EP0597904A1 - Adhesif aqueux. - Google Patents

Adhesif aqueux.

Info

Publication number
EP0597904A1
EP0597904A1 EP92915970A EP92915970A EP0597904A1 EP 0597904 A1 EP0597904 A1 EP 0597904A1 EP 92915970 A EP92915970 A EP 92915970A EP 92915970 A EP92915970 A EP 92915970A EP 0597904 A1 EP0597904 A1 EP 0597904A1
Authority
EP
European Patent Office
Prior art keywords
adhesive
weight
derivatives
glue
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92915970A
Other languages
German (de)
English (en)
Other versions
EP0597904B1 (fr
Inventor
Ludwig Broich
Bernhard Herlfterkamp
Hermann Onusseit
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP0597904A1 publication Critical patent/EP0597904A1/fr
Application granted granted Critical
Publication of EP0597904B1 publication Critical patent/EP0597904B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
    • C09J103/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J189/00—Adhesives based on proteins; Adhesives based on derivatives thereof
    • C09J189/005—Casein
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor

Definitions

  • the invention relates to a water-based adhesive based on glue and resin and its use for gluing paper
  • Glues are aqueous colloidal solutions of a) animal polymers, e.g. Casein and glutin or polymers from hides, bones or fish, b) from vegetable polymers, e.g. Gum arabic, cellulose nitrate, carboxymethyl cellulose as well as cellulose ether, dextrin and starch, c) synthetic polymers such as polyvinyl pyrrolidone, polyacrylic acid derivatives and polyvinyl alcohol.
  • animal polymers e.g. Casein and glutin or polymers from hides, bones or fish
  • vegetable polymers e.g. Gum arabic, cellulose nitrate, carboxymethyl cellulose as well as cellulose ether, dextrin and starch
  • synthetic polymers such as polyvinyl pyrrolidone, polyacrylic acid derivatives and polyvinyl alcohol.
  • the glues belong to the class of one-component, physically cold or hot setting adhesives, in which the water escapes during bonding. They are therefore mainly used for gluing absorbent materials such as paper, cardboard or wood together. However, the glues are unsuitable for permanently bonding paper, in particular paper labels, to plastic surfaces (see K. Dullinger "Labeling Technology from A to Z” in Zeitschrift für Strukturtechnik (ZFL) 1987, pp. 503 to 507). It is also known to add glues, for example starch and dextrin glues, to synthetic resin dispersions in order to improve their water resistance.
  • Synthetic resin dispersions for example polyvinyl esters and polyacrylic acid esters and their copolymers, are also used alone or together with polyvinyl alcohol for gluing paper to plastic.
  • the addition of polyvinyl alcohol serves to increase the wet tack of the dispersion.
  • Fully synthetic systems of this type are well suited for the adhesive bonding of paper to plastic surfaces (see Dullinger, quotation above).
  • DE 40 00 241 A1 describes an adhesive made from animal glue, glue hydrolyzate or acid casein and at least one substance from the group: urea, thio-urea, N-alkyl urea and guanidine nitrate and, if appropriate, others in the production of glue usual additives described.
  • Balsam resin, sugar or dextrin can be added to improve flatness.
  • Glycerol or polyglycol for example, can be used as hygroscopic substances.
  • the adhesive can be used in the form of an aqueous solution or as a solid. Use as a warm (hot) sealing material or hot adhesive, in particular for surface coating, is claimed.
  • the glues can also be based on synthetic polymers, e.g. on polyvinyl alcohol, but glues from one or more constituents of the following group are preferred: casein, starch, starch derivatives, dextrin and cellulose ether.
  • casein the casein obtained from milk by acid precipitation is particularly suitable.
  • Starch derivatives which can be obtained by reacting native or degraded, for example oxidatively degraded, starch are suitable. These starch derivatives are generally reaction products with, for example, ethylene oxide, propylene oxide, acrylonitrile, chloroacetic acid or also epoxypropanesulfonic acid. The degree of substitution should be relatively low, approximately between 0.02 and 0.1 DS.
  • the commercially available thin-, medium- or thick-boiling dextrin can be used as dextrin, which can be obtained in a known manner by breaking down starch.
