EP0375572A1 - Tiefziehbare Aluminiumlegierung, die Silicium, Magnesium und Kupfer enthält - Google Patents
Tiefziehbare Aluminiumlegierung, die Silicium, Magnesium und Kupfer enthält Download PDFInfo
- Publication number
- EP0375572A1 EP0375572A1 EP89420499A EP89420499A EP0375572A1 EP 0375572 A1 EP0375572 A1 EP 0375572A1 EP 89420499 A EP89420499 A EP 89420499A EP 89420499 A EP89420499 A EP 89420499A EP 0375572 A1 EP0375572 A1 EP 0375572A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- content
- contents
- transformation
- dissolution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 17
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 8
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 6
- 229910000838 Al alloy Inorganic materials 0.000 title claims abstract description 5
- 239000010949 copper Substances 0.000 title claims abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title 1
- 239000011777 magnesium Substances 0.000 title 1
- 239000010703 silicon Substances 0.000 title 1
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 14
- 239000000956 alloy Substances 0.000 claims abstract description 14
- 230000009466 transformation Effects 0.000 claims abstract description 10
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 8
- 238000000265 homogenisation Methods 0.000 claims abstract description 8
- 238000004090 dissolution Methods 0.000 claims abstract description 7
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 238000007493 shaping process Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract 6
- 239000000203 mixture Substances 0.000 claims description 8
- 238000005452 bending Methods 0.000 claims description 4
- 238000010791 quenching Methods 0.000 claims description 3
- 230000000171 quenching effect Effects 0.000 claims description 3
- 238000009749 continuous casting Methods 0.000 claims description 2
- 238000000137 annealing Methods 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 238000013000 roll bending Methods 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 3
- 238000001953 recrystallisation Methods 0.000 description 3
- 229910019752 Mg2Si Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910019064 Mg-Si Inorganic materials 0.000 description 1
- 229910019406 Mg—Si Inorganic materials 0.000 description 1
- 229910007981 Si-Mg Inorganic materials 0.000 description 1
- 229910008316 Si—Mg Inorganic materials 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
- C22C21/08—Alloys based on aluminium with magnesium as the next major constituent with silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/12—Alloys based on aluminium with copper as the next major constituent
- C22C21/14—Alloys based on aluminium with copper as the next major constituent with silicon
Definitions
- the invention relates to an Al alloy essentially containing Si, Mg and Cu intended for the manufacture of stampable sheets or strips, in particular sheets used in automobile bodywork.
- the alloy responding to the problem posed above has the following composition by weight:
- the Mn content is further limited since this element has the following disadvantages in higher quantities: . It gives rise to the solidification of intermetallic compounds based on Fe, Mn, Si which reduce the deformation capacity of the alloy and can initiate decohesions and ruptures, during shaping operations; . It increases the critical quenching speed and therefore limits the possibilities of heat treatments for thick products; . It gives the alloy a fairly poor corrosion behavior; . It is not suitable for short-term homogenizations, such as those generally obtained in passage ovens.
- the manufacturing range used generally includes the following operations: . continuous or semi-continuous casting of blanks, possible homogenization, hot transformation, possible cold transformation, dissolution and tempering.
- homogenization at high temperature between 520 ° C and 560 ° C with a holding time of 6 to 24 hours is desirable. Homogenization is preferably preceded by a slow rise in temperature.
- the temperature at the end of hot transformation to avoid these recrystallizations, must imperatively be between 270 ° and 320 ° C.
- the alloy After possible cold transformation, the alloy is put into a complete solution. This takes place in the temperature range between 520 and 560 ° C, and preferably between 530 ° and 550 ° C by targeting the temperature of 550 ° C.
- the rise in temperature before dissolving must be rapid (V ⁇ 10 ° C / sec) and dissolving preferably performed either in a pass-through oven or in a sheet-to-sheet processing oven.
- the processing time varies from a few seconds to a few minutes, without being able to exceed one hour.
- the sheets and strips thus obtained have good isotropy and an average grain size generally not exceeding 60 ⁇ m.
- the quenching must be rapid and depends on the thickness of the product. For sheets and strips, it is generally carried out in calm or pulsed air.
- the parts undergo hardening income, under the usual conditions; the hardening is due to the precipitation of the Mg2Si phase and of AlCuMgSi complex phases. Tempering is typically carried out between 8 and 12 hrs around 165 ° C.
- FIG. 1 giving the field of composition of alloys in the Mg-Si plane and is illustrated by the following example: - A 1100x300x2850 mm3 plate of the following weight composition was poured semi-continuously: Yes 1.05% Mg 0.4% Cu 0.7% Mn 0.25% + Fe 0.24% Ti 0.035% Rest A1
- This plate was homogenized at 530 ° C-8h and immediately hot rolled; up to 4 mm thick, the final rolling temperature was 300 ° C; the strip thus obtained has been cold rolled until 1.2 mm thick, then dissolved in a passing oven at 550 ° C (about 1 min at temperature) at a speed of 20 m / min and quenched in a mist (air + water).
