EP0429549A1 - Auf stärke basierte erzeugnisse für mikrowellenkochen und -erhitzen - Google Patents
Auf stärke basierte erzeugnisse für mikrowellenkochen und -erhitzenInfo
- Publication number
- EP0429549A1 EP0429549A1 EP19890912077 EP89912077A EP0429549A1 EP 0429549 A1 EP0429549 A1 EP 0429549A1 EP 19890912077 EP19890912077 EP 19890912077 EP 89912077 A EP89912077 A EP 89912077A EP 0429549 A1 EP0429549 A1 EP 0429549A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- product
- degree
- dough
- edible
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920002472 Starch Polymers 0.000 title claims description 31
- 239000008107 starch Substances 0.000 title claims description 31
- 235000019698 starch Nutrition 0.000 title claims description 25
- 238000010411 cooking Methods 0.000 title claims description 23
- 238000010438 heat treatment Methods 0.000 title description 15
- 230000002829 reductive effect Effects 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims description 95
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- 235000013312 flour Nutrition 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 239000004094 surface-active agent Substances 0.000 claims description 25
- 230000001953 sensory effect Effects 0.000 claims description 22
- 235000013305 food Nutrition 0.000 claims description 18
- 230000003993 interaction Effects 0.000 claims description 16
- 235000008429 bread Nutrition 0.000 claims description 15
- 239000007800 oxidant agent Substances 0.000 claims description 15
- 239000003112 inhibitor Substances 0.000 claims description 14
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 102000004190 Enzymes Human genes 0.000 claims description 12
- 108090000790 Enzymes Proteins 0.000 claims description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 108091005804 Peptidases Proteins 0.000 claims description 11
- 239000004365 Protease Substances 0.000 claims description 10
- 239000003638 chemical reducing agent Substances 0.000 claims description 10
- 238000011161 development Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 230000006916 protein interaction Effects 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 9
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 8
- 238000004904 shortening Methods 0.000 claims description 8
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 7
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 claims description 7
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 6
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical group [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims description 6
- JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical group [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 claims description 6
- 239000001230 potassium iodate Substances 0.000 claims description 6
- 235000006666 potassium iodate Nutrition 0.000 claims description 6
- 229940093930 potassium iodate Drugs 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 5
- 150000001728 carbonyl compounds Chemical class 0.000 claims description 5
- -1 diacetyl ester Chemical class 0.000 claims description 5
- DNISEZBAYYIQFB-PHDIDXHHSA-N (2r,3r)-2,3-diacetyloxybutanedioic acid Chemical compound CC(=O)O[C@@H](C(O)=O)[C@H](C(O)=O)OC(C)=O DNISEZBAYYIQFB-PHDIDXHHSA-N 0.000 claims description 4
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 claims description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 4
- 108010024636 Glutathione Proteins 0.000 claims description 4
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- 229960003180 glutathione Drugs 0.000 claims description 4
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 4
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 4
- 229940113124 polysorbate 60 Drugs 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 229940068968 polysorbate 80 Drugs 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 3
- 239000004151 Calcium iodate Substances 0.000 claims description 3
- UHWJJLGTKIWIJO-UHFFFAOYSA-L calcium iodate Chemical compound [Ca+2].[O-]I(=O)=O.[O-]I(=O)=O UHWJJLGTKIWIJO-UHFFFAOYSA-L 0.000 claims description 3
- 235000019390 calcium iodate Nutrition 0.000 claims description 3
- 235000018417 cysteine Nutrition 0.000 claims description 3
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 claims description 3
- 235000019964 ethoxylated monoglyceride Nutrition 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 2
- 101001122938 Homo sapiens Lysosomal protective protein Proteins 0.000 claims description 2
- 102100028524 Lysosomal protective protein Human genes 0.000 claims description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 2
- 239000012298 atmosphere Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- VHJLVAABSRFDPM-QWWZWVQMSA-N dithiothreitol Chemical compound SC[C@@H](O)[C@H](O)CS VHJLVAABSRFDPM-QWWZWVQMSA-N 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- KSEBMYQBYZTDHS-HWKANZROSA-N ferulic acid Chemical compound COC1=CC(\C=C\C(O)=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-N 0.000 claims description 2
- 239000012138 yeast extract Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 11
- 239000002535 acidifier Substances 0.000 claims 8
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims 4
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims 2
- 239000004156 Azodicarbonamide Substances 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims 2
- 235000019399 azodicarbonamide Nutrition 0.000 claims 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims 2
- 239000001530 fumaric acid Substances 0.000 claims 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 2
- 239000011976 maleic acid Substances 0.000 claims 2
- 239000004334 sorbic acid Substances 0.000 claims 2
- 235000010199 sorbic acid Nutrition 0.000 claims 2
- 229940075582 sorbic acid Drugs 0.000 claims 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 150000003573 thiols Chemical group 0.000 claims 2
- KSEBMYQBYZTDHS-HWKANZROSA-M (E)-Ferulic acid Natural products COC1=CC(\C=C\C([O-])=O)=CC=C1O KSEBMYQBYZTDHS-HWKANZROSA-M 0.000 claims 1
- WCLKSQYCWXZMGX-UHFFFAOYSA-N 1,2,3,4-tetrabromo-5,6-dimethoxybenzene Chemical compound COC1=C(Br)C(Br)=C(Br)C(Br)=C1OC WCLKSQYCWXZMGX-UHFFFAOYSA-N 0.000 claims 1
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 claims 1
- 239000004154 Calcium bromate Substances 0.000 claims 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 claims 1
