EP0481129A1 - Elément récepteur pour le transfert de colorant par thermosublimation - Google Patents

Elément récepteur pour le transfert de colorant par thermosublimation Download PDF

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Publication number
EP0481129A1
EP0481129A1 EP90202759A EP90202759A EP0481129A1 EP 0481129 A1 EP0481129 A1 EP 0481129A1 EP 90202759 A EP90202759 A EP 90202759A EP 90202759 A EP90202759 A EP 90202759A EP 0481129 A1 EP0481129 A1 EP 0481129A1
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EP
European Patent Office
Prior art keywords
dye
acid
image receiving
receiving element
polyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP90202759A
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German (de)
English (en)
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EP0481129B1 (fr
Inventor
Herman Jozef Uytterhoeven
August Marcel Marien
Rolf Wehrmann
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Agfa Gevaert NV
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Agfa Gevaert NV
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Filing date
Publication date
Application filed by Agfa Gevaert NV filed Critical Agfa Gevaert NV
Priority to EP19900202759 priority Critical patent/EP0481129B1/fr
Priority to DE1990609057 priority patent/DE69009057T2/de
Priority to EP19910114420 priority patent/EP0481200B1/fr
Priority to DE91114420T priority patent/DE59100636D1/de
Priority to US07/773,036 priority patent/US5250494A/en
Priority to JP3298289A priority patent/JP2623181B2/ja
Priority to JP3296629A priority patent/JPH04263991A/ja
Publication of EP0481129A1 publication Critical patent/EP0481129A1/fr
Application granted granted Critical
Publication of EP0481129B1 publication Critical patent/EP0481129B1/fr
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5272—Polyesters; Polycarbonates

