EP0468016A1 - Procede de preparation de pate a papier kraft. - Google Patents

Procede de preparation de pate a papier kraft.

Info

Publication number
EP0468016A1
EP0468016A1 EP91903366A EP91903366A EP0468016A1 EP 0468016 A1 EP0468016 A1 EP 0468016A1 EP 91903366 A EP91903366 A EP 91903366A EP 91903366 A EP91903366 A EP 91903366A EP 0468016 A1 EP0468016 A1 EP 0468016A1
Authority
EP
European Patent Office
Prior art keywords
cellulosic material
carried out
temperature
pulp
cooking
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91903366A
Other languages
German (de)
English (en)
Other versions
EP0468016B1 (fr
Inventor
Panu Olavi Tikka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Metso Paper Pori Oy
Original Assignee
Sunds Defibrator Rauma Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8529860&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0468016(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Sunds Defibrator Rauma Oy filed Critical Sunds Defibrator Rauma Oy
Publication of EP0468016A1 publication Critical patent/EP0468016A1/fr
Application granted granted Critical
Publication of EP0468016B1 publication Critical patent/EP0468016B1/fr
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C1/00—Pretreatment of the finely-divided materials before digesting
    • D21C1/06—Pretreatment of the finely-divided materials before digesting with alkaline reacting compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/0021—Introduction of various effluents, e.g. waste waters, into the pulping, recovery and regeneration cycle (closed-cycle)

