EP0532901B1 - Méthode et installation pour gazéifier des combustibles solides contenant des matériaux fusibles non-combustibles - Google Patents

Méthode et installation pour gazéifier des combustibles solides contenant des matériaux fusibles non-combustibles Download PDF

Info

Publication number
EP0532901B1
EP0532901B1 EP92113622A EP92113622A EP0532901B1 EP 0532901 B1 EP0532901 B1 EP 0532901B1 EP 92113622 A EP92113622 A EP 92113622A EP 92113622 A EP92113622 A EP 92113622A EP 0532901 B1 EP0532901 B1 EP 0532901B1
Authority
EP
European Patent Office
Prior art keywords
gasification
silo
furnace
charging silo
zone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP92113622A
Other languages
German (de)
English (en)
Other versions
EP0532901A1 (fr
Inventor
Gino Tomadini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sas Gino Tomadini & C
Original Assignee
Sas Gino Tomadini & C
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sas Gino Tomadini & C filed Critical Sas Gino Tomadini & C
Publication of EP0532901A1 publication Critical patent/EP0532901A1/fr
Application granted granted Critical
Publication of EP0532901B1 publication Critical patent/EP0532901B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/22—Arrangements or dispositions of valves or flues
    • C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
    • C10J3/26—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
    • C10J3/60—Processes
    • C10J3/64—Processes with decomposition of the distillation products
    • C10J3/66—Processes with decomposition of the distillation products by introducing them into the gasification zone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/80—Other features with arrangements for preheating the blast or the water vapour
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C10J2200/158—Screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C10J2300/092—Wood, cellulose
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1861—Heat exchange between at least two process streams
    • C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas

Definitions

  • This invention concerns a method to gasify solid fuels containing non-combustible meltable materials and concerns also a gasification plant which employs such method, as set forth in the respective main claims.
  • the invention concerns a method for the intensified gasification of solid fuels that is suitable to produce fuel gas with working systems which are less polluting for the exterior environment and provide a greater yield from the point of view of output.
  • the gasification method according to the invention enables solid fuels to be gasified which contain non-combustible meltable materials, such as glass and metals for instance, at the same time preventing the formation of lumps of such meltable materials which might cause blockage of the gasification plant itself.
  • the method concerns in particular, but not only, the gasification of solid urban wastes and, in general, the gasification of solid low-cost products such as wood wastes, wood chips, solid combustible wastes of an industrial origin, biomasses of an agricultural origin, tyres, peat, lignite, coal and other materials.
  • the state of the art covers a plurality of methods and apparatuses to produce gas from solid fuels. Among such methods can be listed applications in the fields of road transport, heating and lighting and the incineration and disposal of solid urban wastes.
  • dioxin may be present as a harmful substance produced by combustion.
  • US-A-4,175,929 discloses a process to gasify coal whereby in a step after the gasification all the polluting substances contained in the gas so produced are substantially eliminated.
  • the gas from the gasification plant is passed through scrubbing and condensation steps in which the gas is purified.
  • DE-A-3.523.765 discloses a method and device to gasify carbonous material, whereby the gas, distilled in a traditional manner by partial combustion of the solid fuel, is delivered to an oxidation zone free of solid materials and is burned there almost completely.
  • FR-A-7.830.787 concerns a method and device to produce gas from wood by using the combined principle of production of gas by a gasification plant and of water gas, by means of air, of water vapour and tar vapour.
  • WO-A-8.002.563 discloses a method for the complete gasification of carbonous material by means of forced pyrolysis, whereas WO-A-8.100.112 describes a process and plant to gasify solid fuels whereby the gasification is performed in three separate stages.
  • DE-A-3.327.203 discloses a method and apparatus to gasify solid wastes whereby the gas leaving the distillation zone as a distilled gas with water vapour is sent back to the melting zone to be burnt at least partly.
  • IT-A-83.352 discloses a method and device to gasify solid fuels whereby the gases of pyrolysis and the distillation products which form in the gasification step are taken up to be wholly or partly pre-combusted before being sent for complete combustion in the actual combustion zone.
  • EP-A-0433547 discloses a method and apparatus to gasify solid wastes by the simultaneous application of direct flame and inverted flame to the solid fuel.
  • EP-A-0055440 discloses the introduction of materials from above into a charging silo and a substantially vertical descent of the materials therefrom to a furnace; it also provides for the gases in the furnace to lap the charging silo before reaching their outlet.
  • US-A-4,306,506 discloses the introduction of materials from above into a charging silo and a substantially vertical descent of the materials therefrom to a furnace; it discloses also the recovery of the gases in the upper part of the silo and the injection of the gases at the base of the silo after they have been mixed with air drawn from the exterior.
  • US-A-4,309,195 discloses the introduction of materials from above into a charging silo and a substantially vertical descent of the materials therefrom to a furnace; it discloses also that the gases in the furnace, before reaching their outlet, lap the charging silo; it arranges also the recovery of the gases in the upper part of the silo and the injection of the gases at the base of the silo after they have been mixed with air drawn from the exterior.
  • the temperature near the inlets of air with oxidizing flame may reach 1500°-1600°C, whereas in the reducing flame zones far from the air inlets the temperature may go down to 500°-600°C.
  • the non-combustible meltable material passes from high temperature zones in which it melts to lower temperature zones in which it solidifies, thus forming lumps which cause jamming and the resulting blockage of the regular flow of the solid material to be gasified.
  • the method to gasify solid fuels according to the invention makes use of the recovery of heat contained in the combustible gases produced by the gasification plant so as to heat the solid fuels and to gasify the volatile parts of the same while these solid fuels are still held in the charging silo of the gasification plant.
  • the gasification method according to the invention gives precedence to the recovery of heat to be recycled in the process and to the reduction of non-productive absorption of heat during the process, so as to obtain not only a greater yield of energy but also a gas possessing greater calorific power per cu.metre.
  • the method of gasifying solid fuels according to the invention performs an action of evaporation and distillation of the volatile parts contained in the solid fuels while the latter are still in the charging silo of the gasification plant.
  • the gas thus produced is also better owing to the greater quantity it contains of unburnt or pyrolysed distillates or distillates subjected to cracking.
  • a part of the sensible heat contained in the hot gas produced by the gasification is removed advantageously by a liquid, such as oil, or water, or steam, which circulates in an appropriate circuit or Perkin's type tubes.
  • This liquid circulates advantageously in an interspace machined in the outer sidewall surrounding and delimiting the chamber for separation of the hot gases generated by gasification of the solid fuel and removes heat.
  • the liquid thus heated circulates in an endless circuit and has the task of heating the distillation gases which are recirculated in the mass of solid fuel held in the charging silo.