- an alloy with the following weight composition If: 1%; Mg: 0.4%; Cu: 0.15%; Mn: 0.1%; rest Al and usual impurities having followed the same range of transformation and heat treatment as above, has the following characteristics in state T4: R 0.2 (MPa) Rm (MPa) AT (%) 100 205 26.5
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cookers (AREA)
- Continuous Casting (AREA)
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Lead Frames For Integrated Circuits (AREA)
- Conductive Materials (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT89420499T ATE90978T1 (de) | 1988-12-21 | 1989-12-19 | Tiefziehbare aluminiumlegierung, die silicium, magnesium und kupfer enthaelt. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8817621 | 1988-12-21 | ||
| FR8817621A FR2642436B1 (fr) | 1988-12-21 | 1988-12-21 | Alliage d'a1 contenant essentiellement du si, du mg et du cu pour emboutissage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0375572A1 true EP0375572A1 (de) | 1990-06-27 |
| EP0375572B1 EP0375572B1 (de) | 1993-06-23 |
Family
ID=9373742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89420499A Expired - Lifetime EP0375572B1 (de) | 1988-12-21 | 1989-12-19 | Tiefziehbare Aluminiumlegierung, die Silicium, Magnesium und Kupfer enthält |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0375572B1 (de) |
| AT (1) | ATE90978T1 (de) |
| DE (1) | DE68907332T2 (de) |
| ES (1) | ES2041438T3 (de) |
| FR (1) | FR2642436B1 (de) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995014113A1 (fr) * | 1993-11-17 | 1995-05-26 | Pechiney Rhenalu | Alliage de type aluminium-silicon-magnesium a ductilite et emboutissabilite ameliorees et procede d'obtention |
| EP0714993A1 (de) * | 1994-11-29 | 1996-06-05 | Alusuisse-Lonza Services AG | Tiefziehbare und schweissbare Aluminiumlegierung vom Typ ALMgSi |
| FR2748035A1 (fr) * | 1996-04-29 | 1997-10-31 | Pechiney Rhenalu | Alliage aluminium-silicium-magnesium pour carrosserie automobile |
| WO1997047779A1 (en) * | 1996-06-14 | 1997-12-18 | Aluminum Company Of America | Highly formable aluminum alloy rolled sheet |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2360684A1 (fr) * | 1976-08-05 | 1978-03-03 | Aluminum Co Of America | Elements de structure ameliores en aluminium, pour vehicules automobiles |
| US4424084A (en) * | 1980-08-22 | 1984-01-03 | Reynolds Metals Company | Aluminum alloy |
| US4614552A (en) * | 1983-10-06 | 1986-09-30 | Alcan International Limited | Aluminum alloy sheet product |
| WO1987002712A1 (en) * | 1985-11-04 | 1987-05-07 | Aluminum Company Of America | Aluminum alloy vehicular member |
| US4788037A (en) * | 1982-11-30 | 1988-11-29 | Kabushiki Kaisha Kobe Seiko Sho | High strength, corrosion-resistant aluminum alloys for brazing |
-
1988
- 1988-12-21 FR FR8817621A patent/FR2642436B1/fr not_active Expired - Fee Related
-
1989
- 1989-12-19 AT AT89420499T patent/ATE90978T1/de active
- 1989-12-19 DE DE89420499T patent/DE68907332T2/de not_active Expired - Lifetime
- 1989-12-19 EP EP89420499A patent/EP0375572B1/de not_active Expired - Lifetime
- 1989-12-19 ES ES198989420499T patent/ES2041438T3/es not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2360684A1 (fr) * | 1976-08-05 | 1978-03-03 | Aluminum Co Of America | Elements de structure ameliores en aluminium, pour vehicules automobiles |
| US4424084A (en) * | 1980-08-22 | 1984-01-03 | Reynolds Metals Company | Aluminum alloy |
| US4788037A (en) * | 1982-11-30 | 1988-11-29 | Kabushiki Kaisha Kobe Seiko Sho | High strength, corrosion-resistant aluminum alloys for brazing |
| US4614552A (en) * | 1983-10-06 | 1986-09-30 | Alcan International Limited | Aluminum alloy sheet product |
| WO1987002712A1 (en) * | 1985-11-04 | 1987-05-07 | Aluminum Company Of America | Aluminum alloy vehicular member |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995014113A1 (fr) * | 1993-11-17 | 1995-05-26 | Pechiney Rhenalu | Alliage de type aluminium-silicon-magnesium a ductilite et emboutissabilite ameliorees et procede d'obtention |
| FR2713664A1 (fr) * | 1993-11-17 | 1995-06-16 | Pechiney Rhenalu | Alliage type Al-Si-Mg à ductilité et emboutissabilité améliorées et procédé d'obtention. |
| EP0714993A1 (de) * | 1994-11-29 | 1996-06-05 | Alusuisse-Lonza Services AG | Tiefziehbare und schweissbare Aluminiumlegierung vom Typ ALMgSi |
| CH688379A5 (de) * | 1994-11-29 | 1997-08-29 | Alusuisse Lonza Services Ag | Tiefziehbare und schweissbare Aluminiumlegierung vom Typ AlMgSi |
| FR2748035A1 (fr) * | 1996-04-29 | 1997-10-31 | Pechiney Rhenalu | Alliage aluminium-silicium-magnesium pour carrosserie automobile |
| WO1997041272A1 (fr) * | 1996-04-29 | 1997-11-06 | Pechiney Rhenalu | Alliage aluminium-silicium-magnesium pour carrosserie automobile |
| WO1997047779A1 (en) * | 1996-06-14 | 1997-12-18 | Aluminum Company Of America | Highly formable aluminum alloy rolled sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2642436B1 (fr) | 1991-06-14 |
| ATE90978T1 (de) | 1993-07-15 |
| DE68907332T2 (de) | 1993-11-11 |
| DE68907332D1 (de) | 1993-07-29 |
| EP0375572B1 (de) | 1993-06-23 |
| FR2642436A1 (fr) | 1990-08-03 |
| ES2041438T3 (es) | 1993-11-16 |
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