EP0410877B1 - Zusammensetzung für chemische und biologische Reinigung von verunreinigtem Wasser und Verfahren für ihre Zubereitung - Google Patents

Zusammensetzung für chemische und biologische Reinigung von verunreinigtem Wasser und Verfahren für ihre Zubereitung Download PDF

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Publication number
EP0410877B1
EP0410877B1 EP19900402135 EP90402135A EP0410877B1 EP 0410877 B1 EP0410877 B1 EP 0410877B1 EP 19900402135 EP19900402135 EP 19900402135 EP 90402135 A EP90402135 A EP 90402135A EP 0410877 B1 EP0410877 B1 EP 0410877B1
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EP
European Patent Office
Prior art keywords
bacteria
composition
composition according
water
mineral substances
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP19900402135
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English (en)
French (fr)
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EP0410877A1 (de
Inventor
Jean-Claude Van Den Hecke
Estelle Dubourg
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HECKE JEAN CLAUDE VAN DEN
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HECKE JEAN CLAUDE VAN DEN
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Priority to AT90402135T priority Critical patent/ATE98941T1/de
Publication of EP0410877A1 publication Critical patent/EP0410877A1/de
Application granted granted Critical
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/02—Aerobic processes
    • C02F3/10—Packings; Fillings; Grids
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N11/00—Carrier-bound or immobilised enzymes; Carrier-bound or immobilised microbial cells; Preparation thereof
    • C12N11/14—Enzymes or microbial cells immobilised on or in an inorganic carrier
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00—Technologies for wastewater treatment
    • Y02W10/10—Biological treatment of water, waste water, or sewage