Definitions

  • the present invention relates to a process for preparing kraft pulp. More particularly, the present invention relates to processes for preparing kraft pulp in which cellulosic material is treated with white or fresh liquor for dissolving the lignin therein. The present invention specifically relates to the pretreatment of the lignin-containing material before the lignin digestion step. BACKGROUND OF THE INVENTION
  • the kraft process has been developed by means of different technical processing means.
  • the need to save energy has led to new solutions, the most important of which have been continuous cooking processes (see, e.g., Finnish Patent No. 54155) .
  • the equipment used in such continuous cooking processes can include the use of several co- and countercurrent circulations, as well as separate impregnation vessels.
  • impregnating of the cellulosic material with spent alkaline cooking liquor employs liquor having a pH of between about 11.5 and 13.5, and preferably between about 12.5 and 13.5.
  • heating of the impregnated cellulosic material is carried out for a period of from about 1 to 30 minutes, whereby the pH of the spent alkaline cooking liquor impregnated into the cellulosic material is decreased to between about 9 and 11, and preferably to between about 9.5 and 10.5.
  • the spent and fresh alkaline cooking liquor comprises sodium hydroxide.
  • the spent alkaline cooking liquor has a residual sodium hydroxide content of between about 4 and 20 grams of sodium hydroxide per liter, and more preferably between about 6 and 15 grams of sodium hydroxide per liter.
  • the step of heating the impregnated cellulosic material is carried out at a temperature of between about 135 and 155'C. Preferably this step is carried out for a period of between about 10 and 30 minutes.
  • the cellulosic material is hardwood and the step of delignifying the heated cellulosic material is carried out using an H-factor of between about 900 and 1000, in order to produce a readily fiberized paper pulp.
  • the cellulosic material is softwood and the step of delignifying the heated cellulosic material is carried out using an H-factor of between about 400 and 700, in order to produce a readily fiberized paper pulp.
  • the step of delignifying the heated cellulosic material is carried out at a temperature of between about 180 and 190 * C.
  • the principal advantage of the process of the present invention is that digestion of the lignin with white liquor is greatly facilitated by means of this process. DETAILED DESCRIPTION it is essential that in accordance with the present invention the chips are pretreated with spent cooking liquor, or so-called black liquor. This pretreatment takes place in two steps. In the first step the chips are impregnated with the spent liquor, and in the second step they are reacted with it.
  • the chips are essentially filled with the spent liquor.
  • the temperature of this impregnation step must be below 100*C in order to avoid reaction therewith on the surface of the chips. In practice temperatures of from about 20 to 100*C can be utilized.
  • the time of this impregnation step should be from at least about 10 minutes, and preferably between about 15 and 20 minutes. Impregnation times of more than about 30 minutes are unnecessary.
  • the pH of the spent liquor is between about 12.5 and 13.5, and the residual alkali content is from about 4 to 20 g NaOH/1, and preferably between about 6 and 15 g NaOH/1.
  • the pretreatment reaction or heating step which follows the impregnation step is carried out at an elevated temperature of from about 120 to 180*C.
  • the reaction time depends on the temperature which is utilized, and is generally from about 1 to 30 minutes.
  • a reaction temperature of from about 135 to 155*C, and a reaction time of from about 10 to 30 minutes is utilized.
  • the residual chemicals in the black liquor react with the wood aterial, and alkali is consumed.
  • the pH within the chips is thus decreased to from about 9 to 10.
  • H-factor In a normal kraft process of, e.g., Scandinavian softwood, H-factors of from about 1600 to 1800 are required. In the present process, H-factors can be diminished by about 400 to 1000. This means that the overall digestion time can be significantly shortened.
  • An additional advantage of the present process is the increased selectivity of the delignification reaction. This, in turn, leads to higher yields and superior pulp quality, or to a lower consumption of cooking chemicals.
  • the digestion reaction can now al o be run for a longer period of time, and a lower lignin concentration can thus be achieved than is the case in conventional processes.
  • the pulp which is obtained thereby thus requires less bleaching, which, in turn, decreases the amount of harmful compounds which are discharged from the bleach plant into the waste waters therefrom.
  • the contents of the digester are heated to a temperature in the range of the reaction temperature in the case of (i) conventional batch processes, by means of the digester circulation being equipped with a heat exchanger, or by direct steam injection, and (ii) in case of low energy batch cooking, using the displacement technique, by displacing the colder impregnation black liquor with hotter black liquor for the purpose of carrying the process heat back to the digester.
  • Another embodiment of this invention utilizing batch digesters is to impregnate the chips with the black liquor in the context of chip filling in separate equipment.
  • the reaction stage would thus appear as the first step in the digester after chip filling, and could be very effectively carried out by the use of direct steam subsequent to the draining of the impregnation black liquor, or by displacing the impregnation/filling media black liquor by hotter black liquor.
  • continuous impregnation is carried out while charging the digester and is combined with batch cooking techniques, thus resulting in (i) compensation for the extra time spent with the black liquor stage, and (ii) reduction of the total cooking cycle time due to the greater speed of the cooking step.
  • the present invention can also be carried out in connection with continuous cooking processes.
  • the continuous digester -equipment presently being used including separate impregnation vessels and various co- and countercurrent circulations, effectively segregate the cooking process into several steps, in which the present invention can include starting the process with black liquor and without white liquor.
  • the chips are fed into the digester or impregnation vessel along with the black liquor, the temperature is elevated to the reaction range by heating with the aid of liquor circulation-heat exchanger.
  • the white liquor is then fed into the digester, displacing the black liquor, the temperature is again increased by means of a circulation-heat exchanger and the rest of the process is carried out in the conventional manner.
  • An alternative continuous process is to carry out the black liquor treatment stage as a countercurrent operation.
  • a forced circulation 20 liter digester was charged with pine chips in an amount corresponding to
  • Example 2 An industrial batch digester having a capacity of 140 3 was filled with pane chips and spent black liquor (pH 13.4) ⁇ om previous cookings. The temperature was elevated to 140'C, and maintained at that temperature for 15 minutes. The pH thus decreased to 11.
  • White liquor was added directly after filling with black liquor.
  • Pulp kappa number 15.2 Pulp viscosity 905 Cook C This Cook was carried out in the manner of a conventional batch Cook, without black liquor impregnation and treatment stages:
  • the alkali charge was 21% effective alkali as Na2 ⁇ > per wood
  • the pulps were analyzed in terms of strength by tear-tensile comparison, as is illustrated in FIG. 5. It is clear therefrom that, when the tensile index is increased to the useful range for paper making by beating (i.e., a tensile index of from 70 to 80), the conventionally cooked pulp loses its tear strength (curve "C") , while the pulp cooked with the treatment stage of the present invention still maintains its tear strength (curve *SB”) .
  • the advantage for pulp *SB" is three tear index units, or from 20 to 25% higher.
  • Example 2 Cooks 5 and 6, except that the cooking temperature was not limited to 170"C (curve “NTP" in
  • Example 2 Cooks 5,6: 25.4
  • the tear-tensile relationship of the pulp was analyzed in order to evaluate the pulp strength.
  • the tear index was 16, which equals the value found on curve " ⁇ " in FIG. 4 in Example 2, applying a normal cooking temperature and black liquor treatment. This slightly exceeded that of a normal cooking temperature with no black liquor treatment.
  • FIG. 6 sets forth a comparison between cooking temperature and time profiles for the Cook in this Example, and that of Cook Nos. 5 and 6 in Example 2 * , representing normal cooking temperatures.
  • Example 5 The results of this Example demonstrate that the pulps inside the digester prepared in accordance with the present invention are in extremely good condition to resist the physical damage during the discharge which arises by various blow methods, as compared to pulps cooked without the use of such a black liquor treatment stage.
  • the pulp conditions prior to the blow were determined by hanging baskets filled with the same chip material inside the digester. After the blow, pulp which had not been blown could thus be recovered from these baskets, and compared to samples of the blown pulp.
  • the analysis carried out was in terms of a so-called strength delivery, which is the percentage of the pulp strength as tear index at a tensile index of 70 measured in the blown pulp as compared to that of non-blown pulp in the basket.
  • Cooks were carried out with a black liquor treatment stage as described in Example 2, Cook Nos. 4-6, discharged by: hot blow, directly from full cooking temperature; cold blow, after cooling displacement to under 100*C; and pump discharge after cooling displacement.

