EP0631005A1 - Tissu pour impression par jet d'encre et procédé d'impression par jet d'encre - Google Patents

Tissu pour impression par jet d'encre et procédé d'impression par jet d'encre Download PDF

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Publication number
EP0631005A1
EP0631005A1 EP93110102A EP93110102A EP0631005A1 EP 0631005 A1 EP0631005 A1 EP 0631005A1 EP 93110102 A EP93110102 A EP 93110102A EP 93110102 A EP93110102 A EP 93110102A EP 0631005 A1 EP0631005 A1 EP 0631005A1
Authority
EP
European Patent Office
Prior art keywords
water
ink
cloth
absorbing resin
insoluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP93110102A
Other languages
German (de)
English (en)
Inventor
Akira Fukunishi
Risa Fujiwara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyo Chemical Industries Ltd
Original Assignee
Sanyo Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP3359451A priority Critical patent/JPH0742658B2/ja
Application filed by Sanyo Chemical Industries Ltd filed Critical Sanyo Chemical Industries Ltd
Priority to EP93110102A priority patent/EP0631005A1/fr
Priority to CA002115184A priority patent/CA2115184A1/fr
Publication of EP0631005A1 publication Critical patent/EP0631005A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing

Definitions

  • the present invention relates to a cloth capable of obtaining a printing image of excellent sharpness and build-up by applying printing ink by an ink-jet process, and an ink-jet printing processing using the same cloth.
  • a method is proposed, for example, to solve these problems, in which the cloth is pretreated with a compound substantially not dyeable with the ink to be used, selected from a group consisting of water soluble polymer, water soluble salts, and water insoluble inorganic fine powder; ink-jet printing is then performed (Japanese Patent Publication No. 31594/1988).
  • the invention relates to a cloth for ink-jet printing, wherein 0.01 to 10 % by weight of a water-insoluble water-absorbing resin having a water absorption capability of 50 to 1,000 ml/g to purified water is deposited on said cloth; and an ink-jet printing process of cloth comprising the steps of depositing 0.01 to 10 wt.% of the the above mentioned water-insoluble water-absorbing resin to the cloth, applying printing ink by the ink-jet process, heating and fixing the printing ink, and washing and removing the water-insoluble water-absorbing resin.
  • the water-insoluble water-absorbing resin may be composed of 1 resins obtainable by polymerizing, (a) starch or cellulose, (b) a water-soluble monomer having a carboxyl group or a sulfonic acid group and/or a monomer capable of becoming water-soluble through hydrolysis (hereinafter, designated as a water-soluble monomer) and (c) a crosslinking agent and subsequently carrying out, if necessary, hydrolysis (hereinafter, 1 is designated as a starch or cellulose series crosslinking material).
  • Examples of (a) include raw starches such as sweet potato starch, potato starch, wheat starch, corn starch, rice starch, and tapioca starch; processed starch such as oxidized starch, dialdehyde starch, alkyl etherized starch, oxy alkylated starch, amino ethyl etherized starch, and cyano ethyletherized starch; and celluloses such as natural cellulose, carboxymethyl cellulose, and cellulose ether.
  • raw starches such as sweet potato starch, potato starch, wheat starch, corn starch, rice starch, and tapioca starch
  • processed starch such as oxidized starch, dialdehyde starch, alkyl etherized starch, oxy alkylated starch, amino ethyl etherized starch, and cyano ethyletherized starch
  • celluloses such as natural cellulose, carboxymethyl cellulose, and cellulose ether.
  • Examples of (b) include monomers possessing a carboxy group such as (meth)acrylic acid and maleic anhydride; monomers possessing a carboxylate group such as sodium (meth)acrylate, sodium maleate, trimethylamine salt of (meth)acrylic acid, and triethanol amine salt of (meth)acrylic acid; monomers possessing a sulfonic acid group such as vinyl sulfonic acid, vinyl toluene sulfonic acid and sulfopropyl (meth)acrylate; and monomers possessing a sulfonate group such as sodium vinyl sulfonate, methyl amine salt of vinyl sulfonic acid, and sulfopropyl diethanol amine salt of (meth)acrylic acid.