Definitions

  • the present invention relates to dye-image receiving elements for use according to thermal dye sublimation transfer.
  • Thermal dye sublimation transfer also called thermal dye diffusion transfer is a recording method in which a dye-donor element provided with a dye layer containing sublimable dyes having heat transferability is brought into contact with a dye-image receiving element and selectively, in accordance with a pattern information signal, heated with a thermal printing head provided with a plurality of juxtaposed heat- generating resistors, whereby dye from the selectively heated regions of the dye-donor element is transferred to the dye-image receiving element and forms a pattern thereon, the shape and density of which is in accordance with the pattern and intensity of heat applied to the dye-donor element.
  • a dye-image receiving element for use according to thermal dye sublimation transfer usually comprises a support, e.g. paper or a transparant film, coated with a dye-image receiving layer, into which the dye can diffuse more readily.
  • An adhesive layer may be provided between the support and the receiving layer.
  • the dye-image receiving layer may comprise as binder, for example, a polycarbonate, a polyurethane, a polyester, a polyamide, a polyvinyl chloride, a polystyrene-co-acrylonitrile, a polycaprolactone or mixtures thereof.
  • binder for example, a polycarbonate, a polyurethane, a polyester, a polyamide, a polyvinyl chloride, a polystyrene-co-acrylonitrile, a polycaprolactone or mixtures thereof.
  • a generally used binder is (co)polyester obtained by (co)polycondensation between one or more dicarboxylic acids and one or more diols.
  • at least one of the dicarboxylic acids and/or diols contains an aromatic moiety so that the glass transition point of the (co)polyester is at least 0 ° C, preferably at least 20 ° C.
  • polyester receiving layers are described in e.g. EP 289161, EP 275319, EP 261505, EP 368318, JP 86/3796 and JP 89/269589.
  • JP 89/269589 there are described polyester image receiving layers with as examples of dicarboxylic acid condensation residues malonic acid, succinic acid, fumaric acid, maleic acid, glutaric acid and adipic acid.
  • diols examples include ethylene glycol and neopentylglycol.
  • a release agent is generally incorporated in the image-receiving layer of the prior art or in a topcoat on this image receiving layer.
  • a dye-image receiving element for use according to thermal dye sublimation transfer, said dye-image receiving element comprising a support having thereon a dye-image receiving layer containing a (co)polyester comprising condensation residues of one or more diols and one or more dicarboxylic acids characterized in that at least one of said diols and/or said dicarboxylic acids contains not more than 5 carbon atoms in the main chain and contains a long chain alkyl or alkylene group having at least 6 carbon atoms in a side chain.
  • a (co)polyester comprising condensation residues of one or more diols and one or more dicarboxylic acids characterized in that at least one of said diols and/or said dicarboxylic acids contains not more than 5 carbon atoms in the main chain and contains a long chain alkyl or alkylene group having at least 6 carbon atoms in a side chain.
  • the long chain side group contains at least 10 carbon atoms.
  • the long chain alkyl or alkylene group of the side-chain may be branched or non-branched. Also two or more long chain alkyl or alkylene side-groups may be contained in the present diol or dicarboxylic acid either on the same carbon atom of the main chain or on different carbon atoms.
  • the long chain alkyl or alkylene side-group may be linked to the main chain via linking groups such as aromatic moieties, alicyclic moieties, hetero atoms (e.g. -O-, -NH-, -O-CO-, -NH-CO-).
  • linking groups such as aromatic moieties, alicyclic moieties, hetero atoms (e.g. -O-, -NH-, -O-CO-, -NH-CO-).
  • Examples of the present short chain diols containing a long chain alkyl or alkylene side-group include 1,2-octanediol, 1,2-decanediol, 1,2-dodecanediol, 1,2-hexadecanediol, 1,4-octadecanediol, N,N-di-(n-decyl)-amino-2,3-propanediol, glycerine mono stearate, glycerine mono oleate, glycerine mono ricinoleate, glycerine mono laurate, glycerine mono caprylate, pentaerytritol distearate and pentadecylresorcine.
  • 1,2-dodecanediol 1,2-hexadecanediol, glycerine mono stearate, glycerine mono oleate, pentaerytritol distearate and pentadecylresorcine are particularly preferred.
  • Examples of the present short chain dicarboxylic acids containing a long chain alkyl or alkylene side-group include tetradecylmalonic acid, hexadecylmalonic acid, octadecylmalonic acid, diheptylmalonic acid, octylsuccinic acid, decylsuccinic acid, dodecylsuccinic acid, tetradecylsuccinic acid, hexadecylsuccinic acid, octadecylsuccinic acid, octenylsuccinic acid, iso-octenylsuccinic acid, decenylsuccinic acid, dodecenylsuccinic acid, tetradecenylsuccinic acid, hexadecenylsuccinic acid, octadecenylsuccinic acid, docosylsuccinic acid, doco