Landscapes

  • Inorganic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Paper (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Inorganic Insulating Materials (AREA)
  • Iron Core Of Rotating Electric Machines (AREA)
  • Holo Graphy (AREA)
  • Nonmetallic Welding Materials (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Noodles (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

Le procédé décrit, qui sert à préparer de la pâte à papier kraft, consiste à soumettre à un traitement préalable la substance cellulosique ou les copeaux au moyen d'une liqueur de cuisson épuisée à une température comprise entre environ 20 et 100 °C, puis à chauffer les copeaux ainsi imprégnés à une température comprise entre environ 120 et 100 °C et à procéder ensuite à la digestion de la lignine au moyen d'une liqueur fraîche, ce qui est facilité grâce à l'utilisation de l'étape de pré-traitement.
EP91903366A 1990-02-09 1991-02-11 Procede de preparation de pate a papier kraft Revoked EP0468016B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI900663 1990-02-09
FI900663A FI93866B (fi) 1990-02-09 1990-02-09 Menetelmä sulfaattimassan valmistamiseksi
PCT/FI1991/000043 WO1991012368A1 (fr) 1990-02-09 1991-02-11 Procede de preparation de pate a papier kraft

Publications (2)

Publication Number Publication Date
EP0468016A1 true EP0468016A1 (fr) 1992-01-29
EP0468016B1 EP0468016B1 (fr) 1996-08-14

Family

ID=8529860

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91903366A Revoked EP0468016B1 (fr) 1990-02-09 1991-02-11 Procede de preparation de pate a papier kraft

Country Status (14)

Country Link
EP (1) EP0468016B1 (fr)
JP (1) JP2900091B2 (fr)
AT (1) ATE141351T1 (fr)
AU (1) AU639304B2 (fr)
BR (1) BR9104333A (fr)
CA (1) CA2049322C (fr)
DE (1) DE69121332T2 (fr)
ES (1) ES2091319T3 (fr)
FI (1) FI93866B (fr)
NO (1) NO178935C (fr)
NZ (1) NZ236941A (fr)
PT (1) PT96713B (fr)
WO (1) WO1991012368A1 (fr)
ZA (1) ZA91958B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013164234A1 (fr) 2012-05-03 2013-11-07 Annikki Gmbh Procédé de production de cellulose à faible teneur en lignine à partir d'un matériau lignocellulosique

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE469842C (sv) * 1992-01-21 1996-01-15 Sunds Defibrator Ind Ab Blekning av kemisk massa med peroxid
NZ247276A (en) * 1992-04-06 1994-12-22 Westvaco Corp Production of papermaking fibre of low lignin content from recycled high lignin waste paper; mixtures with fresh pulp and products produced therefrom
FI970254A7 (fi) * 1997-01-22 1998-07-23 Ahlstrom Machinery Oy Menetelmä ja laitteisto massan keittämiseksi
FI20002586A7 (fi) * 2000-11-24 2002-05-25 Metso Paper Inc Alkalinen eräkeittomenetelmä kuitumateriaalille
FI20002587L (fi) * 2000-11-24 2002-05-25 Metso Paper Inc Alkalinen keittomenetelmä kuitumateriaalille
KR20110123184A (ko) 2010-05-06 2011-11-14 바히아 스페셜티 셀룰로스 에스에이 높은 알파 용해 펄프 제조를 위한 방법 및 시스템
KR102143773B1 (ko) * 2018-10-25 2020-08-12 한국세라믹기술원 리그노셀룰로오스 바이오매스를 이용한 부분결정성 활성탄의 제조방법 및 상기 부분결정성 활성탄을 이용한 슈퍼커패시터의 제조방법
KR102157512B1 (ko) * 2018-11-16 2020-09-18 한국세라믹기술원 리그노셀룰로오스 바이오매스를 이용한 구형의 다공성 활성탄 제조방법 및 이를 이용한 슈퍼커패시터의 제조방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE101369C1 (fr) *
US1687076A (en) * 1927-10-12 1928-10-09 Venning D Simons Process for cooking wood chips by the alkaline process of pulp manufacture
US2639987A (en) * 1947-07-09 1953-05-26 Ass Pulp & Paper Mills Two-stage pulping process
US4578149A (en) * 1981-03-05 1986-03-25 Fagerlund Bertil K E Process for digesting cellulosic material with heat recovery

