EP0531391A1 - Wasserstoffperoxid-zubereitungen - Google Patents

Wasserstoffperoxid-zubereitungen

Info

Publication number: EP0531391A1
Authority: EP; European Patent Office
Prior art keywords: weight; group; hair; hydrogen peroxide; bleaching
Prior art date: 1990-06-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP19910910298

Other languages

German (de)

English (en)

French (fr)

Inventor

Horst Höffkes

Karin Nelles

Winifried Neuhaus

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Henkel AG and Co KGaA

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-06-07

Filing date

1991-05-29

Publication date

1993-03-17

1991-05-29 Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA

1993-03-17 Publication of EP0531391A1 publication Critical patent/EP0531391A1/de

Status Withdrawn legal-status Critical Current

Links

MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 46
238000002360 preparation method Methods 0.000 title claims description 42
239000006071 cream Substances 0.000 claims abstract description 19
238000004043 dyeing Methods 0.000 claims abstract description 18
238000004061 bleaching Methods 0.000 claims abstract description 16
239000003945 anionic surfactant Substances 0.000 claims abstract description 14
125000000217 alkyl group Chemical group 0.000 claims abstract description 13
230000003647 oxidation Effects 0.000 claims abstract description 13
238000007254 oxidation reaction Methods 0.000 claims abstract description 13
229920000642 polymer Polymers 0.000 claims abstract description 13
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 10
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 10
230000008719 thickening Effects 0.000 claims abstract description 7
239000003513 alkali Substances 0.000 claims abstract description 4
125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
125000005037 alkyl phenyl group Chemical group 0.000 claims abstract description 3
229920001577 copolymer Polymers 0.000 claims description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
239000002736 nonionic surfactant Substances 0.000 claims description 6
239000000118 hair dye Substances 0.000 claims description 4
238000000034 method Methods 0.000 claims description 4
230000001590 oxidative effect Effects 0.000 claims description 4
239000007764 o/w emulsion Substances 0.000 claims description 2
239000003051 hair bleaching agent Substances 0.000 claims 1
238000005187 foaming Methods 0.000 abstract description 9
239000000203 mixture Substances 0.000 abstract description 5
239000006260 foam Substances 0.000 abstract description 4
239000000839 emulsion Substances 0.000 abstract description 3
239000004094 surface-active agent Substances 0.000 abstract description 2
125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 abstract 1
238000006213 oxygenation reaction Methods 0.000 abstract 1
238000002156 mixing Methods 0.000 description 9
-1 alkane sulfonates Chemical class 0.000 description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 7
239000003925 fat Substances 0.000 description 7
239000006185 dispersion Substances 0.000 description 5
239000000975 dye Substances 0.000 description 5
150000002191 fatty alcohols Chemical class 0.000 description 5
239000000243 solution Substances 0.000 description 5
238000004040 coloring Methods 0.000 description 4
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
239000007800 oxidant agent Substances 0.000 description 4
229920000151 polyglycol Polymers 0.000 description 4
239000010695 polyglycol Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
150000003839 salts Chemical group 0.000 description 3
239000007787 solid Substances 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
239000007844 bleaching agent Substances 0.000 description 2
229960000541 cetyl alcohol Drugs 0.000 description 2
WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
239000003205 fragrance Substances 0.000 description 2
230000037308 hair color Effects 0.000 description 2
239000007788 liquid Substances 0.000 description 2
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
238000005192 partition Methods 0.000 description 2
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
230000006641 stabilisation Effects 0.000 description 2
238000011105 stabilization Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
RVGOBWDGAVAVPJ-UHFFFAOYSA-N (4-hydroxyphenyl)azanium;chloride Chemical compound Cl.NC1=CC=C(O)C=C1 RVGOBWDGAVAVPJ-UHFFFAOYSA-N 0.000 description 1
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
KZTWOUOZKZQDMN-UHFFFAOYSA-N 2,5-diaminotoluene sulfate Chemical compound OS(O)(=O)=O.CC1=CC(N)=CC=C1N KZTWOUOZKZQDMN-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
HDGMAACKJSBLMW-UHFFFAOYSA-N 4-amino-2-methylphenol Chemical compound CC1=CC(N)=CC=C1O HDGMAACKJSBLMW-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
229910006069 SO3H Inorganic materials 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
230000010933 acylation Effects 0.000 description 1
238000005917 acylation reaction Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
229910001854 alkali hydroxide Inorganic materials 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
125000005250 alkyl acrylate group Chemical group 0.000 description 1
150000001348 alkyl chlorides Chemical class 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
229910052921 ammonium sulfate Inorganic materials 0.000 description 1
235000011130 ammonium sulphate Nutrition 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
229920006317 cationic polymer Polymers 0.000 description 1
239000003086 colorant Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000000694 effects Effects 0.000 description 1
GDCRSXZBSIRSFR-UHFFFAOYSA-N ethyl prop-2-enoate;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.CCOC(=O)C=C GDCRSXZBSIRSFR-UHFFFAOYSA-N 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229920003145 methacrylic acid copolymer Polymers 0.000 description 1
229940117841 methacrylic acid copolymer Drugs 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
229910000069 nitrogen hydride Inorganic materials 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
239000002243 precursor Substances 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
GJAWHXHKYYXBSV-UHFFFAOYSA-N quinolinic acid Chemical compound OC(=O)C1=CC=CN=C1C(O)=O GJAWHXHKYYXBSV-UHFFFAOYSA-N 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000001993 wax Substances 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/08—Preparations for bleaching the hair
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair

