EP0498317A1 - Procédé d'opération d'un système de réfrigération - Google Patents
Procédé d'opération d'un système de réfrigération Download PDFInfo
- Publication number
- EP0498317A1 EP0498317A1 EP92101651A EP92101651A EP0498317A1 EP 0498317 A1 EP0498317 A1 EP 0498317A1 EP 92101651 A EP92101651 A EP 92101651A EP 92101651 A EP92101651 A EP 92101651A EP 0498317 A1 EP0498317 A1 EP 0498317A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- refrigerant
- compressor
- auxiliary
- returned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000005057 refrigeration Methods 0.000 title claims abstract description 23
- 239000003507 refrigerant Substances 0.000 claims abstract description 72
- 238000000034 method Methods 0.000 claims abstract description 20
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract description 6
- 238000005406 washing Methods 0.000 abstract description 6
- 239000001273 butane Substances 0.000 abstract description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract description 4
- AFYPFACVUDMOHA-UHFFFAOYSA-N chlorotrifluoromethane Chemical compound FC(F)(F)Cl AFYPFACVUDMOHA-UHFFFAOYSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 62
- 239000000243 solution Substances 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000010687 lubricating oil Substances 0.000 description 5
- 239000003599 detergent Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 206010016256 fatigue Diseases 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 239000012772 electrical insulation material Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- -1 polyol esters Chemical class 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B31/00—Compressor arrangements
- F25B31/002—Lubrication
- F25B31/004—Lubrication oil recirculating arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B43/00—Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat
- F25B43/02—Arrangements for separating or purifying gases or liquids; Arrangements for vaporising the residuum of liquid refrigerant, e.g. by heat for separating lubricants from the refrigerant
Definitions
- the invention relates to a method for operating a refrigeration system, in which a refrigerant is conveyed through an refrigerant circuit by means of an oil-lubricated compressor, oil coming from the compressor into the refrigerant circuit, and in which an additive which is insoluble in it but is soluble in the oil is added to the refrigerant .
- Synthetic oils such as polyol esters and polyalkylene glycols have therefore been developed that dissolve to a limited extent in the chlorine-free refrigerants.
- these new oils have considerable disadvantages. They work e.g. aggressive to certain materials within the refrigerant circuit, for example electrical insulation and sealing materials, and have strong hygroscopic properties. In addition, they tend to copper plating and have insufficient thermal stability.
- the addition of oil-dissolving additives is intended to prevent the lubricating oil from stagnating or the removal of paraffin in parts of the refrigeration system.
- solvents are introduced into the refrigeration cycle at various points in the refrigeration system.
- the diluted oil then settles at various oil collection points and can be removed from the extraction points.
- the solvent is added abundantly so that a certain part gets into the evaporator to dissolve the sticked paraffin hanging on the walls.
- the aim is to dilute the lubricating oil by adding a solvent and to guide the diluted lubricating oil in the refrigerant circuit via the compressor or to discharge it from the circuit.
- lubricating oil and solvent are passed through the evaporator, which affects the economic efficiency and operational safety of the refrigeration system.
- the present invention has for its object to design a method of the type mentioned so that even when using oil-insoluble refrigerant, a large return of the oil to the compressor is achieved in an economical manner, without adversely affecting the economy and reliability of the refrigeration system.
- the invention is particularly intended for use with chlorine-free refrigerants or other refrigerants that are not soluble with conventional oils.
- these refrigerants are soluble in the auxiliary, extensive de-oiling of the refrigerant is possible.
- a short chain hydrocarbon e.g. Butane, propane or pentane.
- Conventional refrigeration oils of mineral origin and synthetic oils based on hydrocarbons are soluble in these hydrocarbons in all proportions.
- the addition of small amounts of auxiliary substance is sufficient to achieve a constant washing out of the oil within the refrigerant circuit.
- the oil can be easily recovered with an oil ejector, as described in DE-PS 22 52 583, and can be returned to any point in the refrigerant circuit, in particular to the engine of the compressor.
- the two phases namely the essentially oil-free refrigerant on the one hand and the oil-auxiliary solution on the other hand, are separated by means of a floating process (similar to gasoline separator DIN 1999).
- a collection bottle is used, which in the Refrigerant circuit is switched on.
- the oil-auxiliary solution usually has a lower specific weight than the refrigerant, so that an oil-auxiliary phase floating on top and a pure refrigerant phase underneath arise in the collecting bottle.