- GHAZCVNUKKZTLG-UHFFFAOYSA-N N-ethyl-succinimide Natural products CCN1C(=O)CCC1=O GHAZCVNUKKZTLG-UHFFFAOYSA-N 0.000 claims 1
- HDFGOPSGAURCEO-UHFFFAOYSA-N N-ethylmaleimide Chemical compound CCN1C(=O)C=CC1=O HDFGOPSGAURCEO-UHFFFAOYSA-N 0.000 claims 1
- 239000004153 Potassium bromate Substances 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- OFHCOWSQAMBJIW-AVJTYSNKSA-N alfacalcidol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C OFHCOWSQAMBJIW-AVJTYSNKSA-N 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 238000006664 bond formation reaction Methods 0.000 claims 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 1
- 235000019397 calcium bromate Nutrition 0.000 claims 1
- 229940041514 candida albicans extract Drugs 0.000 claims 1
- 235000013985 cinnamic acid Nutrition 0.000 claims 1
- 229930016911 cinnamic acid Natural products 0.000 claims 1
- 125000002228 disulfide group Chemical group 0.000 claims 1
- 235000001785 ferulic acid Nutrition 0.000 claims 1
- 229940114124 ferulic acid Drugs 0.000 claims 1
- KSEBMYQBYZTDHS-UHFFFAOYSA-N ferulic acid Natural products COC1=CC(C=CC(O)=O)=CC=C1O KSEBMYQBYZTDHS-UHFFFAOYSA-N 0.000 claims 1
- 229960002598 fumaric acid Drugs 0.000 claims 1
- 235000011087 fumaric acid Nutrition 0.000 claims 1
- 229960000789 guanidine hydrochloride Drugs 0.000 claims 1
- PJJJBBJSCAKJQF-UHFFFAOYSA-N guanidinium chloride Chemical compound [Cl-].NC(N)=[NH2+] PJJJBBJSCAKJQF-UHFFFAOYSA-N 0.000 claims 1
- 239000004310 lactic acid Substances 0.000 claims 1
- 235000014655 lactic acid Nutrition 0.000 claims 1
- 229940098895 maleic acid Drugs 0.000 claims 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims 1
- 235000013348 organic food Nutrition 0.000 claims 1
- 235000011007 phosphoric acid Nutrition 0.000 claims 1
- 235000019396 potassium bromate Nutrition 0.000 claims 1
- 229940094037 potassium bromate Drugs 0.000 claims 1
- 235000019260 propionic acid Nutrition 0.000 claims 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims 1
- 239000000376 reactant Substances 0.000 claims 1
- QURCVMIEKCOAJU-UHFFFAOYSA-N trans-isoferulic acid Natural products COC1=CC=C(C=CC(O)=O)C=C1O QURCVMIEKCOAJU-UHFFFAOYSA-N 0.000 claims 1
- 238000012545 processing Methods 0.000 abstract description 12
- 102000004169 proteins and genes Human genes 0.000 description 28
- 108090000623 proteins and genes Proteins 0.000 description 28
- 235000018102 proteins Nutrition 0.000 description 27
- 108010068370 Glutens Proteins 0.000 description 26
- 235000021312 gluten Nutrition 0.000 description 24
- 230000000694 effects Effects 0.000 description 22
- 238000012360 testing method Methods 0.000 description 19
- 239000004615 ingredient Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 16
- 235000015895 biscuits Nutrition 0.000 description 15
- 239000003925 fat Substances 0.000 description 12
- 238000002156 mixing Methods 0.000 description 11
- 238000003303 reheating Methods 0.000 description 9
- 239000004464 cereal grain Substances 0.000 description 8
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 230000007423 decrease Effects 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 230000004850 protein–protein interaction Effects 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- 244000098345 Triticum durum Species 0.000 description 5
- 235000007264 Triticum durum Nutrition 0.000 description 5
- 238000013459 approach Methods 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 235000014469 Bacillus subtilis Nutrition 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 244000098338 Triticum aestivum Species 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 235000019820 disodium diphosphate Nutrition 0.000 description 4
- 235000012470 frozen dough Nutrition 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 102000035195 Peptidases Human genes 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 235000012791 bagels Nutrition 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- DCXYFEDJOCDNAF-UHFFFAOYSA-N Asparagine Natural products OC(=O)C(N)CC(N)=O DCXYFEDJOCDNAF-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- DCXYFEDJOCDNAF-REOHCLBHSA-N L-asparagine Chemical compound OC(=O)[C@@H](N)CC(N)=O DCXYFEDJOCDNAF-REOHCLBHSA-N 0.000 description 2
- ZDXPYRJPNDTMRX-VKHMYHEASA-N L-glutamine Chemical compound OC(=O)[C@@H](N)CCC(N)=O ZDXPYRJPNDTMRX-VKHMYHEASA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 235000009582 asparagine Nutrition 0.000 description 2
- 229960001230 asparagine Drugs 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N aspartic acid group Chemical group N[C@@H](CC(=O)O)C(=O)O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000012813 breadcrumbs Nutrition 0.000 description 2
- 210000002421 cell wall Anatomy 0.000 description 2
- 235000014510 cooky Nutrition 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 230000000875 corresponding effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001962 electrophoresis Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 230000007071 enzymatic hydrolysis Effects 0.000 description 2
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 description 2
- 229940088598 enzyme Drugs 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000014594 pastries Nutrition 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 235000012471 refrigerated dough Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012956 testing procedure Methods 0.000 description 2
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- WSWCOQWTEOXDQX-MQQKCMAXSA-M (E,E)-sorbate Chemical compound C\C=C\C=C\C([O-])=O WSWCOQWTEOXDQX-MQQKCMAXSA-M 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- KHICUSAUSRBPJT-UHFFFAOYSA-N 2-(2-octadecanoyloxypropanoyloxy)propanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC(C)C(=O)OC(C)C(O)=O KHICUSAUSRBPJT-UHFFFAOYSA-N 0.000 description 1
- 235000007319 Avena orientalis Nutrition 0.000 description 1
- 244000075850 Avena orientalis Species 0.000 description 1
- 241000194108 Bacillus licheniformis Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- 102000001554 Hemoglobins Human genes 0.000 description 1
- 108010054147 Hemoglobins Proteins 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241001047198 Scomberomorus semifasciatus Species 0.000 description 1
- 241000209056 Secale Species 0.000 description 1