  • hexadecylmalonic acid octadecylmalonic acid, hexadecylsuccinic acid, octadecylsuccinic acid and docosenylsuccinic acid are particularly preferred.
  • the (co)polyester of the present invention may be obtained by condensing one or more dicarboxylic acids with one or more diols including aromatic and aliphatic dicarboxylic acids and diols and including one or more of the present short chain diols or dicarboxylic acids containing a long chain alkyl or alkylene side group.
  • the condensation can also be carried out by using derivatives of the dicarboxylic acids in the form of their corresponding esters and/or derivatives of the diols in the form of their corresponding epoxides or in the form of their corresponding acetates.
  • At least one of the condensation residues contains an aromatic moiety.
  • aromatic dicarboxylic acids examples include terephthalic acid, isophthalic acid, sulfoisophthalic acid, orthophtalic acid, t-butylisophthalic acid, 4,4'-oxybisbenzoic acid, 2,5-, 2,6- or 2,7-naphthalenedicarboxylic acid, 4,4-diphenyldicarboxylic acid, dipicolinic acid and 2,2-bis(p-carboxyphenyl)propane.
  • aromatic diols examples include bisphenol A, ethoxylized bisphenol A (e.g. Dianol 22 supplied by Akzo), propoxylized bisphenol A (e.g. Dianol 33 supplied by Akzo), p-xylyleneglycol, 5-sodium sulforesor- cine.
  • aliphatic dicarboxylic acids examples include malonic acid, succinic acid, glutaric acid, adipic acid, itaconic acid, maleic acid, 1,4-cyclohexanedicarboxylic acid.
  • aliphatic diols examples include ethylene glycol, diethyleneglycol, triethyleneglycol, neopentylglycol, 1,4-butanediol, 1,2-propanediol, 1,3-propanediol, 1,2-hexanediol, 1,6-hexanediol, 1,4-cyclohexanedimethanol, 1,4-cyclohexanediol, 2,2'-bis(4-hydroxy-cyclohexyl)propane.
  • diols and dicarboxylic acids there can be incorporated in the polyester small amounts of long chain diols and/or dicarboxylic acids and/or hydroxy-carboxylic acids to further enhance the dyeability.
  • Examples of said long chain diols include 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,14-tetradecanediol, 1,15-pentadecanediol, 1,16-hexadecanediol, 1,17-heptadecanediol, 1,12-octadecanediol, 1,18-octadecanediol, 1,2-epoxyoctadecanediol, 1,19-nonadecanediol, 1,20-eicosanediol, 1,21-heneicosanediol, 1,22-docosanediol, 1,25-pentacosanediol,
  • Examples of said long chain dicarboxylic acids include sebacic acid, azelaic acid, decane dicarboxylic acid, undecane dicarboxylic acid, dodecane dicarboxylic acid, tridecane dicarboxylic acid, tetradecane dicarboxylic acid, heptadecane dicarboxylic acid, octadecane dicarboxylic acid, nonadecane dicarboxylic acid, eicosane dicarboxylic acid, docosane dicarboxylic acid, dimer fatty acids and derivatives such as PRIPOL 1008/1009 (CAS registry no.
  • hydroxy-carboxylic acids containing a long chain alkyl or alkylene group examples include methyl-n-hexylglycolic acid, 2,3-dihydroxynonanoic acid, 11-hydroxyundecanoic acid, 2-hydroxy-4,6,6-trimethylheptanoic acid, 16-hydroxyhexadecanoic acid, 12-hydroxystearic acid, 12-hydroxy-9-octadecenic acid, ricinoleic acid, 12,13-epoxy-9-octadecenic acid, anacardic acid.
  • polyester resins used according to the present invention can be prepared by the condensation polymerisation reactions known in the art. In the case of polyester containing one or more double bonds inhibitors can be added to avoid crosslinking and/or side-reactions.
  • the present short chain diols or dicarboxylic acids containing a long chain alkyl or alkylene side-group are preferably incorporated in the polyester in an amount of between 1 and 60 mole % of the total diol respectively dicarboxylic acid content, preferably between 5 and 25 mole %, more preferably between 5 and 10 mole %.
  • the molecular weight of the polyester binder according to the present invention is preferably about 1000 to 10000.
  • the molecular weight can be increased by adding during the polycondensation reaction small amounts (for example approximately 0.1 mole %) of a trifunctional or tetrafunctional product e.g. a compound corresponding to the following structure
  • a solubilizing group such as COO-, SO 3 , 0- or a polyethyleneoxide chain is incorporated in the (co)polyester either via one of the dicarboxylic acids (e.g. sulfoisophthalic acid, sulfoterephthalic acid, sulfo-orthophthalic acid) or via one of the diols (e.g. Tegomer DS 3117 corresponding to formula (a) below or Tegomer D 3403 corresponding to formula (b) below, both supplied by Goldschmidt) with the advantage that an aqueous application of the image receiving layer to the support is then easily conducted.
  • the solubilizing groups are described in EP 368318 and JP 86/3796.
  • Preferred (co)polyester resins of the present invention are indicated below in table 1, but the invention is not limited thereto.
  • TPA TPA
  • IPA SIPA
  • EG DIA22
  • CHDM CHDM
  • NPG NPG
  • TEGODS TEGOD
  • MAL MAL
  • HSA HSA and LCA
  • polyester resins of the present invention are preferably coated in an amount of from 0.5 gram to 100 grams per square meter of the support, preferably from 1 to 10 g/m 2 .