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9112368A1 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013164234A1 (fr) 2012-05-03 2013-11-07 Annikki Gmbh Procédé de production de cellulose à faible teneur en lignine à partir d'un matériau lignocellulosique

Also Published As

Publication number Publication date
NO178935C (no) 2000-06-26
JPH04505485A (ja) 1992-09-24
ZA91958B (en) 1991-11-27
PT96713B (pt) 2001-05-31
CA2049322A1 (fr) 1991-08-10
CA2049322C (fr) 2002-08-20
JP2900091B2 (ja) 1999-06-02
FI93866B (fi) 1995-02-28
WO1991012368A1 (fr) 1991-08-22
NO913873L (no) 1991-10-02
FI900663A0 (fi) 1990-02-09
BR9104333A (pt) 1992-04-21
DE69121332T2 (de) 1997-03-13
ES2091319T3 (es) 1996-11-01
EP0468016B1 (fr) 1996-08-14
NO913873D0 (no) 1991-10-02
AU7218991A (en) 1991-09-03
NZ236941A (en) 1993-10-26
DE69121332D1 (de) 1996-09-19
FI900663L (fi) 1991-08-10
AU639304B2 (en) 1993-07-22
ATE141351T1 (de) 1996-08-15
NO178935B (no) 1996-03-25
PT96713A (pt) 1991-10-31

Similar Documents

Publication Publication Date Title
US5589033A (en) Production of prehydrolyzed pulp
US3652387A (en) Process for the manufacture of dissolving-grade pulp
US4248662A (en) Oxygen pulping with recycled liquor
CA1226705A (fr) Production chimicothermique de la pate a papier par traitements distincts a l'alcali et au sulfite
US5676795A (en) Process for the production of viscose pulp
US8475627B2 (en) Process of treating a lignocellulosic material
US3888727A (en) Treatment of lignocellulosic material in an alkaline pulping liquor containing anthraquinone sulphonic acid followed by oxygen delignification
US8262851B2 (en) Processes and systems for the pulping of lignocellulosic materials
US4076579A (en) Pulping of lignocellulosic material by sequential treatment thereof with nitric oxide and oxygen
US5183535A (en) Process for preparing kraft pulp using black liquor pretreatment reaction
AU639304B2 (en) Process for preparing kraft pulp
EP0810321B1 (fr) Procédé en discontinu pour préparation des pâtes kraft ameliorées
US3919041A (en) Multi-stage chlorine dioxide delignification of wood pulp
US3829357A (en) Oxidative manufacture of pulp with chlorine dioxide
US3520773A (en) Alkaline pulping processes with chemical pretreatment
US20060175029A1 (en) Batch process for preparing pulp
US3773611A (en) Two-stage sodium sulfite-oxygen pulping
US1841551A (en) Multiple-step process of fiber liberation
US3046184A (en) Manufacture of cellulosic products
SU779471A1 (ru) Способ получени целлюлозы
Resende et al. HEMICELLULOSES EXTRACTION AND USES IN THE PULP INDUSTRY
Colodette et al. THE TRUE IMPORTANCE OF OXYGEN DELIGNIFICATION FOR EUCALYPTUS KRAFT PULPS

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19910919

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT DE ES FR GB IT SE

17Q First examination report despatched

Effective date: 19930906

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: SUNDS DEFIBRATOR PORI OY

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT DE ES FR GB IT SE

REF Corresponds to:

Ref document number: 141351

Country of ref document: AT

Date of ref document: 19960815

Kind code of ref document: T

REF Corresponds to:

Ref document number: 69121332

Country of ref document: DE

Date of ref document: 19960919

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2091319

Country of ref document: ES

Kind code of ref document: T3

ITF It: translation for a ep patent filed
ET Fr: translation filed
PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

26 Opposition filed

Opponent name: KVAERNER PULPING AB

Effective date: 19970502

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

PLBF Reply of patent proprietor to notice(s) of opposition

Free format text: ORIGINAL CODE: EPIDOS OBSO

RDAH Patent revoked

Free format text: ORIGINAL CODE: EPIDOS REVO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

APAE Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOS REFNO

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20020129

Year of fee payment: 12

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20020207

Year of fee payment: 12

PLBQ Unpublished change to opponent data

Free format text: ORIGINAL CODE: EPIDOS OPPO

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: METSO CHEMICAL PULPING OY

R26 Opposition filed (corrected)

Opponent name: KVAERNER PULPING AB

Effective date: 19970502

APAC Appeal dossier modified

Free format text: ORIGINAL CODE: EPIDOS NOAPO

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20030130

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20030204

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20030206

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20030217

Year of fee payment: 13

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

27W Patent revoked

Effective date: 20030120

GBC Gb: translation of claims filed (gb section 78(7)/1977)

Free format text: 20030120

REG Reference to a national code

Ref country code: SE

Ref legal event code: ECNC

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO