EP0341643B1 - Acier formé à froid résistant à la corrosion et composite contenant une matrice de cet acier et un matériau dur - Google Patents
Acier formé à froid résistant à la corrosion et composite contenant une matrice de cet acier et un matériau dur Download PDFInfo
- Publication number
- EP0341643B1 EP0341643B1 EP89108269A EP89108269A EP0341643B1 EP 0341643 B1 EP0341643 B1 EP 0341643B1 EP 89108269 A EP89108269 A EP 89108269A EP 89108269 A EP89108269 A EP 89108269A EP 0341643 B1 EP0341643 B1 EP 0341643B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- percent
- matrix
- cold
- corrosion
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 36
- 239000010959 steel Substances 0.000 title claims abstract description 36
- 239000000463 material Substances 0.000 title claims abstract description 19
- 239000011159 matrix material Substances 0.000 title claims abstract description 14
- 238000005260 corrosion Methods 0.000 title claims abstract description 12
- 230000007797 corrosion Effects 0.000 title claims abstract description 12
- 239000002131 composite material Substances 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims abstract description 12
- 238000001513 hot isostatic pressing Methods 0.000 claims abstract description 6
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 3
- 239000012535 impurity Substances 0.000 claims abstract 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract 2
- 238000005482 strain hardening Methods 0.000 abstract 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 238000000137 annealing Methods 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 230000002349 favourable effect Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
- C22C33/0292—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with more than 5% preformed carbides, nitrides or borides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0278—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5%
- C22C33/0285—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements with at least one alloying element having a minimum content above 5% with Cr, Co, or Ni having a minimum content higher than 5%
Definitions
- the invention relates to a cold work steel formed by hot isostatic pressing of a prealloyed powder and to a steel matrix-hard material composite material containing such a cold work steel.
- DE-PS 29 37 724 describes a cold work steel known as CPM 10 V with the following analysis (in percent by weight): 2.45 C. 0.50 mn 0.90 Si 5.25 cr 9.75 V. 1.30 mo 0.07 p Rest of Fe. For him, the carbide content is approx. 33% by volume with an MC content of approx. 16%.
- the materials mentioned are characterized by good machinability, since the carbide distribution is in fine form.
- the object of the invention is to provide a cold work steel which has both a high carbide content and is corrosion-resistant, as well as a steel matrix-hard material composite material containing such cold work steel, which is corrosion-resistant and in which the service hardness of the steel matrix is the hardness of the hard material is as close as possible.
- the pre-alloyed powder which is preferably obtained by atomizing - most preferably spherical - has a grain size of less than 500 micrometers in pure cold work steel.
- the grain size - spherical or speckled - in adaptation to a hard material powder with a grain size of 5-10 micrometers is preferably less than 50 micrometers.
- CPM T 440 Another well-known stainless cold steel sold under the name CPM T 440 with the composition (in percent by weight) 2.20 C. 0.50 mn 0.50 Si 17.50 cr 5.75 V. 0.50 mo 0.06 p Rest of Fe can at best be described as inert because, due to the high carbon layer of 2.20%, most of the 17.50% chromium present is bound in the form of carbides, so that the matrix sinks below the resistance limit of 13% chromium.