Definitions

the invention relates to aqueous preparations of hydrogen peroxide, which are particularly suitable as oxidizing agent preparations for bleaching and for oxidative coloring of the hair with oxidizing coloring agents.
the bleaching and dyeing of the hair with oxidation hair dyeing agents is generally carried out with the aid of two separately packaged preparations - the bleaching cream or oxidation hair dyeing cream (A) and the oxidizing agent preparation (B) - which are combined only shortly before use and in one Application bottle is mixed by simple shaking and then applied to the hair as a ready-to-use blending or dyeing preparation.
Two-chamber mixing and dispensing containers have also been developed for home use, in which components A and B are packed separately from one another in a suitable quantity ratio and have a partition which can be mechanically destroyed from the outside between the two chambers and a dispensing opening on one of the two chambers . Shortly before use, the partition is destroyed, whereupon components A and B are combined and mixed by shaking or other mechanical measures. Then the ready-to-use hair dyeing or bleaching preparation can be removed through the dispensing opening or applied directly to the hair to be colored.
a rapid and homogeneous mixing of the bleaching or coloring cream (A) and the oxidizing agent preparation (B) is very important for the success of the dyeing process.
Foaming is caused primarily by the fact that the oxidizing agent preparations, generally aqueous preparations of hydrogen peroxide, contain strongly foaming anionic surfactants for stabilization. These are necessary in order to stabilize the dispersions of alkali-soluble, thickening, carboxyl-containing polymers contained in such preparations for increasing viscosity after mixing. Bleaching and oxidation dye creams also often contain highly foaming anionic surfactants in order to keep the fatty alcohols dispersed in these products for viscosity build-up in the dispersed state. Since the use of these high-foaming anionic surfactants cannot be avoided for the reasons mentioned, the problem arises of controlling the development of foam by means of a suitable additive.
the invention relates to aqueous preparations of hydrogen peroxide for the oxidative dyeing and bleaching of the hair with a content of anionic surfactants and a thickening, carboxyl group-containing polymer or copolymer with addition of a nonionic surfactant of the formula I which is soluble in aqueous alkali
R * is an alkyl or alkenyl group with 10 - 22 C atoms or an alkylphenyl group with 6 - 15 C atoms in the alkyl group
the preparations of hydrogen peroxide according to the invention are preferably in the form of an aqueous dispersion of the carboxyl group-containing polymer merisats- or copolymer, but they can also contain an emulsified or dispersed fat phase.
the hydrogen peroxide content is preferably 1-15% by weight of the preparations.
a polymer or copolymer of acrylic acid or methacrylic acid is preferably used as the polymer or copolymer containing carboxyl groups.
Such polymers and copolymers are known per se and have long been used as thickeners for aqueous solutions.
GB-A 870 994 e.g. Dispersions of copolymers of at least 10% by weight of lower alkyl acrylate, 25 to 70% by weight of methacrylic acid and optionally 0 to 40% by weight of another comonomer with a solids content of 25 to 50% by weight are described.
Copolymers of 50-75% by weight of ethyl acrylate, 25-35% by weight of acrylic acid and 0 to 25% by weight of other comonomers are known from DE-A 11 64 095.
copolymers can be modified by adding crosslinking, polyunsaturated copolymerizable comonomers in molecular weight and thus in the thickening effect.
Particularly effective acrylate dispersions for this purpose are e.g. known from DE-A 3445549.
the suitable polymers are usually aqueous dispersions, usually with a solids content of 20 to 30% by weight, which are stable and have a low viscosity in a pH range of about 2 to 5.
aqueous bases for example by alkali hydroxide solutions (for example sodium hydroxide solution or potassium hydroxide solution), ammonia solution, alkanolamines (for example; mono-, di- or triethanolamine) and the carboxyl groups are converted into the salt form,
alkali hydroxide solutions for example sodium hydroxide solution or potassium hydroxide solution
ammonia solution for example sodium hydroxide solution or potassium hydroxide solution
alkanolamines for example; mono-, di- or triethanolamine
the polymers are preferably present in the preparations according to the invention in an amount of 0.1-10% by weight (calculated as solids) based on the preparation.
the preparations according to the invention contain anionic surfactants for stabilization.
