EP0442938A1 - Utilisation de melanges d'adhesifs contenant de la gomme arabique pour coller les soudures longitudinales des papiers a cigarettes - Google Patents
Utilisation de melanges d'adhesifs contenant de la gomme arabique pour coller les soudures longitudinales des papiers a cigarettesInfo
- Publication number
- EP0442938A1 EP0442938A1 EP89912789A EP89912789A EP0442938A1 EP 0442938 A1 EP0442938 A1 EP 0442938A1 EP 89912789 A EP89912789 A EP 89912789A EP 89912789 A EP89912789 A EP 89912789A EP 0442938 A1 EP0442938 A1 EP 0442938A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- viscosity
- starch
- parts
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 27
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 14
- 229920000084 Gum arabic Polymers 0.000 title claims abstract description 12
- 235000010489 acacia gum Nutrition 0.000 title claims abstract description 12
- 239000000205 acacia gum Substances 0.000 title claims abstract description 12
- 241000978776 Senegalia senegal Species 0.000 title abstract 2
- 229920002472 Starch Polymers 0.000 claims abstract description 22
- 235000019698 starch Nutrition 0.000 claims abstract description 22
- 239000008107 starch Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 239000003755 preservative agent Substances 0.000 claims abstract description 6
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 4
- 230000015556 catabolic process Effects 0.000 claims abstract description 4
- 229920001353 Dextrin Polymers 0.000 claims description 15
- 239000004375 Dextrin Substances 0.000 claims description 14
- 235000019425 dextrin Nutrition 0.000 claims description 14
- 244000215068 Acacia senegal Species 0.000 claims description 10
- 238000004026 adhesive bonding Methods 0.000 claims description 8
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 4
- 239000007857 degradation product Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 229940069338 potassium sorbate Drugs 0.000 claims description 4
- 235000010241 potassium sorbate Nutrition 0.000 claims description 4
- 239000004302 potassium sorbate Substances 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- 240000008042 Zea mays Species 0.000 claims description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 3
- 235000005822 corn Nutrition 0.000 claims description 3
- 240000003183 Manihot esculenta Species 0.000 claims description 2
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 2
- 244000061456 Solanum tuberosum Species 0.000 claims description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 2
- 230000002335 preservative effect Effects 0.000 claims description 2
- 229940100486 rice starch Drugs 0.000 claims description 2
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 claims 1
- -1 p-hydroxybenzoic acid ester Chemical class 0.000 claims 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims 1
- 239000007787 solid Substances 0.000 abstract description 5
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000005168 4-hydroxybenzoic acids Chemical class 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000007794 yellow potato Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/14—Machines of the continuous-rod type
- A24C5/24—Pasting the seam
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J105/00—Adhesives based on polysaccharides or on their derivatives, not provided for in groups C09J101/00 or C09J103/00
- C09J105/14—Hemicellulose; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Definitions
- the invention relates to the use of adhesive mixtures containing 100 parts by weight of water
- the invention is directed to the use of special adhesive mixtures which ensure a safe and permanent gluing of longitudinal seams of cigarette tubes with the machines customary in the cigarette industry, in particular taking into account the high production speeds required there, which do not lead to decomposition phenomena while releasing unpleasant Odors tend and which do not require heated equipment to apply.
- This object is achieved by using the above-mentioned adhesive mixtures based on gum arabic.
- the gum arabic varieties which can be used according to the invention should be of first quality, e.g. so-called hand-picked
- the water-soluble starch degradation products to be used according to the invention include oxidatively or hydrolytically degraded starches and dextrins (roasted dextrins), in particular white and yellow dextrins, which e.g. in Ulimanns' Encyclopedia of Technical Chemistry, 4th edition, volume 22, pages 191-194, publisher
- thick-boiling dextrins are preferred.
- Typical representatives for these dextrins are a) medium-viscosity dextrins with a viscosity in 60% solution of 1000 to 8000 mPas according to Brookfield (RVT, 20 ° C.), measured on a freshly prepared solution, b) highly viscous dextrins with a viscosity in 50% solution from 500 to 2000 mPas according to Brookfield (RVT, 20 ° C), measured on a freshly prepared solution, c) white dextrins with a viscosity in 40% solution from 100 to 1000 mPas according to Brookfield (RVT, 20 ° C), measured on a freshly prepared solution.
- Potato, corn, tapioca and / or rice starch are suitable as gelatinized starches to be used according to the invention; Corn, starch is particularly preferred. They are advantageously added to the adhesives to be used according to the invention as native starches and gelatinized by heating the adhesive.
- Suitable preservatives are those which are customary in the adhesive and tobacco industry, in particular potassium sorbate and / or p-hydroxybenzoic acid esters.
- the adhesive mixtures are applied to the ones to be glued in conventional cigarette manufacturing machines via nozzles
- the preparation was carried out by adding starch and / or dextrins, the crushed gum arabic and the preservative to water. The mixture was heated to 90 ° C. with stirring and left at this temperature for 15 minutes. The mixture was then cooled to ambient temperature with stirring and poured through a fine sieve.