  • Mixtures of the present (co)polyester resins can be used in the present invention, and mixtures of these resins with other known dye receiving resins can also be used.
  • synthetic resins (a) to (e) shown below can be used singly or as a mixture of two or more kinds in combination with the present (co)polyester resin.
  • the receiving layer can be constituted of a resin mixture of a (co)polyester according to the present invention and a conventional (co)polyester resin.
  • the amount of the other resin is preferably 0 to 100 parts by weight per 100 parts by weight of the present (co)polyester resin.
  • High boiling organic solvents or thermal solvents or plasticizers can be included in the image-receiving layer, as substances which can accept or dissolve the dyes or as diffusion promotors for the dyes.
  • Useful examples of such high boiling organic solvents and thermal solvents include the compounds disclosed in, for example, JP 62/174754, JP 62/245253, JP 61/209444, JP 61/200538, JP 62/8145, JP 62/9348, JP 62/30247, JP 62/136646.
  • a white pigment can be added to the receiving layer.
  • the white pigment titanium oxide, zinc oxide, kaolin, clay, calcium carbonate, fine powdery silica, etc. can be employed, and these can be used as a mixture of two or more kinds as described above.
  • one or two or more kinds of additives such as UV-ray absorbers, light stabilizers and antioxidants, can be added, if necessary.
  • the amounts of these UV-ray absorbers and light stabilizers is preferably 0.05 to 10 parts by weight and 0.5 to 3 parts by weight, respectively, per 100 parts of the resin constituting the receiving layer.
  • the dye receiving element of the present invention can contain a release agent for improvement of the release property with respect to the donor element.
  • a release agent for improvement of the release property with respect to the donor element.
  • solid waxes such as polyethylene wax, amide wax, and Teflon powder; fluorine based and phosphate ester based surfactants; and paraffin based, silicone based and fluorine based oils.
  • Silicone oils preferably reactive silicone oils and silicone containing copolymers such as a polysiloxane-polyether copolymer, are preferred.
  • a release agent can be provided by applying a coating of a solution or a dispersion of the above release agent in an appropriate solvent and then carrying out drying and other steps.
  • the thickness of the release layer is preferably 0.01 to 5 am, particularly 0.05 to 2 ⁇ m.
  • Formation of the receiving layer may be practiced not only by a known coating or printing method, but also by first coating the receiving layer composition obtained by dissolving or dispersing the appropriate materials on a separate temporary carrier and then transferring it therefrom to the permanent support.
  • the support for the receiver sheet it is possible to use a transparant film or sheet of various plastics such as polyethylene terephthalate, polyolefin, polyvinyl chloride, polystyrene, polycarbonate, polyether sulfone, polyimide, cellulose ester or polyvinyl alcohol-co-acetal.
  • the support may also be a reflective one such as paper (top quality paper, art paper, cellulose fiber paper), baryta-coated paper, polyolefin-coated paper e.g. dual polyethylene-coated paper, synthetic paper (polyolefin type, polystyrene type) or white polyester i.e. white-pigmented polyester.
  • a laminated product by any desired combination of the above can be used.
  • Typical examples of the laminates include a laminate of cellulose fiber paper and synthetic paper and a laminate of cellulose fiber paper and a plastic film or sheet.
  • a plastic film can be used with synthetic paper instead of cellulose fiber paper.
  • a laminate of cellulose fiber paper, plastic film and synthetic paper can also be used.
  • the support sheet serves to support the dye receiving layer, and it is desirable that the support sheet has mechanical strength sufficient enough to handle the dye receiving sheet which is heated at the time of heat transfer recording. If the dye-receiving layer alone has the necessary mechanical strength, the support sheet may be omitted.
  • the dye-receiving layer of the present invention preferably has an overall thickness of from 0.5 to 50 am, more preferably from 2.5 to 10 am, when the dye-receiving layer is provided on a support sheet, or preferably from 3 to 120 ⁇ m when a support sheet is omitted.
  • the image receiving layer may be a single layer, or two or more such layers may be provided on the support.
  • receiving layers may be formed on both surfaces of the support.
  • receiving layers may be formed on both surfaces of the support.
  • the image receiving element of the present invention may also have one or more intermediate layers between the support and the image receiving layer.
  • the intermediate layers may function as cushioning layers, porous layers or dye diffusion preventing layers, or may fulfill two or more of these functions, and they may also serve the purpose of an adhesive, depending on the particular application.
