EP0347409A1 - Procédé de fabrication de pièces soumises à de fortes contraintes et ayant une surface résistant à l'usure - Google Patents
Procédé de fabrication de pièces soumises à de fortes contraintes et ayant une surface résistant à l'usure Download PDFInfo
- Publication number
- EP0347409A1 EP0347409A1 EP89890161A EP89890161A EP0347409A1 EP 0347409 A1 EP0347409 A1 EP 0347409A1 EP 89890161 A EP89890161 A EP 89890161A EP 89890161 A EP89890161 A EP 89890161A EP 0347409 A1 EP0347409 A1 EP 0347409A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tempering
- hardness
- wear
- alloy
- strength
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000005496 tempering Methods 0.000 claims abstract description 27
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 19
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 14
- 239000000956 alloy Substances 0.000 claims abstract description 14
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 14
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 10
- 239000010959 steel Substances 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 9
- 238000007493 shaping process Methods 0.000 claims abstract description 6
- 238000005299 abrasion Methods 0.000 claims abstract description 5
- 238000005520 cutting process Methods 0.000 claims abstract description 5
- 229910000851 Alloy steel Inorganic materials 0.000 claims abstract description 3
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 230000007704 transition Effects 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 2
- 238000011282 treatment Methods 0.000 abstract description 6
- 230000017525 heat dissipation Effects 0.000 abstract description 2
- 238000001125 extrusion Methods 0.000 description 4
- 239000011162 core material Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005256 carbonitriding Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000009859 metallurgical testing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
- C21D1/09—Surface hardening by direct application of electrical or wave energy; by particle radiation
Definitions
- the invention relates to a process for the production of highly stressed parts with a wear-resistant surface, in particular tools made of hot-work steel, for the chipless shaping of workpieces with temperatures of above 250 ° C., in particular above 400 ° C., and parts produced by this process.
- Highly stressed components in particular tools for non-cutting deformation of workpieces with higher temperatures, are subject to different loads in practical use, which consistently combine material stresses consisting of e.g. Cause pressure, tension, bending, abrasion or wear, etc.
- appropriate material selection or use of a hardenable steel is carried out, the properties of which can be adjusted by means of a tempering process consisting of hardening and tempering treatments.
- the chemical composition of the hardenable steel or the alloy determines the conversion behavior during heat treatment.
- the remuneration process that ultimately brings about the properties of the tool should be selected with regard to the critical type of stress.
- tools subject to bending and wear are made of tough material due to the risk of breakage, or the hardenable alloy becomes one subject to high toughness-based remuneration procedures.
- this tempering treatment tailored to this alloy the required toughness properties of the material are achieved, but the desired high hardness and wear resistance of the tool cannot be set, so that its service life is unsatisfactory.
- Hard coatings e.g. with titanium nitride, only improved the service life in some cases.
- the object of the invention was to develop a method for high to create stressed parts with a hard, wear-resistant surface, in particular tools made of hot-work steel, for the non-cutting shaping of workpieces with temperatures of over 250 ° C., in particular over 400 ° C.
- Another object of the invention concerned highly stressed parts with a hard, wear-resistant surface, in particular tools made of hot-work steel, for the non-cutting shaping of workpieces with temperatures of over 250 ° C., in particular over 400 ° C.
- This object is achieved in a method in that the part made of a hardenable steel alloy undergoes a heat treatment consisting of at least one cooling of at least the austenitizing temperature, in particular 1050 ° C., and one or more warmings to tempering temperatures, in particular between 510 and 610 ° C, whereupon one or more overlay hardening (s), possibly in the surface areas or zones close to the surface subject to abrasion or wear, by local heating with high power density to at least the austenitizing temperature and an accelerated cooling of the austenitized area or in the austenitic area State of the alloy present near-surface zone below the martensite point of the alloy.
- a heat treatment consisting of at least one cooling of at least the austenitizing temperature, in particular 1050 ° C., and one or more warmings to tempering temperatures, in particular between 510 and 610 ° C, whereupon one or more overlay hardening (s), possibly in the surface areas or zones close to the surface subject to abrasion or wear, by
- the heating of the zone near the surface is carried out with a power density of at least 1 ⁇ 10 3 W / cm 2 and the structure is austenitized to a depth of at most 8 mm, preferably at most 5 mm. It is particularly advantageous if, after the zone near the surface has been heated, the area in the austenitic microstructure is rapidly cooled below the martensite point of the alloy with high intensity by essentially dissipating heat into the part or by dissipating heat through the part.
- the solution of a further object is that the part has a tempering structure with high material toughness, which merges in the direction of the surface, in particular in the areas of the surface that are subject to wear, into a martensitic structure with high strength and high hardness. It is advantageous if the strength and hardness of the transition area from the tempering structure of the base material to the martensitic structure of the surface zone, which has a thickness of at least 0.2 mm, preferably at least 0.5 mm, but at most 8 mm, preferably at most 5 mm, are essentially increasing.
- the tempering structure has a strength of 1450 N / mm2 to 1780 N / mm2 and a hardness of 480 HV to 520 HV, and the surface or the martensitic zone near the surface has a strength of 1800 N / mm2 to 1900 N / mm2 , and a hardness of 550 HV to 650 HV.
