EP0353080A1 - Composition antitache - Google Patents

Composition antitache Download PDF

Info

Publication number: EP0353080A1
Authority: EP; European Patent Office
Prior art keywords: process according; stain; fibres; fluorocarbon; textiles
Prior art date: 1988-07-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP89307682A

Other languages

German (de)

English (en)

Inventor

Peter Edward Dr. Ingham

Susan Frances Napier

Penelope Christine Myers

Michael John Palin

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

International Wool Secretariat

Wool Research Organization of New Zealand Inc

Original Assignee

International Wool Secretariat

Wool Research Organization of New Zealand Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-07-27

Filing date

1989-07-27

Publication date

1990-01-31

1989-07-27 Application filed by International Wool Secretariat, Wool Research Organization of New Zealand Inc filed Critical International Wool Secretariat

1990-01-31 Publication of EP0353080A1 publication Critical patent/EP0353080A1/fr

Status Withdrawn legal-status Critical Current

Links

230000000903 blocking effect Effects 0.000 title claims description 4
238000000034 method Methods 0.000 claims abstract description 50
230000008569 process Effects 0.000 claims abstract description 45
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 20
239000004753 textile Substances 0.000 claims abstract description 19
239000000203 mixture Substances 0.000 claims abstract description 5
239000004952 Polyamide Substances 0.000 claims abstract description 4
229920002647 polyamide Polymers 0.000 claims abstract description 4
238000011282 treatment Methods 0.000 claims description 19
210000002268 wool Anatomy 0.000 claims description 11
BPRYUXCVCCNUFE-UHFFFAOYSA-N 2,4,6-trimethylphenol Chemical compound CC1=CC(C)=C(O)C(C)=C1 BPRYUXCVCCNUFE-UHFFFAOYSA-N 0.000 claims description 7
239000000835 fiber Substances 0.000 claims description 7
238000005299 abrasion Methods 0.000 claims description 6
150000001875 compounds Chemical class 0.000 claims description 5
238000004043 dyeing Methods 0.000 claims description 5
IIACRCGMVDHOTQ-UHFFFAOYSA-N sulfamic acid Chemical compound NS(O)(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-N 0.000 claims description 5
239000003795 chemical substances by application Substances 0.000 claims description 4
150000003839 salts Chemical class 0.000 claims description 4
-1 alkali metal salt Chemical class 0.000 claims description 3
238000002203 pretreatment Methods 0.000 claims description 3
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 claims description 2
229910006069 SO3H Inorganic materials 0.000 claims description 2
239000004809 Teflon Substances 0.000 claims description 2
229920006362 Teflon® Polymers 0.000 claims description 2
230000002378 acidificating effect Effects 0.000 claims description 2
229910052783 alkali metal Inorganic materials 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
238000004061 bleaching Methods 0.000 claims description 2
239000000084 colloidal system Substances 0.000 claims description 2
239000007859 condensation product Substances 0.000 claims description 2
FLGPRDQFUUFZBL-UHFFFAOYSA-N formaldehyde;naphthalen-1-ol Chemical compound O=C.C1=CC=C2C(O)=CC=CC2=C1 FLGPRDQFUUFZBL-UHFFFAOYSA-N 0.000 claims description 2
SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical group O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 claims description 2
JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
229920001568 phenolic resin Polymers 0.000 claims 1
238000010186 staining Methods 0.000 description 11
239000000975 dye Substances 0.000 description 7
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
239000000243 solution Substances 0.000 description 5
230000000694 effects Effects 0.000 description 4
239000007921 spray Substances 0.000 description 4
239000004677 Nylon Substances 0.000 description 3
235000011128 aluminium sulphate Nutrition 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
239000003599 detergent Substances 0.000 description 3
239000004744 fabric Substances 0.000 description 3
229920001778 nylon Polymers 0.000 description 3
238000012545 processing Methods 0.000 description 3
241000238631 Hexapoda Species 0.000 description 2
229920002292 Nylon 6 Polymers 0.000 description 2
229920002302 Nylon 6,6 Polymers 0.000 description 2
239000001164 aluminium sulphate Substances 0.000 description 2
238000013459 approach Methods 0.000 description 2
230000007812 deficiency Effects 0.000 description 2
BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 2
239000003792 electrolyte Substances 0.000 description 2
239000002657 fibrous material Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000002940 repellent Effects 0.000 description 2
239000005871 repellent Substances 0.000 description 2
239000002689 soil Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000012360 testing method Methods 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
DUFCMRCMPHIFTR-UHFFFAOYSA-N 5-(dimethylsulfamoyl)-2-methylfuran-3-carboxylic acid Chemical compound CN(C)S(=O)(=O)C1=CC(C(O)=O)=C(C)O1 DUFCMRCMPHIFTR-UHFFFAOYSA-N 0.000 description 1
235000009328 Amaranthus caudatus Nutrition 0.000 description 1
240000001592 Amaranthus caudatus Species 0.000 description 1
229910020148 K2ZrF6 Inorganic materials 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
159000000013 aluminium salts Chemical class 0.000 description 1
229910000329 aluminium sulfate Inorganic materials 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
239000004178 amaranth Substances 0.000 description 1
235000012735 amaranth Nutrition 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
CEZCCHQBSQPRMU-UHFFFAOYSA-L chembl174821 Chemical compound [Na+].[Na+].COC1=CC(S([O-])(=O)=O)=C(C)C=C1N=NC1=C(O)C=CC2=CC(S([O-])(=O)=O)=CC=C12 CEZCCHQBSQPRMU-UHFFFAOYSA-L 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000010276 construction Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
239000000989 food dye Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
FJQXCDYVZAHXNS-UHFFFAOYSA-N methadone hydrochloride Chemical compound Cl.C=1C=CC=CC=1C(CC(C)N(C)C)(C(=O)CC)C1=CC=CC=C1 FJQXCDYVZAHXNS-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000009971 piece dyeing Methods 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
239000000047 product Substances 0.000 description 1
239000000779 smoke Substances 0.000 description 1
238000007447 staining method Methods 0.000 description 1
239000012192 staining solution Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
238000003809 water extraction Methods 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Images