anionic surfactants examples include alkyl sulfates, alkane sulfonates, ⁇ -olefin sulfonates, alkyl polyglycol ether sulfates and alkyl polyglycol ether sulfonates.
Other suitable anionic surfactants are sulfosuccinic acid monoester salts, alkyl polyglucol ether carboxylates, oleic acid sulfonates and other high-foaming, anionic sulfate or sulfonate surfactants.
the anionic surfactants are preferably in the form of their alkali metal, magnesium, ammonium or mono-, di- or trialkanolammonium salts with 2-4 C atoms in the alkanol group. They are preferably contained in an amount of 0.1-10% by weight of the preparation.
the nonionic surfactants of the formula I to be used according to the invention for foam control are substances which are known per se and are commercially available. They are produced by adding x moles of ethylene oxide to fatty alcohols, preferably to linear, saturated fatty alcohols, with 10-22 carbon atoms and then adding a less hydrophilic end group R 2 . This end group can be introduced, for example, by adding 3-5 moles of propylene oxide to the ethoxylate.
R 2 is either a group -0 (C3H5 ⁇ ) 4-H d 0 e -j he ne n-butyl group.
a polymer which contains carboxyl groups and is thickening in aqueous alkali 1-10% by weight of a polymer which contains carboxyl groups and is thickening in aqueous alkali, and 0.1-5% by weight of a nonionic surfactant of the formula I.
the hydrogen peroxide preparation according to the invention can also contain an emulsified or dispersed fat phase for clouding and for setting an increased viscosity and better miscibility.
fat components e.g. Paraffins, petroleum jelly, waxes, hard fats, fatty acid mono- and diglycerides and especially linear, saturated fatty alcohols, preferably cetyl and stearyl alcohol, are added to the preparation in an amount of 0.5-5% by weight.
These fat components can either already be added in dispersed form or can be dispersed in the preparation with the aid of the anionic and nonionic surfactant.
the hydrogen peroxide preparations according to the invention can also contain other auxiliaries in minor amounts.
auxiliaries e.g., phenol, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, benzyl sulfate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium sulfate, sodium bicarbonate, sodium bicarbonate, sodium sulfate, sodium sulfate, sodium
- Stabilizers for hydrogen peroxide such as dipicolinic acid, quinolinic acid, polyphosphates or those from DE-B 11 07 207 known acylation products of phosphorous acid, for example l-hydroxyethane-l, l-diphosphonic acid in an amount of about 0.05 to 1.5% by weight
the bleaching or dyeing preparations used for bleaching or dyeing the hair are preferably oil-in-water emulsions (creams).
fat components they preferably contain the fat components already mentioned above, preferably cetyl and stearyl alcohol.
the coloring creams serve as carriers for the oxidation dye or products dissolved in them.
these oil-in-water emulsions only occasionally contain smaller amounts of oxidation dye precursors which, when used, compensate for too strong, natural shades of yellow and red in the hair.
the bleaching and coloring creams are preferably at a pH of 8-11 and are mixed with the hydrogen peroxide preparation according to the invention before use.
the invention therefore furthermore relates to a process for dyeing or lightening the hair using an oxidation hair dyeing cream or bleaching cream (A) in the form of an oil-in-water emulsion with a pH of 8-11.
A oxidation hair dyeing cream or bleaching cream
B hydrogen peroxide preparation
the hydrogen peroxide preparations according to the invention can be mixed by shaking them gently in the application bottle without great energy expenditure or long shaking times. The homogeneity of the dyeing or blending preparations achieved is shown in an improved dyeing result.
each of the hydrogen peroxide preparations 1,1 or 1,2 according to the invention or of the comparison preparation 1,3 were filled into flexible 100 ml polyethylene application bags.
the Oxidations ⁇ hair dye cream was filled in 40 nl tubes.
the contents of one tube of oxidation hair dye cream were pressed into one of the application vials with the hydrogen peroxide preparation. After unscrewing the the contents were mixed by hand shaking. It was found that the preparation 1, 3 not according to the invention was only mixed with the cream so homogeneously after very long shaking that no inhomogeneities could be seen with the naked eye. The reason for the poorer mixing was obviously due to the strong foaming, which hindered the mechanical movement of the liquid when shaken.
the ready-to-use dyeing preparations obtained after mixing were applied to the hair in a customary manner and washed out with water after the exposure time. When washing out, a sufficient amount of foam still developed in the preparations according to the invention.

