EP0397146A2 - Matériau photosensible pour électrophotographie du type laminé - Google Patents
Matériau photosensible pour électrophotographie du type laminé Download PDFInfo
- Publication number
- EP0397146A2 EP0397146A2 EP90108738A EP90108738A EP0397146A2 EP 0397146 A2 EP0397146 A2 EP 0397146A2 EP 90108738 A EP90108738 A EP 90108738A EP 90108738 A EP90108738 A EP 90108738A EP 0397146 A2 EP0397146 A2 EP 0397146A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- charge
- transporting
- photosensitive material
- generating
- electrophotography
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording-members for original recording by exposure, e.g. to light, to heat or to electrons; Manufacture thereof; Selection of materials therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G5/00—Recording-members for original recording by exposure, e.g. to light, to heat or to electrons; Manufacture thereof; Selection of materials therefor
- G03G5/02—Charge-receiving layers
- G03G5/04—Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G5/043—Photoconductive layers characterised by having two or more layers or characterised by their composite structure
- G03G5/047—Photoconductive layers characterised by having two or more layers or characterised by their composite structure characterised by the charge-generation layers or charge transport layers
Definitions
- the present invention relates to a laminate type photosensitive material for the electrophotography, which comprises a charge-generating layer and a charge-transporting layer, which are formed on an electroconductive substrate.
- a laminate type photosensitive material having the above-mentioned structure has been publicly known as the so-called function-separated photosensitive material.
- a substance having a higher ionization potential than that of the charge-transporting substance is used as the charge-generating substance.
- the charge-generating material and the charge-transporting material are used in the above-mentioned combination, when the photosensitive material is used repeatedly, the stability of the surface potential is bad.
- Another object of the present invention is to provide a laminate type photosensitive material for the electrophotography, in which the stability at the repeated use is improved by preventing the deterioration by light or heat.
- a laminate type photosensitive material for the electrophotography which comprises a charge-generating layer and a charge-transporting layer, which are formed on an electroconductive substrate, wherein the charge-transporting layer comprises a first charge-transporting material having an ionization potential smaller than that of a charge-generating material used for the charge-generating layer and a second charge-transporting material having an ionization potential larger than that of the charge-generating material.
- the present invention is prominently characterized in that a charge-transporting material having an ionization potential smaller than that of an charge-generating material used for the charge-generating layer and a charge-transporting material having an ionization potential larger than that of the charge-generating material are used in combination as the charge-transporting material constituting the charge-transporting layer.
- the laminate type photosensitive material of the present invention comprises an electroconductive substrate, a charge-generating layer formed on the substrate and a charge-transporting layer formed on the charge-generating layer.
- a sheet or drum formed of a foil or sheet of a metal such as aluminum, copper or tin or a tin plate is used as the electroconductive substrate.
- a substrate formed by depositing a metal as mentioned above on a film substrate such as a biaxially drawn polyester film or a glass substrate by vacuum deposition, sputtering or electroless plating can be used.
- a film substrate such as a biaxially drawn polyester film or a glass substrate by vacuum deposition, sputtering or electroless plating
- an electroconductively treated paper sheet can be used.
- the charge-generating layer formed on the above-mentioned electroconductive substrate is formed of a dispersion of a charge-generating material in an electrically insulating binder resin.
- Known electrically insulating materials can be used.
- a polyester resin an acrylic resin, a styrene resin, an epoxy resin, a silicone resin, an alkyd resin and a vinyl chloride/vinyl acetate copolymer resin can be used.
- any of materials capable of generating carriers on receipt of light known in the field of the electrophotography, can be used as the charge-generating material.
- a phthalocyanine pigment for example, there can be mentioned a phthalocyanine pigment, a perylene pigment, a quinacridone pigment, a pyranthrone pigment, a disazo pigment and a trisazo pigment.
- the charge-generating material is finely dispersed in the form of particles having a particle size smaller than 5 ⁇ m in the binder resin, and the charge-generating material is used in an amount of 5 to 100 parts by weight, especially 10 to 50 parts by weight, per 100 parts by weight of the binder resin.
- the charge-generating layer is formed in a thickness of 0.05 to 3 ⁇ m, especially 0.3 to 1 ⁇ m.
- the charge-transporting layer formed on the charge-generating layer is formed of a dispersion of a charge-transporting material in a binder resin as described above with respect to the charge-generating layer.
- a first charge-transporting material having an ionization potential smaller than that of the used charge-generating material and a second charge-generating material having an ionization potential larger than that of the used charge-generating material are used in combination as the charge-transporting material.
- charge-transporting materials can be used in the present invention, and two kinds of charge-generating materials satisfying the above requirement are used in combination.
- the difference of each of the ionization potentials of the first and second charge-transporting materials from that of the charge-generating material be within ⁇ 0.2 eV.
- the ionization potential of the first charge-transporting material is too small, the reduction of the surface potential is too large, and if the ionization potential (abbreviated to "Ip" hereinafter) of the second charge-transporting material is too large, the injection of holes becomes difficult and the accumulation of residual charges tends to increase.