  • monomers possessing a carboxy group such as (meth)acrylic acid and maleic anhydride
  • monomers possessing a carboxylate group such as sodium (meth)acrylate, sodium maleate, trimethylamine salt of (
  • Examples of (c) include polyols such as ethylene glycol and trimethylol propane; bisacrylamides such as N,N-methylene-bisacrylamide; multifunctional (meth)acrylic esters such as ethylene diglycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, and trimethylol propane tri(meth)acrylate; methylol (meth)acrylamide, and glioxazal.
  • polyols such as ethylene glycol and trimethylol propane
  • bisacrylamides such as N,N-methylene-bisacrylamide
  • multifunctional (meth)acrylic esters such as ethylene diglycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, and trimethylol propane tri(meth)acrylate
  • methylol (meth)acrylamide examples include glioxazal.
  • (meth)acrylic- means “acrylic-” or “methacrylic-”.
  • Examples of the water-insoluble water-absorbing resin other than those noted above, are 2 those obtainable by polymerizing the components (a) and (b), e.g., hydrolyzed product of starch-acrylonitrile graft copolymer or hydrolyzed product of cellulose-acrylonitrile graft copolymer (hereinafter, 2 is designated as a starch- or cellulose-acrylonitrile graft copolymer); 3 crosslinked material of (a) (e.g., crosslinked carboxymethylcellulose); 4 a copolymer of the components (b) and (c) (e.g., partially hydrolyzed product of crosslinked polyacrylamide, crosslinked acrylic acid-acrylamide copolymer, crosslinked sulfonated polystyrene, saponified vinylester-unsaturated carboxylic acid copolymer disclosed in Japanese Patent Application Laid-Open No.
  • crosslinked polyacrylic acid or salts thereof crosslinked acrylic acid-acrylic acid ester copolymer, cross linked isobutylene-maleic acid anhydride copolymer and crosslinked carboxylic acid denaturated polyvinyl alcohol); and 5 self-crosslinking polymerization product of the component (b) (e.g., self-crosslinkable polyacrylic acid salts).
  • component (b) e.g., self-crosslinkable polyacrylic acid salts.
  • water-insoluble water-absorbing resins 1 and some of 4 such as the partially hydrolyzed product of crosslinked polyacrylamide, crosslinked acrylic acid-acrylamide copolymer, crosslinked polyacrylic acid salts (e.g., alkali metal salts, ammonium salts, etc.), crosslinked acrylic acid-acrylic acid ester copolymer, crosslinked isobutylene-maleic acid anhydride copolymer and crosslinked carboxylic acid denaturated polyvinyl alcohol, are preferable.
  • crosslinked polyacrylamide crosslinked acrylic acid-acrylamide copolymer
  • crosslinked polyacrylic acid salts e.g., alkali metal salts, ammonium salts, etc.
  • crosslinked acrylic acid-acrylic acid ester copolymer e.g., alkali metal salts, ammonium salts, etc.
  • crosslinked acrylic acid-acrylic acid ester copolymer e.g., alkali metal salts, ammonium salts, etc.
  • the preferable water-insoluble water-absorbing resins above are those having a water absorption capability with respect to pure water of 50 to 1,000 ml/g, preferably 100 to 900 ml/g.
  • the shape of the water-insoluble water-absorbing resin is not limited specifically, but powder- or granule-like particles (usually of 5 mm or less in size) are preferable.
  • the ink-jet process employed in the invention may be achieved by discharging the printing ink effectively from the nozzle, and applying on the cloth - which is the object of ink-jet printing - and its typical methods have been disclosed, for example, in I.E.E.E. Transactions on Industry Applications, Vol. 1A-13, No. 1; and Nikkei Electronics, April 19, 1976 and February 3, 1977.
  • (1) is an Electrostatic attraction system: a method in which a ferroelectric field is applied between a nozzle and an accelerating electrode disposed several millimeters ahead thereof; ink is granulated and drawn out of the nozzle successively, and the information signal is given to deflecting electrodes to record when the drawn ink particles jump between deflecting electrodes.
  • (2) is an Ultrasonic vibration system: a method in which high pressure is applied to the ink by a small pump, the nozzle is vibrated mechanically by a quartz oscillator or the like, and small ink particles are forcibly jetted out.