  • the rosin is a glassy amorphous mass with average molecular weights below 2,000 g / mol. They are obtained from the raw resin of conifers. They mainly consist of unsaturated carboxylic acids with the gross formula C20H30O2 such as abietic acid and its isomers. In addition, more or less neutral substances such as fatty acid esters, terpene alcohols and hydrocarbons can also be contained.
  • a derivatized rosin is preferably used, for example a hydrogenated or disproportionated rosin, the Derivatization, especially to increase water solubility, eg saponification or addition of maleic acid. Rosin resins and their derivatives that can be used are balsam, tall and root resins. Water-soluble balsam resin derivatives with a solubility of at least 3 g in 100 g of water at 25 ° C. are particularly suitable.
  • Synthetic resins are understood to mean products which are formed by condensation or polymerization, are generally amorphous, have no sharp softening point and the state of which can range from liquid to resinous to solid.
  • Hydrocarbon resins are preferably used, ie thermoplastic polymers with a low average molecular mass of less than 2000. Both petroleum resins, coal tar resins and terpene resins are suitable.
  • the alcohols not only serve as solubilizers, they are also essential for the strength of the bond. They are therefore preferably liquid and practically do not evaporate from the adhesive system at 25 ° C. Alcohols with a solubility of more than 3 g in 100 g of water at 25 ° C. are preferably used.
  • the alcohols can be aliphatic or cycloaliphatic, saturated or unsaturated hydrocarbons with a straight or branched chain. They can also contain further heteroatoms, for example 0 in the form of an ether group. Specific examples are methanol, ethanol, propanol, butanol, benzyl alcohol, cyclohexanol, di-, tri- and polyethylene glycol.
  • dihydric and polyhydric alcohols in particular ethane-1,2-diol, propane-1,2-diol and / or propane-1,2,3-triol.
  • the content of components A), B) and C) in the finished adhesive can vary within a wide range. It depends not only on the content of the other components, but also on the conditions of use and on the concentration of other additives. However, it is advantageous if the content of glue-forming polymers in the finished adhesive is 3 to 50, preferably 5 to 20% by weight, the content of rosin or synthetic resin or their derivatives is 3 to 75, preferably 5 to 50% by weight and the alcohol content 3 to 50, preferably 5 to 25% by weight.
  • the adhesive can contain additives in order to achieve special properties, e.g. with regard to viscosity, solubility, durability, processing properties, color, etc.
  • benzoates fluorides such as sodium fluoride, amidic substances and hydroxybenzoic acid esters, e.g. p-Oxybenzoic acid methyl ester or - butyl ester in amounts of 0.2 to 0.6 wt .-%.
  • Possible antifoams are: stearates, silicone oil and addition products of ethylene oxide or propylene oxide with fatty alcohols with 12 to 18 carbon atoms in amounts of 0.3 to 2.5% by weight.
  • the flowability of the adhesive can be regulated in a manner known per se by adding certain water-soluble low-molecular plasticizers.
  • Urea, thiourea and / or dicyandiamide are particularly suitable for this, but also inorganic or organic salts such as halides, nitrates, sulfates, etc.
  • Such substances are advantageously used in a concentration of 0 to 25% by weight, preferably 1 to 15% by weight. % used.
  • Other additives can be: fragrances, dyes or fillers and surfactants as wetting agents.
  • the total solids content of the adhesives according to the invention is in the range from 25 to 75% by weight, preferably in the range from 30 to 65% by weight, based on the finished adhesive.
  • the adhesive according to the invention is produced by mixing the components in a manner known per se.
  • the glue is expediently first prepared, preferably in accordance with DE 3146364, and then mixed with an aqueous or alcoholic solution or dispersion of the rosin or its derivative and with the alcohol at 20 to 30 ° C. in a stirred mixer until it is homogeneous Distribution is achieved.
  • the additives are expediently added to the glue.
  • the viscosity of the final adhesive is normally in Be ⁇ ranging from 10,000 to 200,000 mPa 's, in particular in the range of approximately 20,000 to 100,000 at 25 ° C according to Brookfield.
  • the adhesives according to the invention are particularly suitable for bonding plastic surfaces to paper, in particular to paper labels.