- the adhesive mixture had a Brookfield viscosity of 1800 mPas (RVT, spindle 4, 20 revolutions, 20 ° C.), a refxactometric solids content of approx. 46% and a pH of 4.4.
- the product had a viscosity of 3500 mPas according to Brookfield (RVT, spindle 4, 20 revolutions / 20 ° C.) of 3500 mPas, a refractory solids content of approx. 46% and a pH of 4.3.
- the viscosity of the adhesive mixture was 2800 mPas according to Brookfield (RVT, spindle 4, 20 revolutions, 20 ° C.), the refractometric solids content was approx. 45%, the pH was 4.4.
- the viscosity of the adhesive mixture was 2500 mPas according to Brookfield (RVT, spindle 4, 20 revolutions, 20 ° C.); the refractometric solids content was approximately 44% and the pH was 4.2.
- Adhesive strength of the longitudinal seams When the seams were forcibly separated, the adhesive areas became matted.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Manufacturing Of Cigar And Cigarette Tobacco (AREA)
- Paper (AREA)
Abstract
On obtient des papiers à cigarettes à soudures longitudinales par collage mécanique particulièrement solides en utilisant des mélanges d'adhésifs, comprenant 100 parties en poids d'eau, 40 à 120 parties en poids de gomme arabique, 3 à 80 parties en poids de produits de dégradation de l'amidon solubles dans l'eau et/ou de carboxyméthylamidon et/ou d'amidon empâté, et, le cas échéant, les agents de conservation habituels, en solution aqueuse, la viscosité du produit étant comprise entre 1.000 et 15.000, en particulier entre 1.700 et 5.000, mPa selon l'échelle de viscosité RVT de Brookfield à 20°C.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3838255 | 1988-11-11 | ||
| DE3838255A DE3838255A1 (de) | 1988-11-11 | 1988-11-11 | Verwendung von gummi arabicum enthaltenden klebstoffgemischen zur laengsnahtverleimung von zigarettenhuellen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0442938A1 true EP0442938A1 (fr) | 1991-08-28 |
Family
ID=6366953
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89120265A Expired - Lifetime EP0368136B1 (fr) | 1988-11-11 | 1989-11-02 | Utilisation de compositions adhésives contenant de la gomme arabique pour le collage longitudinal de gaines de cigarettes |
| EP89912789A Pending EP0442938A1 (fr) | 1988-11-11 | 1989-11-02 | Utilisation de melanges d'adhesifs contenant de la gomme arabique pour coller les soudures longitudinales des papiers a cigarettes |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89120265A Expired - Lifetime EP0368136B1 (fr) | 1988-11-11 | 1989-11-02 | Utilisation de compositions adhésives contenant de la gomme arabique pour le collage longitudinal de gaines de cigarettes |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5155140A (fr) |
| EP (2) | EP0368136B1 (fr) |
| AT (1) | ATE85638T1 (fr) |
| CA (1) | CA2002841A1 (fr) |
| DE (2) | DE3838255A1 (fr) |
| ES (1) | ES2040965T3 (fr) |
| WO (1) | WO1990005169A1 (fr) |
| ZA (1) | ZA898613B (fr) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5490875A (en) * | 1993-07-13 | 1996-02-13 | American Maize Technology, Inc. | Adhesive composition for cigarette seams |
| US6221420B1 (en) | 1993-07-30 | 2001-04-24 | National Starch And Chemical Investment Holding Corporation | Foods containing thermally-inhibited starches and flours |
| US6451121B2 (en) | 1993-07-30 | 2002-09-17 | National Starch And Chemical Investment Holding Corporation | Thermally-inhibited non-pregelatinized granular starches and flours and process for their preparation |
| US5932017A (en) * | 1993-07-30 | 1999-08-03 | National Starch And Chemical Investment Holding Corporation | Thermally-inhibited non-pregelatinized granular starches and flours and process for their preparation |
| US5718770A (en) * | 1994-08-25 | 1998-02-17 | National Starch And Chemical Investment Holding Corporation | Thermally-inhibited pregelatinized granular starches and flours and process for their production |
| DE4441882A1 (de) * | 1994-11-24 | 1996-05-30 | Henkel Kgaa | Klebstoff mit enzymatisch abgebauter Stärke |
| JPH10506921A (ja) * | 1995-01-18 | 1998-07-07 | ナショナル スターチ アンド ケミカル インベストメント ホールディング コーポレイション | 熱抑制されたデンプンを含む化粧品 |
| US5830884A (en) * | 1995-01-18 | 1998-11-03 | National Starch And Chemical Investment Holding Corporation | Pharmaceutical products containing thermally-inhibited starches |
