EP0302049A1 - Procédé de traitement thermique de fontes malléables - Google Patents
Procédé de traitement thermique de fontes malléables Download PDFInfo
- Publication number
- EP0302049A1 EP0302049A1 EP88890197A EP88890197A EP0302049A1 EP 0302049 A1 EP0302049 A1 EP 0302049A1 EP 88890197 A EP88890197 A EP 88890197A EP 88890197 A EP88890197 A EP 88890197A EP 0302049 A1 EP0302049 A1 EP 0302049A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- temperature
- castings
- cooled
- cast iron
- annealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 23
- 229910001296 Malleable iron Inorganic materials 0.000 title claims abstract description 11
- 238000005266 casting Methods 0.000 claims abstract description 27
- 238000001816 cooling Methods 0.000 claims abstract description 11
- 238000000137 annealing Methods 0.000 claims description 24
- 238000010438 heat treatment Methods 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000004568 cement Substances 0.000 claims description 7
- 229910000831 Steel Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000010583 slow cooling Methods 0.000 claims description 4
- 239000010959 steel Substances 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910001567 cementite Inorganic materials 0.000 abstract 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000005261 decarburization Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 239000011572 manganese Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000013386 optimize process Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D5/00—Heat treatments of cast-iron
- C21D5/04—Heat treatments of cast-iron of white cast-iron
- C21D5/06—Malleabilising
- C21D5/08—Malleabilising with oxidation of carbon
- C21D5/10—Malleabilising with oxidation of carbon in gaseous agents
Definitions
- the invention relates to a method for the heat treatment of malleable cast iron in a continuous gas tempering furnace.
- a decarburizing annealing must be carried out for the production of white malleable cast iron, the known processes providing such a decarburizing annealing in furnaces which can be fed both continuously and discontinuously.
- the annealing treatment for the production of white malleable cast iron it is known to heat the castings to temperatures between 950 ° and 1070 ° C. and to keep them at this temperature for a longer period of time for the purpose of falling cement and the necessary decarburization.
- rapid cooling to room temperature can have no appreciable influence on the mechanical properties by the structure caused.
- decarburization is carried out in addition to the primary carbide decomposition in the case of white malleable cast iron within the holding period at which the castings are kept at temperatures of 1070 ° C.
- the length of the holding period depends essentially on the wall thickness of the castings and the desired degree of decarburization. Usually, hold times of about 40 hours are observed for castings with a maximum wall thickness of 6 mm and hold times of up to 80 hours for thick-walled castings.
- a starting analysis of approximately 2.0 to 3.5% carbon, 0.5 to 1.7% silicon, 0.3 to 1% manganese, remainder iron and steel companion is assumed as the starting material, the sulfur content being up to 0. Can be 30%.
- the sulfur content depends primarily on the smelting unit used. The sulfur content is mostly introduced via the energy source.
- the present invention now aims to provide a method of the type mentioned in the introduction, in which with relatively short annealing times in continuous gas tempering furnaces it is found that the risk of deformation is reduced. Furthermore, the invention aims to achieve castings with higher toughness with sufficient strength.
- the process according to the invention essentially consists in decarburizing the castings in a continuous gas annealing furnace at a temperature of 1000 ° C. to 1100 ° C. and keeping them at this temperature until the cement heater falls completely, then accelerating to 730 ° C.
- the annealing time can therefore, as corresponds to a preferred embodiment of the method according to the invention, be limited to a holding time of 4 to 10 hours at high temperature, preferably 5 to 6 hours.
- the annealing temperature is chosen between 1050 ° C. and 1100 ° C. In this temperature range, it is found that the glow times are particularly short until the cement heater falls.
- the cooling rate of 3 ° C / h to 4 ° C / h is preferably selected and in particular the slow cooling to a temperature of 690 ° C to 700 ° C and then cooled with air to room temperature.
- the casting process is advantageously carried out in such a way that Al and / or boron or Zr is added to the melt for the production of the castings.
- Al and / or boron or Zr is added to the melt for the production of the castings.
- particularly favorable physical properties of the castings have also resulted after the temperature treatment according to the invention.
- the method according to the invention is particularly suitable for the heat treatment of fittings, so that the invention also relates to the use of this method for the heat treatment of fittings.