Definitions

  • the present invention relates to a composition of matter for the chemical and biological purification of polluted water.
  • the invention relates in particular to a mineral and biological composition intended to be spread in the water to be purified, allowing in particular the purification and the degradation of urban, industrial, agro-food, solid or liquid fermentable discharges, accidental pollution, l entophysation and destrophysation of rivers, ponds and pollution prevention above.
  • the object of the present invention is to remedy the drawbacks of known biological purification methods by proposing a composition of material which is both effective and inexpensive.
  • the first material that is to say lime carbonate, has a high porosity and therefore a large contact surface favorable to ionic exchanges with the medium to be purified.
  • the second material consisting of a hydrated alumina silicate, makes it possible to trap the ammonium ions contained in the polluted water which are transformed into harmless molecules by the bacteria adsorbed in the material.
  • the second material above provides real shelter for bacteria. This second material also makes it possible to adsorb by ion exchange certain heavy metals contained in the polluted medium.
  • the first material consists of lithothmamnium calcareum.
  • This material is of planktonic vegetable origin secreted by mono-cellular algae. Its apparent density is from 1.05 to 1.08, and its real density equal to 2.7.
  • the lithothamnium detects cavities 15 to 20 microns long by 8 to 10 microns wide, where a protoplast is housed which contracts during drying and thus leaves an empty place for biological activity and the reserve of oxygen.
  • This product is collected from the seabed from 20 to 50 meters.
  • the second material is a volcanic stone from the zeolite family (alkaline earth hydrated alumina silicate) formed under well-defined temperature and pressure conditions and in the presence of water.
  • zeolite family alkaline earth hydrated alumina silicate
  • This material is of cavernous structure forming micro-channels whose diameter is of the order of a few ⁇ which can represent up to 50% of the volume; they are filled with water which can be removed by heat in a reversible process up to 350 ° C.
  • the structure contains alkaline earth cations of electrical compensation (charge imbalances of Si-Al units) which are located either in the micro-channels or in locations adjacent to the cavities. They are generally exchangeable with heavy metals contained in the polluted environment.
  • this material has the properties of above all: the ion exchange capacity, its large absorption surface which is several hundred m2 / g allowing it to create a real molecular sieve.
  • the composition also contains an anamorphic potassium alumina silicate, the structure of which comprises microcavities.
  • microcavities have a size between 1 and 10 microns, the average dimension being of the order of 5 microns.
  • This compound can exchange potassium with most cations in solution in water.
  • the exchange reaction for example with lead in the form of nitrate, is written: 3 Al2O3, 6 SiO2, 2 K2O, 2 H2O + 2 Pb (NO3) 2 ⁇ 3 Al2O3, 6 SiO2, 2 PbO, 2 H2O + KNO3
  • alumino-silicates are completely insoluble products and that the only way to recover the metal, once fixed, is to dissolve with hot hydrofluoric acid and aqua regia.
  • the bacteria adsorbed in said mineral matter, in granular form are chosen from the group comprising pseudomonas, bacilli, lactobacilli and serratia.
  • the preferred bacteria according to the invention are bacillus cereus and bacillus subtilis.
  • the mineral materials used in the composition according to the invention have a preferred particle size of between 10 ⁇ m and 10 mm.
  • the proportions of the three mineral materials are substantially equal. However, we can favor the proportion of one or the other material, depending on the nature of the pollutants which dominate in the medium to be purified.
  • said mineral materials preferably contain, in the adsorbed state, between approximately 103 and 1010 bacteria per gram.
  • the duration of inoculation (first step) is for example between 30 and 40 hours.
  • composition according to the invention provides an effective solution to the problem of toxic waste.
  • the combination of the three materials of the composition according to the invention acts as a buffer, a growth stimulator, and accelerates the degradation process.
  • a growth stimulator for significant and specific pollution, an addition every 8/10 days of specialized bacteria will be made at the appropriate dose depending on the pollution.
  • the humidity of waste, sludge or soil must be scientifically controlled in order to optimize biological activity.
  • composition according to the invention are as follows: - Balancing role for all plant waste. It can be used for composting, biological reactivation of poor lands, and blocking of heavy metals.
  • It can also be used for drinking water before treatment at the factory.
  • composition according to the invention also makes it possible to remove the radioactive elements from the water.
  • the basic sample being a mixture of Marne water with its bottom vases taken from the place called: "bras du chapter".
  • nitrogen and phosphorus were added at the rate of 10 mg / l and 5 mg / l for 100 mg / l of carbon, so that the effectiveness of the treatment of these parameters can be judged. .
  • the phenomenon can be monitored on the fall in dry matter at the bottom of the tubes.
  • the reductions observed range from 30 to 83% of the mass of mud at the start by mineralization of organic matter.
  • the biomass has the time to degrade most of the organic matter, but leaves molecules (amino acids and others) not yet degraded. Since the supply of effluent was constant and important (5% per day), the residence time in the tube became too short, to degrade both the organic matter of the vessels and the soluble COD.
  • Nitrogen is decreased in treated samples with reduction rates ranging from 50 to 78%.
  • the recorded performances are as follows: - Large grains, small grains, calcium sulphate, but without biological effect.
  • BIOFIXATION in accordance with the present invention by its ionic physicochemical quality has formed almost definitively insoluble complexes.
  • composition of the assembly mainly formed of CaO3 is perfectly suitable for chromatographic absorption. Moreover, if we pass an aqueous solution of lead nitrate 10 ⁇ 2M over a column of the product, the water is completely rid of Pb ions. The retention is also spectacular with cupric ions.
  • the big global problem is the elimination of radioactive ions that arise every day.
  • a radioactive water originating from Saclay and having the following composition was treated with a composition according to the invention:
  • the materials constituting the composition according to the invention have a large contact surface and cavities connected together by channels of variable dimensions between 2 and 76 angstroms representing from 35 to 50% of their volume and a minimum surface of 400 m2 at cm3 of materials.
  • This structure on the electrochemical level, includes an additional electron which, to rebalance, will fix the electro-positive ions.
  • a passage of air under pressure can only improve the electrical absorption mechanisms.
  • the physical properties of the biofixation composition according to the invention allow it to be an excellent natural ion exchanger (exchange cavity of 3 to 4 meq / gram).
  • the microscopic structure of the materials offers a set of housings favorable to their fixation and their proliferation.
  • Bacterial activity should provide significant declogging in the continuous system, thus avoiding the troubles of repetitive cleaning.
  • the process according to the invention thus provides better quality of the purified air with reduced servitude compared to the other existing processes.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Microbiology (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Hydrology & Water Resources (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Zoology (AREA)
  • Genetics & Genomics (AREA)
  • Biomedical Technology (AREA)
  • Biotechnology (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Biological Treatment Of Waste Water (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Treatment Of Biological Wastes In General (AREA)
  • Water Treatment By Sorption (AREA)

Claims (8)