- the oil auxiliary phase is drawn off at the top and supplied to an oil ejector as described in DE-PS 22 52 583. In the oil ejector, the oil is expelled from the oil-auxiliary solution and then returned to the compressor.
- the phases are separated on the high pressure side of the refrigeration system. In this way, a migration of oil to the evaporator side of the refrigeration system is largely avoided, so that the evaporator can be operated with practically pure refrigerant.
- the method according to the application is not simply a dilution of the lubricating oil, but rather a washing-out process in which the oil on the high-pressure side of the refrigeration system is constantly washed out of the refrigerant and returned to the compressor.
- the auxiliary agent acting as a detergent remains on the high-pressure side of the refrigeration system.
- the two phases of refrigerant and oil auxiliary solution are separated from each other in the collecting bottle by floating, i.e. the specifically lighter phase floats on top of the specifically heavier phase.
- the oil auxiliary solution is expediently fed to the oil expeller via a connecting line and a check valve.
- the oil ejector it is used as a detergent serving auxiliary evaporates and is returned as gas via the connecting line to the collecting bottle.
- the auxiliary substance constantly moves back and forth on the high-pressure side between the condenser and the oil expeller, washing the oil out of the refrigerant. The washed-out oil is separated from the auxiliary in the oil expeller and returned to the compressor.
- the invention is explained in more detail below on the basis of an exemplary embodiment shown schematically in the drawing:
- the figure shows a flow diagram of a refrigeration system with an oil washing device.
- the diagram shows a conventional refrigerant circuit, consisting of a refrigerant compressor 1 with a downstream oil separator 2, a condenser 4 with a collecting bottle 5, an expansion device 6 for the refrigerant and a refrigerant evaporator 7.
- a conventional refrigerant circuit an oil expeller is attached to the collecting bottle 5 3 connected, as described in DE-PS 22 52 583.
- the butane-oil mixture has a lower specific weight than the refrigerant and therefore floats on top of the collecting bottle 5 (12). From there, the butane-oil mixture is removed by means of a sampling tube 10 and fed to the oil ejector 3 by means of the connecting line 9 via the sight glass 8 and a check valve 30. In the oil ejector 3, which is heated with hot refrigerant compressed gas, the auxiliary substance serving as a detergent is evaporated.
- the check valve 30 has a check valve with at least one bore opening against a bias in the gas flow direction. When the non-return valve is opened, the auxiliary substance evaporated in the oil expeller flows back unhindered at a constant speed through the connecting line 9 to the collecting bottle 5.
- the hole in the check valve remains liquid butane-oil mixture, adapted to the heating output, metered again to the oil ejector 3.
- the auxiliary substance therefore constantly moves back and forth on the high-pressure side between the condenser 4 and the oil ejector 3, washing the oil out of the refrigerant in the process.
- the washed-out oil is separated from the auxiliary material in the oil ejector 3 and returned directly to the engine of the compressor 1 via line 11.
- the pure refrigerant phase 13 located at the bottom of the collecting bottle 5 is drawn off via line 14 and returned to the compressor 1 via the expansion device 6 and the evaporator 7.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Power Engineering (AREA)
- Compressor (AREA)
- Lubricants (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19914103406 DE4103406A1 (de) | 1991-02-05 | 1991-02-05 | Verfahren zum betreiben einer kaelteanlage |
| DE4103406 | 1991-02-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP0498317A1 true EP0498317A1 (fr) | 1992-08-12 |
Family
ID=6424401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP92101651A Withdrawn EP0498317A1 (fr) | 1991-02-05 | 1992-01-31 | Procédé d'opération d'un système de réfrigération |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0498317A1 (fr) |