  • the heat thus removed from the gas produced by the gasification is employed to heat and dry beforehand the solid fuels held in the charging silo of the gasification plant and causes the evaporation of the volatile parts of those fuels and thus generates distilled gases which are recirculated intensely within the charging silo.
  • any excessive heat of the liquid being circulated can also be employed not only to pre-heat the combustion-supporting air but also to dry beforehand any solid fuel containing excessive humidity before that fuel enters the gasification plant.
  • Such excessive heat can also be employed for other uses such as heating the environment, heating other liquids, etc. or else can be dispersed to the exterior environment with the help of heat exchangers operating by air and/or a liquid.
  • the hot gas produced by the gasification is brought indirectly into contact with the solid fuel material.
  • the gas produced by the combustion is delivered into an interspace which surrounds fully the outer sidewall of the charging silo before being sent to usage means.
  • the gas produced is sent from this interspace to the usage means connected to the gasification plant.
  • the distilled gas thus obtained is conveyed and redistributed continuously in the mass of solid fuel contained in the charging silo by means of fans; this circulation of distilled gases may reach as much as 10-20 thousand cu.metres per hour per tonne per hour of solid gasified fuel.
  • the silo is equipped with a suitable fan, which recirculates continuously within the silo the gaseous fluid generated therein by means of ducts or interspaces.
  • the temperature of the solid fuel rises to a greater extent and more evenly than in the traditional methods and causes the volatile parts of the fuel to evaporate and distil and carbonizes or cokes the carbonous part of the fuel.
  • this part too of the gas coming from the distillation undergoes a pyrolysis or cracking action, the effects of which can be modulated by regulating the quantity of air immitted into the gasification plant.
  • the gasification plants have to be equipped with safety devices able to prevent the explosion of the plant itself when an explosive mixture of air and gas is formed within the plant itself.
  • the aspiration pipes of the combustion-supporting air in the apparatus employing the gasification method according to the invention are equipped with non-return valves which, besides preventing the exit of gas from the gasification plant, permit the mixture of gas and air to flare up without bringing the gasification plant under pressure or indeed causing it to explode.
  • the gasification plant according to the invention is suitable to gasify solid fuels containing non-combustible meltable materials such as glass or metals.
  • This purpose is achieved by creating within the gasification plant a zone having at all times a temperature higher than the melting temperature of the non-combustible meltable materials.
  • This higher temperature zone is advantageously inclined so as to collect these molten materials and take them in the molten state to the discharge outlet located in the lower part of the gasification plant.
  • the higher temperature can be maintained in the zone of the melting and sliding of these molten materials by means of the introduction of solid fuel possessing a greater calorific power.
  • the plant to gasify solid fuels containing meltable materials is not of an intensified type, and the internal recovery of heat and the prior gasification of the volatile parts of the solid fuel are independent from the melting of such materials.
  • the reference number 10 indicates generally a gasification plant employing the method according to this invention.
  • the gasification plant 10 consists substantially of a charging silo 11, a furnace 12 and a chamber 13 for separation of powders.
  • the gasification plant 10 shown in the figures is of a type with a quadrangular cross section, but the considerations cited in the following description are valid also for gasification plants 10 having a circular cross section or any other desired shape.
  • the solid fuel is fed from above to the charging silo 11 by means of a hopper 23 cooperating with a worm 24, both of which are positioned higher than the charging silo 11.
  • a star-shaped rotary valve 25 is fitted in this case to control the outlet of the hopper 23.
  • the gas produced by the gasification is collected in the powders separation chamber 13 positioned so as to surround the lower part of the furnace 12 of the gasification plant 10.
  • the powders separation chamber 13 is surrounded on its outside by an interspace 14, in which a cooling liquid, advantageously oil, circulates so as to cool the hot gas produced and to heat the solid fuel held in the charging silo 11.
  • a cooling liquid advantageously oil
  • the gas produced by the gasification and leaving the lower end zones 15 and 16 of the furnace 12 enters the powders separation chamber 13 and undergoes a first cooling by the oil circulating in the oil circulation interspace 14.
  • the partly cooled gas is conveyed through flues 46 into an interspace 17, which surrounds fully and delimits the charging silo 11 and serves for the circulation of the gas.
  • the gas is further cooled and releases heat through the inner sidewall of the gas circulation interspace 17 to the fuel material held in the charging silo 11.
  • the interspace 17 is equipped with an outlet duct 47 through which the gas produced is delivered to various usage means.
  • the charging silo 11 there are in the upper part of the charging silo 11 means 18 to recirculate the distilled gas, which consist, for instance, of a plurality of centrifugal fans that aspirate the evaporated and distilled gases contained in the upper portion of the charging silo 11 above the solid fuel: these fans 18 inject these gases downwards into the mass of solid fuel through ducts 19 which convey the distilled gases.
  • the distilled gas consist, for instance, of a plurality of centrifugal fans that aspirate the evaporated and distilled gases contained in the upper portion of the charging silo 11 above the solid fuel: these fans 18 inject these gases downwards into the mass of solid fuel through ducts 19 which convey the distilled gases.