  1. Stoffzusammensetzung für die chemische und biologische Klärung von Abwässern, wobei diese Zusammensetzung im zu klärenden Wasser verteilt wird, dadurch gekennzeichnet, daß sie mindestens die zwei folgenden körnigen Mineralstoffe aufweist:
    - ein an Spurenelementen reiches poröses Kalziumkarbonat,
    - ein wasserreiches Aluminiumsilikat zeolithischen Ursprungs, das Erdalkalimetalle enthält und Mikrokanäle aufweist,
    wobei diese zwei Stoffe Bakterien in adsorbiertem Zustand enthalten, die besonders für den biologischen Abbau von organischen Stoffen mit einer Kohlenstoffkette geeignet sind.
  2. Zusammensetzung nach Anspruch 1, dadurch gekennzeichnet, daß das Kalziumkarbonat lithothamnium calcareum ist.
  3. Zusammensetzung nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß sie des weiteren ein Anamorphose-Kaliumaluminiumsilikat enthält, dessen Struktur Mikrohohlräume aufweist.
  4. Zusammensetzung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die in den körnigen Mineralstoffen adsorbierten Bakterien aus der aus Pseudomonas, Bazillen, Lactobazillen und Serratia bestehenden Gruppe ausgewählt sind.
  5. Zusammensetzung nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die Mineralstoffe eine Korngröße zwischen 10 Mikrometer und 10 Millimeter haben.
  6. Zusammensetzung nach Anspruch 4 oder 5, dadurch gekennzeichnet, daß die Anteile der drei Mineralstoffe im wesentlichen gleich sind.
  7. Zusammensetzung nach einem der Anspruche 1 bis 6, dadurch gekennzeichnet, daß die Mineralstoffe ca. 1 000 bis 10 000 000 000 Bakterien pro Gramm in adsorbiertem Zustand enthalten.
  8. Verfahren zur Herstellung der Stoffzusammensetzung nach einem der Anprüche 1 bis 7, gekennzeichnet durch die folgenden Schritte:
    - die Bakterien werden bei einer Temperatur zwischen 25 und 37°C auf einen Nährboden geimpft,
    - der geimpfte Nährboden wird ultrazentrifugiert, so daß der mit Bakterien angereicherte Nährboden in dem körnigen Mineralstoffgemisch konzentriert wird, und
    - das Ganze wird bei einer Temperatur unter 40°C getrocknet.
EP19900402135 1989-07-28 1990-07-25 Zusammensetzung für chemische und biologische Reinigung von verunreinigtem Wasser und Verfahren für ihre Zubereitung Expired - Lifetime EP0410877B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT90402135T ATE98941T1 (de) 1989-07-28 1990-07-25 Zusammensetzung fuer chemische und biologische reinigung von verunreinigtem wasser und verfahren fuer ihre zubereitung.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8910226A FR2650265B1 (fr) 1989-07-28 1989-07-28 Composition de matiere pour l'epuration chimique et biologique des eaux polluees et procede de preparation de cette composition
FR8910226 1989-07-28

Publications (2)

Publication Number Publication Date
EP0410877A1 EP0410877A1 (de) 1991-01-30
EP0410877B1 true EP0410877B1 (de) 1993-12-22

Family

ID=9384267

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19900402135 Expired - Lifetime EP0410877B1 (de) 1989-07-28 1990-07-25 Zusammensetzung für chemische und biologische Reinigung von verunreinigtem Wasser und Verfahren für ihre Zubereitung

Country Status (6)

Country Link
EP (1) EP0410877B1 (de)
AT (1) ATE98941T1 (de)
CA (1) CA2028497A1 (de)
DE (1) DE69005387T2 (de)
ES (1) ES2062447T3 (de)
FR (1) FR2650265B1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023187220A1 (fr) 2022-04-01 2023-10-05 Idrabel Composition pour dégrader une matière organique, son procédé de fabrication et utilisations de celle-ci
WO2023187221A1 (fr) 2022-04-01 2023-10-05 Idrabel Assemblage et procede pour la depollution d'un milieu aquatique

