EP0320126A1 - Détergents liquides pour machine à laver la vaisselle à stabilité améliorée - Google Patents

Détergents liquides pour machine à laver la vaisselle à stabilité améliorée Download PDF

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Publication number
EP0320126A1
EP0320126A1 EP88310674A EP88310674A EP0320126A1 EP 0320126 A1 EP0320126 A1 EP 0320126A1 EP 88310674 A EP88310674 A EP 88310674A EP 88310674 A EP88310674 A EP 88310674A EP 0320126 A1 EP0320126 A1 EP 0320126A1
Authority
EP
European Patent Office
Prior art keywords
composition according
clay
composition
silicate
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP88310674A
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German (de)
English (en)
Inventor
Jose Antonio Lopez
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Publication of EP0320126A1 publication Critical patent/EP0320126A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions

Definitions

  • This invention relates to liquid or gel-like automatic dishwashing detergents which are useful in cleaning soil from dishes, glasses and the like. More particularly it provides for such a composition containing a relatively high level of silicate to enhance the physical stability of the composition.
  • liquid automatic dishwashing detergents LADD
  • the physical stability of the liquid or gel product is essential for meeting overall consumer satisfaction.
  • Liquid ADDs for use in most available automatic dishwashing machines is difficult because these auto­ matic machines have dispensers which are designed to dispense detergents in powder form and are unsuitable for retaining low viscosity liquid detergents.
  • Relatively high viscosity liquid detergents ⁇ 1500 cps
  • Liquids with a viscosity above about 2500 cps may be retained in the dispenser even after partial dilution with water but are inconvenient to pour into the dispenser cups.
  • a relatively high viscosity thixotropic system capable of shear-thinning to about 200 cps, and then reverting to high viscosity while at rest, is preferred.
  • a relatively high viscosity thixotropic system capable of shear-thinning to about 200 cps, and then reverting to high viscosity while at rest.
  • Such a system can be easily dispersed from a container, and facilitates usage by the consumer.
  • the system must also provide sufficient viscosity and yield point to remain within the dispenser until the cup opens at the start of the main wash cycle.
  • compositions are normally of gel consistency, having Bingham plastic characteristics and thus rel­atively high yield values.
  • a definite shear force is necessary to initiate or increase flow. This force would be present within the agitated dispenser cup of an automatic dishwasher. Under these conditions, the composition is quickly fluidized and easily dispersed. When the shear force is discontinued, the fluid composition quickly reverts back to a high viscosity, Bingham plastic state closely approximating its prior consistency.
  • Typical viscosity ranges for the high silicate formula of this invention are: ⁇ 1 180-230 ⁇ 2 1400-2000 ⁇ 3 1500-2100 Stability is of primary importance, i.e., there should be no sig­nificant evidence of phase separation or leaking after long standing.
  • auto­matic dishwashing detergents contain (1) sodium tripolyphosphate (NaTPP); (2) sodium silicate to supply the alkalinity necessary for effective detergency and to provide protection for fine china glaze and patterns; (3) sodium carbonate, to enhance alkalinity; (4) a chlorine-releasing agent; and (5) a defoamer and/or surfac­tant to enhance machine efficiency and supply detergency.
  • NaTPP sodium tripolyphosphate
  • sodium silicate to supply the alkalinity necessary for effective detergency and to provide protection for fine china glaze and patterns
  • sodium carbonate to enhance alkalinity
  • (4) a chlorine-releasing agent to enhance machine efficiency and supply detergency
  • a defoamer and/or surfac­tant to enhance machine efficiency and supply detergency.
  • Patent 4,115,308 discloses thixotropic auto­matic dishwasher pastes containing a suspending agent; inorganic salts, surfactant and a suds depressant.
  • U.S. Patent No. 4,147,650 optionally includes a bleach.
  • U.S. Patent No. 3,985,668 describes abrasive scouring cleaners.
  • U.K. Patent Applications GB 2,118,199A, GB 2,140,450A, and GB 2,185,037A dis­close automatic dishwasher compositions having thixotropic, gel-­type structures
  • U.K. Patent Application 2 176 495A is similar to GB 2,118,199A and GB 2,140,450A but improved physical stability is disclosed by incorporating salts of polyvalent metal stearates.
  • compositions having a suffi­ciently high viscosity not to leak out of dispenser cups with sufficiently shear thinning behavior to be easily dispensed from a container, good solubility, good washing properties, good con­sumer acceptability with long shelf life at a relatively low cost, has not been satisfactory without using special stabilizers whose purpose is not to achieve cleaning, but rather, is directed to physical stabilization.
  • the present invention provides a normally gel-­like aqueous automatic dishwasher detergent composition having thixotropic properties.
  • the composition includes, on a weight basis:
  • the LADD composition can be readily poured into the dispensing cup of the automatic dishwashing machine and will promptly thicken to its normal gel-­like state to remain securely within the dispensing cup until shear forces are again applied, such as by the water spray from the dishwashing machine.