- 235000007238 Secale cereale Nutrition 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- 235000011684 Sorghum saccharatum Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 235000019714 Triticale Nutrition 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000001944 accentuation Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- ZQKXOSJYJMDROL-UHFFFAOYSA-H aluminum;trisodium;diphosphate Chemical compound [Na+].[Na+].[Na+].[Al+3].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O ZQKXOSJYJMDROL-UHFFFAOYSA-H 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 235000015173 baked goods and baking mixes Nutrition 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 235000012467 brownies Nutrition 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229940114081 cinnamate Drugs 0.000 description 1
- 229940117916 cinnamic aldehyde Drugs 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 1
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 239000008121 dextrose Substances 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 description 1
- 230000006334 disulfide bridging Effects 0.000 description 1
- 235000012489 doughnuts Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 235000013601 eggs Nutrition 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000001976 enzyme digestion Methods 0.000 description 1
- 235000013861 fat-free Nutrition 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 229940114123 ferulate Drugs 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 235000010855 food raising agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000012490 fresh bread Nutrition 0.000 description 1
- 229940050411 fumarate Drugs 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 125000000291 glutamic acid group Chemical group N[C@@H](CCC(O)=O)C(=O)* 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000018984 mastication Effects 0.000 description 1
- 238000010077 mastication Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 235000012796 pita bread Nutrition 0.000 description 1
- 235000013550 pizza Nutrition 0.000 description 1
- 235000012830 plain croissants Nutrition 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108010056119 protease So Proteins 0.000 description 1
- 229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000012237 sodium aluminium phosphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940075554 sorbate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- IQQWMJSNEUUJAY-UHFFFAOYSA-D trialuminum;sodium;dihydrogen phosphate;hydrogen phosphate;tetrahydrate Chemical compound O.O.O.O.[Na+].[Al+3].[Al+3].[Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O.OP([O-])([O-])=O.OP([O-])([O-])=O IQQWMJSNEUUJAY-UHFFFAOYSA-D 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 229940006076 viscoelastic substance Drugs 0.000 description 1
- 239000003190 viscoelastic substance Substances 0.000 description 1
- 241000228158 x Triticosecale Species 0.000 description 1
- 150000007934 α,β-unsaturated carboxylic acids Chemical class 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D8/00—Methods for preparing or baking dough
- A21D8/02—Methods for preparing dough; Treating dough prior to baking
- A21D8/04—Methods for preparing dough; Treating dough prior to baking treating dough with microorganisms or enzymes
- A21D8/042—Methods for preparing dough; Treating dough prior to baking treating dough with microorganisms or enzymes with enzymes
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/02—Treatment of flour or dough by adding materials thereto before or during baking by adding inorganic substances
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/14—Organic oxygen compounds
- A21D2/145—Acids, anhydrides or salts thereof
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/14—Organic oxygen compounds
- A21D2/16—Fatty acid esters
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/24—Organic nitrogen compounds
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/28—Organic sulfur compounds
-
- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D8/00—Methods for preparing or baking dough
- A21D8/06—Baking processes
Definitions
- Microwaves are at the lower energy end of the electromagnetic radiation spectrum which includes gamma rays, X-rays, ultraviolet, visible light, near infrared, infrared radiation, microwaves and radio waves.
- Microwave processing offers advantages over conventional oven heating for some food products because it produces rapid product heating without excessively high surface temperatures. However, this type of heating is "opposite to" conventional cooking of foods with respect to moisture and heat transfer.
- the present invention relates to solutions for overcoming or reducing at least two problems relating to crumb texture attendant with heating precooked or uncooked bread-like products in a microwave oven.
- Precooked and uncooked bread-like products may exhibit both toughness and firmness as a result of microwave heating.
- a major technical difficulty for microwaving bread ⁇ like products is the development of the aforediscussed unacceptable texture.
- the outer crust layer may become so tough that it is difficult to tear such a product.
- the inner crumb may become very difficult to chew.
- the textural quality can deteriorate much faster than that of a conventional oven baked product during the course of cooling. Overcooking in a microwave oven may exacerbate the problem while a reduction in overall cooking or reheating may reduce toughness and firmness.
- Toughness can be defined and assessed in sensory terms as a leathery or rubbery eating texture. For example, a bagel is tough while a croissant is tender. Firmness can be defined and assessed in sensory terms as the force required to bite through the sample without tearing or pulling. A "stale" dough-based product can be characterized as firm while fresh bread immediately after conventional cooking would be considered non-firm.
- Whether or not a product is tough or firm or, more accurately, is objectionably tough or firm depends on the product type and the consumer. For example, the expectation for bread is that it should be soft and not tough. If bread had a bagel texture it would be objectionable because of the toughness. However, a bagel, even though it is tough, is not objectionable since the expectation is for a product that has a tough texture. Thus, the type of product and the consumer will set the standard for what level of toughness or firmness is objectionable or desirable.