  • the adhesive according to the invention can also be used for other plastics, for example for polyethylene or polypropylene.
  • the molded parts to be glued can be made entirely of plastic, for example plastic containers such as bottles, cans, buckets, cups, etc. However, they can also have only one plastic surface and otherwise be made of metal, glass or wood, for example tinplate cans, coated glass bottles, lacquered wood, etc.
  • Paper is understood to mean a flat material consisting essentially of fibers, predominantly of vegetable origin, which is obtained by dewatering a fiber slurry and then compressing and drying the fiber felt.
  • the weight per unit area is generally up to 225 g / m 2 . But it can also go beyond (cardboard and cardboard).
  • the publication by K. Dullinger shows which special requirements are to be made of papers for paper labels (see above quotation).
  • the paper can also be coated, for example with aluminum or a plastic layer.
  • the adhesive according to the invention it is possible to glue paper to untreated plastics much better than with the usual glues of starch, casein, etc.
  • the strength is increased to such an extent that labels tear when plastic objects are removed, just as with Dispersion adhesives based on synthetic resin.
  • This high strength was not to be expected, since components A), B) and C) do not lead to such strength either individually or in pairs. This strength is only achieved by combining all three components.
  • the adhesive according to the invention enables a wet force that is significantly above the level of commercially available dispersion adhesives.
  • the invention enables the production of aqueous adhesives based on natural raw materials. It is also possible to produce transparent adhesives. They are completely unproblematic with regard to storage stability and phase separation. The invention will now be described in detail using examples:
  • the casein adhesive had a solids content of approximately 35% by weight and consisted essentially of 25% by weight of casein, approximately 8% by weight of urea and 2% by weight of sodium hydroxide solution in the form of a 35% solution. The remainder of 65% by weight was deionized water.
  • the resin soap is a mixture of 50 parts by weight of balsam resin, 15 parts by weight of KOH and 35 parts by weight of water.
  • the adhesive was also transparent with a layer thickness of 10 cm. It had a viscosity of 30,000 mPa ⁇ s at 25 ° C according to Brookfield.
  • casein adhesive As indicated above, 50 parts by weight of casein adhesive, 30 parts by weight of resin soap (as above) and 20 parts by weight of ethylene glycol were mixed.
  • the adhesive was also transparent and had a viscosity of 20,000 mPa ⁇ s at 25 ° C according to Brookfield.
  • Example I 25 parts by weight of casein adhesive, 34 parts by weight of WINGTACK 10, 36 parts by weight of rosin resin and 5 parts by weight of glycerin were mixed.
  • the adhesive was transparent and had a viscosity of 40,000 mPa-s at 25 ° C according to Brookfield.
  • WINGTACK 10 is a commercial product from Goodyear. It consists of a mixture of terpene and petroleum resins and softens at 10 ° C. Its viscosity is 20,000 to 40,000 cP at 25 ° C. Its molecular weight is 450. Verklebun ⁇
  • the label is glued to the plastic bottles with the aid of the individual starting components, that is to say solely with the casein adhesive, the resin soap and the glycerin or with a mixture of two components thereof, namely casein adhesive / resin soap , Casein adhesive / glycerin and resin soap / glycerin in a weight ratio of 1/1, then the label could be easily removed after drying. Sometimes it even fell down from a11eine.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Afin d'accroître la force d'adhérence de colles, on y ajoute des résines de colophane et/ou leurs dérivés, ainsi que des alcools monovalents ou polyvalents solubles dans l'eau. Lorsque l'on colle avec ces colles des étiquettes en papier sur des matières plastiques telles que le téréphtalate de polyéthylene, le polycarbonate, le polystyrol, le chlorure de polyvinyle, on ne peut les enlever qu'en les déchirant.
EP92915970A 1991-08-07 1992-07-29 Adhesif aqueux Expired - Lifetime EP0597904B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4126074 1991-08-07
DE4126074A DE4126074A1 (de) 1991-08-07 1991-08-07 Wasserhaltiger klebstoff
PCT/EP1992/001721 WO1993003111A1 (fr) 1991-08-07 1992-07-29 Adhesif aqueux