- this steel Due to the favorable ratio of service hardness to annealing hardness, i.e. low annealing hardness and high service hardness, in connection with its corrosion resistance, this steel also forms the matrix basis for an advantageous metal matrix-hard material composite material of the basic type, as described for example in DE-OS 35 07 332, because this composite material is itself easily machinable in the soft-annealed state and is resistant to abrasive wear in the hardened state of the matrix, since washing out of the matrix is largely avoided due to the proximity of the hardness of the matrix and hardness of the hard material.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
- Gripping Jigs, Holding Jigs, And Positioning Jigs (AREA)
Claims (6)
- Acier pour travail à froid, résistant à la corrosion, formé par compression isostatique à chaud de poudre prémélangée composée de (en % en poids)
2,0 - 3,5 % de C 0 - 1,5 % de Si 0 - 1,5 % de Mn 23,0 - 27,0 % de Cr 0,5 - 2,5 % de Mo 3,0 - 6,0 % de V le reste étant constitué de Fe et d'impuretés inévitables. - Acier pour travail à froid, résistant à la corrosion, ayant la composition suivante (en % en poids):
2,0 - 3,5 % de C 0 - 1,5 % de Si 0 - 1,5 % de Mn 24,0 - 26,0 % de Cr 0,5 - 2,5 % de Mo 3,0 - 6,0 % de V le reste étant constitué de Fe et d'impuretés inévitables. - Acier pour travail à froid, résistant à la corrosion, ayant la composition suivante (en % en poids):
2,3 % de C ≦0,4 % de Si ≦0,4 % de Mn 25,0 % de Cr 1,0 % de Mo 4,1 % de V le reste étant constitué de Fe et d'impuretés inévitables. - Matériau composite à base d'une matrice en acier et d'une matière dure, formé par compression isostatique à chaud d'un mélange de poudres constitué de 60 à 90 % en volume d'une poudre prémélangée de matrice en acier pour travail à froid, durcissable, de composition (en % en poids):
et de 40 à 10 % en volume d'une poudre d'une des matières dures TiC, Al₂O₃, B₄C, VC ou d'un mélange de deux de ces matières dures ou plus.2,0 - 3,5 % de C 0 - 1,5 % de Si 0 - 1,5 % de Mn 23,0 - 27,0 % de Cr 0,5 - 2,5 % de Mo 3,0 - 6,0 % de V le reste étant constitué de Fe et d'impuretés inévitables, - Matériau composite à base d'une matrice en acier et d'une matière dure, selon la revendication 4, comportant une matrice en acier pour travail à froid de composition suivante (en % en poids):
2,0 - 3,5 % de C 0 - 1,5 % de Si 0 - 1,5 % de Mn 24,0 - 26,0 % de Cr 0,5 - 2,5 % de Mo 3,0 - 6,0 % de V le reste étant constitué de Fe et d'impuretés inévitables. - Matériau composite à base d'une matrice en acier et d'une matière dure, selon la revendication 5, comportant une matrice en acier pour travail à froid de composition suivante (en % en poids):
2,3 % de C ≦0,4 % de Si ≦0,4 % de Mn 25,0 % de Cr 1,0 % de Mo 4,1 % de V le reste étant constitué de Fe et d'impuretés inévitables.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT89108269T ATE81874T1 (de) | 1988-05-09 | 1989-05-09 | Korrosionsbestaendiger kaltarbeitsstahl und diesen kaltarbeitsstahl aufweisender stahlmatrix- hartstoff-verbundwerkstoff. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3815833 | 1988-05-09 | ||
| DE3815833A DE3815833A1 (de) | 1988-05-09 | 1988-05-09 | Korrosionsbestaendiger kaltarbeitsstahl und diesen kaltarbeitsstahl aufweisender stahlmatrix-hartstoff-verbundwerkstoff |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0341643A1 EP0341643A1 (fr) | 1989-11-15 |
| EP0341643B1 true EP0341643B1 (fr) | 1992-10-28 |
Family
ID=6354000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89108269A Expired - Lifetime EP0341643B1 (fr) | 1988-05-09 | 1989-05-09 | Acier formé à froid résistant à la corrosion et composite contenant une matrice de cet acier et un matériau dur |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0341643B1 (fr) |
