Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
  • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
  • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
  • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
  • D06N3/065—PVC together with other resins except polyurethanes
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
  • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
  • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
  • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
  • D06N3/128—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with silicon polymers
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
  • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
  • D06N7/0005—Floor covering on textile basis comprising a fibrous substrate being coated with at least one layer of a polymer on the top surface
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31652—Of asbestos
  • Y10T428/31663—As siloxane, silicone or silane

Definitions

• the present invention relates to a method for manufacturing floor or wall coverings based on plastisol, having improved resistance to soiling. It also relates to a floor or wall covering obtained by said process.
• the object of the present invention is to provide a method of manufacturing floor or wall coverings based on plastisol comprising a wear layer having improved resistance to soiling, in particular to soiling by the heels of shoes.
• Another object of the present invention is to provide a floor covering having a wear layer based on plastisol of a new type.
• An additional object of the present invention is to provide a floor covering having a plastisol-based wear layer having improved resistance to soiling, in particular to soiling due on the heels of shoes, even after repeated washing and / or cleaning.
• the method of manufacturing floor or wall covering based on plastisol, having improved resistance to soiling is characterized in that it is deposited on a decorative support, as a layer of wear, a mixture of plastisol containing a silicone polymer, a crosslinking agent and optionally a catalyst and in that the pregelling and gelling of the wear layer are carried out.
• the silicone polymer is incompatible with the plastisol of the wear layer.
• the crosslinking of the silicone polymer is carried out at the same time as the gelling of the plastisol of the wear layer.
• the silicone polymer is allowed to migrate to the surface by controlling the crosslinking thereof which is preferably carried out at the same time as the gelling of the plastisol, thanks to the appropriate choice of the catalyst / crosslinking agent couple and by the proper dosage of these.
• the silicone polymer used consists of a silicone gum carrying functional -OH groups.
• the crosslinking agent may consist of a silicone-based fluid with reactive -H groups. It may however also consist of an isocyanate which may be of the blocked type. When a blocked type isocyanate is used, the system and the release of -NCO- groups allowing the crosslinking of the silicone polymer to -OH groups is triggered at a relatively high temperature but below the maximum working temperature, for example 130 ° C.
• 0.1 to 10% of silicone polymer carrying OH groups and allowing crosslinking in the plastisol of the wear layer is between 10/10 and 10 / 0.1.
• the catalyst / silicone ratio can be between 0.1 and 0.001.
• a floor or wall covering characterized in that it comprises a decorative support obtained according to methods known per se, coated with a wear layer based on of plastisol containing a crosslinked silicone polymer.
• micronized polyethylene wax can be added to the plastisol mixture intended to form the wear layer.
• the crosslinked silicone polymer is found at a higher surface density than at the core of said wear layer.
• the silicone polymer used is a gum of the type Q 2 32 38 (trade name) from Dow Corning carrying functional -OH groups.
• the crosslinking agent is Dow Corning 1107 Fluid which contains silicone -H groups.
• non-crosslinked silicone gum (1) avoids immediate soiling but does not prevent the relatively heavy soiling after a few cleaning cycles. This is due to the fact that the silicone is not crosslinked and is in an emulsifiable system washable with cleaning water.
• Tests (2), (3) and (4) show that thanks to the use of a crosslinking agent for the silicone polymer, the resistance to soiling is notably improved, even after 100 cleaning cycles.
• test no. 4 Through the use of a catalytic system which adapts the crosslinking in order to allow surface migration of the silicone polymer incompatible with the plastisol in which it is mixed.
• a polyaliphatic polyisocyanate in solution containing about 8% free isocyanate was used as the crosslinking agent.
• this crosslinking agent Thanks to the use of this crosslinking agent, the ability of the product obtained to be stored is improved and the migration of the silicones on the surface is favored, since the release of the blocked NCO groups is only carried out from with a temperature of the order of 130 ° C.
• composition used is: - PVC 100 plastisol - silicone polymer (Q 2 32 38 Dow Corning) 1.25 - micronized polyethylene wax 2 - crosslinking agent: HÜLS IPDI B 1370 (trade name) 0.35 - tin catalyst (dibutyltin dilaurate) 0.001
• the plastisol mixture used can be stored for an extended period without undergoing crosslinking of the silicone system.

Landscapes

• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Chemical & Material Sciences (AREA)
• Dispersion Chemistry (AREA)
• Paints Or Removers (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Floor Finish (AREA)
• Application Of Or Painting With Fluid Materials (AREA)
• Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
• Laminated Bodies (AREA)
• Panels For Use In Building Construction (AREA)
• Polysaccharides And Polysaccharide Derivatives (AREA)
• Curing Cements, Concrete, And Artificial Stone (AREA)
• Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
• Finishing Walls (AREA)

Priority Applications (1)

Applications Claiming Priority (2)

Publications (2)

Family

ID=19730790

Family Applications (1)

Country Status (19)

Families Citing this family (8)

Citations (3)

Family Cites Families (5)

• 1986
  • 1986-10-03 LU LU86620A patent/LU86620A1/xx unknown
• 1987
  • 1987-09-01 FR FR8712126A patent/FR2604714B1/fr not_active Expired - Fee Related
  • 1987-09-02 DK DK458387A patent/DK458387A/da not_active Application Discontinuation
  • 1987-09-03 NZ NZ22167087A patent/NZ221670A/xx unknown
  • 1987-09-04 AU AU77973/87A patent/AU608771B2/en not_active Ceased
  • 1987-09-10 JP JP22751787A patent/JP2534512B2/ja not_active Expired - Fee Related
  • 1987-09-14 US US07/096,376 patent/US4886708A/en not_active Expired - Lifetime
  • 1987-09-15 PT PT85717A patent/PT85717B/pt not_active IP Right Cessation
  • 1987-09-16 DE DE8787113518T patent/DE3772145D1/de not_active Expired - Fee Related
  • 1987-09-16 ES ES87113518T patent/ES2023865B3/es not_active Expired - Lifetime
  • 1987-09-16 EP EP19870113518 patent/EP0264620B1/de not_active Expired - Lifetime
  • 1987-09-16 AT AT87113518T patent/ATE66259T1/de not_active IP Right Cessation
  • 1987-09-23 IT IT2199987A patent/IT1222708B/it active
  • 1987-09-28 CN CN87106612A patent/CN1022762C/zh not_active Expired - Fee Related
  • 1987-09-29 CA CA 548190 patent/CA1325929C/en not_active Expired - Fee Related
  • 1987-09-29 IE IE261987A patent/IE60728B1/en not_active IP Right Cessation
  • 1987-09-30 KR KR1019870010947A patent/KR960002732B1/ko not_active Expired - Fee Related
  • 1987-09-30 NO NO874123A patent/NO169086C/no not_active IP Right Cessation
• 1991
  • 1991-10-03 GR GR91401472T patent/GR3002831T3/el unknown

Patent Citations (3)

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