Publications (2)

Publication Number Publication Date
EP0597904A1 true EP0597904A1 (fr) 1994-05-25
EP0597904B1 EP0597904B1 (fr) 1995-12-27

Family

ID=6437824

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92915970A Expired - Lifetime EP0597904B1 (fr) 1991-08-07 1992-07-29 Adhesif aqueux

Country Status (6)

Country Link
US (1) US5441562A (fr)
EP (1) EP0597904B1 (fr)
CA (1) CA2115046A1 (fr)
DE (2) DE4126074A1 (fr)
ES (1) ES2081122T3 (fr)
WO (1) WO1993003111A1 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4443539A1 (de) * 1994-12-07 1996-06-13 Buna Sow Leuna Olefinverb Gmbh Bioabbaubare thermoplastisch verformbare Materialien
DE19521564A1 (de) * 1995-06-19 1997-01-02 Henkel Kgaa Klebstoff-System zum Verkleben von Rundumetiketten
US6998435B1 (en) 2002-10-22 2006-02-14 Henkel Corporation Aqueous adhesive composition
GB0302935D0 (en) * 2003-02-10 2003-03-12 Ucb Sa Labels
FR2855524B1 (fr) * 2003-05-30 2007-04-06 Roquette Freres Utilisation d'un amidon de legumineuse dans une composition adhesive pour etiquetage
RU2277564C2 (ru) * 2004-04-29 2006-06-10 Закрытое акционерное общество "Макполимер" Клеевая композиция этикетировочного назначения
US7915338B2 (en) * 2005-12-28 2011-03-29 3M Innovative Properties Company Adhesive with alkanoate blend
DE602007004607D1 (de) * 2007-08-16 2010-03-18 Henkel Ag & Co Kgaa In Wasser wieder lösliches Klebemittel
DE102007048141A1 (de) 2007-10-05 2009-04-09 Henkel Ag & Co. Kgaa Wässrige Dispersion
US20090312472A1 (en) * 2008-06-17 2009-12-17 3M Innovative Properties Company Glycol-free glue stick
ES2883566T3 (es) * 2013-12-10 2021-12-09 Buckman Laboratories Int Inc Formulación de adhesivo y métodos de crepado para su utilización
US10655042B2 (en) * 2015-11-13 2020-05-19 Schlumberger Norge As Wellbore strengthening additive and uses thereof
CN109852279B (zh) * 2018-12-27 2021-06-01 绍兴明基新材料有限公司 蔬菜水果用捆绑植物基胶带及其制备方法
JP7729196B2 (ja) * 2021-12-15 2025-08-26 王子ホールディングス株式会社 包装材料および包装体

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB531084A (en) * 1939-06-22 1940-12-30 Trygve Sparre Improvements relating to the production of a resin-like casein glue
US2357073A (en) * 1940-11-27 1944-08-29 Hercules Powder Co Ltd Adhesive composition
US2361302A (en) * 1940-12-28 1944-10-24 Hercules Powder Co Ltd Adhesive composition
US2566529A (en) * 1948-02-14 1951-09-04 Chemical Mfg Company Coating of paper
US2651580A (en) * 1949-09-01 1953-09-08 Warren S D Co Mineral coated paper and coating composition therefor
US2943071A (en) * 1954-12-08 1960-06-28 Swift & Co Non-tear case sealing adhesive
US3692713A (en) * 1969-12-23 1972-09-19 Borden Inc Labeling adhesive composition
US4013479A (en) * 1975-05-23 1977-03-22 Arthur Biddle Aqueous natural resinoid compositions
DE2925362C2 (de) * 1978-06-23 1985-08-14 Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa Schutzmittel vom Emulsionstyp für die Oberfläche von lithographischen Druckplatten
JPS5519504A (en) * 1978-06-23 1980-02-12 Fuji Photo Film Co Ltd Lithoprinting plate protective agent
US4364837A (en) * 1981-09-08 1982-12-21 Lever Brothers Company Shampoo compositions comprising saccharides
DE3146364A1 (de) * 1981-11-23 1983-06-01 Henkel KGaA, 4000 Düsseldorf Verfahren zur herstellung von waessrigen klebstoffloesungen sowie deren verwendung zum etikettieren von flaschen
NO157180C (no) * 1981-11-23 1988-02-03 Henkel Kgaa Fremgangsmaate til fremstilling av vandige klebestoffblanding og anvendelse av den for maskinell etikettering, spesielt av glassvarer.
JPS62167377A (ja) * 1986-01-18 1987-07-23 Arakawa Chem Ind Co Ltd 水性エマルジヨン型粘着付与剤の皮張り防止方法
JPH0794192B2 (ja) * 1988-10-24 1995-10-11 富士写真フイルム株式会社 平版印刷版用版面保護剤
DE4000241A1 (de) * 1990-01-06 1991-07-11 Fritz Haecker U Sohn Gmbh & Co Verwendung eines klebstoffs, mit dem klebstoff beschichteter traeger und klebeverfahren
JP3072142B2 (ja) * 1991-04-02 2000-07-31 ハリマ化成株式会社 製紙用サイズ剤組成物