- Additional factors may affect product identity. Some of these factors include, for example: type of fat; type of leavener; dough formation method; method of fat inclusion; method of cooking the product e.g., steaming, frying, baking, etc.; method of assembling the dough product, for example, laminating versus nonlaminating, etc. These and many related factors and principles are discussed in Hoseney (1986).
- Dough-based products may be prepared from one cereal grain flour or mixtures of several cereal grain flours.
- the cereal flour should be capable of forming a viscoelastic continuous protein matrix upon hydration.
- the present invention easily permits maintenance of product identity while being able to freely manipulate toughness and firmness. Toughness and firmness can be reduced from any point along scales ranging from non-tough and non-firm products to very firm and tough products. More specifically, the present: invention involves methods to reduce toughness and firmness to the desired degree relative to a similar formula product when heated in a microwave oven. The present invention provides the latitude to manipulate toughness and firmness regardless of the original toughness and firmness for a similar non- invention product.
- the present invention involves means and methods to reduce the degree of the above-mentioned toughening and/or firming of bread-like products upon their heating, e.g., reheating or cooking by microwave irradiation.
- the present invention also relates to a product composition with gluten of reduced molecular weight to provide a product with improved microwaveability.
- the present invention includes a product formulation with low pH and/or low ionic strength to provide improved microwaveability.
- the present invention also describes a dough-based composition containing a surfactant to provide improved microwaveability.
- Embodiments of the invention can provide good quality microwaveabie bread-like products including unleavened and leavened products.
- Leavened products include those leavened by microorganisms such as yeast, chemicals, arid steam, etc. as is known in the art.
- a good quality microwaveabie product including reconstitutable dry mix, fresh or raw dough, frozen dough or precooked bakery products may be prepared in the microwave oven.
- the present invention can be practiced with starch containing or starch-based products. These products can take the form of dough products and non-dough products. Dough products will exhibit toughness and often firmness as a textural problem. Dough-based can be defined as a product which has a continuous matrix of gluten.
- Such products have at least 4% gluten by weight in the dry flour. More preferably a dough-based product will have 6% or more gluten by weight of dry flour.
- Non- dough products hereafter referred to as batter-based products, are characterized in that they have minimal or no gluten matrix in the plasticized mixture of flour and plasticizers.
- batter-based products have low gluten i.e., less than about 8% gluten by weight of dry flour, and can have no gluten.
- Batter-based products may exhibit firmness as a result of microwave heating and not toughness because of the lack or low degree of the continuous gluten matrix.
- toughening is predominantly a protein related phenomenon, more specifically a gluten related phenomenon.
- firming is a predominantly starch related phenomenon.
- any cereal grain based product from which a dough or batter can be made can be utilized. Firming in any of these products may be improved by practice of this invention. Products containing on a dry flour basis, at least 4% gluten may utilize the invention to reduce toughening.
- Combinations of cereal grains can also be utilized to form a dough or batter. Cereal grains include wheat, corn, rye, barley, oats, sorghum, triticale, etc.
- bread-like product is not limited to breads as defined in the standards of identity under the Food, Drug and Cosmetic Act.
- Bread-like products include such foods as breads, biscuits, cornbread, quickbreads, pastries, sweet rolls, pita bread, pie crust, pizza crust, pasta, dumplings, etc. whether or not the product is made from a dough-based product or batter-based product as defined herein.
- the term “dough-based product” includes products that are partially cooked or cooked and were in a dough form just prior to cooking by any means.
- the term “dough-based product” also includes products that are dough prior to cooking or reheating in a microwave oven. Dough may be defined as a viscoelastic substance which is developed or partially developed.
- batter based product includes products that are partially cooked or cooked and were in batter form just prior to cooking.
- batter based product also includes products that are batter prior to cooking or reheating in a microwave oven.
- Batter may be a liquid or can be a pastry material much like “brownie dough” or “cookie dough”.
- a product intermediate is either a dough based or batter based product in whatever form, for example, in a cooked, partially cooked or uncooked (raw) state just prior to exposure to microwave radiation.
- the products when cooked typically have a composition by weight of about 20-85% flour, about 15 to 45% total water, and about 0 to 50% fat.
- the products in their uncooked condition typically have a composition by weight of about 20 to 80% flour, about 18 to 55% total water, and about 0 - 45% fat.
- Dry mix as used herein means a mixture of ingredients normally used to make a dough or batter as is known in the industry. Such mixes can come in any package size and are generally sold through retail, food service or commercial outlets.
- the dry mix has added to it liquid ingredients such as water and fats, which are plasticizers, and other optional ingredients such as eggs, etc.
- An acceptable texture is more like the texture of a conventionally cooked equivalent or similar product as is known in the industry.
- Conventional cooking includes convection, conduction, non-microwave irradiation like radiant heat cooking, electrical resistance heating i.e., the food product or bread-like product is used to conduct current, etc.
- the invention product texture is better than the texture of an equivalent product without using the invention.
- a similar or equivalent product is a product that has substantially the same formula except for the ingredient(s) added or processing for microwave texture improvement as hereinafter described. Such a product is also analogously processed i.e., it is processed in the same way and precooked and or heated the same.
- the improvement in product with the invention relative to a similar product without the invention being distinguishable to a consumer and is at least about 5, preferably at least about 10 or more preferably at least about 15 points on a 0-60 organoleptic relative sensory testing scale (with 60 representing high toughness or firmness) using a trained panel. Such a testing procedure is known in the art. It is preferred that the improvement in the product with the invention relative to a similar product without the invention is at least about 10%, preferably at least about 20%, and more preferably at least about 30% improvement on the relative sensory testing scale as described herein.