  • the distilled gas conveyor ducts 19 may be included in various numbers and be arranged peripherally about the charging silo 11.
  • the charging silo 11 has a quadrangular cross section and the conveyor ducts 19 are four in number and are positioned in the corners of the charging silo 11.
  • the distilled gas conveyor ducts 19 include in their lower part a terminal segment 22 consisting of perforated sheet so as to provide more openings for passage of the distilled heating gases, which rise from below to the top of the charging silo 11, thus passing through the mass of solid fuel contained therein and being aspirated by the recirculation means 18.
  • the distilled gases recirculated within the combustible mass in the charging silo 11 have the purpose also of displacing the solid fuel fed to the furnace 12 and of preventing that fuel becoming aggregated together and of assisting gasification of the same.
  • the oil is circulated in appropriate radiant tubes 20 arranged at the upper inlet of the distilled gas conveyor ducts 19 and in the oil circulation interspace 21 of the same distilled gas conveyor ducts 19.
  • the outcome is an appreciable increase in the temperature of the solid fuel within the charging silo 11 so as to cause evaporation and distillation of the volatile parts, and this fact enables the carbonous part of the solid fuel to be carbonized or coked, thus increasing the overall yield of the successive gasification process carried out in a traditional manner.
  • a part of the distilled gas produced in the charging silo 11 is aspirated from the bottom portion 26 of the charging silo 11 and is conveyed in a conduit 27 to a pyrolysis zone 28 of the furnace 12.
  • this pyrolysis zone 28 of the furnace 12 is kept under a greater negative pressure, and the gas immitted therein undergoes an action of pyrolysis or cracking, which can be modulated by regulating as required the quantity of air to be introduced from the exterior.
  • valve 36 is opened to a greater extent to make possible a partial or full combustion of the part of the distilled gases re-immitted through the conduit 27 into the pyrolysis zone 28 of the furnace 12.
  • valve 36 is closed, with occurrence of cracking.
  • This regulation of the flow of combustion-supporting air can be automated by controlling the valve 36 regulating the combustion-supporting air by means of a thermal probe 38 which monitors the temperature of the gases entering the powders separation chamber 13.
  • the circuit of the cooling oil consists of a delivery tube 31, which conveys the oil from the interspace 14 surrounding the powders separation chamber 13 to an expansion vessel 32. Thence the oil, after being cooled by passing through the radiant tubes 20 and the oil circulation interspaces 21 of the distilled gases conveyor ducts 19, reaches a re-circulation pump 33 through a return pipe 34.
  • the regulation of the three-way valve 29 can be governed by a thermostat 35 fitted, in this case, to the oil circuit delivery tube 31.
  • a further recovery of energy can be achieved in a known manner by pre-heating the combustion-supporting air at the expense of the cooling oil circulating in the oil circulation interspace 14 or else by making use of the sensible heat of the produced gas leaving the gasification plant 10 through the gas discharge outlet 47 before that gas is sent to the usage means.
  • a known system 48 to collect and discharge ashes is included at the bottom of the gasification plant 10 according to the invention and consists, for instance, of a grill 49 subjected to intermittent vibration and suitable to retain the fuel and to allow the passage of the ashes to a discharge means positioned below, a worm 50 for instance.
  • Fig.4 shows a gasification plant 110 especially suitable for gasifying solid fuels containing non-combustible meltable materials.
  • This gasification plant 110 to gasify solid fuels containing non-combustible meltable materials consists substantially of a main charging silo 51, a possible secondary charging silo 52, a furnace 53 and a device 54 to collect, discharge and remove the molten material.
  • the main charging silo 51 to feed solid fuel material to be gasified is positioned vertically, whereas the underlying portion consisting of the furnace 53, which in this example has a five-sided section, comprises a channel 54 to collect molten material.
  • the channel 54 to collect molten material consists of two sidewalls 55a-55b of the furnace 53, which form between them an angle of about 60° on a horizontal plane; these sidewalls 55a-55b are kept at a high temperature to prevent solidification of the sliding molten material.
  • This collection channel 54 is sloped in relation to the vertical in such a way that it collects the molten material from the furnace 53 and enables that material to slide to a discharge outlet 59.
  • the secondary charging silo 52 is included.
  • the furnace 53 is fed by this secondary charging silo 52 as required with a charge of solid fuel having a higher calorific power.
  • the furnace 53 comprises upper 56 and lateral 57 inlets for air and also inlets 58 for hot gases produced by distillation of the volatile substances contained in the solid fuel, as indicated above in greater detail.
  • Fig.5 shows also flues 46 to covey the hot gases produced, in view of a further recovery of heat within the gasification plant 10.
  • the safety means (Fig.3) are provided by placing the aspiration intakes of the ducts 39 feeding the air above terminal outlets 40 of the ducts introducing the air, whether that air is heated or not.
  • a rotary non-return valve 41 which permits the entry of aspirated air during the working of the gasification plant 10 and prevents the entry of air and the exit of gas when the plant 10 is halted.
  • the rotary valve 41 shown in Fig.3 consists of a lid 45 hinged on a pivot 43, which is fitted to the upper part of the air aspiration duct 39.
  • the lid 45 resting by gravity on the intake of the air aspiration duct 39, prevents the entry of further air into the gasification plant 10.
  • the lid 45 in its closed position abuts against a peripherally arranged packing 42.
  • the lid 45 of the rotary valve 41 rests against two lateral sides 44, which too are hinged on the pivot 43.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (5)