- first charge-transporting material and second charge-transportion material be used in such amounts that the weight ratio of the first charge-transporting material to the second charge-transporting material be from 10/90 to 90/10, especially from 30/70 to 70/30.
- the charge-transporting materials are used in a total amount of 50 to 300 parts by weight, especially 70 to 100 parts by weight, per 100 parts by weight of the binder resin.
- phenol type antioxidant that can be used in the present invention, there can be mentioned 2,6-t-butyl-p-cresol, triethylene glycol-bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)] propionate, octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate, bis(1,2,2,6,6-pentamethyl-4-piperidyl) 2-(3,5-di-t-butyl-4-hydroxybenzyl)-2-n-butylmalonate and 4,4′-thiobis(3-methyl-6-t-butylphenol).
- phenol type antioxidants can be used singly or in the form of mixtures of two or more of them.
- octadecyl-3-(3,5-di-t-butyl-4-hydroxydiphenyl) propionate and bis(1,2,2,6,6-pentamethyl-4-piperidyl) 2-(3,5-di-t-butyl-4-hydroxybenzyl)-2-n-butyl-malonate are preferably used.
- the phenol type antioxidant is used in an amount of 5 to 50 parts by weight per 100 parts by weight of the binder resin. If the amount used of the phenol type antioxidant exceeds 50 parts by weight, the sensitivity is reduced and the residual potential rises at the repeated use. If the amount of the phenol type antioxidant is smaller than 5 parts by weight, a sufficient stability of the surface potential cannot be obtained at the repeated use.
- the charge-transporting layer is formed in a thickness of 10 to 30 ⁇ m, especially 15 to 20 ⁇ m.
- a ball mill was charged with 100 parts by weight polyvinyl butyral (S-Lec BL1 supplied by Sekisui Kagaku) as the binder, 200 parts by weight of metal-free phthalocyanine as the charge-generating material and a predetermined amount of tetrahydrofuran, and the mixture was stirred for 24 hours to form a charge-generating layer-forming coating liquid.
- the obtained coating liquid was coated on an aluminum drum by the dipping method and dried with hot air at 110°C for 30 minutes to effect curing and form a charge-generating layer having a thickness of 0.5 ⁇ m.
- a homomixer 100 parts by weight of a polycarbonate resin (Upiron supplied by Mitsubishi Gas Kagaku) as the binder, 70 parts by weight of N,N′-bis(o,p-dimethylphenyl)-N,N′-(diphenyl)benzidine (hereinafter referred to as "4Me-TPD") and 30 parts by weight of 1,1-bis(p-diethylaminophenyl)-4,4-diphenyl-1,3-butadiene (hereinafter referred to as "T-405") as the charge-transporting material, and a predetermined amount of toluene were mixed and stirred to form a charge-transporting layer-forming coating liquid.
- a polycarbonate resin Upiron supplied by Mitsubishi Gas Kagaku
- the coating liquid was coated on the surface of the charge-generating layer by the dipping method and dried with hot air at 110°C for 30 minutes to form a charge-transporting layer having a thickness of about 20 ⁇ m.
- a photosensitive material for the electrophotography was prepared.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that the charge-transporting material used for the formation of the charge-transporting material was changed to 60 parts by weight of 4Me-TPD and 40 parts by weight of T-405.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that the charge-transporting material used for the formation of the charge-transporting layer was changed to 50 parts by weight of 4Me-TPD and 50 parts by weight of T-405.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that the charge-transporting material used for the formation of the charge-transporting layer was changed to 40 parts by weight of 4Me-TPD and 60 parts by weight of T-405.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that the charge-transporting material used for the formation of the charge-transporting layer was changed to 30 parts by weight of 4Me-TPD and 70 parts by weight of T-405.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that 70 parts by weight of 4Me-TPD and 30 parts by weight of 4-(N,N- diethylamino)benzaldehyde-N,N-diphenylhydrazone instead of T-405 were used as the charge-transporting material for the formation of the charge-transporting layer.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that the charge-transporting material used for the formation of the charge-transporting layer was changed to 100 parts by weight of 4Me-TPD.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that the charge-transporting material used for the formation of the charge-transporting layer was changed to 100 parts by weight of T-405.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 1 except that 5 parts by weight of 2,6-di-t-butyl-p-cresol (BHT supplied by Kawaguchi Kagaku) was added as the phenol type antioxidant.
- BHT 2,6-di-t-butyl-p-cresol
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 25 parts by weight of 2,6-di-t-butyl-p-cresol (BHT supplied by Kawaguchi Kagaku) was used as the phenol type antioxidant.
- BHT 2,6-di-t-butyl-p-cresol
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 50 parts by weight of 2,6-di-t-butyl-p-cresol (BHT supplied by Kawaguchi Kagaku) was used as the phenol type antioxidant.