  • the material constituting the intermediate layer may include, for example, urethane resin, acrylic resin, ethylenic resin, butadiene rubber, or epoxy resin.
  • the thickness of the intermediate layer may preferably be about 2 to 20 am.
  • Dye diffusion preventing layers are layers which prevent the dye from diffusing into the support.
  • the binders used to form these layers may be water soluble or organic solvent soluble, but the use of water soluble binders is preferred, and especially gelatin is most desirable.
  • Porous layers are layers which prevent the heat which is applied at the time of thermal transfer from diffusing from the image receiving layer to the support to ensure that the heat which has been applied is used efficiently.
  • Fine powders consisting of silica, clay, talc, diatomaceous earth, calcium carbonate, calcium sulfate, barium sulfate, aluminum silicate, synthetic zeolites, zinc oxide, lithophone, titanium oxide or alumina for example, can be included in the image receiving layers, cushioning layers, porous layers, diffusion preventing layers and adhesive layers, etc. constituting the thermal transfer image receiving element of the present invention.
  • the image receiving element of the present invention can have antistatic treatment applied to the front or back surface thereof.
  • antistatic treatment may be carried out by incorporating an antistatic agent in, for example, the image receiving layer which becomes the front surface or in an antistatic preventive layer applied to the image receiving surface.
  • a similar treatment can also be effected to the back surface.
  • the image receiving sheet can have a lubricating layer provided on the back surface of the sheet support.
  • the material for the lubricating layer may include methacrylate resins such as methyl methacrylate, etc. or corresponding acrylate resins, vinyl resins such as vinyl chloride-vinyl acetate copolymer.
  • the receiving element can have detection marks provided on one surface, preferably the back surface so that the receiving element can be accurately set at a desired position during transfer, whereby the image can be formed always at a correct desired position.
  • a dye-donor element for use according to thermal dye sublimation transfer in combination with the present receiving element usually comprises a very thin support e.g. a polyester support, one side of which is covered with a dye layer, which contains the printing dyes.
  • a dye layer which contains the printing dyes.
  • an adhesive or subbing layer is provided between the support and the dye layer.
  • a slipping layer that provides a lubricated surface against which the thermal printing head can pass without suffering abrasion.
  • An adhesive layer may be provided between the support and the slipping layer.
  • the dye layer can be a monochrome dye layer or it may comprise sequential repeating areas of different colored dyes like e.g. of cyan, magenta, yellow and optionally black hue.
  • a dye-donor element containing three or more primary color dyes is used, a multicolor image can be obtained by sequentially performing the dye transfer process steps for each color.
  • the dye layer of such a thermal dye sublimation transfer donor element is formed preferably by adding the dyes, the polymeric binder medium, and other optional components to a suitable solvent or solvent mixture, dissolving or dispersing the ingredients to form a coating composition that is applied to a support, which may have been provided first with an adhesive or subbing layer, and dried.
  • the dye layer thus formed has a thickness of about 0.2 to 5.0 am, preferably 0.4 to 2.0 am, and the ratio of dye to binder is between 9:1 and 1:3 by weight, preferably between 2:1 and 1:2 by weight.
  • polymeric binder As polymeric binder the following can be used: cellulose derivatives, such as ethyl cellulose, hydroxyethyl cellulose, ethylhydroxy cellulose, ethylhydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, nitrocellulose, cellulose acetate formate, cellulose acetate hydrogen phthalate, cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, cellulose acetate pentanoate, cellulose acetate benzoate, cellulose triacetate; vinyl-type resins and derivatives, such as polyvinyl alcohol, polyvinyl acetate, polyvinyl butyral, copolyvinyl butyral-vinyl acetal-vinyl alcohol, polyvinyl pyrrolidone, polyvinyl acetoacetal, polyacrylamide; polymers and copolymers derived from acrylates and acrylate derivatives, such as polyacrylic acid, poly
  • Any dye can be used in such a dye layer provided it is easily transferable to the dye-image-receiving layer of the receiver sheet by the action of heat.
  • Particularly preferred dyes or dye mixtures for use in the primary color dye-donor elements are for yellow a mixture of a dye corresponding to the formula
  • the binder that is preferably used in said primary color dye layers is a mixture of co-styrene-acrylonitrile and co-styrene-acrylonitrile-butadieen in a ratio ranging from 0 to 100 % of either of the constituents.