Landscapes

Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Public Health (AREA)
Veterinary Medicine (AREA)
Animal Behavior & Ethology (AREA)
General Health & Medical Sciences (AREA)
Epidemiology (AREA)
Birds (AREA)
Emergency Medicine (AREA)
Cosmetics (AREA)
Coating Apparatus (AREA)
Delivering By Means Of Belts And Rollers (AREA)
Registering, Tensioning, Guiding Webs, And Rollers Therefor (AREA)
Sheets, Magazines, And Separation Thereof (AREA)
Application Of Or Painting With Fluid Materials (AREA)

EP19910910298 1990-06-07 1991-05-29 Wasserstoffperoxid-zubereitungen Withdrawn EP0531391A1 (de)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE4018259		1990-06-07
DE19904018259 DE4018259A1 (de)	1990-06-07	1990-06-07	Wasserstoffperoxid-zubereitungen

Publications (1)

Publication Number	Publication Date
EP0531391A1 true EP0531391A1 (de)	1993-03-17

Family

ID=6407970

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP19910910298 Withdrawn EP0531391A1 (de)	1990-06-07	1991-05-29	Wasserstoffperoxid-zubereitungen

Country Status (6)

Country	Link
EP (1)	EP0531391A1 (cs)
JP (1)	JPH05507476A (cs)
CS (1)	CS168391A3 (cs)
DE (1)	DE4018259A1 (cs)
WO (1)	WO1991018584A1 (cs)
YU (1)	YU97991A (cs)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5221286A (en) *	1992-07-17	1993-06-22	Eastman Kodak Company	Cold mix emulsions used as a developer composition for oxidative hair dyes and for hair bleaches
DE4332965A1 (de) *	1993-09-28	1995-03-30	Wella Ag	Oxidationshaarfärbemittel aus einer cremeförmigen Farbstoffträgermasse und einer ein Polymer und ein Oxidationsmittel enthaltenden Zubereitung sowie Verfahren zum oxidativen Färben von Haaren
DE4333370A1 (de) *	1993-09-30	1995-04-06	Henkel Kgaa	Wasserstoffperoxid-Zubereitungen
DE4431577A1 (de) *	1994-09-05	1996-03-07	Wella Ag	Wasserstoffperoxidhaltiges Aerosolpräparat
DE19714370A1 (de) †	1997-04-08	1998-10-15	Henkel Kgaa	Wäßrige pflegende Haut- und Haarbehandlungsmittel
DE10016497A1 (de) *	2000-04-01	2001-10-18	Goldwell Gmbh	Verfahren und Zusammensetzung zum oxidativen Färben von menschlichen Haaren
JP2011184428A (ja) *	2010-02-10	2011-09-22	Kao Corp	染色又は脱色キット
DE102010003265A1 (de)	2010-03-25	2011-09-29	Henkel Ag & Co. Kgaa	Färbemittel für keratinische Fasern mit optimierter Viskositätseinstellung
EP2425809A1 (en) *	2010-09-03	2012-03-07	KPSS-Kao Professional Salon Services GmbH	Aqueous colouring composition

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2112678A1 (de) *	1971-03-16	1972-09-28	Henkel & Cie Gmbh	Mittel zur Herstellung waessriger,in der Kaelte wirksamer Oxydationsbaeder,insbesondere in der Kaelte wirksamer Bleich- und Waschlaugen fuer Textilien
LU71985A1 (cs) *	1975-03-06	1977-01-28
DE3015958A1 (de) *	1980-04-25	1981-11-05	Hoechst Ag, 6000 Frankfurt	Verwendung von alkylpolyglykoltert-butylaether als bleichhilfsmittel und diese hilfsmittel enthaltende bleichbaeder
DE3732147A1 (de) *	1987-09-24	1989-04-06	Henkel Kgaa	Emulsionsfoermige wasserstoffperoxid-zubereitungen zum blondieren und oxidativen faerben der haare