  • the effectiveness of automatic dishwashing detergents is related to (a) available chlorine levels; (b) alkalinity; (c) solubility in washing medium; and (d) foam inhibition.
  • the pH of the ADD composition is at least about 9.5, more preferably from about 10.5 to 13.5 and most preferably at least about 11.5.
  • Addition of NaOH is often required to achieve a pH within these ranges, to increase flowability properties and to neutralize certain phosphate esters.
  • the presence of carbonate helps to maintain the desired pH level but, excess carbonate is to be avoided, to prevent destabilization. It should be noted that in certain cases suffilycient alkalinity may be provided by the sodium silicate.
  • the alkali metal tripolyphosphate in the composition is present in a range of about 15 to 17 wt%, and preferably about 15.5 to 16.5 wt%. It should preferably be free of heavy metal which has a tendency to decompose or inactivate sodium hypochlorite and other chlorine bleach compounds.
  • Preferably sodium tripolyphosphate (NaTPP) is employed.
  • the NaTPP should have an average degree of hydration of less than about 1.
  • Pre-­moisturization to an average of about 0.3 to 1% water is most effective, and expedites hydration and solubilization of the remaining NaTPP.
  • the NaTPP contains on the average about 1% by weight of water. If only NaTPP hexahydrate is used. the deter­gent product has little if any thixotropic character. If only the pre-moisturized NaTPP is used, at the specified level, the preferred rheological profile is obtained.
  • Foam inhibits machine efficiency. Foam may be suffi strictlyciently reduced by suitable selection of the type and amount of detergent active material, the main foam-producing component, however, it is generally preferred to include a chlorine bleach stable foam depressant or inhibitor.
  • Inhibitors of the alkyl phosphonic acid esters of following formula are effective These esters are available from BASF-Wyandote. Alkyl acid phos­phate esters of the formula available from Occidental Petroleum are preferred. In these esters, one or both R groups may be independently a C12 ⁇ 20 alkyl group. Mixtures of phosphates with phosphate esters as well as mixtures of mono- and di- esters of the same type, may be employed.
  • 0.1 to 5wt%, preferably about 0.1 to 0.5wt%, of foam depressant in the composition is typical,
  • inorganic chlorine bleach compounds may be employed in the compositions of the invention, such as chlorinated trisodium phosphate, alkali or alkaline earth metal hypochlorite, especially sodium hypochlorite is preferred.
  • Sodium dichloro isocyanurate has been found to destabilize the compositions.
  • the composition typically contains sufficient chlorine bleach com­pound to provide about 0.5 to 3.0% by weight of available chlorine, as determined for example by iodometric titration. About 0.8 to 1.6% by weight of available chlorine is especially preferred.
  • the alkali metal silicate which provides alkalinity and protection of hard surfaces such as fine china glaze is employed in an amount ranging from about 12.0 to 18.0 wt%, preferably about 15 wt%, in the composition.
  • the silicate is preferably sodium silicate and is generally added in the form of an aqueous solution, preferably having an Na2O:SiO2 ratio of about 1:2.2 to 1:2.8, preferably 1:2.4. Amounts of silicate in excess of about 18%, while feasible, significantly affect ease of processing by conventional mixing methods due to increase in viscosity during addition of phosphate.
  • the NaOH, sodium hypochlorite and foam depressant when employed are added as aqueous dispersions or solutions.
  • the detergent active materials or surfactants must be stable in the presence of chlorine bleach, especially hypochlorite bleach and are preferably anionic. These surfac­tants are used in amounts of from about 0.1 to 3% preferably about 0.6 to 2.0%, more preferably about 0.3 to 0.6%.
  • the pre­ferred surfactants are the alkali metal sulfate salts of mono- or di- alkyl diphenyl oxides. These surfactants are commercially available as DOWFAX 3B-2 and DOWFAX 2A-1. Surfactants of the type mentioned above, all well known in the art, are described, for example, in U.S. Patents 3,985,668, 4,271,030 and GB 2 176 495A. The surfactant of course, should be compatible with the other ingredients of the composition.
  • Other suitable surfactants include alkylsulfates, and sulfonates as well as alkylarylsulfonates and the like.
  • Thixotropic thickeners or suspending agents are those which provide a medium with thixotropic properties. These are well known in the art and may be organic or inorganic, water soluble, water-dispersible or colloid-forming, and monomeric or polymeric.
  • the thickeners must be stable in the compositions, e.g. stable to high alkalinity and chlorine bleach compounds.
  • the preferred thickeners include inorganic, colloid-forming clays of the smectite and/or attapulgite types.
  • the amounts of the clays of the smectite and/or attapulgite types in the composition range from about 0.5 to 5%, preferably 1.5 to 3.0% by weight and these amounts are generally sufficient to achieve the desired thixotropic properties when used in combination with the propor­tion of ingredients disclosed herein.