  • the binder/dye ratio is between 5:1 and 1:5.
  • the coating layer may also contain other additives, such as curing agents, preservatives, organic or inorganic fine particles, dispersing agents, antistatic agents, defoaming agents, viscosity controlling agents, etc., these and other ingredients being described more fully in EP 133011, EP 133012, EP 111004 and EP 279467.
  • additives such as curing agents, preservatives, organic or inorganic fine particles, dispersing agents, antistatic agents, defoaming agents, viscosity controlling agents, etc.
  • any material can be used as the support for the dye-donor element provided it is dimensionally stable and capable of withstanding the temperatures involved, up to 400 ° C over a period of up to 20 msec, and is yet thin enough to transmit heat applied on one side through to the dye on the other side to effect transfer to the receiver sheet within such short periods, typically from 1 to 10 msec.
  • Such materials include polyesters such as polyethylene terephthalate, polyamides, polyacrylates, polycarbonates, cellulose esters, fluorinated polymers, polyethers, polyacetals, polyolefins, polyimides, glassine paper and condenser paper. Preference is given to a polyethylene terephthalate support. In general, the support has a thickness of 2 to 30 am.
  • the support may also be coated with an adhesive or subbing layer, if desired.
  • the dye layer of the dye-donor element may be coated on the support or printed thereon by a printing technique such as a gravure process.
  • a dye-barrier layer comprising a hydrophilic polymer may also be employed in the dye-donor element between its support and the dye layer to improve the dye transfer densities by preventing wrong-way transfer of dye towards the support.
  • the dye barrier layer may contain any hydrophilic material which is useful for the intended purpose.
  • gelatin polyacryl amide, polyisopropyl acrylamide, butyl methacrylate grafted gelatin, ethyl methacrylate grafted gelatin, ethyl acrylate grafted gelatin, cellulose monoacetate, methyl cellulose, polyvinyl alcohol, polyethylene imine, polyacrylic acid, a mixture of polyvinyl alcohol and polyvinyl acetate, a mixture of polyvinyl alcohol and polyacrylic acid or a mixture of cellulose monoacetate and polyacrylic acid.
  • Suitable dye barrier layers have been described in e.g. EP 227091 and EP 228065.
  • hydrophilic polymers for example those described in EP 227091, also have an adequate adhesion to the support and the dye layer, thus eliminating the need for a separate adhesive or subbing layer.
  • These particular hydrophilic polymers used in a single layer in the donor element thus perform a dual function, hence are referred to as dye-barrier/subbing layers.
  • the reverse side of the dye-donor element can be coated with a slipping layer to prevent the printing head from sticking to the dye-donor element.
  • a slipping layer would comprise a lubricating material such as a surface active agent, a liquid lubricant, a solid lubricant or mixtures thereof, with or without a polymeric binder.
  • the surface active agents may be any agents known in the art such as carboxylates, sulfonates, phosphates, aliphatic amine salts, aliphatic quaternary ammonium salts, polyoxyethylene alkyl ethers, polyethylene glycol fatty acid esters, fluoroalkyl C 2 -C 2o aliphatic acids.
  • liquid lubricants include silicone oils, synthetic oils, saturated hydrocarbons and glycols.
  • solid lubricants include various higher alcohols such as stearyl alcohol, fatty acids and fatty acid esters. Suitable slipping layers are described in e.g. EP 138483, EP 227090, US 4567113, US 4572860, US 4717711.
  • the slipping layer comprises as binder a styrene-acrylonitrile copolymer or a styrene-acrylonitrile- butadiene copolymer or a mixture thereof and as lubricant in an amount of 0.1 to 10 % by weight of the binder (mixture) a polysiloxane-polyether copolymer or polytetrafluoroethylene or a mixture thereof.
  • the dye layer of the dye-donor element may also contain a releasing agent that aids in separating the dye-donor element from the dye-receiving element after transfer.
  • the releasing agents can also be applied in a separate layer on at least part of the dye layer.
  • solid waxes fluorine- or phosphate-containing surfactants and silicone oils are used. Suitable releasing agents are described in e.g. EP 133012, JP 85/19138, EP 227092.
  • the dye-receiving elements according to the invention are used to form a dye transfer image.
  • Such a process comprises placing the dye layer of the donor element in face-to-face relation with the dye-receiving layer of the receiver sheet and imagewise heating from the back of the donor element.
  • the transfer of the dye is accomplished by heating for about several milliseconds at a temperature of 400 C.
  • a monochrome dye transfer image is obtained.
  • a multicolor image can be obtained by using a donor element containing three or more primary color dyes and sequentially performing the process steps described above for each color.