  1. Procédé de gazéification de combustibles solides, qui sont avantageusement des déchets urbains solides, des déchets de bois, et des copeaux de bois, des déchets de combustibles solides d'origine industrielle, des biomasses d'origine agricole, des pneus, de la tourbe, du lignite, du charbon et des matières analogues ou apparentées, ces combustibles solides étant amenés dans une partie haute d'une trémie de chargement (11-51) d'une installation de gazéification (10) d'où les combustibles sont déversés directement, d'une partie basse plus étroite (26) de la trémie dans un four vertical (12-53) dans lequel la gazéification se produit, le four vertical (12) comprenant une zone terminale basse (15) connectée et jointive à une zone terminale supérieure (16) d'une zone de pyrolyse (28) qui contient à son extrémité inférieure un dispositif de collecte et d'évacuation des cendres, les gaz chauds produits par la gazéification de ces combustibles solides et quittant les zones terminales (15-16) du four (12) traversant une chambre de séparation des poudres (13) avant de traverser une double paroi (17) ceinturant la trémie de chargement (11-51) et un conduit de sortie (47), le procédé étant caractérisé en ce qu'au moins une partie de la chaleur sensible des gaz chauds produits par la gazéification des combustibles solides est cédée, d'une part, à un fluide diathermique circulant dans une double paroi (14) de circulation et de chauffage qui ceinture au moins partiellement la chambre de séparation des poudres (13) et, d'autre part, aux gaz distillés produits par l'évaporation des matières volatiles contenues dans les combustibles solides de la trémie de chargement (11-51), le fluide diathermique chauffé étant utilisé pour chauffer le combustible solide dans la trémie de chargement (11-51), produisant ainsi des gaz distillés, et pour chauffer les gaz distillés, ceux-ci étant récupérés, partiellement au moins, dans la partie supérieure de la trémie de chargement (11-51) et étant réinjectés intensivement de cette partie supérieure de la trémie de chargement (11-51) vers la partie basse (26) de la trémie de chargement (11-51), tandis qu'au moins une partie de ces gaz distillés recyclés sont envoyés par un conduit (27) dans une zone de pyrolyse (28) du four (12-53).
  2. Procédé de gazéification selon la revendication 1, au moyen duquel une partie au moins des gaz distillés produits dans la trémie de chargement (11-51) et envoyés dans la zone de pyrolyse (28) du four (12-53) est mélangée à de l'air extérieur dans une quantité commandée par un thermostat (38).
  3. Procédé de gazéification selon la revendication 1 ou 2, par lequel les gaz circulant de la zone terminale basse (15) du four (12-53) et de la zone terminale supérieure (16) de la zone de pyrolyse (28) vers la chambre de séparation des poudres (13) enveloppent les parois extérieures de la chambre (13) et les parois intérieures de la double paroi (14) dans laquelle circule le fluide diathermique.
  4. Installation de gazéification de combustibles solides qui sont avantageusement des déchets urbains solides, des déchets de bois et des copeaux de bois, des déchets de combustibles solides d'origine industrielle, des biomasses d'origine agricole, des pneus, de la tourbe, du lignite, du charbon, etc., l'installation de gazéification (10-110) comprenant de haut en bas une trémie de chargement (11-51) comprenant une partie haute et une partie basse plus étroite (26) communiquant directement avec un four vertical (12-53), le four vertical (12-53) comprenant une zone terminale basse (15) connectée et jointive à une zone terminale haute (16) d'une zone de pyrolyse (28), qui contient à son extrémité inférieure un dispositif de collecte et d'évacuation dès cendres, la zone terminale basse (15) du four (12-53) et la zone terminale haute (16) de la zone de pyrolyse (28) étant connectées à une chambre de séparation des poudres (13) raccordée à un conduit de sortie (47) et à une double paroi (17) qui ceinture la trémie de chargement (11-51), l'installation étant caractérisée en ce qu'elle comprend :
    - des conduits (19) pour transporter les gaz distillés, les conduits (19) comprenant au moins partiellement une double paroi (21) pour le fluide diathermique de chauffage, les conduits (19) de transport des gaz distillés raccordant la partie haute de la trémie de chargement (11-51) à la partie basse (26) de la trémie de chargement (11-51);
    - des conduits (39) d'amenée d'air coopérant avec le four vertical (12-53);
    - une double paroi (14) de circulation et de chauffage du fluide diathermique, cette double paroi (14) ceinturant au moins partiellement la chambre de séparation des poudres (13), et
    - un conduit (27) d'entrée et de transport qui raccorde la partie basse (26) de la trémie de chargement (11-51) à la zone de pyrolyse (28).
  5. Installation de gazéification de combustibles solides selon la revendication 4, dans laquelle les conduits (19) transportant les gaz distillés sont assistés par au moins un ventilateur (18) de capacité et puissance élevées.
EP92113622A 1991-09-18 1992-08-10 Méthode et installation pour gazéifier des combustibles solides contenant des matériaux fusibles non-combustibles Expired - Lifetime EP0532901B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITUD910143 1991-09-18
ITUD910143A IT1252838B (it) 1991-09-18 1991-09-18 Procedimento potenziato di gassificazione per gassificatori di combustibili solidi e apparecchiatura adottante tale procedimento

