07-29 | 1991-02-20 | Bayer Ag | Préparation sèche d'un mélange pour améliorer la résistance à la lumière |
| US5045083A (en) * | 1989-02-22 | 1991-09-03 | Sandoz Ltd. | Light-fast dyeing of synthetic polyamide fibers: anionic dye, oxazolo-anilide and a copper complex |
| US5076808A (en) * | 1989-12-14 | 1991-12-31 | Basf Aktiengesellschaft | Dyeing of polyamide substrates with an organic n-nitroso-hydroxylamine as light stabilizer |
| KR101495050B1 (ko) * | 2014-10-21 | 2015-02-25 | 아이씨이아이우방(주) | 이온성 일광견뢰도 증진제 및 이를 포함하는 염색조제 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119768485A (zh) * | 2022-09-16 | 2025-04-04 | 东丽株式会社 | 颜色转换组合物、颜色转换片材、光源单元、显示装置以及照明装置 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB689629A (en) * | 1950-01-20 | 1953-04-01 | Ici Ltd | Compositions comprising nylon |
| US3226178A (en) * | 1962-10-31 | 1965-12-28 | Du Pont | Process for dyeing and aftertreating polyethylene oxide modified nylon fibers |
| DE1264388B (de) * | 1962-10-10 | 1968-03-28 | Basf Ag | Verfahren zur Verbesserung der thermischen Bestaendigkeit von Faerbungen auf Gebilden aus linearen Polyestern bzw. deren Mischungen mit Cellulose- oder animalischen Fasern |
| EP0162811A1 (fr) * | 1984-05-22 | 1985-11-27 | Ciba-Geigy Ag | Procédé de stabilisation photochimique de matériaux textiles contenant des fibres en polyamide |
| EP0181836A1 (fr) * | 1984-11-09 | 1986-05-21 | Ciba-Geigy Ag | Procédé d'amélioration de la solidité à la lumière de cuirs teints |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5756590A (en) * | 1980-09-16 | 1982-04-05 | Toray Industries | Treatment for enhancing light fastness of dyed polyamide fiber |
| DE3041153A1 (de) * | 1980-10-31 | 1982-06-16 | Bayer Ag, 5090 Leverkusen | Verfahren zur verbesserung der lichtechtheit von polyamidfaerbungen |
-
1986
- 1986-07-08 DE DE19863622864 patent/DE3622864A1/de not_active Withdrawn
-
1987
- 1987-06-26 ES ES87109228T patent/ES2012074B3/es not_active Expired - Lifetime
- 1987-06-26 DE DE8787109228T patent/DE3761152D1/de not_active Expired - Lifetime
- 1987-06-26 EP EP87109228A patent/EP0252386B1/fr not_active Expired
- 1987-07-06 JP JP62167142A patent/JPS6321986A/ja active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB689629A (en) * | 1950-01-20 | 1953-04-01 | Ici Ltd | Compositions comprising nylon |
| DE1264388B (de) * | 1962-10-10 | 1968-03-28 | Basf Ag | Verfahren zur Verbesserung der thermischen Bestaendigkeit von Faerbungen auf Gebilden aus linearen Polyestern bzw. deren Mischungen mit Cellulose- oder animalischen Fasern |
| US3226178A (en) * | 1962-10-31 | 1965-12-28 | Du Pont | Process for dyeing and aftertreating polyethylene oxide modified nylon fibers |
| EP0162811A1 (fr) * | 1984-05-22 | 1985-11-27 | Ciba-Geigy Ag | Procédé de stabilisation photochimique de matériaux textiles contenant des fibres en polyamide |
| EP0181836A1 (fr) * | 1984-11-09 | 1986-05-21 | Ciba-Geigy Ag | Procédé d'amélioration de la solidité à la lumière de cuirs teints |
Non-Patent Citations (2)
| Title |
|---|
| CHEMICAL ABSTRACTS, Band 101, Nr. 20, November 1984, Seiten 107-108, Zusammenfassung Nr. 173255u, Columbus, Ohio, US; & JP-A-59 53 564 (DAINIPPON TORYO CO., LTD) 28-03-1984 * |
| CHEMICAL ABSTRACTS, Band 96, Nr. 16, April 1982, Seite 88, Zusammenfassung Nr. 124453b, Columbus, Ohio, US; & JP-A-82 05 987 (SAND K.K.) 12-01-1982 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4775386A (en) * | 1986-05-05 | 1988-10-04 | Ciba-Geigy Corporation | Process for photochemical stabilization of undyed and dyed polyamide fibre material and blends thereof with other fibres: copper complex and light stabilizer treatment |
| US5045083A (en) * | 1989-02-22 | 1991-09-03 | Sandoz Ltd. | Light-fast dyeing of synthetic polyamide fibers: anionic dye, oxazolo-anilide and a copper complex |
| EP0413146A1 (fr) * | 1989-07-29 | 1991-02-20 | Bayer Ag | Préparation sèche d'un mélange pour améliorer la résistance à la lumière |
| US5076808A (en) * | 1989-12-14 | 1991-12-31 | Basf Aktiengesellschaft | Dyeing of polyamide substrates with an organic n-nitroso-hydroxylamine as light stabilizer |
| KR101495050B1 (ko) * | 2014-10-21 | 2015-02-25 | 아이씨이아이우방(주) | 이온성 일광견뢰도 증진제 및 이를 포함하는 염색조제 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6321986A (ja) | 1988-01-29 |