  • the above sandwich of donor element and receiver sheet is formed on three occasions during the time when heat is applied by the thermal printing head. After the first dye has been transferred, the elements are peeled apart.
  • a second dye-donor element (or another area of the donor element with a different dye area) is then brought in register with the dye-receiving element and the process repeated.
  • the third color and optionally further colors are obtained in the same manner.
  • detection marks are commonly provided on one surface of the donor element.
  • optically detectable marks are used that can be detected by a light source and a photo sensor; detection can be done by measuring the light transmitted through the detection mark or reflected from said mark.
  • the marks being in the form of a light- absorbing or light-reflecting coating are formed in a preassigned position on the donor element by e.g. gravure printing.
  • the detection marks can comprise an infrared absorbing compound such as carbon black.
  • the detection mark can also comprise one of the image dyes that are used for the image formation, with the detection being in the visible range.
  • thermal heads In addition to thermal heads, laser light, infrared flash or heated pens can be used as the heat source for supplying heat energy.
  • Thermal printing heads that can be used to transfer dye from the dye-donor elements of the present invention to a receiver sheet are commercially available.
  • the dye layer or another layer of the dye element has to contain a compound that absorbs the light emitted by the laser and converts it into heat, e.g. carbon black.
  • the support of the dye-donor element may be an electrically resistive ribbon consisting of, for example, a multi-layer structure of a carbon loaded polycarbonate coated with a thin aluminum film.
  • Current is injected into the resistive ribbon by electrically addresssing a print head electrode resulting in highly localized heating of the ribbon beneath the relevant electrode.
  • the fact that in this case the heat is generated directly in the resistive ribbon and that it is thus the ribbon that gets hot leads to an inherent advantage in printing speed using the resistive ribbon/electrode head technology compared to the thermal head technology where the various elements of the thermal head get hot and must cool down before the head can move to the next printing position.
  • the esterification started rapidly and methanol was distilled off. During about 60 to 90 minutes the temperature was raised to 255 ° C and the theoretical amount of methanol was distilled off. The reaction product was condensed under reduced pressure in 60 to 120 minutes at 255-280"C until the desired polymerization degree was obtained. The excess of ethyleneglycol was distilled off during the condensation reaction.
  • polyester resins according to the present invention such as those listed in table 1 can be prepared according to the above method.
  • a 10 wt % aqueous polyester dispersion was applied to the support material (polyethylene coated paper) by bar coating in a wet thickness of 20 ⁇ m and dried at 40 ° C and further dried at 90 ° C for 30 minutes.
  • Image receiving elements comprising the polyester resins identified in table 2 below were prepared in this manner.
  • a commercially available Mitsubishi material type CK 100S was used as dye donor element.
  • the obtained dye receiving element was printed in combination with the dye-donor element in a Mitsubishi video printer type CP 100 so as to form a black image by superposition of yellow, magenta and cyan images.
  • the receiver sheet was separated from the dye-donor element and the color density of the recorded black image on the receiving sheet was measured by means of a Macbeth RD919 densitometer.
  • the anti-sticking properties of the image receiving layer without using a releasing compound in the receiving layer or in a toplayer are improved.
  • a release agent needs to be incorporated in the layer in order to prevent adherence of the donor element to the receiving element.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Laminated Bodies (AREA)
EP19900202759 1990-10-17 1990-10-17 Elément récepteur pour le transfert de colorant par thermosublimation Expired - Lifetime EP0481129B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP19900202759 EP0481129B1 (fr) 1990-10-17 1990-10-17 Elément récepteur pour le transfert de colorant par thermosublimation
DE1990609057 DE69009057T2 (de) 1990-10-17 1990-10-17 Empfangselement für die Farbstoffübertragung durch Thermosublimation.
DE91114420T DE59100636D1 (de) 1990-10-17 1991-08-28 Farbakzeptorelement für das Thermosublimationsdruckverfahren.
EP19910114420 EP0481200B1 (fr) 1990-10-17 1991-08-28 Elément récepteur de colorant pour un procédé d'impression par sublimation par la chaleur
US07/773,036 US5250494A (en) 1990-10-17 1991-10-08 Dye acceptor element for the thermal sublimation printing process
JP3298289A JP2623181B2 (ja) 1990-10-17 1991-10-16 熱染料昇華転写受容材料
JP3296629A JPH04263991A (ja) 1990-10-17 1991-10-17 熱昇華焼き付け方法用染料受容体要素

