EP0335012B1 - Procédé pour la production continue par coulée centrifuge d'un composite métal-matériau dur résistant à l'usure - Google Patents
Procédé pour la production continue par coulée centrifuge d'un composite métal-matériau dur résistant à l'usure Download PDFInfo
- Publication number
- EP0335012B1 EP0335012B1 EP88121821A EP88121821A EP0335012B1 EP 0335012 B1 EP0335012 B1 EP 0335012B1 EP 88121821 A EP88121821 A EP 88121821A EP 88121821 A EP88121821 A EP 88121821A EP 0335012 B1 EP0335012 B1 EP 0335012B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- molten metal
- casting
- centrifugal casting
- hard material
- mould
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims abstract description 40
- 238000009750 centrifugal casting Methods 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract 3
- 238000000034 method Methods 0.000 title claims description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 42
- 239000002184 metal Substances 0.000 claims abstract description 41
- 238000005266 casting Methods 0.000 claims abstract description 24
- 239000007787 solid Substances 0.000 claims abstract description 10
- 150000001247 metal acetylides Chemical class 0.000 claims abstract description 9
- 150000002739 metals Chemical class 0.000 claims abstract description 4
- 239000011230 binding agent Substances 0.000 claims abstract description 3
- 238000005054 agglomeration Methods 0.000 claims abstract 2
- 230000002776 aggregation Effects 0.000 claims abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims description 3
- 229910033181 TiB2 Inorganic materials 0.000 claims description 3
- -1 ferrous metals Chemical class 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910052580 B4C Inorganic materials 0.000 claims description 2
- 229910000531 Co alloy Inorganic materials 0.000 claims description 2
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 229910034327 TiC Inorganic materials 0.000 claims description 2
- 229910009001 W2C Inorganic materials 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- 229910003468 tantalcarbide Inorganic materials 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- 229910001018 Cast iron Inorganic materials 0.000 claims 1
- 239000007769 metal material Substances 0.000 abstract 1
- 239000002905 metal composite material Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 229910001208 Crucible steel Inorganic materials 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- 229910001060 Gray iron Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D13/00—Centrifugal casting; Casting by using centrifugal force
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/08—Casting in, on, or around objects which form part of the product for building-up linings or coverings, e.g. of anti-frictional metal
Definitions
- the invention relates to a method for the continuous production of a wear-resistant hard metal composite by centrifugal casting, in which solid powdery and / or granular synthetic metallic and / or non-metallic hard materials are temporarily poured into a centrifugal casting mold while it is being poured into a centrifugal casting mold rotating about its axis of symmetry metal melt flowing into the mold can be added.
- a disadvantage of these procedures is, in particular, that when hard materials are added to the ladle filled with molten metal, a large part of the hard materials dissolves due to the long action time of the molten metal on the solid particles and the exchange of substances supported by stirring, for example, and therefore does not act as a wear protection or an additional time-consuming work step is associated with the sprinkling of the hard materials onto a dough or liquid centrifugal casting layer.
- Patent Abstracts of Japan, Volume 6 No. 150 (M-148) (1028), August 10, 1982 describes a method for centrifugally casting a roll in which hard materials, e.g. WC powder to which molten metal is added in a pouring funnel.
- the residence time of the hard materials in the molten metal is shorter than in the known processes mentioned above, but it must be doubted that a uniform distribution of the hard materials in the molten metal is achieved.
- hard materials of low density such as B4C, TiB2, TiC, although they have a much higher hardness than, for example, tungsten carbide, cannot be used to reinforce the outer surface of the casting facing the mold wall.
- these hard materials accumulate preferentially on the inside or in the core region of the casting are therefore ineffective with regard to the wear protection of the outer surface of cast solid bodies.
- the invention has for its object to provide a method of the type mentioned, which in particular in a cost-effective manner a simple parameter control for reproducible generation of a hard material-metal composite for the reinforcement of large rotationally symmetrical components against wear even using metallic and non-metallic hard materials of high hardness and low density enables.
- This object is achieved in that the added hard materials are injected into the molten metal during the pouring of the molten metal in the feed pipe of the casting device.
- the process according to the invention reduces the dwell time of the hard materials in the molten metal before they enter the mold and increases their discharge; on the other hand, the distribution and depth of storage of the hard materials can be adjusted simply and reproducibly by the choice of the time and the duration of the injection .
- the casting process is continued continuously with pure metal melt in order to complete the cast body.
- Metal melts composed of alloyed or unalloyed steel or gray cast iron, pure non-ferrous metals such as cobalt and nickel or of a nickel or cobalt-based alloy are preferably suitable for the application of synthetic hard materials.
- carbides of the elements Mo, Nb, Ta, V, W and Zr are advantageous, in particular because of their high density and low dissolution rate. Due to the high centrifugal acceleration occurring during centrifugal casting, these are transported radially through the melt towards the mold wall and accumulate in the cast body in front of the outer processing layer.