- the products of the present invention comprise flour and sufficient plasticizer to form a dough or batter.
- the dough or batter can include aqueous and nonaqueous plasticizers.
- Nonaqueous plasticizers include fats. However, in some products, added fat is not necessary, for example, with French bread.
- the water content used herein, unless otherwise indicated is added water. It is to be understood that flour contains approximately 14% water by weight of flour.
- a good quality cooked or uncooked microwaveabie product can be produced, such products can be distributed, and/or stored under conditions such as frozen, refrigerated (pressurized or unpressurized), and shelf-stable systems.
- An advantage of the present invention is that the treatment means, by way of process and/or additives for the dough-based or batter-based products is effective in reducing microwave-induced toughness and firmness a distinguishable amount.
- Another advantage of the present invention is that the treatment means for reducing toughness and/or firmness does not require special processing equipment to e fectuate.
- Another advantage of the present invention is that the treatment means is effective for reducing the toughness or firmness from any level of toughness or firmness for an equivalent product that does not utilize the treatment means.
- Figure 1 Graphically illustrates different product identities and the corresponding product characteristics
- Figure 2 shows the effect of a reducing agent on product quality.
- Figure 3 shows the effect of an alpha, beta- unsaturated carbonyi compound on product quality.
- Figure 4 shows the effect of a fast acting oxidant on product quality.
- Figure 5 A and B show the effect of proteolytic enzymes on product quality.
- Figure 5A shows B. subtilis protease and
- Figure 5B shows licheniformis protease.
- Figure 6 shows the effect of low pH and ionic strength on product quality.
- Figure 7 shows the effect of urea on relative firmness as measured by a Kramer shear press.
- Figure 8 shows the effect of surfactants on product quality.
- Figure 9 shows the effect of overmixing on product quality.
- Figure 10 shows the effect of wheat flour type on product quality.
- the present invention provides means and methods for controlling toughening and firming in microwaved dough- based and batter-based products. As discussed above, these attributes of the product can, when not properly controlled, cause negative consumer reactions to the products.
- microwave energy to dough-based and batter-based products provides additional or different structures in the resulting cooked or reheated product as compared with conventionally cooked or heated products.
- structure building elements such as protein and starch interact to provide the desired structure.
- Microwave heating accentuates formation of or enhances this structure, which may cause textural problems.
- theories are presented herein concerning potential bases of microwave-induced toughening and firming. These theories are included to more fully envision but not limit uses of the present invention but may eventually prove to be incomplete or inaccurate.
- Toughening of dough-based and batter-based products subjected to microwaving is thought to be predominantly a protein related pnenomenon. It has been found that such toughening can be significantly reduced by the use of protein interaction inhibitors.
- Protein interactions or toughness may be inhibited by treatment means, for example, by processing such as overdevelopment or the inclusion of agents such as preferential binding materials such as surfactants, by reduction in the molecular weight of the protein, by increasing electrostatic repulsion and by using hydrogen bond breakers.
- treatment means for example, by processing such as overdevelopment or the inclusion of agents such as preferential binding materials such as surfactants, by reduction in the molecular weight of the protein, by increasing electrostatic repulsion and by using hydrogen bond breakers.
- Firming induced by microwaving may be reduced by limiting the starch-starch interaction. This can be done by treatment means, for example, by processing such as overdevelopment or by the inclusion of agents that limit the amount of starch swelling.
- Exemplary starch swelling inhibitors include surfactants or shortenings. Substances characteristically inhibiting protein-protein interactions have been found to often decrease microwave- induced firming.
- a panel of trained people was used to evaluate products.
- An initial training session was used to familiarize the panelists with the range of products that would be tested. Reference standards were presented in this session to train the panelists to recognize the differences between the product attributes that were to be measured.
- the trained panel marked two reference products used as standards on a 0-60 point line scale with 0 being the low end and 60 the high end.
- Two standards (low end and high end of the scale) were tasted prior to each evaluation session, and were marked on the score sheets.
- the presentation of references at each session was used so that responses which occurred at different times could be standardized. The mean score is reported. Evaluations by panelists which were significantly different from the remainder of the panel were eliminated from consideration. This testing procedure is more fully disclosed in Moskowitz (1983), the entire disclosure of which is incorporated herein by reference.
- Firmness was assessed by the force required to bite through the sample without tearing or pulling.
- Toughness was assessed as the rate of breakdown at which the sample came apart during mastication.
- Crumb samples (4.0 x 4.0 x 1.5 cm) were cut using a template.
- a crumb sample is a product sample taken from the interior section of the product with no crust.
- the crosshead speed was 12.7 cm/minute.
- the stress (kPa) was continuously recorded up to 200% strain.
- the instrumental results were correlated with assessments of a trained panel. To establish correlations between the sensory scores and the instrumental measurements of maximum stress (kPa) measured with the Kramer Shear Press, twenty different dough products conventionally baked and/or microwaved, were assessed.
- Inhibitors of protein-protein interactions include compounds or agents that preferentially react or bind with proteins to minimize these interactions. Sufficient protein interaction inhibitor may be added to dough prior to microwave cooking or reheating to reduce toughening.
- surfactants may be used to reduce protein-protein interaction and subsequent toughening induced by microwave irradiation.
- Surfactants have been used in conventionally cooked dough products for the purpose of dough conditioning (strengthening dough) and to prevent staling.