Publications (2)

Publication Number Publication Date
EP0532901A1 EP0532901A1 (fr) 1993-03-24
EP0532901B1 true EP0532901B1 (fr) 1995-09-20

Family

ID=11420907

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92113622A Expired - Lifetime EP0532901B1 (fr) 1991-09-18 1992-08-10 Méthode et installation pour gazéifier des combustibles solides contenant des matériaux fusibles non-combustibles

Country Status (6)

Country Link
EP (1) EP0532901B1 (fr)
AT (1) ATE128175T1 (fr)
DE (1) DE69204948T2 (fr)
DK (1) DK0532901T3 (fr)
ES (1) ES2079115T3 (fr)
IT (1) IT1252838B (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100659497B1 (ko) 2005-03-25 2006-12-20 한국에너지기술연구원 농임산폐기물의 유동층 열분해 및 가스화 장치와 그 방법

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4447357C2 (de) * 1994-12-20 1999-01-07 Umweltgemeinschaft Rundum Ev Verfahren und Vorrichtung zum Aufbereiten von Altreifen durch eine chemisch-thermische Behandlung
IT1310872B1 (it) * 1999-07-06 2002-02-22 Tomadini Gino & C Gasogeno per la produzione di gas metano ed ossido di carbonio
ITTO20120856A1 (it) * 2012-10-02 2013-01-01 Giancarlo Baldi Gassificatore in continuo, in particolare per biomasse e rifiuti urbani e industriali.
DE102013017546A1 (de) * 2013-10-22 2015-04-23 Linde Aktiengesellschaft Verfahren und Anlage zur Vergasung von Einsatzmaterial
CZ26592U1 (cs) * 2013-12-18 2014-03-10 Tarpo Spol.S R.O. Zařízení pro vícestupňové zplyňování uhlíkatých paliv

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR885704A (fr) * 1941-10-20 1943-09-23 Daimler Benz Ag Procédé pour obtenir un gaz de gazogène à partir de briquettes de lignite ou de combustibles analogues fortement bitumeux, riches en cendres et ayant aisément tendance à la formation de scories
DE2436268A1 (de) * 1974-07-27 1976-02-12 Ernst Kirchgaessner Verfahren und vorrichtung zum erzeugen von treib- und/oder brenngasen aus minderwertigen brennstoffen
BE865649A (fr) * 1978-04-04 1978-10-04 Lambiotte & Cie Gazogene
US4306506A (en) * 1980-06-02 1981-12-22 Energy Recovery Research Group, Inc. Gasification apparatus
US4309195A (en) * 1980-06-02 1982-01-05 Energy Recovery Research Group, Inc. Apparatus for gasifying solid fuels and wastes
DD202176A5 (de) * 1980-12-27 1983-08-31 Kernforschungsanlage Juelich Verfahren und einrichtung zur kontinuierlichen erzeugung von brenngas aus organischen abfallstoffen

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100659497B1 (ko) 2005-03-25 2006-12-20 한국에너지기술연구원 농임산폐기물의 유동층 열분해 및 가스화 장치와 그 방법