- the tempering method is advantageously performed in such a way that in the transition area from the tempering structure of the base material to the martensitic structure of the zone near the surface, the values for the drop in strength are at most 150 N / mm2, preferably less than 80 N / mm2, and the values for drop in hardness are at most 50 HV, preferably less than 30 HV, these tempered parts are subsequently reheated to temperatures in the range above the tempering temperature and below the austenitizing temperature, so as is known to any person skilled in the art, the strength and hardness of the part decrease significantly to low values, this material state also h for the machining of Tools is used. This effect of the decisive reduction in strength and hardness also occurs in the case of partial heating to the austenitizing temperature with conventional methods for tempered parts,
- the matrices were subjected to a tempering treatment consisting of hardening by cooling from a temperature of 1050 ° C., followed by a first tempering in the range of the secondary hardness maximum of the alloy at a temperature of 510 ° C., a second tempering at working temperature at a temperature of 610 ° C and a third temper to relax at a temperature of 580 ° C followed.
- the same superimposed hardening of the surface zones subject to abrasion was carried out on two matrices by laser beam heating with an intensity of 3.25 x 103 W / cm2.
- the hardened matrix and a matrix with overlay hardening were tested for the production of compacts with the same cross-section.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT1517/88 | 1988-06-13 | ||
| AT151788A AT393696B (de) | 1988-06-13 | 1988-06-13 | Verfahren zur herstellung von hochbeanspruchten teilen mit verschleissfester oberflaeche |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0347409A1 true EP0347409A1 (fr) | 1989-12-20 |
Family
ID=3515360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89890161A Withdrawn EP0347409A1 (fr) | 1988-06-13 | 1989-06-12 | Procédé de fabrication de pièces soumises à de fortes contraintes et ayant une surface résistant à l'usure |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0347409A1 (fr) |
| AT (1) | AT393696B (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174388B1 (en) * | 1999-03-15 | 2001-01-16 | Lockheed Martin Energy Research Corp. | Rapid infrared heating of a surface |
| WO2007014610A1 (fr) * | 2005-07-29 | 2007-02-08 | Zf Friedrichshafen Ag | Procédé pour recuire des pièces sans contact par un rayonnement en faisceau |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001889A1 (fr) * | 1977-10-17 | 1979-05-16 | Sciaky Bros., Inc. | Procédé pour la trempe superficielle des métaux |
| DE2940127A1 (de) * | 1978-10-05 | 1980-04-17 | Coherent Inc | Verfahren und vorrichtung zur waermebehandlung |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD204106B1 (de) * | 1982-03-31 | 1988-02-03 | Adw Ddr | Verfahren zur oberflaechenhaertung von eisen-kohlenstoff-legierungen |
-
1988
- 1988-06-13 AT AT151788A patent/AT393696B/de not_active IP Right Cessation
-
1989
- 1989-06-12 EP EP89890161A patent/EP0347409A1/fr not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0001889A1 (fr) * | 1977-10-17 | 1979-05-16 | Sciaky Bros., Inc. | Procédé pour la trempe superficielle des métaux |
| DE2940127A1 (de) * | 1978-10-05 | 1980-04-17 | Coherent Inc | Verfahren und vorrichtung zur waermebehandlung |
Non-Patent Citations (7)
| Title |
|---|
| DESIGN ENGINEERING, Oktober 1987, Seiten 47,48,50,54, London, GB; "Industrial lasers making light work" * |
| HÄRTEREI-TECHNISCHE MITTEILUNGEN (HTM), Band 42, Nr. 2, März/April 1987, Seiten 83-89, Carl Hanser Verlag, München, DE; J. RUGE et al.: "Untersuchungen zum Elektronenstrahl-Randschichthärten von Warmarbeitsstahl" * |
| HTM - HÄRTEREI-TECHNISCHE MITTEILUNGEN, Band 43, Nr. 2, März/April 1988, Seiten 103-111, Carl Hanser Verlag, München, DE; S. PANZER et al.: "Härten von Oberflächen mit Elektronenstrahlen" * |
| JOURNAL OF METALS, Band 35, Nr. 5, Mai 1983, Seiten 18-26, Warrendale, Pennsylvania, US; J. MAZUMDER: "Laser heat treatment: The state of the art" * |
| PATENT ABSTRACTS OF JAPAN, Band 13, Nr. 156 (C-585)[3504], 14. April 1989; & JP-A-63 312 914 (BROTHER IND. LTD) 21-12-1988 * |
| PATENT ABSTRACTS OF JAPAN, Band 3, Nr. 75 (C-50), 27. Juni 1979, Seite 150 C 50; & JP-A-54 526 625 (TOKYO SHIBAURA DENKI K.K.) 25-04-1979 * |
| WELDING INTERNATIONAL, Band 2, Nr. 2, 1988, Seiten 180-183, Abington, Cambridge, GB; M. MÜLLER et al.: "Surface hardening by electron beam" * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6174388B1 (en) * | 1999-03-15 | 2001-01-16 | Lockheed Martin Energy Research Corp. | Rapid infrared heating of a surface |
| US6432555B1 (en) | 1999-03-15 | 2002-08-13 | U.T. Battelle, Llc | Rapid infrared heating of a surface |
| US6667111B2 (en) | 1999-03-15 | 2003-12-23 | Ut Battelle Llc | Rapid infrared heating of a surface |
| WO2007014610A1 (fr) * | 2005-07-29 | 2007-02-08 | Zf Friedrichshafen Ag | Procédé pour recuire des pièces sans contact par un rayonnement en faisceau |
Also Published As
| Publication number | Publication date |
|---|---|
| AT393696B (de) | 1991-11-25 |
| ATA151788A (de) | 1991-05-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT DE FR GB IT SE |
|
| 17P | Request for examination filed |
Effective date: 19900307 |
|
| 17Q | First examination report despatched |
Effective date: 19910830 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19920310 |