- very hard and only slowly soluble borides, oxides and carbides of low density such as TiB2, Al2O3, TiO2, B4C, TiC
- metals and / or high density carbides such as Co, Ni, Ta, W, TaC, W2C, WC, are connected.
- the advantages achieved by the invention are, in particular, that the casting process for producing a hard material-metal composite takes place in a continuous and simple, inexpensive manner and that the distribution, composition, concentration and depth of the hard materials in the centrifugal casting body can be adjusted reproducibly.
- FIG. 1 shows the diagrammatic representation of the method according to the invention for the continuous production of a wear-resistant hard material-metal composite by centrifugal casting (here: horizontal centrifugal casting).
- the centrifugal casting mold 1 is first set into a rotational movement about its axis of symmetry by the drive rollers 2. After reaching a sufficiently high rotational speed for the uniform distribution of the molten metal in the centrifugal casting mold 1, after the usual application of a size to the mold wall (not shown in the figure), pure molten metal 3 from the ladle 4 through the casting device 5 into the cold centrifugal casting mold 1 poured. Due to the high heat dissipation caused by the cold centrifugal casting mold 1, an approx. 5 - 15 mm thick processing layer 6 solidifies immediately of the casting, the machining of this layer, the manufacturing tolerances attributable to the casting process and the mold contour can be compensated for.
- solid powdery and / or granular hard materials 9 are then passed through an opening 10 in the casting device 5 with an inert protective gas as carrier or conveying gas 8, preferably argon the vicinity of the centrifugal casting mold 1 into which the metal stream flowing through the casting device 5 is injected.
- an inert protective gas as carrier or conveying gas 8 preferably argon the vicinity of the centrifugal casting mold 1 into which the metal stream flowing through the casting device 5 is injected.
- the hard materials are metered in a simple manner by adjusting the carrier gas pressure.
- the casting process is continued by interrupting the powder supply with pure metal melt 12 until the casting is finished.
- FIG. 2 shows, by way of example, a cross section through a roller cast according to the developed method with a processing layer made of cast steel 13, a wear-resistant layer 14 made of cast steel with embedded synthetic hard materials 15 and a core made of cast steel 16.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Centrifugal Separators (AREA)
Claims (6)
- Procédé de production en continu d'un composite substance dure-métal résistant à l'usure par coulée par centrifugation, qui consiste à ajouter de temps en temps, à l'aide d'un dispositif convoyeur, des substances dures synthétiques, métalliques et/ou non métalliques solides, pulvérulentes et/ou en grains pendant la coulée du métal fondu dans une coquille de coulée par centrifugation tournant autour de son axe de symétrie, caractérisé en ce qu'il consiste à injecter les substances (9) à ajouter dans le métal fondu (3) par un orifice (10) du conduit d'alimentation du dispositif d'attaque (5), en utilisant un gaz inerte d'entraînement.
- Procédé suivant la revendication 1, caractérisé en ce qu'il consiste à couler, avant l'addition de substances dures (9) synthétiques solides dans le métal fondu (3) pénétrant dans la coquille (1), d'abord une couche de surépaisseur (13) qui peut être enlevée.
- Procédé suivant la revendication 1 ou 2, caractérisé en ce qu'il consiste à poursuivre en continu, après la coulée du métal fondu (3) chargé de substances dures (9) synthétiques dans la coquille (1) de coulée par centrifugation, le processus de coulée avec du métal fondu pur.
- Procédé suivant l'une des revendications 1 à 3, caractérisé en ce que le métal fondu (3) est de l'acier moulé allié ou non allié ou de la fonte grise alliée ou non alliée, des métaux non ferreux purs comme le cobalt et le nickel, ou un alliage à base de nickel ou de cobalt.
- Procédé suivant l'une des revendications 1 à 4, caractérisé en ce qu'il consiste à utiliser, de préférence, pour l'injection dans le métal fondu (3), des carbures des éléments Mo, Nb, Ta, V, W et Zr.