Classifications

- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
- D06M15/412—Phenol-aldehyde or phenol-ketone resins sulfonated
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance

Definitions

This invention relates to a process for treating fibrous materials and textiles and in particular relates to a process for treating fibres and textiles in order to improve the stain resistance thereof.
Nylon carpets may be treated with compounds known as stain-blockers and/or fluorocarbons in order to increase their resistance to staining.
stain-blockers and/or fluorocarbons are commonly employed treatment method, which fits in with the finishing routes employed on nylon carpets, and subsequently spray fluorocarbon on to the finished carpet.
staining liquids often penetrate to the back of the carpet. After initial cleaning the immediately affected area on the top of the carpet pile is cleaned of stain, but the stain in the backing tends to wick up the pile producing staining around the original area.
the methods of application used in connection with nylon carpet may not be applicable to home furnishings made of other fibres such as keratinous fibres like wool.
Another deficiency with many existing treatments is the limited fastness of the treatment to shampooing and wear.
An object of the invention is to provide a process for applying stain blockers and fluorocarbons to keratinous and polyamide fibres.
a process for improving the stain resistance of polyamide and keratinous fibres and textiles which comprises treating the fibres or textile in an aqueous dye bath at a long liquor ratio firstly with a fluorocarbon composition and subsequently with a stain blocker.
the invention further provides processess for improving the wet-fastness and durability of the stainblocking effect produced.
stain blocker does not exhaust completely and residual stain blocker in the bath interferes with the application of the fluorocarbon.
stainblocker on the fibre surface is believed to interfere with fluorocarbon application.
the process of the invention is particularly beneficial with wool fibres and textiles especially wool home furnishing textiles.
the process can be applied at the loose wool, roving, slubbing, yarn, or made up textile article stages.
the process is applied in the dye bath immediately subsequent to dyeing or bleaching of the fibres.
the stain blockers which can be employed in the process of the invention are those currently available for this purpose, such as those described in European patent applications numbers 0242495 and 0242496.
Such compounds are commercially available, inter alia, under the trade names Granofin WG (Hoechst AG), Mesitol NBS (Bayer), Alguard WR (Allied Colloids), Erionall RF (Ciba Geigy); or Scotchguard FX 369 (3M Corporation).
commercial compounds sold as synthetic tanning agents have been found to be effective, for example Baykanol HLX (Bayer) and Tanigan OS (Bayer).
Typical stain blockers are sulphonated phenol-formaldehyde or naphthol-formaldehyde condensation products.
sulphonated is meant that the product contains a -SO3H group or a salt thereof, such as an alkali metal salt.
the fluorocarbons useful in the process of the invention can be selected from those commonly used for textile treatments with the caveat that they should have good soil repellent characteristics and be compatible with subsequent application conditions so, for example, that they will not become de-exhausted under low pH conditions.
Typical fluorocarbons useful in the invention comprise acrylate or urethane backbone chains with pendant fluorinated alkyl groups.
Suitable fluorocarbons are available commercially under the trade names Teflon TC (DuPont), Scotchguard FC 397 (3M), Scotchguard FG 396 (3M) and Scotchguard FX 3602 (3M).
the process is advantageously carried out under acidic conditions, typically between pH 2 and 5, especially about pH 3, and the pH can be adjusted with sulphamic acid.
the temperature is preferably elevated and can be in the region of 30 to 100 degrees Celsius, especially 50 to 80 degress.
the process is an exhaustion process from long liquor ratios and liquor to goods ratios of 1:10 to 1:100 can be employed, typically a ratio of 1:30.
auxiliaries can be added to the dye bath to promote exhaustion and/or distribution of the stain blocker. In general any effect seen was only marginal. However two particular auxiliaries, Baylan NT (Bayer) and Lanasan LT (Sandoz), used for the low temperature dyeing of wool, gave very significant improvements to the process.