- Usable or potentially usable surfactants include stearyl- 2-lactylates; sorbitan mono-fatty acid esters; monoglvcerides; 1-propylene glycol mono-fatty acid esters; sucrose fatty acid esters; diacetyl tartaric acid ester of monogycerides and ethoxylated monoglycerides; polysorbate 60; polysorbate 80, etc.
- Figure 8 shows that the effect of surfactants is independent of HLB values.
- HLB values are represented by the following emulsifiers respectively:
- Another class of interaction inhibitors acts to reduce he molecular weight of the protein. This can be done by the cleavage of gluten disulfide bonds with mixing agents (disulfide reductants), e.g., cysteine (see Figure 2), glutathione from dry yeast, bisulfites, dithiothreitol, and mercaptoethanol.
- mixing agents disulfide reductants
- cysteine see Figure 2
- glutathione from dry yeast bisulfites, dithiothreitol, and mercaptoethanol.
- Gluten disulfide bonds can be broken by mixing and their reformation can be prevented by the addition of alpha, beta-unsaturated carbonyl compounds such as sorbate, maleate, N-ethylmaieimide, cinnamate, ferulate, fumarate, cinnamaldehyde, crotonaldehyde, maleic anhydride and acrolein.
- alpha, beta-unsaturated carbonyl compounds such as sorbate, maleate, N-ethylmaieimide, cinnamate, ferulate, fumarate, cinnamaldehyde, crotonaldehyde, maleic anhydride and acrolein.
- Figure 3 shows the effect of potassium sorbate on the firmness and toughness of biscuits.
- Fast acting oxidants such as potassium iodate, calcium iodate or diazocarbonamide represent a class of compounds that may produce alpha, beta-unsaturated carbonyl compounds, for example, during high shear mixing.
- Figure 4 shows the effect of potassium iodate (KIO.,) on product quality. Any oxidizing agent with reduction potential higher than that of ortho or para-quinones is expected to be functional.
- the molecular weight of proteins can also be reduced by the enzymatic hydrolysis of peptide bonds.
- the bacterial proteases tested were effective at decreasing microwave-induced toughness and firmness. Other plant, animal and microbial proteases are also expected to be effective.
- One Anson Unit (AU) is the amount of enzyme which, under standard conditions, liberates an amount of TCA soluble product which gives the same color with phenol reagent as one milliequivalent of tyrosine.
- the standard conditions are: substrate — denatured hemoglobin, temperature — 25"C, pH — 7.5, reaction time — 10 minutes.
- Figure 5 shows that the level of enzymes was directly related to product quality.
- a preferred group of ingredients are yeast extracts and autolysates which contain both protease and glutathione as a reducing agent.
- Hydrogen bonds in gluten can also be broken to reduce protein interactions. These relatively weak bonds can be broken with chemicals such as urea, guanidine, dimethylsulfoxide and N,N-dimethylformamide. Although all the above hydrogen bond-breaking compounds are not food approved, at least some were tested to see if disruption of hydrogen bonds reduced firmness. As shown in Figure 7, increasing concentrations of urea decreases firmness. Since decreases in firmness and toughness attributes are highly correlated, the firmness results shown probably also represent the reduction in toughness.
- a deamidase can be used to hydrolyze asparagine and glutamine to aspartic and glutamic acid residues. Approximately 35% - 40% of the 20 amino acids present in gluten are asparagine and glutamine. Their enzymatic hydrolysis to aspartic acid and glutamic acid, respectively, decreases the isoelectric point of gluten molecules and also decreases their hydrophobicity which reduces hydrophobic interaction. Also, the pH of the product will be higher than the isoelectric point of gluten and in the presence of high electrolyte concentration from leavening agents and added salt, the protein-protein ionic attraction will be minimized.
- the second approach for minimizing ionic attraction is to lower the product pH and ionic strength.
- the high net positive charge on the protein at low pH also results in electrostatic repulsion, particularly at low ionic strength.
- an unexpected finding is that by encapsulating soda, the pH and/or ionic strength effect which significantly reduces microwave-induced toughening is magnified.
- the pH can be lowered using any food grade acid.
- a preferred group of acids are alpha, beta-unsaturated carboxylic acids. Fruits high in these " kinds of acids or even cinnamon which contains alpha, beta-unsaturated aldehydes and acids may be included, too.
- the foregoing methods may be utilized to reduce microwave-induced toughness in precooked dough-based products that are reheated in the microwave oven, in products which are cooked from the dough form in a microwave oven, and in products reconstituted from dry mixes and then cooked in a microwave oven.
- the rate of firming upon cooling is accelerated by microwave reheating or cooking.
- the reasons for the accentuation of both toughening and firming is not completely understood. While toughening has been found to be predominantly a protein-related phenomenon, firming has been found to be predominantly a starch-related phenomenon.
- the solutions for microwave-induced firming can be used for both dough-based and batter-based bread ⁇ like products.
- Starch-starch interaction can be minimized by a broad class of inhibitors such as surfactants, ' hydrogen bond breaking agents, and high molecular './eight polymers such as gums. Since starch granules are embedded in a gluten film all the gluten interaction inhibitors described above for minimizing toughening development may also minimize firming because the degree of swelling and ensuing starch interaction is modified by the presence of the gluten film. Examples include low ionic strength and/or pH, chemical reducing agents, surfactants, etc.
- Firmness can also be reduced by decreasing the product cooling rate after reheating or cooking in the microwave oven. This can be done by cooling the product in an enclosed plastic pouch after heating or cooking as disclosed by Anderson et al., cited above.
- the desired product structure can be obtained by processing steps such as chemical or yeast leavening of dough combined with intermittent punching which leads to subdivision of air cells.