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP19900202759 EP0481129B1 (fr) 1990-10-17 1990-10-17 Elément récepteur pour le transfert de colorant par thermosublimation

Publications (2)

Publication Number Publication Date
EP0481129A1 true EP0481129A1 (fr) 1992-04-22
EP0481129B1 EP0481129B1 (fr) 1994-05-18

Family

ID=8205145

Family Applications (2)

Application Number Title Priority Date Filing Date
EP19900202759 Expired - Lifetime EP0481129B1 (fr) 1990-10-17 1990-10-17 Elément récepteur pour le transfert de colorant par thermosublimation
EP19910114420 Expired - Lifetime EP0481200B1 (fr) 1990-10-17 1991-08-28 Elément récepteur de colorant pour un procédé d'impression par sublimation par la chaleur

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP19910114420 Expired - Lifetime EP0481200B1 (fr) 1990-10-17 1991-08-28 Elément récepteur de colorant pour un procédé d'impression par sublimation par la chaleur

Country Status (3)

Country Link
EP (2) EP0481129B1 (fr)
JP (1) JP2623181B2 (fr)
DE (2) DE69009057T2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0627662A1 (fr) * 1993-05-24 1994-12-07 Agfa-Gevaert N.V. Matériau photographique comprenant un support en copolyester
EP0526645B1 (fr) * 1991-02-15 1997-11-05 Toyo Boseki Kabushiki Kaisha Resine colorable pour recepteur d'images par transfert du type a sublimation et recepteur d'images utilisant une telle resine
EP1415798A4 (fr) * 2001-07-30 2005-09-07 Kiwa Chemical Ind Co Ltd Lamine d'impression support de couche temporaire d'affichage

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0289162A2 (fr) * 1987-04-24 1988-11-02 Imperial Chemical Industries Plc Couche réceptrice
EP0364900A2 (fr) * 1988-10-17 1990-04-25 Dai Nippon Insatsu Kabushiki Kaisha Procédé pour l'enregistrement par transfer thermique.

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0289162A2 (fr) * 1987-04-24 1988-11-02 Imperial Chemical Industries Plc Couche réceptrice
EP0364900A2 (fr) * 1988-10-17 1990-04-25 Dai Nippon Insatsu Kabushiki Kaisha Procédé pour l'enregistrement par transfer thermique.

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0526645B1 (fr) * 1991-02-15 1997-11-05 Toyo Boseki Kabushiki Kaisha Resine colorable pour recepteur d'images par transfert du type a sublimation et recepteur d'images utilisant une telle resine
EP0627662A1 (fr) * 1993-05-24 1994-12-07 Agfa-Gevaert N.V. Matériau photographique comprenant un support en copolyester
EP1415798A4 (fr) * 2001-07-30 2005-09-07 Kiwa Chemical Ind Co Ltd Lamine d'impression support de couche temporaire d'affichage

Also Published As

Publication number Publication date
JPH04282293A (ja) 1992-10-07
DE69009057T2 (de) 1994-11-10
DE69009057D1 (de) 1994-06-23
DE59100636D1 (de) 1994-01-05
EP0481129B1 (fr) 1994-05-18
EP0481200A1 (fr) 1992-04-22
EP0481200B1 (fr) 1993-11-24
JP2623181B2 (ja) 1997-06-25

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