EP0280152B1 - Agent d'hydrofugation du cuir - Google Patents
Agent d'hydrofugation du cuir Download PDFInfo
- Publication number
- EP0280152B1 EP0280152B1 EP88102224A EP88102224A EP0280152B1 EP 0280152 B1 EP0280152 B1 EP 0280152B1 EP 88102224 A EP88102224 A EP 88102224A EP 88102224 A EP88102224 A EP 88102224A EP 0280152 B1 EP0280152 B1 EP 0280152B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- leather
- water
- aminosiloxane
- preparation
- hydrocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010985 leather Substances 0.000 title claims description 30
- 238000004078 waterproofing Methods 0.000 title description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- -1 aminosiloxanes Chemical class 0.000 claims description 21
- 239000003995 emulsifying agent Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 150000007513 acids Chemical class 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 229910021645 metal ion Inorganic materials 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 description 15
- 239000000839 emulsion Substances 0.000 description 11
- 229920001296 polysiloxane Polymers 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 239000012188 paraffin wax Substances 0.000 description 6
- 239000005871 repellent Substances 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000005452 bending Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000035515 penetration Effects 0.000 description 4
- 230000002940 repellent Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 101500021084 Locusta migratoria 5 kDa peptide Proteins 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 2
- 229940113162 oleylamide Drugs 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000004569 hydrophobicizing agent Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052751 metal Chemical class 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
- C14C9/04—Fixing tanning agents in the leather
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
Definitions
- the present invention relates to aminosiloxane or aminopolysiloxane-containing waterproofing agents for leather.
- a particular advantage of this barrel waterproofing on wet leather compared to waterproofing with silicones or fluorocarbons, which are applied to dry leather in a post-treatment mostly from water-immiscible organic solutions, is that they are used completely or at least partially in place of the customary licker lubrication can and in addition to the actual hydrophobization softens the leather (see e.g. preparations made from natural and / or synthetic fatty substances and waxes as well as paraffin hydrocarbons with emulsifiers, which are fixed by fixation with acids or metal salts and thereby lose their hydrophilicity).
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Claims (1)
- Composition utilisable pour rendre le cuir hydrophobe, contenant les constituants suivants :a) des hydrocarbures saturés et non saturés linéaires et ramifiés ayant au moins 10 atomes de carbone, qui sont partiellement halogénés,b) des amino-siloxanes ou des amino-polysiloxanes,c) des émulsionnants porteurs de groupes carboxyle, pouvant être fixés sur le cuir par des acides ou par des ions de métaux polyvalents, ainsi que le cas échéant,d) de l'eau.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19873706203 DE3706203A1 (de) | 1987-02-26 | 1987-02-26 | Hydrophobiermittel fuer leder |
| DE3706203 | 1987-02-26 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0280152A2 EP0280152A2 (fr) | 1988-08-31 |
| EP0280152A3 EP0280152A3 (en) | 1990-02-28 |
| EP0280152B1 true EP0280152B1 (fr) | 1994-05-18 |
Family
ID=6321824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88102224A Expired - Lifetime EP0280152B1 (fr) | 1987-02-26 | 1988-02-16 | Agent d'hydrofugation du cuir |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0280152B1 (fr) |
| JP (1) | JPS63210200A (fr) |
| KR (1) | KR880010136A (fr) |
| BR (1) | BR8800810A (fr) |
| DE (2) | DE3706203A1 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4139090A1 (de) * | 1991-11-28 | 1993-06-03 | Stockhausen Chem Fab Gmbh | Verwendung von copolymerisaten mit polysiloxan-einheiten zur behandlung von leder und pelzen |
| DE4415062B4 (de) * | 1994-04-29 | 2004-04-01 | Stockhausen Gmbh & Co. Kg | Mittel und Verfahren zur Hydrophobierung von Ledern und Pelzen |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3494977A (en) * | 1968-03-28 | 1970-02-10 | Dow Corning | Treatment for leather |
| GB1346070A (en) * | 1971-02-03 | 1974-02-06 | Dow Corning Ltd | Water repellent process and composition |
| DE3529869A1 (de) * | 1985-08-21 | 1987-02-26 | Basf Ag | Verfahren zum hydrophobieren von leder und pelzen |
-
1987
- 1987-02-26 DE DE19873706203 patent/DE3706203A1/de not_active Withdrawn
-
1988
- 1988-02-16 EP EP88102224A patent/EP0280152B1/fr not_active Expired - Lifetime
- 1988-02-16 DE DE3889558T patent/DE3889558D1/de not_active Expired - Fee Related
- 1988-02-19 JP JP63035419A patent/JPS63210200A/ja active Pending
- 1988-02-25 BR BR888800310A patent/BR8800810A/pt not_active Application Discontinuation
- 1988-02-26 KR KR1019880001968A patent/KR880010136A/ko not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP0280152A2 (fr) | 1988-08-31 |
| EP0280152A3 (en) | 1990-02-28 |
| DE3706203A1 (de) | 1988-09-08 |
| JPS63210200A (ja) | 1988-08-31 |
| DE3889558D1 (de) | 1994-06-23 |
| KR880010136A (ko) | 1988-10-07 |
| BR8800810A (pt) | 1988-10-04 |
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