  • the jetted ink particles are electrically charged depending on the information signal when the ink particles are jetted out.
  • the charged ink particles are deflected depending on the amount of charge when passing through deflecting electrode plates.
  • (3) is a Piezoresistive element system: a method in which piezoresistive elements are utilized, that is, the piezoresistive elements are provided with electric signals to cause mechanical displacement, and pressure is applied to ink to jet out from the nozzle.
  • the cloth in the invention may be woven cloth, knitted cloth or nonwoven cloth, including carpet material.
  • Fiber materials used in the cloth may be arbitrary synthetic fibers (e.g. polyester, polyamide, acrylic fiber), semisynthetic fibers (e.g. acetate, rayon), natural fibers (e.g. cotton, silk, wool), and their mixtures (e.g. blended woven fabric, twisted union fabric, knit/textile union fabric) and all other fiber materials.
  • the printing ink used in the invention must contain a dye applicable to the cloth, and examples of dyes include acid dye, direct dye, reactive dye, cationic dye, and disperse dye.
  • the dye composing the printing ink must be changed depending on the fiber material to be used.
  • a disperse dye is used to compose the printing ink.
  • anionic dye In the case of the cloth made of wool, silk, polyamide, cotton, rayon, and other materials printable by anionic dye, a direct dye, acid dye, reactive dye, and other anionic dyes are applicable. For materials such as acrylic fiber and cationic dyeable polyester fiber, cationic dyes are used.
  • Disperse dyes include azo, anthraquinone, nitrodiphenylamine, naphthal imide, naphthoquinone imide, and metine types. Practical examples of these dyes are listed in pages 725-816 of the New Dye Handbook (published by Maruzen).
  • Direct dyes include azo, stylbene, thiazole, dioxsazine, and phthalocyanine types. Practical examples of these dyes are listed in pages 317-396 of the same Handbook.
  • Acid dyes include azo, anthraquinone, triphenyl methane, and xanthine types. Practical examples of these dyes are listed in pages 393-526 of the same Handbook.
  • Reactive dyes include azo, anthraquinone, and phthalocyanine types. Practical examples of these dyes are listed in pages 881-934 of the same Handbook.
  • Cationic dyes include practical examples of dyes listed in pages 529-562 of the same Handbook.
  • the printing ink may be designed to suit the individual ink-jet systems, and from the viewpoint of environmental protection and blurring or running on the cloth, a water-based ink, such as aqueous solution of dye and water disperse solution of dye may be preferably used.
  • a water-based ink such as aqueous solution of dye and water disperse solution of dye may be preferably used.
  • the ink is blended with additives as required, such as property-regulating agents (for adjusting viscosity, surface tension, electric conductivity, pH, etc.), antimold agents, sterilizers, chelating agents, and ink drying inhibitors.
  • the ink drying inhibitor acts to prevent clogging of the ink-jet nozzle with ink, of which examples include polyols such as ethylene glycol and glycerin, N-alkyl pyrrolidone such as N-methyl pyrrolidone and N-ethyl pyrrolidone, ether compounds such as methyl cellosolve, ethyl cellosolve, and methyl carbitol, formamide derivatives such as N-cyclohexyl formamide and N,N-dibutyl formamide, and aralkyl alcohol such as benzyl alcohol and 1-phenyl ethyl alcohol.
  • the water-insoluble water-absorbing resin is dispersed in water or hydrophilic organic solvent (e.g. methanol, isopropyl alcohol, ethylene glycol, propylene glycol, dimethylformamide), or a mixed solution of water and hydrophilic organic solvent, and a disperse solution is prepared.
  • a disperse solution may be prepared by using an aromatic organic solvent (e.g. toluene, xylene).
  • the depositing weight of the water-insoluble water-absorbing resin is 0.01 to 10 wt.% of the cloth, and preferably 0.1 to 5 wt.%. If less than 0.01%, the blurring preventive effect of the printing ink is small, and a sharp printing image is not obtained. If exceeding 10 wt.%, the blurring preventive effect is increased, but the build-up of the printing image is extremely impaired, and thus is not desirable. That is, the dye deposit rate on the cloth is greatly diminished, and is not economical. (The build-up refers to the quantity rate of dye-deposition in the printing process; that is, a degree of dye exhaustion.)