- BHT 2,6-di-t-butyl-p-cresol
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 5 parts by weight of triethylene glycol bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate] (Irganox 245 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 25 parts by weight of triethylene glycol bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate] (Irganox 245 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 50 parts by weight of triethylene glycol bis[3-(3-t-butyl-5-methyl-4-hydroxyphenyl)propionate] (Irganox 245 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 5 parts by weight of octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate (Irganox 1076 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 25 parts by weight of octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate (Irganox 1076 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 50 parts by weight of octadecyl-3-(3,5-di-t-butyl-4-hydroxyphenyl)propionate (Irganox 1076 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 5 parts by weight of bis(1,2,2,6,6-pentamethyl-4-piperidyl 2-(3,5-di-t-butyl-4-hydroxybenzyl)-2-n-butylmalonate (Tinuvin 144 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 25 parts by weight of bis(1,2,2,6,6-pentamethyl-4-piperidyl 2-(3,5-di-t-butyl-4-hydroxybenzyl)-2-n-butyl-malonate (Tinuvin 144 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 50 parts by weight of bis(1,2,2,6,6-pentamethyl-4-piperidyl 2-(3,5-di-t-butyl-4-hydroxybenzyl)-2-n-butylmalonate (Tinuvin 144 supplied by Ciba-Geigy) was used as the phenol type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 10 parts by weight of 4,4′-isopropylidene-diphenol alkyl (C12 to C15) phosphite (Mark 1500 supplied by Adeca-Argus) was used as the phosphorus type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 10 parts by weight of diisodecyl pentaerythritol diphosphite (Himo supplied by Sanko Kagaku) was used as the phosphorus type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 10 parts by weight of 1,3-bis(dimethylaminopropyl-2-thiourea (Nolax NS10 supplied by Ouchi Shinko Kagaku) was used as the amine type antioxidant.
- a photosensitive material for the electrophotography was prepared in the same manner as described in Example 7 except that 10 parts by weight of bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate (Sanol 770 supplied by Sankyo Kagaku) was used as the amine type antioxidant. (Evaluation of Photosensitive Materials for Electrophotography).
- Photographic characteristics such as the charging capacity and residual potential were measured by using an apparatus as shown in Fig. 2.
- a photosensitive material 5 obtained in each example was negatively charged by carrying out corona discharge under -6 kV by using Corontron 1 while rotating the photosensitive material 5, and the surface potential V SP (V) was measured by a surface potentiometer arranged at a position 7.
- the surface potential V 100SP (V) was measured after 100 cycles of the above-mentioned electrophotographic process and the difference ⁇ V SP (V) between this surface potential and the initial surface potential V SP (V) of the photosensitive material was calculated.
- the photosensitive material of Comparative Example 1 had a high residual potential, though the stability of the surface potential at the repeated use was good.
- the photosensitive material of Comparative Example 2 had no stability of the surface potential at the repeated use, though the residual potential was low.
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Photoreceptors In Electrophotography (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP114308/89 | 1989-05-09 | ||
| JP1114308A JPH02293853A (ja) | 1989-05-09 | 1989-05-09 | 積層型電子写真用感光体 |
| JP313645/89 | 1989-11-30 | ||
| JP31364589A JPH06103394B2 (ja) | 1989-11-30 | 1989-11-30 | 積層型電子写真用感光体 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0397146A2 true EP0397146A2 (fr) | 1990-11-14 |
| EP0397146A3 EP0397146A3 (fr) | 1991-04-24 |
| EP0397146B1 EP0397146B1 (fr) | 1994-08-03 |
Family
ID=26453088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP90108738A Expired - Lifetime EP0397146B1 (fr) | 1989-05-09 | 1990-05-09 | Matériau photosensible pour électrophotographie du type laminé |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP0397146B1 (fr) |
| KR (1) | KR960010180B1 (fr) |
| CA (1) | CA2016257C (fr) |
| DE (1) | DE69011185T2 (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1073935A4 (fr) * | 1998-04-24 | 2004-10-27 | Lexmark Int Inc | Photoconducteurs a deux couches comportant une couche productrice de charge qui contient un compose de transport de charge |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5767934A (en) * | 1980-10-16 | 1982-04-24 | Konishiroku Photo Ind Co Ltd | Electrophotographic receptor |
-
1990
- 1990-05-08 CA CA002016257A patent/CA2016257C/fr not_active Expired - Fee Related
- 1990-05-09 KR KR1019900006505A patent/KR960010180B1/ko not_active Expired - Fee Related
- 1990-05-09 EP EP90108738A patent/EP0397146B1/fr not_active Expired - Lifetime
- 1990-05-09 DE DE69011185T patent/DE69011185T2/de not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1073935A4 (fr) * | 1998-04-24 | 2004-10-27 | Lexmark Int Inc | Photoconducteurs a deux couches comportant une couche productrice de charge qui contient un compose de transport de charge |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0397146B1 (fr) | 1994-08-03 |
| CA2016257C (fr) | 1995-09-05 |
| EP0397146A3 (fr) | 1991-04-24 |
| KR960010180B1 (ko) | 1996-07-26 |
| CA2016257A1 (fr) | 1990-11-09 |
| DE69011185T2 (de) | 1994-12-08 |
| DE69011185D1 (de) | 1994-09-08 |
| KR900018749A (ko) | 1990-12-22 |
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