  • Smectite clays are especially preferred, and include montmorillonite (bentonite), hectorite and the like. Materials of this type are available from Georgia Kaolin under the trade name of Korthix and Gelwhite GP,H, etc. from Southern Clay Products. Both Gelwhite and Korthix are montmorillonite clays. Attapulgite clays include materials commercially available under the trade names Attagel 40, Attagel 50 and Attagel 150 from Englehard Minerals and Chemicals Corporation. Exclusive use of attapulgite clays should be avoided since it becomes difficult to maintain a proper thixotropic profile on aging. Mixtures of smectite and attapulgite types in weight ratios of about 4:1 are useful. Thickening or suspending agents of the types described are well known in the art.
  • the amount of water contained in the compositions must be tailored to achieve the proper rheological properties. This amount is usually about 50 to 65wt%.
  • the desired thixotropic properties and physical stability can be obtained, without the need for a special stabilizing agent.
  • the present composition accomplishes the desired physical stability by way of balancing the functional dishwashing ingredients of the composition in proper proportions without the need for special stabilizing additives.
  • compositions may be included in these compositions in amounts generally less than about 3wt% such as perfume, preservatives, dyestuffs, pigments and the like. Any such adjuvants of course must be stable to chlorine bleach com­pounds and high alkalinity. Coloring may be accomplished by the chlorinated phthalocyanines and/or polysulfides of aluminosilicate. TiO2 may also be employed.
  • Laboratory batches may be prepared in pyrex beakers set on a heating plate, in a water bath, at high shear with a Talboy stirring motor.
  • the ingredients are added in the sequence shown above with the following conditions:
  • the finished product is homogenized with a Gifford-Wood homogenizer at the highest speed and shear settings for 2 to 3 minutes. Longer homogenization periods usually increase the batch temperature to above 40°C unless the batch is previously cooled to below about 20°C. Rheology measurements and/or dis­penser cup tests are run immediately after homogenizing and again after about 24 hrs. aging at room temperature.
  • the practical method for manufacturing the formulations of the invention with a high level of silicate does not involve pre-­dispersion (pre-mix) of the clay as a separate step in the process.
  • Pre-dispersion of the clay in the compositions contain­ing silicate levels in the 12 to 18% range is impractical since a major portion of the total water in the composition is associated with the liquid silicate which as a raw material contains between 53 and 55% water. Since the water is part of the silicate solu­tion it is not available during the early stages in the process before the addition of the silicate. It would thus be impracti­cal to prepare a clay pre-mix with the relatively small amount of the remaining process-water unless the clay premix was incorpo­rated early enough in the process to supply sufficient water to disperse the electrolytes.
  • the in-situ clay process does not require the pre-­swelling of the bentonite clay as a separate step in the process.
  • the bentonite clay is added "as purchased" (powder form) during either a very early or very late step in the process.
  • An obvious advantage of the in-situ process is the omission of the clay pre-swelling step.
  • the sequence in which the raw materials are added appears to have a determining effect on the viscosity of the batch throughout the process. Raw material addition sequences that yield a lower viscosity during the process generally require a relatively higher degree of homogenization for the finished batch to be satisfactory in the dispenser cup.
  • the percent separation is determined by way of direct measurements in millimeters (mm) from clear glass and plastic containers (8 oz.; 16 oz.) and represents the ratio of clear supernatant (mm) to overall height of product with the jar.
  • Example “B” shows the improvement over “A” in product stability when the level of phosphate is reduced from 21% to 16% in compositions containing a relatively low level of silicate (8%).
  • Examples “C” through “G” show a further improvement in product stability when the silicate level is increased to 12% or above.
  • Examples “H” and “I” show the criticality of the level of phosphate on product stability even for compositions contain­ing higher silicate levels.
  • Table III represents results to further define criticalities in composition that may be pertinent to product stability.
  • TABLE III % active in product J K L M N O P Q R S NaTPP 16.0 16.0 16.0 18.0 20.0 12.0 18.0* 16.0 16.0 16.0 NaSilicate (2.4r) 15.0 15.0 15.0 15.0 18.0 18.0 15.0 15.0 18.0 18.0 Soda ash 6.0 8.0 4.0 4.0 0.0 8.0 6.0 6.0 6.0 6.0 6.0 6.0 6.0 6.0 6.0 6.0 6.0 MSAP (defoamer)** 0.16 0.16 0.16 0.16 0.16 0.16 0.16 0.16 0.0 0.0 0.16 NaOH 1.4 Na Hypochlorite (as cl2) 1.0 Dowfax (Surfactant) 0.36 Bentonite clay 3.0 Water q.s Stability 2 wks.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Degasification And Air Bubble Elimination (AREA)
EP88310674A 1987-11-12 1988-11-11 Détergents liquides pour machine à laver la vaisselle à stabilité améliorée Withdrawn EP0320126A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11974987A 1987-11-12 1987-11-12
US119749 1987-11-12