- the present invention is particularly applicable to those bread like products which, when cooked either by conventional means or microwave radiation, may contain ingredients as described above and other additional ingredients can be contained in the product as are known in the art.
- the products herein described in their uncooked state i.e., the batter or dough state may contain ingredients as described above and additional ingredients as are known in the art.
- Refrigerated doughs are known in the industry. They are raw or fresh dough stored in a sealed container. When pressurized, the gauge pressure is in the range of between about one-half and about 2 atmospheres, preferably about 1 atmosphere. Refrigerated storage temperatures are less than about 5"C and preferably in the range of between about O'C and about 5"C. Storage time is typically 6-12 weeks.
- Frozen doughs are stored at a temperature of less than 0"C and preferably less than about -10 C.
- the invention further extends to a refrigerated or frozen dough product suitable for heating or cooking by microwave irradiation, and to an edible product heated or cooked by microwave irradiation, which products have been produced using any of the methods of this invention.
- the biscuits were made according to the following procedure:
- the proofed product can be covered and stored frozen or refrigerated until use for microwave baking.
- the proofed product can be cooked (e.g. 232 ⁇ C for 7 minutes) in the oven prior to storage.
- the biscuits were made according to the following procedure:
- Doughs were prepared according to the straight dough process described by Finney (1984) except a 1500 g batch was prepared using a model N-50 Hobart mixer equipped with a dough hook. From that dough, 300 g loaves were baked in a conventional oven for 24 minutes at 218"C. After cooling, the loaf was cut into 1.25 cm, 18 g slices. The slices were microwaved on high for 25 seconds. The microwaved slices were evaluated using the Kramer Shear Press as described above. Sample J gave consistently lower firmness and toughness values than sample I. TABLE 8
- This example shows the effect of protease on firmness and toughness of frozen dough product.
- Chemically leavened biscuits were cooked in the microwave oven from frozen raw dough.
- the biscuits had the following formulas:
- the biscuits were made according to the following procedure: 1. Mixing - Preblend all dry ingredients in Hobart bowl with a Model N-50 mixer at low speed (#1) for 1 1/2 min with dough hook. Add molten shortening while preblending. Add water and mix for an additional 2 minutes.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Microbiology (AREA)
- Bakery Products And Manufacturing Methods Therefor (AREA)
- General Preparation And Processing Of Foods (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP94102720A EP0617896B1 (de) | 1988-06-29 | 1989-06-29 | Auf Stärke basierte Erzeugnisse für Mikrowellenkochen oder -erhitzen |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US21307588A | 1988-06-29 | 1988-06-29 | |
| US213075 | 1988-06-29 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94102720A Division EP0617896B1 (de) | 1988-06-29 | 1989-06-29 | Auf Stärke basierte Erzeugnisse für Mikrowellenkochen oder -erhitzen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0429549A1 true EP0429549A1 (de) | 1991-06-05 |
Family
ID=22793651
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19890912077 Withdrawn EP0429549A1 (de) | 1988-06-29 | 1989-06-29 | Auf stärke basierte erzeugnisse für mikrowellenkochen und -erhitzen |
| EP94102720A Expired - Lifetime EP0617896B1 (de) | 1988-06-29 | 1989-06-29 | Auf Stärke basierte Erzeugnisse für Mikrowellenkochen oder -erhitzen |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94102720A Expired - Lifetime EP0617896B1 (de) | 1988-06-29 | 1989-06-29 | Auf Stärke basierte Erzeugnisse für Mikrowellenkochen oder -erhitzen |
Country Status (5)
| Country | Link |
|---|---|
| EP (2) | EP0429549A1 (de) |
| AU (1) | AU4484889A (de) |
| CA (1) | CA1318171C (de) |
| DE (1) | DE68929424T2 (de) |
| WO (1) | WO1990000010A2 (de) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5049398A (en) * | 1989-12-08 | 1991-09-17 | General Mills, Inc. | Method of preparing microwave bread |
| BE1010277A3 (nl) * | 1996-04-19 | 1998-05-05 | Puratos Nv | Verbeteraar voor door microgolven opgewarmde gebakken producten. |
| JP2000513231A (ja) * | 1996-07-01 | 2000-10-10 | ノボ ノルディスク アクティーゼルスカブ | ベーキングにおけるデアミダーゼの利用 |
| US6123975A (en) * | 1997-04-21 | 2000-09-26 | Ohlin; Edward Arthur | Improver for microwave-reheatable bakery products |
| GB0228548D0 (en) * | 2002-12-06 | 2003-01-15 | Unilever Plc | Microwavable food product |
| US20080008782A1 (en) * | 2004-02-17 | 2008-01-10 | Wageningen Centre For Food Sciences | Method of Preparing a Bread Dough or Part Baked Bread |
| CN116420790A (zh) | 2013-02-05 | 2023-07-14 | 奥特丽有限公司 | 液体燕麦基料 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR380769A (fr) * | 1907-08-12 | 1907-12-17 | David Chidlow | Procédé de fabrication du pain |