  • a disperse solution composed of water-insoluble water-absorbing resin is applied to the cloth, and dried to obtain the cloth for ink-jet printing of the invention.
  • a printing ink is applied by an ink-jet printing machine.
  • to heat the dye applied to the cloth to develop color it is processed by steaming or dry heat.
  • the heat fixing condition of the dye varies with the kind of dye and the kind of cloth, and it is treated for 10 to 30 minutes at 100 to 130 °C in the case of steaming, and 1 to 5 minutes at 180 to 210 °C in the case of dry heat.
  • soaping or reduction cleaning is effected to remove the unbonded dye and water-insoluble water-absorbing resin.
  • the medium is mostly water, and is an aqueous solution of water-soluble dye or a water dispersion solution of fine dispersed dye.
  • the key point is how to absorb the ink on the cloth promptly regardless of the ink volume.
  • the ink When the cloth for ink-jet printing of the invention is used, when the ink deposits on the cloth for printing, the ink is mostly absorbed promptly without blurring. This is explained by the ink being entrapped within the cross linked high molecular meshes of the water-insoluble water-absorbing resin, and migration is prevented, thereby forming a sharp print. Besides, since the water-insoluble water-absorbing resin is poor in affinity for these dyes, if the dye entrapped in the high molecular meshes is heated and fixed, it is not diffused in the water-insoluble water-absorbing resin, and migrates only to the fibers having greater affinity. Therefore, a sharp printing image is obtained.
  • the ink when the ink is similarly bonded, it dissolves these compounds, is absorbed while diffusing; that is, the ink is absorbed while blurring, so that a sharp printing image may not be obtained.
  • the ink is contained in the gaps of particles by the capillary phenomenon to achieve an absorption state.
  • the rate of absorption is slow, and the amount of absorption is limited, and much is not absorbed. Therefore, the printing image is not only poor in build-up but also low in sharpness.
  • this refers to the ratio of the dot diameter of the printed image of ink on the cloth to the diameter of jumping ink drops. The less ink blurs, the smaller the ratio becomes.
  • Geometrical patterns (cross stripes) were printed by the ink-jet printing process, and the sharpness was observed by the naked eye.
  • the saturation (*C) was measured, and the differential saturation ( ⁇ *C) was calculated.
  • the differential saturation denotes the difference in saturation between printed cloths in the case of dyeing cloth bonded with water-insoluble water-absorbing resin and the case of dyeing cloth that is not bonded. A smaller value means the differential saturation is smaller.
  • the lightness (L value) of the printed cloth which was mentioned at the above item 3 was measured by spectrophotometer ("Multi Spectro MSC-2" manufactured by Suga Sikenki Co., Ltd.), and the color depth was measured. A smaller value denotes deeper printing.
  • composition of ink for ink-jet process is a composition of ink for ink-jet process
  • SUMIKARON BRILLIANT BLUE S-BL (disperse dye, Sumitomo Chemical Co., Ltd.) 8 (parts by weight) N-methyl pyrrolidone 10 Ethylene glycol 15 Ion exchange water 67 Total 100 (parts by weight) Viscosity (mPa.s(cps), 25°C): 8 Surface tension (mN/m (dyne/cm), 25°C): 58.2 pH: 7.8
  • a cloth for ink jet printing was prepared by using crosslinked polyacrylic acid (salt) water-insoluble water-absorbing resin ("AQUARIC CA-ML" of NIPPON SHOKUBAI CO., LTD.) instead of starch series crosslinked-type water-insoluble water-absorbing resin as in Example 1.
  • the same ink-jet printing test as in Example 1 was conducted.
  • a cloth for ink-jet printing was prepared by using crosslinked polyacrylic acid (salt) water-insoluble water-absorbing resin ("SANWET IM-5000" of Sanyo Chemical Industries, Ltd.) instead of starch series crosslinked-type water-insoluble water-absorbing resin as in Example 1.
  • SANWET IM-5000 crosslinked polyacrylic acid (salt) water-insoluble water-absorbing resin