Publications (1)

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EP0320126A1 true EP0320126A1 (fr) 1989-06-14

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EP88310674A Withdrawn EP0320126A1 (fr) 1987-11-12 1988-11-11 Détergents liquides pour machine à laver la vaisselle à stabilité améliorée

Country Status (6)

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EP (1) EP0320126A1 (fr)
JP (1) JPH02501488A (fr)
AU (1) AU2511188A (fr)
BR (1) BR8807290A (fr)
WO (1) WO1989004362A1 (fr)
ZA (1) ZA888457B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009100227A1 (fr) * 2008-02-05 2009-08-13 Amcol International Corporation Compositions de nettoyage résistantes à l’égouttement

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA887068B (en) * 1987-09-29 1990-05-30 Colgate Palmolive Co Thixotropic aqueous liquid automatic dishwashing detergent composition
DE3802127C1 (fr) * 1988-01-26 1988-12-01 Kaiser, H.-G.
EP0407187A3 (en) * 1989-07-07 1991-07-17 Unilever Plc Aqueous thixotropic cleaning composition
US5258496A (en) * 1990-07-10 1993-11-02 Scios Nova Inc. Isolation and purification of lung surfactant protein
EP0475447A3 (en) * 1990-09-14 1992-09-23 Fuji Photo Film Co Ltd Magnetically recordable photographic film, recording method and system therefor and camera-laboratory system
US5873931A (en) * 1992-10-06 1999-02-23 Minnesota Mining And Manufacturing Company Coating composition having anti-reflective and anti-fogging properties
US5929008A (en) * 1997-09-29 1999-07-27 The Procter & Gamble Company Liquid automatic dishwashing compositions providing high pH wash solutions

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2520004A1 (fr) * 1982-01-18 1983-07-22 Colgate Palmolive Co Compositions du type de gel douees de proprietes thixotropes pour machines a laver la vaisselle automatiques
GB2140450A (en) * 1983-05-24 1984-11-28 Colgate Palmolive Co Thixotropic automatic dishwasher composition with chlorine bleach
GB2163448A (en) * 1984-08-13 1986-02-26 Colgate Palmolive Co Detergent for automatic dishwasher

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2520004A1 (fr) * 1982-01-18 1983-07-22 Colgate Palmolive Co Compositions du type de gel douees de proprietes thixotropes pour machines a laver la vaisselle automatiques
GB2140450A (en) * 1983-05-24 1984-11-28 Colgate Palmolive Co Thixotropic automatic dishwasher composition with chlorine bleach
GB2163448A (en) * 1984-08-13 1986-02-26 Colgate Palmolive Co Detergent for automatic dishwasher

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009100227A1 (fr) * 2008-02-05 2009-08-13 Amcol International Corporation Compositions de nettoyage résistantes à l’égouttement

Also Published As

Publication number Publication date
AU2511188A (en) 1989-05-18
JPH02501488A (ja) 1990-05-24
BR8807290A (pt) 1990-03-27
ZA888457B (en) 1990-07-25
WO1989004362A1 (fr) 1989-05-18

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