- Procédé suivant l'une des revendications 1 à 5, caractérisé en ce qu'il consiste à utiliser, pour l'injection dans le métal fondu (3) pénétrant dans la coquille (1), des borures, des oxydes et des carbures de faible densité, comme TiB₂, Al₂O₃, TiO₂, B₄C, TiC, qui sont liés, à l'aide d'un liant minéral ou organique, par agglomération à des métaux et/ou à des carbures de grande densité, comme Co, Ni, Ta, W, TaC, W₂C, WC.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT88121821T ATE89205T1 (de) | 1988-03-08 | 1988-12-29 | Verfahren zum kontinuierlichen herstellen eines verschleissbestaendigen hartstoff-metallverbundes durch schleudergiessen. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3807512 | 1988-03-08 | ||
| DE3807512A DE3807512A1 (de) | 1988-03-08 | 1988-03-08 | Verfahren zum kontinuierlichen herstellen eines verschleissbestaendigen hartstoff-metallverbundes durch schleudergiessen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0335012A1 EP0335012A1 (fr) | 1989-10-04 |
| EP0335012B1 true EP0335012B1 (fr) | 1993-05-12 |
Family
ID=6349121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP88121821A Expired - Lifetime EP0335012B1 (fr) | 1988-03-08 | 1988-12-29 | Procédé pour la production continue par coulée centrifuge d'un composite métal-matériau dur résistant à l'usure |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0335012B1 (fr) |
| AT (1) | ATE89205T1 (fr) |
| DE (2) | DE3807512A1 (fr) |
| ES (1) | ES2042706T3 (fr) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2641795B1 (fr) * | 1989-01-16 | 1993-09-24 | Bronzes Ind Sa | Fabrication de pieces en materiau composite |
| RU2171731C1 (ru) * | 1999-12-20 | 2001-08-10 | Дочернее предприятие "НЕКСУС - Производственно-коммерческая компания" | Способ центробежного литья заготовок роликов машин непрерывного литья заготовок |
| UA29555C2 (uk) * | 1999-12-20 | 2000-11-15 | Дочірнє Підприємство "Нексус - Виробничо-Комерційна Компанія " | Спосіб відцентрового відливання заготовок роликів машин безперервного відливання заготовок |
| AT412074B (de) * | 2002-09-16 | 2004-09-27 | Bernhard Dr Feistritzer | Verfahren zur herstellung von rotationssymmetrischen guss-stücken |
| RU2268106C1 (ru) * | 2004-07-02 | 2006-01-20 | Юрий Апполинарьевич Караник | Способ изготовления отливок |
| RU2381087C1 (ru) * | 2008-07-14 | 2010-02-10 | Государственное образовательное учреждение высшего профессионального образования "Южно-Уральский государственный университет" | Способ формирования трубной заготовки |
| RU2443505C1 (ru) * | 2010-10-06 | 2012-02-27 | Государственное образовательное учреждение высшего профессионального образования "Южно-Уральский государственный университет" (ГОУ ВПО "ЮУрГУ") | Способ получения стальной трубной заготовки |
| DE102010042402A1 (de) * | 2010-10-13 | 2012-04-19 | Federal-Mogul Burscheid Gmbh | Verfahren zur Herstellung eines Kolbenrings mit eingelagerten Partikeln |
| CN101954466B (zh) * | 2010-11-02 | 2015-09-02 | 北京中煤矿山工程有限公司 | 双金属复合冶金楔齿滚刀刀壳离心铸造工艺 |
| RU2647975C1 (ru) * | 2016-12-12 | 2018-03-21 | федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ" (НИУ)") | Способ получения стальных отливок центробежным литьем |
| RU2643850C1 (ru) * | 2016-12-12 | 2018-02-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" (ФГАОУ ВО "ЮУрГУ (НИУ)") | Способ получения тонкостенной трубной заготовки |
| DE102017208000A1 (de) * | 2017-05-11 | 2018-11-15 | Mahle International Gmbh | Verfahren zur Herstellung eines Motorblocks |
| JP7230782B2 (ja) * | 2019-11-15 | 2023-03-01 | トヨタ自動車株式会社 | 鋳造装置 |
| RU2742093C1 (ru) * | 2020-07-30 | 2021-02-02 | Федеральное государственное автономное образовательное учреждение высшего образования "Южно-Уральский государственный университет (национальный исследовательский университет)" ФГАОУ ВО "ЮУрГУ (НИУ)" | Способ получения стальной трубной заготовки с повышенной радиационной стойкостью |
| CN114210943B (zh) * | 2021-12-28 | 2023-03-14 | 马鞍山市海天重工科技发展有限公司 | 一种卸料门弧衬板的浇注生产工艺 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE861005C (de) * | 1944-09-07 | 1952-12-29 | Gussstahlwerk Bochumer Ver Ag | Verfahren zur Bildung von poren- und rissefreien Oberflaechen eines im Schleudergiessverfahren gegossenen Hohlkoerpers |
| US2681260A (en) * | 1951-07-27 | 1954-06-15 | Norton Co | Cylinder and liner |
-
1988
- 1988-03-08 DE DE3807512A patent/DE3807512A1/de not_active Withdrawn
- 1988-12-29 ES ES88121821T patent/ES2042706T3/es not_active Expired - Lifetime
- 1988-12-29 AT AT88121821T patent/ATE89205T1/de not_active IP Right Cessation
- 1988-12-29 EP EP88121821A patent/EP0335012B1/fr not_active Expired - Lifetime
- 1988-12-29 DE DE8888121821T patent/DE3881029D1/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATE89205T1 (de) | 1993-05-15 |
| ES2042706T3 (es) | 1993-12-16 |
| EP0335012A1 (fr) | 1989-10-04 |
| DE3881029D1 (de) | 1993-06-17 |
| DE3807512A1 (de) | 1989-09-21 |
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