carpets are often steamed in a normal finishing route.
atmospheric steaming of carpets treated in accordance with the process of the invention materially improved the stain blocking effect.
a particularly preferred carpet processing route is as follows: Start at 20 o C at long liquor ratio 1:20 to 1:60 Add 2% fluorochemical at pH 3 (sulphamic acid) Raise to 50 o C at 1 deg C/min. Run at 50 o C for 30 min Add 8% Stainblocker 2% Auxiliary Readjust to pH 3-3.5 (sulphamic acid) Raise to 65 o C at 1 deg C/min. Run at 65 o C for 30 min Drop bath. Hydroextract and dry.
the above processing sequence is carried out in one bath, preferably in the dye bath subsequent to the dyeing operation.
the following fixing treatment can be employed as a pre- or post-treatment.
a pre-treatment Start at 20 o C at liquor ratio to 1:60 Add fixing chemical (low smoke Zirpro formulation (containing zirconium acetate) or Al2(SO4)3) 16H2O. Raise to 70 o C at 1 deg C/min. Run 30 minutes, and continue with the preferred processing route described above.
post-treatment after running at 65 o C for 30 minutes, add the fixing chemical. Run 15 minutes, then drop bath and rinse in cold water. Hydroextract and dry. After manufacture the carpet pile should preferably be steamed at atmospheric conditions for 2 minutes.
carpet is of a tufted or cut pile construction it may be preferable to over spray the finished carpet with further fluorocarbon or stain blocker/fluorocarbon mixture to seal the cut ends and increase resistance to staining the improve durability of the stain resist treatment.
further fluorocarbon or stain blocker/fluorocarbon mixture to seal the cut ends and increase resistance to staining the improve durability of the stain resist treatment.
the setting is sufficient to allow piece dyeing without significant loss of tuft definition. Since the process of the invention is applied after dyeing, the cut ends are treated in the exhaust bath obviating the need to over spray the carpet.
Fabric specimens are abraded against standard abrasive fabric using a Martindale Abrasion Tester for 500 rubs. The specimens were then stained.
Detergent solution (10 ml/l of anionic detergent, pH 7.5 at 40 o C) was applied under pressure and removed by vacuum using a spray extraction machine. This cleansing procedure was carried out five times. The dried specimens were then stained.
Fabric specimens were individually agitated in a staining solution (0.8 g/l FD + C Red 40, 0.4 g/l citric acid, 0.1 g/l non-ionic wetting agent) at liquor to goods ratio of 20:1 for 5 min at 20 o C. Excess solution was gently shaken off. Specimens were left to lie uncovered on a polyethylene sheet for 24 hours at ambient temperature, rinsed in cold water until no further stain was removed, hydro-extracted and dried for 30min at 60-70 o C.
a staining solution 0.8 g/l FD + C Red 40, 0.4 g/l citric acid, 0.1 g/l non-ionic wetting agent
FC fluorocarbon (Scotchguard FC 397)
SB stain blocker (Mesitol NBS) Stainblocker Treatments on Nylon 6 and 66 Example Treatment ⁇ E(24 hour) nylon 6 nylon 66 Untreated 52.7 43.3 7 5% Mesitol NBS 3.9 3.3 8 5% Mesitol NBS, 2% Baylan NT 3.3 2.8 9 2% FC 397, 5% Mesitol NBS 4.8 4.5 10 2% FC 397, 5% Mesitol NBS, 2% Baylan NT 3.8 4.5
Figure 1 shows a durability trial using a hexapod carpet wear testing mechanism.
the carpet samples were all stained with a solution of a food dye, Amaranth, 0.08 g/l by introducing 10ml of the dye solution onto the carpet surface using a standard stain applicator which evenly applies the dye solution over an 80 mm diameter circular area. This was left to dry for 24 h and removal of the stain was attempted using a commercial hot water extraction carpet shampooer with appropriate detergent. The carpet was then dried and the amount of residual stain remaining was measured by a Minolta Chroma-meter CR110 with the results calculated as colour difference ( ⁇ E) with respect to the unstained carpet.
⁇ E colour difference
Figure 2 shows results of staining carried out after various numbers of shampooing cycles.
Baykanol HLX treated samples showed some loss of stain-resistance after shampooing; with Baylan NT as an auxiliary and an aluminium sulphate aftertreatment there is virtually no loss in stain-resistance after shampooing.