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9303111A1 *

Also Published As

Publication number Publication date
US5441562A (en) 1995-08-15
DE4126074A1 (de) 1993-02-11
WO1993003111A1 (fr) 1993-02-18
EP0597904B1 (fr) 1995-12-27
ES2081122T3 (es) 1996-02-16
CA2115046A1 (fr) 1993-02-18
DE59204862D1 (de) 1996-02-08

Similar Documents

Publication Publication Date Title
EP0597904B1 (fr) Adhesif aqueux
EP0597920B1 (fr) Colle aqueuse a base de caseine
DE69902545T2 (de) Verfahren zum getrennten auftragen eines harzes und eines härters
DE2550066C2 (de) Wäßriges Trennüberzugsmittel für Ablöse- oder Trennblätter und dessen Verwendung
EP2730626A1 (fr) Adhésif thermofusible de polyoléfine réactif ayant une faible adhérence aux outils en aluminium non revêtus et son utilisation en tant que masque thermofusible
DE3786283T2 (de) Mischung, Polyvinylalkohol enthaltend, zur Herstellung von schnell aushärtendem Klebstoff auf der Basis von Stärke und Verwendung bei der Herstellung von Wellpappe.
DE2820907C3 (de) Verleimungsverfahren mit härtbaren Klebern auf Formaldehydbasis und Härterzusammensetzung
DE19521564A1 (de) Klebstoff-System zum Verkleben von Rundumetiketten
EP0729496A1 (fr) Agent antiglissement aqueux
DE3888959T2 (de) Entfernbare feste Klebstoffe.
DE19747449B4 (de) Verwendung einer wässrigen Klebstoffzubereitung
DE1953307A1 (de) Klebstoff
DE1567378A1 (de) Verbundkoerper aus mindestens zwei miteinander verleimten Lagen,deren eine aus einem Cellulosesubstrat besteht,und dazu geeigneter Leim
WO2008037764A1 (fr) Utilisation de poly(alcool de vinyle) hydrosoluble comme adhésif pour des étiquettes en matière plastique
DE2219003A1 (de) Klebstoffmischung und deren Verwendung
EP0016247A1 (fr) Colle thermodurcissable contenant une résine époxyde et un copolymère d'acrylate et son utilisation pour faire adhérer des matières plastiques à des métaux
EP0427058B1 (fr) Composition aqueuse de durcisseur pour durcir des résines aminoplastes
DE875568C (de) Verfahren zur Herstellung von harzartigen, wasserloeslichen, haertbaren Kondensationsprodukten in Pulverform
DE688346C (de) Klebstoff fuer gehaertete Kunstharze
DE102006043494A1 (de) Spaltmittel zur Erleichterung des Ablösens von aufgeklebten Schichtmaterialzuschnitten und Verfahren zum lösbaren Aufkleben von Schichtmaterialzuschnitten
EP0184646A2 (fr) Durcisseur pour résines aminoplastes, leur utilisation dans le doublage et le placage de panneaux de bois ainsi qu'un procédé de doublage et placage de panneaux de bois
DE2063364A1 (de) Verfahren zur Herstellung von in or ganischen Losungsmitteln löslichen modifi zierten Mischpolymerisaten Ausscheidung aus 2058666
DE902311C (de) Verfahren zur Verleimen von Holz und holzaehnlichen Stoffen
CH537273A (de) Verfahren zur Herstellung von Holzwerkstoffen mit hoher Heisswasserbeständigkeit
AT343880B (de) Beleimungsverfahren fur das zusammenfugen von holzprodukten

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19940131

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): BE DE ES FR GB IT NL

17Q First examination report despatched

Effective date: 19940919

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE DE ES FR GB IT NL

ET Fr: translation filed
REF Corresponds to:

Ref document number: 59204862

Country of ref document: DE

Date of ref document: 19960208

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2081122

Country of ref document: ES

Kind code of ref document: T3

ITF It: translation for a ep patent filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19960304

NLT2 Nl: modifications (of names), taken from the european patent patent bulletin

Owner name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20000719

Year of fee payment: 9

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20010730

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20020810

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED.

Effective date: 20050729

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20060703

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20060719

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20060726

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20060727

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20060912

Year of fee payment: 15

BERE Be: lapsed

Owner name: *HENKEL K.G.A.A.

Effective date: 20070731

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20070729

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20080201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080201

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070729

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20080331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070731