1990
- 1990-06-07 DE DE19904018259 patent/DE4018259A1/de not_active Withdrawn
1991
- 1991-05-29 JP JP91509536A patent/JPH05507476A/ja active Pending
- 1991-05-29 EP EP19910910298 patent/EP0531391A1/de not_active Withdrawn
- 1991-05-29 WO PCT/EP1991/000999 patent/WO1991018584A1/de not_active Ceased
- 1991-06-03 YU YU97991A patent/YU97991A/sh unknown
- 1991-06-04 CS CS911683A patent/CS168391A3/cs unknown

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9118584A1 *

Also Published As

Publication number	Publication date
WO1991018584A1 (de)	1991-12-12
YU97991A (sh)	1993-11-16
JPH05507476A (ja)	1993-10-28
DE4018259A1 (de)	1991-12-12
CS168391A3 (en)	1992-02-19

Legal Events

Date	Code	Title	Description
1993-01-29	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
1993-03-17	17P	Request for examination filed	Effective date: 19921130
1993-03-17	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IT LI NL SE
1994-03-02	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN
1994-04-20	17Q	First examination report despatched	Effective date: 19940304
1994-04-20	18W	Application withdrawn	Withdrawal date: 19940228

Publication	Publication Date	Title
EP0721321B1 (de)	1998-11-11	Wasserstoffperoxid-zubereitungen
EP0184785B1 (de)	1991-09-11	Acrylatdispersion und deren Verwendung zur Verdickung von Wasserstoffperoxid-Zubereitungen
EP0308825A1 (de)	1989-03-29	Emulsionsförmige Wasserstoffperoxid-Zubereitungen zum Blondieren und oxidativen Färben der Haare
DE60105362T2 (de)	2005-02-17	Wässrige kosmetische gele
DE69712278T2 (de)	2002-12-19	Verdicktes Körperpflegemittel
DE69318288T2 (de)	1999-01-21	Verfahren und zusammensetzung für ein mikroemulsionsgel mit bleichenden und antiseptischen eigenschaften
DE69600140T2 (de)	1998-04-23	Schäumende Emulsion auf der Basis von nicht-ionischen Tensiden, einer Fettphase und einem vernetzten anionischen oder kationischen Polymer zur topischen Anwendung
DE69302387T2 (de)	1996-08-14	Kühlsalbe in bleichmittelzusammensetzung oder in oxidationfärbemittel
EP1086685B1 (de)	2003-03-26	Zwei-komponenten-kit eine lösung und eine Emulsion enthaltend und verfahren zum entfärben von gefärbten Haaren
EP0778020A1 (de)	1997-06-11	Mittel zum Bleichen von Haaren
DE3902374A1 (de)	1990-08-02	Wasch- reinigungs- und/oder koerperreinigungsmittel
DE69127886T2 (de)	1998-03-05	Copolymere auf Basis von N-Alkylacrylamid, deren Herstellung und deren Verwendung als Verdickungsmittel in Shampoozusammensetzungen
DE4026235A1 (de)	1992-02-20	Persulfathaltige zubereitung in form eines granulats, 2-komponenten-mittel und verfahren zum entfaerben und blondieren von haaren
DE1467848B2 (de)	1974-04-18	Unter Druck stehendes, bei Aufhebung des Drucks einen Schaum bildendes Haut-Pflegemittel
DE3623826C2 (cs)	1991-11-07
DE69403888T2 (de)	1997-10-09	Kosmetische Zusammensetzungen für Haarbleichung, Syntheseverfahren und Anwendungen
DE19915837A1 (de)	2000-10-12	Wässrige mehrphasige Tensidzubereitungen
WO1991018584A1 (de)	1991-12-12	Wasserstoffperoxid-zubereitungen
DE1668525C3 (de)	1974-12-12	Hydroxylierte Verbindungen und diese enthaltende Mittel
DE69621409T2 (de)	2003-01-16	Polysaccharidderivat, Verfahren zu deren Herstellung und seine Verwendung
EP0429576B1 (de)	1992-10-28	Klares haar- und körperreinigungsmittel
DE69809821T2 (de)	2003-11-06	Schutz-Schaumstoffe auf Basis von Perfluoropolyethern
DE69105496T2 (de)	1995-06-01	Milde additive für hautreinigungsmittel.
DE69115083T2 (de)	1996-06-20	Verfahren zur Herstellung ein Verdickungsmittel.
DE19722405A1 (de)	1998-12-03	Einkapseln von wasserunlöslichen Wirkstoffen mit amphiphilem Charakter