- the risk of deformation during heat treatment, in which an annealing treatment is carried out at relatively high temperatures, is particularly great, and the relatively short Annealing time reduces the scrap usually caused by the annealing treatment for fittings.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT1901/87 | 1987-07-27 | ||
| AT190187A AT391878B (de) | 1987-07-27 | 1987-07-27 | Verfahren zur waermebehandlung von temperguss |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0302049A1 true EP0302049A1 (fr) | 1989-02-01 |
Family
ID=3523468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88890197A Withdrawn EP0302049A1 (fr) | 1987-07-27 | 1988-07-27 | Procédé de traitement thermique de fontes malléables |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0302049A1 (fr) |
| AT (1) | AT391878B (fr) |
| BR (1) | BR8803713A (fr) |
| HU (1) | HUT50882A (fr) |
| PL (1) | PL273903A1 (fr) |
| PT (1) | PT88105A (fr) |
| YU (1) | YU46472B (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2153010C1 (ru) * | 1999-05-20 | 2000-07-20 | Балтийский государственный технический университет "Военмех" им.Д.Ф.Устинова | Способ термической обработки литой заготовки из ковкого чугуна при наличии в его структуре "отбела" |
| CN113403458A (zh) * | 2021-06-23 | 2021-09-17 | 唐山鑫业科技有限公司 | 白心可锻铸铁生产工艺 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR956234A (fr) * | 1950-01-27 | |||
| DE872352C (de) * | 1950-06-03 | 1953-03-30 | Bergische Stahlindustrie | Aus Temperguss bestehende Formteile, die unabhaengig von ihrer Wandstaerke durch Schmelzschweissen gut schweissbar sind |
| GB897159A (en) * | 1960-05-23 | 1962-05-23 | Matthias Ludwig | Improvements in and relating to the production of high-grade malleable iron castings |
| CH413544A (de) * | 1959-03-16 | 1966-05-15 | Pfaudler Permutit Inc | Verfahren zur Herstellung eines emaillierten Gegenstandes aus duktilem Gusseisen |
| CH485023A (fr) * | 1967-04-05 | 1970-01-31 | Renault | Procédé de fabrication d'une pièce en fonte malléable et pièce en fonte malléable obtenue par ce procédé |
-
1987
- 1987-07-27 AT AT190187A patent/AT391878B/de active
-
1988
- 1988-07-21 YU YU142388A patent/YU46472B/sh unknown
- 1988-07-21 HU HU380288A patent/HUT50882A/hu unknown
- 1988-07-26 PT PT8810588A patent/PT88105A/pt not_active Application Discontinuation
- 1988-07-26 PL PL27390388A patent/PL273903A1/xx unknown
- 1988-07-27 EP EP88890197A patent/EP0302049A1/fr not_active Withdrawn
- 1988-09-26 BR BR8803713A patent/BR8803713A/pt unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR956234A (fr) * | 1950-01-27 | |||
| DE872352C (de) * | 1950-06-03 | 1953-03-30 | Bergische Stahlindustrie | Aus Temperguss bestehende Formteile, die unabhaengig von ihrer Wandstaerke durch Schmelzschweissen gut schweissbar sind |
| CH413544A (de) * | 1959-03-16 | 1966-05-15 | Pfaudler Permutit Inc | Verfahren zur Herstellung eines emaillierten Gegenstandes aus duktilem Gusseisen |
| GB897159A (en) * | 1960-05-23 | 1962-05-23 | Matthias Ludwig | Improvements in and relating to the production of high-grade malleable iron castings |
| CH485023A (fr) * | 1967-04-05 | 1970-01-31 | Renault | Procédé de fabrication d'une pièce en fonte malléable et pièce en fonte malléable obtenue par ce procédé |
Non-Patent Citations (1)
| Title |
|---|
| REVUE DE METALLURGIE, Band 74, Nr. 10, Oktober 1977, Seiten 537-543, S. PARENT-SIMONIN et al.: "Influence de l'atmosphère de recuit sur la structure des fontes malléables" * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2153010C1 (ru) * | 1999-05-20 | 2000-07-20 | Балтийский государственный технический университет "Военмех" им.Д.Ф.Устинова | Способ термической обработки литой заготовки из ковкого чугуна при наличии в его структуре "отбела" |
| CN113403458A (zh) * | 2021-06-23 | 2021-09-17 | 唐山鑫业科技有限公司 | 白心可锻铸铁生产工艺 |
| CN113403458B (zh) * | 2021-06-23 | 2022-03-25 | 唐山鑫业科技有限公司 | 白心可锻铸铁生产工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| PT88105A (pt) | 1989-06-30 |
| PL273903A1 (en) | 1989-04-17 |
| AT391878B (de) | 1990-12-10 |
| HUT50882A (en) | 1990-03-28 |
| ATA190187A (de) | 1990-06-15 |
| BR8803713A (pt) | 1989-02-14 |
| YU142388A (en) | 1990-02-28 |
| YU46472B (sh) | 1993-10-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): CH DE ES FR GB IT LI NL |
|
| 17P | Request for examination filed |
Effective date: 19890609 |
|
| 17Q | First examination report despatched |
Effective date: 19901205 |
|
| RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: FITTINGS TRAISEN GESELLSCHAFT M.B.H. |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Withdrawal date: 19920330 |