| DE3622864A1 (de) | 1988-01-21 |
| DE3761152D1 (de) | 1990-01-18 |
| ES2012074B3 (es) | 1990-03-01 |
| EP0252386B1 (fr) | 1989-12-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2708188C2 (de) | Stabilisierung anionischer Indolfarbstoffe | |
| EP0113856B1 (fr) | Procédé pour améliorer la solidité à la lumière de teintures de polyamide | |
| DE4031650C2 (de) | Farbstoffgemische und ihre Verwendung in Trichromie-Färbeprozessen | |
| EP0252386B1 (fr) | Procédé pour améliorer la solidité à la lumière de teinture de polyamide | |
| EP0230045B1 (fr) | Procédé de teinture de fibres en polyamide | |
| DE2338681C2 (de) | Sulfonsäuregruppenfreie basische Azoverbindungen, deren Herstellung und Verwendung | |
| DE2917996A1 (de) | Organische verbindungen, deren herstellung und verwendung | |
| DE2819197C2 (fr) | ||
| DE2122232B2 (de) | Anthrachinonverbindungen, Verfahren zu deren Herstellung und deren Verwendung | |
| DE69209725T2 (de) | Monoazofarbstoff | |
| DE2712289B2 (de) | Verfahren zum Färben oder Bedrucken von Polyacrylnitrilmaterial | |
| DE2125098C3 (de) | Alkalibeständige unechte Farbstoffe und deren Verwendung | |
| CH649774A5 (de) | Wasserloesliche azoverbindungen. | |
| DE3427806C2 (fr) | ||
| DE3029746A1 (de) | Organische verbindungen, deren herstellung und verwendung | |
| DE2101223C3 (de) | SuIfonsäuregruppenfreie basische Styrylfarbstoffe, ihre Herstellung und Verwendung | |
| DE2839429A1 (de) | Anthrachinon-reaktivfarbstoffverbindungen | |
| EP0474594A1 (fr) | Procédé de teinture de la laine et ses mélanges avec d'autres fibres avec des colorants réactifs | |
| EP0522339A2 (fr) | Colorants de type formazane ayant un reste réactif difluorpyrimidinique | |
| DE3205168A1 (de) | Anionische disazoverbindungen, verfahren zur herstellung und verwendung | |
| DE2400654C2 (de) | Sulfonsäuregruppenhaltige Disazoverbindungen, Verfahren zu deren Herstellung und deren Verwendung | |
| DE1569839C (de) | Metallhaltige oder metallfreie Phthalocyamnverbindungen, Verfahren zu ihrer Her stellung und ihre Verwendung zum Farben | |
| DE2637883A1 (de) | Organische verbindungen | |
| DE2150854A1 (de) | Blaue Antrachinon-Farbstoffe zum unterschiedlichen Einfaerben von Polyamiden | |
| DE2130109A1 (de) | Verfahren zur Herstellung von Monoazoverbindungen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19870626 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): BE CH DE ES FR GB IT LI |
|
| 17Q | First examination report despatched |
Effective date: 19890127 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): BE CH DE ES FR GB IT LI |
|
| ITF | It: translation for a ep patent filed | ||
| ET | Fr: translation filed | ||
| REF | Corresponds to: |
Ref document number: 3761152 Country of ref document: DE Date of ref document: 19900118 |
|
| GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 19900628 Year of fee payment: 4 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed | ||
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF THE APPLICANT RENOUNCES Effective date: 19910627 |
|
| ITTA | It: last paid annual fee | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19930623 Year of fee payment: 7 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19930629 Year of fee payment: 7 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 19940516 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19940527 Year of fee payment: 8 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 19940616 Year of fee payment: 8 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Effective date: 19940630 Ref country code: BE Effective date: 19940630 Ref country code: CH Effective date: 19940630 |
|
| BERE | Be: lapsed |
Owner name: BAYER A.G. Effective date: 19940630 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Effective date: 19950626 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 19950626 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Effective date: 19960229 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Effective date: 19960301 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 19991007 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED. Effective date: 20050626 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Effective date: 19940630 |