EP0566376A1 - Verfahren und Vorrichtung zum Sintern von Flugasche von verbranntem Hausmüll - Google Patents

Verfahren und Vorrichtung zum Sintern von Flugasche von verbranntem Hausmüll Download PDF

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Publication number
EP0566376A1
EP0566376A1 EP19930302881 EP93302881A EP0566376A1 EP 0566376 A1 EP0566376 A1 EP 0566376A1 EP 19930302881 EP19930302881 EP 19930302881 EP 93302881 A EP93302881 A EP 93302881A EP 0566376 A1 EP0566376 A1 EP 0566376A1
Authority
EP
European Patent Office
Prior art keywords
sintering
chamber
pellets
fly ash
municipal waste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19930302881
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English (en)
French (fr)
Other versions
EP0566376B1 (de
Inventor
Yoshihiro C/O K. K. Kobe Seiko Sho Yamamoto
Jiro C/O K. K. Kobe Seiko Sho Terukina
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
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Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Publication of EP0566376A1 publication Critical patent/EP0566376A1/de
Application granted granted Critical
Publication of EP0566376B1 publication Critical patent/EP0566376B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/10—Arrangements for using waste heat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/22—Stationary reactors having moving elements inside in the form of endless belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/005—Fusing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02—Agglomerated materials, e.g. artificial aggregates
    • C04B18/023—Fired or melted materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B21/00—Open or uncovered sintering apparatus; Other heat-treatment apparatus of like construction
    • F27B21/06—Endless-strand sintering machines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Definitions

  • the recovered fly ash contains a substantial amount of various heavy metals and dioxins which are toxic even in a small quantity. Accordingly, it is necessary to process the heavy metals and dioxins contained in the fly ash so as to prevent these from flying and eluting, for example, before the fly ash is buried at a final disposal facility.
  • a hot blast supply duct 7 for supplying a hot blast into the chamber.
  • electric heating elements are provided in the hot blast supply duct 7, drying and preheating chamber 3, ignition chamber 4, and sintering chamber 5.
  • electric heating elements are not required to be provided in all the duct 7 and chambers 3, 4, and 5. It may be possible to provide electric heating elements in either one of the duct 7 and chambers 3, 4, and 5.
  • TABLE-2 shows respective qualities of seventeen types of coal available in Japan. As seen from TABLE-2, these coals have qualities for this embodiment. Specifically, a volatile component is 25 to 45%, a fixed carbon is 32 to 57%, and a heating value is 6300 to 7000 kcal/kg. This coal is excellent as carbon to be mixed into the raw pellets P. Five or less weight percent, preferably 1 to 3 weight percent, of coal is mixed into the raw pellets P. The reason why the added amount of the coal is set at not larger than 5 weight percent is that an ignition loss of the raw pellets P by the combustion of the coal increases if the added amount thereof is larger than 5 weight percent and the sintered pellets P1 having large rigidity cannot be obtained.
  • Portland cement it is sufficient to use commercially available so-called Portland cement.
  • bentonite the brand does not need to be specified.
  • Sodium bentonite or calcium bentonite may be used. Being formed from decomposed ore such as volcanic ash accumulated at a seabed when volcanoes erupt, the bentonite has an exceedingly large water absorbing function and such a property of expanding as a paste-like material when absorbing the water.
  • An example of chemical composition of the Portland cement and bentonite are listed in TABLE-3 below for reference.
  • the molder 26 is not limited to the above.
  • the type of the molder is selected depending upon the application of the final product pellets.
  • the raw pellets P molded in the molder 26 are discharged onto the curing conveyor 27, and are conveyed thereon for about 10 to 30 minutes.
  • the raw pellets P are air-dried while being conveyed.
  • an ignition burner B By igniting this ignition burner B, the raw pellets P conveyed to the chamber 4 while being preheated at 200 to 400 °C are ignited and burnt.
  • the electric heating elements 5c, 7c are also provided in this ignition chamber4 to heat the raw pellets P. The provision of the electric heating elements 5c, 7c in the chamber 4 helps the ignition and combustion of the raw pellets P and ignites the raw pellets P more uniformly than in the existing ignition chamber.
  • the sintered pellets P1 are required to have substantially even diameters in the case where they are used as aggregates, the pellets remaining on the vibrating sieve 12 are separated as the product pellets P2 and are sent to the product bunker 13.
  • the tiny pellets fallen from the sieve 12 are returned to the molder 26 through the dust solo 22, and are used again as a part of the raw material.
  • all the sintered pellets may be product pellets without separating the same by the vibrating sieve 12.
  • the sintered pellets P1 are provided with the uniaxial compressive strength of about 20 to 40 (kg/pellet) and the shape thereof is held stably over a long time, they can be disposed safely in a state where they do not give adverse influence on the final disposal facility. Moreover, the sintered pellets P are suitable for many applications including materials for aggregates for concrete, subgrade, backfill, and drain accelerator for flow beds.
  • the uniaxial compressive strength of any of the materials No. 6 to No. 11 according to the invention are above the target value. It is found out that the compressive strength increases as the amount of additives increases and that the material preferably contains a combination of 2 to 5 weight percent of solidifying agent represented by the bentonite and 0 to 5 weight percent of self-burning agent (carbon) represented by the fine particle coal.
  • the 24 hour water absorption of any material according to the invention is in excess of the target value of 30%.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
EP19930302881 1992-04-15 1993-04-14 Verfahren und Vorrichtung zum Sintern von Flugasche von verbranntem Hausmüll Expired - Lifetime EP0566376B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP95385/92 1992-04-15
JP9538592 1992-04-15