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Textile Engineering (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Coloring (AREA)

EP89307682A 1988-07-27 1989-07-27 Composition antitache Withdrawn EP0353080A1 (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
NZ225580		1988-07-27
NZ22558088		1988-07-27
NZ227981		1989-02-14
NZ22798189		1989-02-14

Publications (1)

Publication Number	Publication Date
EP0353080A1 true EP0353080A1 (fr)	1990-01-31

Family

ID=26650814

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP89307682A Withdrawn EP0353080A1 (fr)	1988-07-27	1989-07-27	Composition antitache

Country Status (2)

Country	Link
EP (1)	EP0353080A1 (fr)
JP (1)	JPH02264071A (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5252375A (en) *	1990-03-22	1993-10-12	Interface, Inc.	Permanent stain resistant treatment for polyamide fibers
US5350426A (en) *	1990-05-04	1994-09-27	Burlington Industries, Inc.	Chlorine resistant cationic dyeable carpet yarn
US5516337A (en) *	1992-09-02	1996-05-14	Minnesota Mining And Manufacturing Company	Chemical system for providing fibrous materials with stain resistance
US5948480A (en) *	1997-03-31	1999-09-07	E.I. Du Pont De Nemours And Company	Tandem application of soil and stain resists to carpeting
US6068805A (en) *	1999-01-11	2000-05-30	3M Innovative Properties Company	Method for making a fiber containing a fluorochemical polymer melt additive and having a low melting, high solids spin finish
US6077468A (en) *	1999-01-11	2000-06-20	3M Innovative Properties Company	Process of drawing fibers
US6117353A (en) *	1999-01-11	2000-09-12	3M Innovative Properties Company	High solids spin finish composition comprising a hydrocarbon surfactant and a fluorochemical emulsion
US6120695A (en) *	1999-01-11	2000-09-19	3M Innovative Properties Company	High solids, shelf-stable spin finish composition
US6207088B1 (en)	1999-01-11	2001-03-27	3M Innovative Properties Company	Process of drawing fibers through the use of a spin finish composition having a hydrocarbon sufactant, a repellent fluorochemical, and a fluorochemical compatibilizer
US6537662B1 (en)	1999-01-11	2003-03-25	3M Innovative Properties Company	Soil-resistant spin finish compositions
US6613862B2 (en)	1998-04-30	2003-09-02	3M Innovative Properties Company	Treatment of fibrous substrates to impart repellency, stain resistance, and soil resistance
WO2006108240A1 (fr) *	2005-04-14	2006-10-19	Feltex Australia Pty Ltd	Procédé de traitement de tapis