| DE1275491B (de) * | 1962-06-15 | 1968-08-22 | Erich Eggebrecht | Verfahren zur Verbesserung der backtechnischen Eigenschaften von Mehl oder Mahlprodukten |
| GB1095144A (en) * | 1964-05-11 | 1967-12-13 | Unilever Ltd | Improvements in farinaceous compositions |
| US3556798A (en) * | 1968-04-09 | 1971-01-19 | Pillsbury Co | Method of using sorbic acid and sorbates as dough conditioning agents |
| US3694228A (en) * | 1970-05-05 | 1972-09-26 | Dca Food Ind | Fried cake mix composition |
| US3630755A (en) * | 1970-07-01 | 1971-12-28 | Dca Food Ind | Dough proofing method |
| DE2246214A1 (de) * | 1972-09-21 | 1974-03-28 | Klein Kg Hans Guenter | Verfahren und vorrichtung zur herstellung von backwaren |
| US4157403A (en) * | 1976-07-12 | 1979-06-05 | International Telephone & Telegraph Corporation | Microwave baking of brown and serve products |
| US4396635A (en) * | 1978-12-26 | 1983-08-02 | The Procter & Gamble Co. | Microwave cake mix |
| US4374150A (en) * | 1980-06-23 | 1983-02-15 | Cain Food Industries, Inc. | Urea yeast food for baking |
| CA1136921A (en) * | 1981-03-11 | 1982-12-07 | Griffith Laboratories, Limited (The) | Production of sponge cake |
| US4448791A (en) * | 1981-11-19 | 1984-05-15 | Campbell Soup Company | Brownable dough for microwave cooking |
| US4419377A (en) * | 1982-03-22 | 1983-12-06 | The Procter & Gamble Company | Cake mix containing a lipophilic emulsifier system |
| KR890003911B1 (ko) * | 1985-10-22 | 1989-10-12 | 하우스 쇼꾸힌 고오교오 가부시끼가이샤 | 케이크의 제조방법 |
| US4917907A (en) * | 1987-08-14 | 1990-04-17 | Campbell Soup Company | Pie having a microwave brownable crust and method of baking same |
| EP0314265B1 (de) * | 1987-10-08 | 1992-08-05 | Borden, Inc. | In einer Stufe aromatisierte Pastenprodukte |
| JP2624537B2 (ja) * | 1989-02-23 | 1997-06-25 | ダイエー食品工業株式会社 | 電子レンジ加熱に適する冷凍パン |
| US4957750A (en) * | 1989-05-05 | 1990-09-18 | Kraft General Foods | Microwaveable baked goods |
| US5124161A (en) * | 1989-06-07 | 1992-06-23 | Nabisco Brands, Inc. | Filled, microwave expandable snack food product and method and apparatus for its production |
-
1989
- 1989-06-29 AU AU44848/89A patent/AU4484889A/en not_active Abandoned
- 1989-06-29 DE DE1989629424 patent/DE68929424T2/de not_active Expired - Fee Related
- 1989-06-29 CA CA000604389A patent/CA1318171C/en not_active Expired - Fee Related
- 1989-06-29 EP EP19890912077 patent/EP0429549A1/de not_active Withdrawn
- 1989-06-29 WO PCT/US1989/002897 patent/WO1990000010A2/en not_active Ceased
- 1989-06-29 EP EP94102720A patent/EP0617896B1/de not_active Expired - Lifetime
Non-Patent Citations (1)
| Title |
|---|
| See references of WO9000010A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0617896A3 (de) | 1994-12-07 |
| EP0617896A2 (de) | 1994-10-05 |
| EP0617896B1 (de) | 2002-09-11 |
| AU4484889A (en) | 1990-01-23 |
| DE68929424D1 (de) | 2002-10-17 |
| WO1990000010A3 (en) | 1990-09-20 |
| DE68929424T2 (de) | 2003-04-30 |
| WO1990000010A2 (en) | 1990-01-11 |
| CA1318171C (en) | 1993-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5035904A (en) | Starch-based products for microwave cooking or heating | |
| Gerrard et al. | Pastry lift and croissant volume as affected by microbial transglutaminase | |
| US4842876A (en) | Method of microwave heating of starch-based products | |
| CN101014248B (zh) | 由整谷粒硬质小麦制得的整谷粒产品 | |
| AU722871B2 (en) | Flexible partially cooked dough composition | |
| CA1115116A (en) | Multi-purpose pre-mix for home baking processes | |
| EP2271220B1 (de) | Teig mit fructan und einem fructan-abbauenden enzym | |
| EP0912100B1 (de) | Verwendung von Peptidoglutaminase im Backvorgang | |
| US20080286411A1 (en) | Bread and dough composition and method | |
| EP0617896B1 (de) | Auf Stärke basierte Erzeugnisse für Mikrowellenkochen oder -erhitzen | |
| US20090297659A1 (en) | Enzymatic dough conditioner and flavor improver for bakery products | |
| US20080166450A1 (en) | Methods for reducing asparagine in a dough food component using water activity | |
| US20020172747A1 (en) | Self rising dough-containing food product | |
| CA2636220C (en) | Methods for reducing asparagine in a dough food component | |
| KAUR et al. | Effect of acetic acid and CMC on rheological and baking properties of flour | |
| US20090123607A1 (en) | Self-rising dough-containing food product and related manufacturing methods | |
| WO2005070217A1 (en) | Self-rising dough-containing food product | |
| US6482454B2 (en) | Microwaveable bread products | |
| CA2662369C (en) | Enzymatic dough conditioner and flavor improver for bakery products | |
| WO1990000001A2 (en) | Dough based products for microwaving | |
| Preston et al. | No-time dough baking performance and mixing properties of Canadian Red Spring wheat cultivars using Canadian and Australian test procedures | |
| US20200068906A1 (en) | Dough products and method of making the same | |
| Vaclavik et al. | Batters and Doughs | |
| Vieira | Bakery products |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 19901128 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE FR GB IT NL |
|
| 17Q | First examination report despatched |
Effective date: 19920610 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
| 18W | Application withdrawn |
Withdrawal date: 19940331 |