Also Published As

Publication number Publication date
DK0532901T3 (da) 1995-11-13
IT1252838B (it) 1995-06-28
ITUD910143A0 (it) 1991-09-18
ATE128175T1 (de) 1995-10-15
DE69204948D1 (de) 1995-10-26
DE69204948T2 (de) 1996-04-25
EP0532901A1 (fr) 1993-03-24
ITUD910143A1 (it) 1993-03-18
ES2079115T3 (es) 1996-01-01

Similar Documents

Publication Publication Date Title
KR100817684B1 (ko) 석탄으로부터 청정 에너지를 생산하기 위한 방법
US4584947A (en) Fuel gas-producing pyrolysis reactors
US5026403A (en) Three stage process for producing producer gas from combustible waste products
CA1075003A (fr) Appareil et methode pour la production de gaz combustible
JP4264525B2 (ja) 有機物質および物質混合物をガス化する方法
US6333015B1 (en) Synthesis gas production and power generation with zero emissions
CN1252413C (zh) 流化床气化和熔融燃烧的方法及装置
US4142867A (en) Apparatus for the production of combustible gas
EP0908672B1 (fr) Procedes pour le traitement par fusion de dechets solides en vue de leur gazeification
SK12912002A3 (sk) Reaktor a spôsob splynenia a/alebo tavenia látok
CN1028112C (zh) 固定床煤的汽化的方法与装置
SU938747A3 (ru) Способ восстановлени дисперсной окиси железа и получени расплавленного чугуна и устройство дл его осуществлени
WO1999023431A1 (fr) Four de gazeification et de chauffage a lit fluidise
SU1114342A3 (ru) Способ непрерывной газификации частиц твердого углеродсодержащего материала во вращающейс печи
CN109054874B (zh) 基于转炉烟尘余热利用的医疗垃圾处理方法
EP0532901A1 (fr) Méthode et installation pour gazéifier des combustibles solides contenant des matériaux fusibles non-combustibles
US20230287285A1 (en) Pyrolysis Plants and Methods for Thermal Mineralization of Biomass and Production of Combustible Gases, Liquids and Biochar
US7736603B2 (en) Thermal waste recycling method and system
EP0433547B1 (fr) Appareil pour gazéifier des combustibles solides
CN111321012B (zh) 一种生物质气化炉
WO2014207755A1 (fr) Gazéification de biomasse ne produisant aucun rejet d'effluent
RU2721695C1 (ru) Способ переработки органического сырья с получением синтетического топливного газа в установке высокотемпературного абляционного пиролиза гравитационного типа
KR100596222B1 (ko) 코크스 건식 소화 장치에서의바이오매스(biomass)의 처리방법
RU2733777C2 (ru) Способ получения свободного от пиролизных смол горючего газа при газификации конденсированного топлива и устройство для его осуществления
US20020117390A1 (en) Method and device for heat treatment of waste products

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU NL PT SE

17P Request for examination filed

Effective date: 19930430

17Q First examination report despatched

Effective date: 19940704

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

ITF It: translation for a ep patent filed
AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU NL PT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 19950920

REF Corresponds to:

Ref document number: 128175

Country of ref document: AT

Date of ref document: 19951015

Kind code of ref document: T

REF Corresponds to:

Ref document number: 69204948

Country of ref document: DE

Date of ref document: 19951026

ET Fr: translation filed
REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

SC4A Pt: translation is available

Free format text: 951013 AVAILABILITY OF NATIONAL TRANSLATION

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2079115

Country of ref document: ES

Kind code of ref document: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 19970718

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 19970722

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19970723

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: LU

Payment date: 19970801

Year of fee payment: 6

Ref country code: ES

Payment date: 19970801

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19970813

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19970818

Year of fee payment: 6

Ref country code: DK

Payment date: 19970818

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19970828

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19970829

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19970831

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19970929

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980810

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980810

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980810

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980811

Ref country code: ES

Free format text: LAPSE BECAUSE OF THE APPLICANT RENOUNCES

Effective date: 19980811

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980831

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980831

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980831

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19980831

BERE Be: lapsed

Owner name: SAS GINO TOMADINI & C.

Effective date: 19980831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19990228

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19990301

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 19980810

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19990430

EUG Se: european patent has lapsed

Ref document number: 92113622.2

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 19990301

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19990601

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 19990228

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20001009

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20050810