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU2011326497A1 (en) *	2010-11-12	2013-05-23	Invista Technologies S.A R.L.	Aqueous dispersion of dye, stain-blocker, and fluorochemical and its use in the manufacture of carpet

Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3459696A (en) *	1965-06-24	1969-08-05	Du Pont	Water-repellent compositions
GB1165203A (en) *	1966-01-21	1969-09-24	Minnesota Mining & Mfg	Fluorocarbon Copolymers
FR2277927A1 (fr) *	1974-07-12	1976-02-06	Martin Inc H C A	Traitement de matieres textiles, notamment traitement antistatique
EP0242496A1 (fr) *	1986-03-06	1987-10-28	Monsanto Company	Fibres en nylon résistant aux taches
WO1988002042A2 (fr) *	1986-09-08	1988-03-24	Allied Corporation	Procede d'amelioration de la resistance aux taches d'un polyamide

1989
- 1989-07-27 JP JP1195388A patent/JPH02264071A/ja active Pending
- 1989-07-27 EP EP89307682A patent/EP0353080A1/fr not_active Withdrawn

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3459696A (en) *	1965-06-24	1969-08-05	Du Pont	Water-repellent compositions
GB1165203A (en) *	1966-01-21	1969-09-24	Minnesota Mining & Mfg	Fluorocarbon Copolymers
FR2277927A1 (fr) *	1974-07-12	1976-02-06	Martin Inc H C A	Traitement de matieres textiles, notamment traitement antistatique
EP0242496A1 (fr) *	1986-03-06	1987-10-28	Monsanto Company	Fibres en nylon résistant aux taches
WO1988002042A2 (fr) *	1986-09-08	1988-03-24	Allied Corporation	Procede d'amelioration de la resistance aux taches d'un polyamide

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5252375A (en) *	1990-03-22	1993-10-12	Interface, Inc.	Permanent stain resistant treatment for polyamide fibers
US5350426A (en) *	1990-05-04	1994-09-27	Burlington Industries, Inc.	Chlorine resistant cationic dyeable carpet yarn
US5516337A (en) *	1992-09-02	1996-05-14	Minnesota Mining And Manufacturing Company	Chemical system for providing fibrous materials with stain resistance
US5948480A (en) *	1997-03-31	1999-09-07	E.I. Du Pont De Nemours And Company	Tandem application of soil and stain resists to carpeting
US6613862B2 (en)	1998-04-30	2003-09-02	3M Innovative Properties Company	Treatment of fibrous substrates to impart repellency, stain resistance, and soil resistance
US6117353A (en) *	1999-01-11	2000-09-12	3M Innovative Properties Company	High solids spin finish composition comprising a hydrocarbon surfactant and a fluorochemical emulsion
US6077468A (en) *	1999-01-11	2000-06-20	3M Innovative Properties Company	Process of drawing fibers
US6120695A (en) *	1999-01-11	2000-09-19	3M Innovative Properties Company	High solids, shelf-stable spin finish composition
US6207088B1 (en)	1999-01-11	2001-03-27	3M Innovative Properties Company	Process of drawing fibers through the use of a spin finish composition having a hydrocarbon sufactant, a repellent fluorochemical, and a fluorochemical compatibilizer
US6468452B1 (en)	1999-01-11	2002-10-22	3M Innovative Properties Company	Process of drawing fibers
US6537662B1 (en)	1999-01-11	2003-03-25	3M Innovative Properties Company	Soil-resistant spin finish compositions
US6536804B1 (en)	1999-01-11	2003-03-25	3M Innovative Properties Company	High solids spin finish composition comprising a hydrocarbon surfactant and a fluorochemical emulsion
US6068805A (en) *	1999-01-11	2000-05-30	3M Innovative Properties Company	Method for making a fiber containing a fluorochemical polymer melt additive and having a low melting, high solids spin finish
WO2006108240A1 (fr) *	2005-04-14	2006-10-19	Feltex Australia Pty Ltd	Procédé de traitement de tapis

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Publication number	Publication date
JPH02264071A (ja)	1990-10-26

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1992-07-29	18D	Application deemed to be withdrawn	Effective date: 19920201

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