Publications (2)

Publication Number Publication Date
EP0566376A1 true EP0566376A1 (de) 1993-10-20
EP0566376B1 EP0566376B1 (de) 1996-01-24

Family

ID=14136185

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19930302881 Expired - Lifetime EP0566376B1 (de) 1992-04-15 1993-04-14 Verfahren und Vorrichtung zum Sintern von Flugasche von verbranntem Hausmüll

Country Status (2)

Country Link
EP (1) EP0566376B1 (de)
DE (1) DE69301367T2 (de)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1995011865A1 (en) * 1993-10-26 1995-05-04 British Technology Group Limited Ceramic materials and method of manufacturing such materials
EP0673988A1 (de) * 1994-03-22 1995-09-27 AUSTRIAN ENERGY & ENVIRONMENT SGP/WAAGNER-BIRO GmbH Verfahren zur Volumensverkleinerung von Aschen
GB2297971A (en) * 1993-10-26 1996-08-21 Univ Staffordshire Entpr Ltd Ceramic materials and method of manufacturing such materials
GB2318115A (en) * 1996-08-01 1998-04-15 Cintag Limited Lightweight aggregate from fly ash and coal tailings
WO1998018738A1 (en) * 1996-10-30 1998-05-07 University Of Sheffield Fly ash treatment
WO2000016917A1 (en) * 1998-09-21 2000-03-30 Spanovic Milli Process of inertisation, immobilisation and stabilisation of solidificates obtained from various waste processings
WO2007124527A1 (de) 2006-05-03 2007-11-08 Ash Dec Umwelt Ag Thermisches verfahren zur abtrennung von schwermetallen aus asche in agglomerierter form
US7462310B2 (en) * 2003-12-11 2008-12-09 Ohonokaihatsu Co., Ltd. Porous landscape pebble and method of manufacturing the same
WO2013135373A1 (de) * 2012-03-16 2013-09-19 Gkn Sinter Metals Holding Gmbh Sinterofen mit einer gasabführvorrichtung
EP2650391A1 (de) * 2012-04-13 2013-10-16 Andritz Energy & Environment GmbH Verfahren zur Inertisierung von Schwermetallen wie z.B. sechswertiges Chrom, Chloriden und anderen Salzbildnern sowie löslichen Feststoffen und metallischen Kontaminationen
CN104456540A (zh) * 2014-12-04 2015-03-25 安徽诚铭热能技术有限公司 环冷热风余热回收利用点火炉
WO2015060735A3 (en) * 2013-10-23 2015-06-18 Lsa Sp. Z O.O. A method and a system for producing a lightweight ceramic aggregate, particularly from coal ash
CN108027210A (zh) * 2015-09-16 2018-05-11 通用电器技术有限公司 用于静电除尘器的烧结带气体的粉尘调节
CN109701321A (zh) * 2019-01-10 2019-05-03 西北大学 利用工业废弃物低温烧结制备颗粒床过滤滤料的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3908172A1 (de) * 1989-03-13 1990-09-20 Andreas Dipl Ing Gumbmann Poroeses mineralisches leichtzuschlagstoffgranulat sowie verfahren zu seiner herstellung

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3908172A1 (de) * 1989-03-13 1990-09-20 Andreas Dipl Ing Gumbmann Poroeses mineralisches leichtzuschlagstoffgranulat sowie verfahren zu seiner herstellung