| DE (1) | DE4103406A1 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1994017348A1 (fr) * | 1993-01-29 | 1994-08-04 | Aka Industriprodukter Kyla Ab | Procede et appareil de purge d'huile des machines frigorifiques et des thermopompes |
| EP0743496A3 (fr) * | 1992-11-30 | 1997-02-05 | Mitsubishi Electric Corp | Système frigorifique utilisant du frigorigène hydrocarbure fluoré |
| EP0846925A3 (fr) * | 1993-04-27 | 1999-12-15 | Mitsubishi Denki Kabushiki Kaisha | Système de circulation de frigorigène |
| WO2003042102A1 (fr) * | 2001-11-15 | 2003-05-22 | Bernard Zimmern | Procede de production d'ammoniac comprime quasiment sans huile et systeme de mise en oeuvre de celui-ci |
| US10119734B2 (en) | 2004-11-05 | 2018-11-06 | Arcelik Anonim Sirketi | Cooling device with compressor cabinet heater and a control method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3274796A (en) * | 1965-09-23 | 1966-09-27 | Vilter Manufacturing Corp | Refrigeration system with lube oil separation means |
| CH437382A (de) * | 1964-01-08 | 1967-06-15 | Linde Ag | Vorrichtung zur Abtrennung von im Kältemittel einer Kompressions-Kältemaschine angereichertem Öl |
| DE2252583B1 (de) * | 1972-10-26 | 1974-04-18 | Linde Ag, 6200 Wiesbaden | Vorrichtung zum Aufkonzentrieren von Öl in einem Öl-Kältemittel-Gemisch |
| DE3245475A1 (de) * | 1981-12-18 | 1983-07-07 | Stal Refrigeration AB, 60187 Norrköping | Verfahren zur rezirkulation von oel in einer kuehlanlage |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1073509B (de) * | 1960-01-21 | Gesellschaft für Linde's Eismaschinen Aktiengesellschaft, Wiesbaden | Verfahren und Anordnung zur Entölung von Kälteanlagen | |
| DE834854C (de) * | 1943-04-13 | 1952-03-24 | Linde Eismasch Ag | Verfahren zur Entoelung von Kaelteanlagen |
| FR2101577A5 (fr) * | 1970-07-13 | 1972-03-31 | Gulf & Western Industries |
-
1991
- 1991-02-05 DE DE19914103406 patent/DE4103406A1/de not_active Ceased
-
1992
- 1992-01-31 EP EP92101651A patent/EP0498317A1/fr not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH437382A (de) * | 1964-01-08 | 1967-06-15 | Linde Ag | Vorrichtung zur Abtrennung von im Kältemittel einer Kompressions-Kältemaschine angereichertem Öl |
| US3274796A (en) * | 1965-09-23 | 1966-09-27 | Vilter Manufacturing Corp | Refrigeration system with lube oil separation means |
| DE2252583B1 (de) * | 1972-10-26 | 1974-04-18 | Linde Ag, 6200 Wiesbaden | Vorrichtung zum Aufkonzentrieren von Öl in einem Öl-Kältemittel-Gemisch |
| DE3245475A1 (de) * | 1981-12-18 | 1983-07-07 | Stal Refrigeration AB, 60187 Norrköping | Verfahren zur rezirkulation von oel in einer kuehlanlage |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0743496A3 (fr) * | 1992-11-30 | 1997-02-05 | Mitsubishi Electric Corp | Système frigorifique utilisant du frigorigène hydrocarbure fluoré |
| EP0738859A3 (fr) * | 1992-11-30 | 1997-02-05 | Mitsubishi Electric Corp | Système frigorifique utilisant du frigorigène hydrocarbure fluoré |
| EP0738858A3 (fr) * | 1992-11-30 | 1997-02-05 | Mitsubishi Electric Corp | Procédé d'assemblage d'un système frigorifique utilisant du frigorigène hydrocarbure fluoré |
| EP0600131B1 (fr) * | 1992-11-30 | 1997-03-05 | Mitsubishi Denki Kabushiki Kaisha | Dispositif frigorifique utilisant du frigorigène hydrocarbure fluoré |
| WO1994017348A1 (fr) * | 1993-01-29 | 1994-08-04 | Aka Industriprodukter Kyla Ab | Procede et appareil de purge d'huile des machines frigorifiques et des thermopompes |
| EP0846925A3 (fr) * | 1993-04-27 | 1999-12-15 | Mitsubishi Denki Kabushiki Kaisha | Système de circulation de frigorigène |
| EP0846751A3 (fr) * | 1993-04-27 | 1999-12-22 | Mitsubishi Denki Kabushiki Kaisha | Système de circulation de frigorigène |
| WO2003042102A1 (fr) * | 2001-11-15 | 2003-05-22 | Bernard Zimmern | Procede de production d'ammoniac comprime quasiment sans huile et systeme de mise en oeuvre de celui-ci |
| US10119734B2 (en) | 2004-11-05 | 2018-11-06 | Arcelik Anonim Sirketi | Cooling device with compressor cabinet heater and a control method |
Also Published As
| Publication number | Publication date |
|---|---|
| DE4103406A1 (de) | 1992-08-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE FR GB IT SE |
|
| 17P | Request for examination filed |
Effective date: 19920916 |
|
| 17Q | First examination report despatched |
Effective date: 19930318 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 19930720 |