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2694441B1 (fr) * 1992-07-29 1994-09-09 Commissariat Energie Atomique Procédé de décontamination par voie biologique d'effluents aqueux radioactifs de moyenne activité.
FR2699525B1 (fr) * 1992-12-22 1995-03-24 Hecke Jean Claude Van Den Composition de matière pour l'épuration chimique, physique et biologique des liquides aqueux pollués, son procédé de préparation et procédé d'épuration utilisant cette composition.
FR2719304B1 (fr) * 1994-04-29 1996-07-19 Rhone Poulenc Chimie Agent de captation de cation de métaux lourds comprenant un composé du type silicate ou aluminosilicate et un composé du type carbonate.
GB2312893B (en) * 1996-10-21 2001-01-24 Holding Company Belgie Nv Zeolite composition
FR2773794B1 (fr) * 1998-01-19 2000-04-07 Solvay Procede d'epuration d'un milieu aqueux contamine par de l'etain
BE1012344A3 (nl) * 1998-05-29 2000-10-03 Avecom Nv Een toeslagproduct ter verwijdering van ammoniak.
RU2143947C1 (ru) * 1999-08-05 2000-01-10 Общество с ограниченной ответственностью "Адекватные технологии" Сорбент для очистки природных вод и почвы от нефтяных загрязнений "москат"
BE1013375A3 (fr) * 2000-04-05 2001-12-04 Fond Universitaire Luxembourge Procede et installation pour la nitrification d'eaux polluees. '
ES2167246B1 (es) * 2000-07-04 2004-02-16 Biointegral S L Composicion para el tratamiento de residuos humanos.
EP1832556A1 (de) * 2006-03-07 2007-09-12 Aqua Service Schwerin Beratungs- und Betriebsführungsgesellschaft mbH Verfahren zum Betreiben einer biologischen Kläranlage
PT1982759E (pt) 2007-03-21 2011-12-23 Omya Development Ag Carbonato de cálcio com superfície tratada e sua utilização no tratamento de água residual
DE602007000783D1 (de) 2007-06-15 2009-05-07 Omya Development Ag Oberflächenreaktives Calciumkarbonat in Kombination mit einem hydrophoben Adsorptionsmittel zur Wasserbehandlung
US10988728B2 (en) 2013-05-20 2021-04-27 BiOWiSH Technologies, Inc. Microbial-based waste water treatment compositions and methods of use thereof
US10766799B2 (en) 2014-05-23 2020-09-08 Nch Corporation Method for improving quality of aquaculture pond water using a nutrient germinant composition and spore incubation method
US10252928B2 (en) 2014-10-31 2019-04-09 BiOWiSH Technologies, Inc. Method for reducing cyanuric acid in recreational water systems
CA2981198A1 (en) 2015-05-05 2016-11-10 BiOWiSH Technologies, Inc. Microbial compositions and methods for denitrification at high dissolved oxygen levels
US10336636B2 (en) 2015-11-02 2019-07-02 BiOWiSH Technologies, Inc. Methods for reducing evaporative loss from swimming pools
CN112512309A (zh) 2018-05-29 2021-03-16 美国宝微技术股份有限公司 用于提高水生动物的存活率的组合物和方法
US11401500B2 (en) 2018-08-29 2022-08-02 Nch Corporation System, method, and composition for incubating spores for use in aquaculture, agriculture, wastewater, and environmental remediation applications
BE1030406B1 (fr) * 2022-04-01 2023-10-30 Idrabel Procede pour reduire la quantite de cyanobacteries d’un milieu aquatique

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FR1314049A (fr) * 1961-12-13 1963-01-04 Accélérateur de fermentation des déchets organiques et son procédé
US4200528A (en) * 1978-03-29 1980-04-29 Pq Corporation Removing metal ions from aqueous effluents
FR2481257B1 (fr) * 1980-04-25 1986-01-10 Eparco Sa Produit et procede de lutte contre la pollution de l'eau
DE3174671D1 (en) * 1981-10-27 1986-06-26 Lumer Soc Ind Des Prod Chim Process for the preparation of an inoculum for the maintenance of septic tanks and the like, comprising dehydrated microorganisms and enzymes, and inoculums prepared by this process
WO1986007346A1 (fr) * 1985-06-07 1986-12-18 Societe Lemaire Procedes d'epuration d'eau et elimination des polluants a base d'algue marine lithothamnium calcareum

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023187220A1 (fr) 2022-04-01 2023-10-05 Idrabel Composition pour dégrader une matière organique, son procédé de fabrication et utilisations de celle-ci
WO2023187221A1 (fr) 2022-04-01 2023-10-05 Idrabel Assemblage et procede pour la depollution d'un milieu aquatique
BE1030414A1 (fr) 2022-04-01 2023-10-24 Idrabel Assemblage et procede pour la depollution d'un milieu aquatique
BE1030405A1 (fr) 2022-04-01 2023-10-24 Idrabel Composition pour dégrader une matière organique, son procédé de fabrication et utilisations de celle-ci
BE1030405B1 (fr) * 2022-04-01 2023-10-30 Idrabel Composition pour dégrader une matière organique, son procédé de fabrication et utilisations de celle-ci

Also Published As

Publication number Publication date
DE69005387T2 (de) 1994-07-28
ATE98941T1 (de) 1994-01-15
ES2062447T3 (es) 1994-12-16
EP0410877A1 (de) 1991-01-30
FR2650265A1 (fr) 1991-02-01
FR2650265B1 (fr) 1991-11-08
CA2028497A1 (fr) 1992-04-25
DE69005387D1 (de) 1994-02-03

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