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, vol. 102, no. 10, March 11, 1985, Columbus, Ohio, USA TANG SATHITKULCHAI, M.; AUSTIN, L. "Studies of sintering of coal ash relevant to pulverized coal utility boilers. 2-Prelimi- nary studies of compressive strength of fly ash sinters" page 147, column 2, abstract-no. 81 399m *
CHEMICAL ABSTRACTS, vol. 99, no. 24, December 1983, Columbus, Ohio, USA KOBE STEEL, LTD "Sintering of fly ash pallets" page 283, column 2, abstract-no. 199 669x & Jpn. Kokai Tokkyo Koho JP 58 115 078 (83 115 078) *

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2297971A (en) * 1993-10-26 1996-08-21 Univ Staffordshire Entpr Ltd Ceramic materials and method of manufacturing such materials
GB2297971B (en) * 1993-10-26 1997-07-09 Univ Staffordshire Entpr Ltd Ceramic materials and method of manufacturing such materials
WO1995011865A1 (en) * 1993-10-26 1995-05-04 British Technology Group Limited Ceramic materials and method of manufacturing such materials
EP0673988A1 (de) * 1994-03-22 1995-09-27 AUSTRIAN ENERGY & ENVIRONMENT SGP/WAAGNER-BIRO GmbH Verfahren zur Volumensverkleinerung von Aschen
AT401023B (de) * 1994-03-22 1996-05-28 Austrian Energy & Environment Verfahren zur volumensverkleinerung von aschen
GB2318115A (en) * 1996-08-01 1998-04-15 Cintag Limited Lightweight aggregate from fly ash and coal tailings
WO1998018738A1 (en) * 1996-10-30 1998-05-07 University Of Sheffield Fly ash treatment
GB2318786B (en) * 1996-10-30 1999-09-01 Univ Sheffield Fly ash treatment
US6105517A (en) * 1996-10-30 2000-08-22 University Of Sheffield Fly ash treatment
HRP980518B1 (en) * 1998-09-21 2009-01-31 �panovi� Milli Process of inactivation, immobilization and stabilization of solid material resulting from the processing of various residues
WO2000016917A1 (en) * 1998-09-21 2000-03-30 Spanovic Milli Process of inertisation, immobilisation and stabilisation of solidificates obtained from various waste processings
US7462310B2 (en) * 2003-12-11 2008-12-09 Ohonokaihatsu Co., Ltd. Porous landscape pebble and method of manufacturing the same
WO2007124527A1 (de) 2006-05-03 2007-11-08 Ash Dec Umwelt Ag Thermisches verfahren zur abtrennung von schwermetallen aus asche in agglomerierter form
WO2013135373A1 (de) * 2012-03-16 2013-09-19 Gkn Sinter Metals Holding Gmbh Sinterofen mit einer gasabführvorrichtung
US9841236B2 (en) 2012-03-16 2017-12-12 Gkn Sinter Metals Holding Gmbh Sintering furnace with a gas removal device
EP2650391A1 (de) * 2012-04-13 2013-10-16 Andritz Energy & Environment GmbH Verfahren zur Inertisierung von Schwermetallen wie z.B. sechswertiges Chrom, Chloriden und anderen Salzbildnern sowie löslichen Feststoffen und metallischen Kontaminationen
WO2015060735A3 (en) * 2013-10-23 2015-06-18 Lsa Sp. Z O.O. A method and a system for producing a lightweight ceramic aggregate, particularly from coal ash
US9938196B2 (en) 2013-10-23 2018-04-10 Lsa Sp. Z O.O. Method and a system for producing a lightweight ceramic aggregate, particularly from coal ash
CN104456540A (zh) * 2014-12-04 2015-03-25 安徽诚铭热能技术有限公司 环冷热风余热回收利用点火炉
CN108027210A (zh) * 2015-09-16 2018-05-11 通用电器技术有限公司 用于静电除尘器的烧结带气体的粉尘调节
CN108027210B (zh) * 2015-09-16 2019-08-09 通用电器技术有限公司 用于静电除尘器的烧结带气体的粉尘调节
CN109701321A (zh) * 2019-01-10 2019-05-03 西北大学 利用工业废弃物低温烧结制备颗粒床过滤滤料的方法

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Publication number Publication date
EP0566376B1 (de) 1996-01-24
DE69301367D1 (de) 1996-03-07
DE69301367T2 (de) 1996-06-27

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