| EP0805840A1 (fr) * | 1995-01-24 | 1997-11-12 | National Starch and Chemical Investment Holding Corporation | Adhesifs a base d'eau contenant des amidons inhibes thermiquement |
| US5494481A (en) * | 1995-05-26 | 1996-02-27 | Anderberg; Steven L. | Rectal plug and method of introducing same into a slaughtered animal |
| US8925556B2 (en) | 2006-03-31 | 2015-01-06 | Philip Morris Usa Inc. | Banded papers, smoking articles and methods |
| US20110030710A1 (en) * | 2007-06-15 | 2011-02-10 | Kesselman Joshua D | Rolling paper structures for creating smoking articles and adhesives comprising hemp additive for same |
| US8701682B2 (en) | 2009-07-30 | 2014-04-22 | Philip Morris Usa Inc. | Banded paper, smoking article and method |
| US10375988B2 (en) | 2010-12-13 | 2019-08-13 | Altria Client Services Llc | Cigarette wrapper with novel pattern |
| RU2592017C2 (ru) | 2010-12-13 | 2016-07-20 | Алтриа Клайент Сервисез Ллс | Способ подготовки печатного раствора и получение сигаретной оберточной бумаги с рисунком |
| US11707082B2 (en) | 2010-12-13 | 2023-07-25 | Altria Client Services Llc | Process of preparing printing solution and making patterned cigarette wrapper |
| EP2709471A4 (fr) | 2011-05-16 | 2015-05-27 | Altria Client Services Inc | Motifs alternés dans un papier de cigarette, article à fumer et procédé |
| CA2873781A1 (fr) | 2012-05-16 | 2013-11-21 | Altria Client Services Inc. | Nouveau papier a cigarette a bague dote de bagues de zone ouverte |
| WO2013173609A1 (fr) | 2012-05-16 | 2013-11-21 | Altria Client Services Inc. | Papier à cigarette doté d'un nouveau motif |
| ITUA20163849A1 (it) | 2016-05-27 | 2017-11-27 | Marco Marzagalli | Composizione di colle per arti grafiche formulate con sostanze utilizzate nel settore alimentare |
| CN107189705B (zh) * | 2017-06-27 | 2018-07-27 | 阜南县力韦包装材料有限公司 | 一种能生物降解的封装胶带 |
| CN110903781A (zh) * | 2019-11-27 | 2020-03-24 | 南京格润包装材料有限公司 | 一种环保型胶水及其生产工艺 |
| EP3912485A1 (fr) | 2020-05-18 | 2021-11-24 | Del-Vis Sp. z o.o. | Produit cigarette et procede de fabrication du produit |
| CN114106734B (zh) * | 2021-11-24 | 2023-10-20 | 四川中烟工业有限责任公司 | 一种雪茄专用高透明度天然粘合剂及其制备方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR408254A (fr) * | 1900-01-01 | |||
| DE626010C (de) * | 1934-01-05 | 1936-02-19 | Albert Mang | Verfahren zur Herstellung eines zum Aufkleben von Papier auf Werkstoffe aller Art bestimmten Klebmittels |
| US3625225A (en) * | 1969-07-24 | 1971-12-07 | Amf Inc | Reconstituted tobacco |
| US4175996A (en) * | 1976-05-13 | 1979-11-27 | Service D'exploitation Industrielle Des Tabacs Et Des Allumettes | Glue for articles in the tobacco industry and method employing same |
| US4936920A (en) * | 1988-03-09 | 1990-06-26 | Philip Morris Incorporated | High void volume/enhanced firmness tobacco rod and method of processing tobacco |
-
1988
- 1988-11-11 DE DE3838255A patent/DE3838255A1/de not_active Withdrawn
-
1989
- 1989-11-02 ES ES198989120265T patent/ES2040965T3/es not_active Expired - Lifetime
- 1989-11-02 WO PCT/EP1989/001313 patent/WO1990005169A1/fr not_active Ceased
- 1989-11-02 US US07/690,970 patent/US5155140A/en not_active Expired - Fee Related
- 1989-11-02 EP EP89120265A patent/EP0368136B1/fr not_active Expired - Lifetime
- 1989-11-02 EP EP89912789A patent/EP0442938A1/fr active Pending
- 1989-11-02 DE DE8989120265T patent/DE58903525D1/de not_active Expired - Fee Related
- 1989-11-02 AT AT89120265T patent/ATE85638T1/de not_active IP Right Cessation
- 1989-11-10 ZA ZA898613A patent/ZA898613B/xx unknown
- 1989-11-14 CA CA002002841A patent/CA2002841A1/fr not_active Abandoned
Non-Patent Citations (1)
| Title |
|---|
| See references of WO9005169A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2002841A1 (fr) | 1990-05-11 |
| DE58903525D1 (de) | 1993-03-25 |
| DE3838255A1 (de) | 1990-05-17 |
| ZA898613B (en) | 1990-07-25 |
| US5155140A (en) | 1992-10-13 |
| EP0368136B1 (fr) | 1993-02-10 |
| ES2040965T3 (es) | 1993-11-01 |
| WO1990005169A1 (fr) | 1990-05-17 |
| ATE85638T1 (de) | 1993-02-15 |
| EP0368136A1 (fr) | 1990-05-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE |
|
| 17P | Request for examination filed |
Effective date: 19910502 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE FR GB IT LI NL |
|
| XX | Miscellaneous (additional remarks) |
Free format text: VERFAHREN ABGESCHLOSSEN INFOLGE VERBINDUNG MIT 89120265.7/0368136 (EUROPAEISCHE ANMELDENUMMER/VEROEFFENTLICHUNGSNUMMER) VOM 20.03.92. |