| AT (1) | ATE81874T1 (fr) |
| DE (2) | DE3815833A1 (fr) |
| ES (1) | ES2035421T3 (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5290507A (en) * | 1991-02-19 | 1994-03-01 | Runkle Joseph C | Method for making tool steel with high thermal fatigue resistance |
| DE4118067A1 (de) * | 1991-06-01 | 1992-12-03 | Krupp Widia Gmbh | Metallbasiswerkstoff, formkoerper und verfahren zu seiner herstellung sowie verwendung |
| DE4235148C1 (de) * | 1992-10-19 | 1994-04-07 | Hans Prof Dr Ing Berns | Verfahren zur Herstellung von PM-Hartlegierungen |
| US5679908A (en) * | 1995-11-08 | 1997-10-21 | Crucible Materials Corporation | Corrosion resistant, high vanadium, powder metallurgy tool steel articles with improved metal to metal wear resistance and a method for producing the same |
| US5900560A (en) * | 1995-11-08 | 1999-05-04 | Crucible Materials Corporation | Corrosion resistant, high vanadium, powder metallurgy tool steel articles with improved metal to metal wear resistance and method for producing the same |
| FR2744046B1 (fr) * | 1996-01-30 | 1998-04-30 | Framatome Sa | Procede de fabrication d'un materiau metallique de grande durete et utilisations |
| SE0200429D0 (sv) * | 2002-02-15 | 2002-02-15 | Uddeholm Tooling Ab | Stållegering och verktyg tillverkat av stållegeringen |
| DE102004034905A1 (de) | 2004-07-19 | 2006-04-13 | Böhler-Uddeholm Precision Strip GmbH & Co. KG | Stahlband für Streichmesser, Auftragsmesser und Kreppschaber und pulvermetallurgisches Verfahren zu ihrer Herstellung |
| US7320832B2 (en) | 2004-12-17 | 2008-01-22 | Integran Technologies Inc. | Fine-grained metallic coatings having the coefficient of thermal expansion matched to the one of the substrate |
| US7387578B2 (en) | 2004-12-17 | 2008-06-17 | Integran Technologies Inc. | Strong, lightweight article containing a fine-grained metallic layer |
| US7354354B2 (en) | 2004-12-17 | 2008-04-08 | Integran Technologies Inc. | Article comprising a fine-grained metallic material and a polymeric material |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1259034B (de) * | 1964-12-22 | 1968-01-18 | Constructa Werke Ges Mit Besch | Vorrichtung zum Erzeugen von Spruehstrahlen, insbesondere fuer eine Geschirrspuelmaschine |
| US4469514A (en) * | 1965-02-26 | 1984-09-04 | Crucible, Inc. | Sintered high speed tool steel alloy composition |
| US4249945A (en) | 1978-09-20 | 1981-02-10 | Crucible Inc. | Powder-metallurgy steel article with high vanadium-carbide content |
| FI830737L (fi) * | 1983-03-04 | 1984-09-05 | Telatek Oy | Foerfarande foer aostadkommande av en belaeggning, som motstaor bra kemisk och mekanisk slitning och en traod foer anvaendning vid foerfarandet. |
| SE450469B (sv) * | 1985-02-19 | 1987-06-29 | Asea Stal Ab | Sett vid framstellning av en formkropp av en jernlegering med hog kromhalt |
| DE3507332A1 (de) * | 1985-03-01 | 1986-09-04 | Seilstorfer GmbH & Co Metallurgische Verfahrenstechnik KG, 8092 Haag | Stahlmatrix-hartstoff-verbundwerkstoff |
| US4765836A (en) * | 1986-12-11 | 1988-08-23 | Crucible Materials Corporation | Wear and corrosion resistant articles made from pm alloyed irons |
-
1988
- 1988-05-09 DE DE3815833A patent/DE3815833A1/de not_active Ceased
-
1989
- 1989-05-09 ES ES198989108269T patent/ES2035421T3/es not_active Expired - Lifetime
- 1989-05-09 EP EP89108269A patent/EP0341643B1/fr not_active Expired - Lifetime
- 1989-05-09 DE DE8989108269T patent/DE58902537D1/de not_active Expired - Lifetime
- 1989-05-09 AT AT89108269T patent/ATE81874T1/de active
Also Published As
| Publication number | Publication date |
|---|---|
| DE58902537D1 (de) | 1992-12-03 |
| EP0341643A1 (fr) | 1989-11-15 |
| ES2035421T3 (es) | 1993-04-16 |
| DE3815833A1 (de) | 1989-11-23 |
| ATE81874T1 (de) | 1992-11-15 |
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