  • a cloth for ink-jet printing was prepared by using 1% aqueous solution of gum arabic (Comparative Example 1) and montmorillonite (Comparative Example 2) instead of starch series crosslinked-type water-insoluble water-absorbing resin as in Example 1.
  • the same ink-jet printing test as in Example 1 was conducted.
  • the cloths for ink-jet printing of the invention can provide ink-jet images excellent in diffusion ratio, sharpness, saturation, and build-up.
  • Comparative Examples 1 and 2 the diffusion ratio and sharpness were slightly lower compared with Examples of the invention, and the saturation and build-up were also inferior.
  • composition of ink for ink-jet process is a composition of ink for ink-jet process
  • KAYACION SCARLET P-RN reactive dye, Nippon Kayaku Co., Ltd. 10 (parts by weight) Urea 10 Sodium carbonate 2 Glycerin 15 Ion exchange water 63 Total 100 (parts by weight) Viscosity (cps/25 °C): 10 Surface tension (dyne/cm, 25°C): 55.3 pH: 10.2
  • a cloth for ink-jet printing was prepared by using crosslinked isobutylene-maleic anhydride copolymer water-insoluble water-absorbing resin ("KIGEL 201K” of KURARAY CO., LTD.) instead of starch series crosslinked-type water-insoluble water-absorbing resin of Example 4. The same ink-jet printing test as in Example 4 was conducted.
  • a cloth for ink-jet printing was prepared by using crosslinked carboxylic acid denatured polyvinyl alcohol water-insoluble water-absorbing resin ("IGETAL P", Sumitomo Chemical Company, Ltd.) instead of starch series crosslinked-type water-insoluble water-absorbing resin of Example 4. The same ink-jet printing test as in Example 4 was conducted.
  • a cloth for ink-jet printing was prepared by using 1% aqueous solution of polyvinyl alcohol ("PVA 117" of KURARAY CO., LTD.) (Comparative Example 3) and CaCl2 (Comparative Example 4) instead of starch series crosslinked-type water-insoluble water-absorbing resin of Example 4. The same ink-jet printing test as in Example 4 was conducted.
  • the cloths for ink-jet printing of the invention (Examples 4 to 6) can provide ink-jet images excellent in diffusion ratio, sharpness, saturation, and build-up.
  • the diffusion ratio and sharpness were slightly lower compared with Examples of the invention, and the saturation and build-up were also inferior.
  • the carpet-base material was printed by the ink-jet process under the same conditions as in Example 1.
  • the obtained ink-jet printed carpet-base material was of high quality and had a differential saturation of -2.2, a build-up (L value) of 25.0, and sharpness of rank A.
  • the cloth for ink-jet printing of the invention By using the cloth for ink-jet printing of the invention, it is possible to print by the ink-jet process and achieve excellent sharpness, build-up and reproducibility. Accordingly, by the printing method of the invention, printed goods as valuable as the high grade printed goods of conventional roller printing or screen printing can be obtained.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
EP93110102A 1991-12-27 1993-06-24 Tissu pour impression par jet d'encre et procédé d'impression par jet d'encre Withdrawn EP0631005A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP3359451A JPH0742658B2 (ja) 1991-12-27 1991-12-27 インクジェット染色用布帛および染色方法
EP93110102A EP0631005A1 (fr) 1991-12-27 1993-06-24 Tissu pour impression par jet d'encre et procédé d'impression par jet d'encre
CA002115184A CA2115184A1 (fr) 1991-12-27 1994-02-08 Procede d'impression au jet d'encre et tissu pour impression selon le procede

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP3359451A JPH0742658B2 (ja) 1991-12-27 1991-12-27 インクジェット染色用布帛および染色方法
EP93110102A EP0631005A1 (fr) 1991-12-27 1993-06-24 Tissu pour impression par jet d'encre et procédé d'impression par jet d'encre
CA002115184A CA2115184A1 (fr) 1991-12-27 1994-02-08 Procede d'impression au jet d'encre et tissu pour impression selon le procede

Publications (1)

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EP0631005A1 true EP0631005A1 (fr) 1994-12-28

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EP93110102A Withdrawn EP0631005A1 (fr) 1991-12-27 1993-06-24 Tissu pour impression par jet d'encre et procédé d'impression par jet d'encre

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EP (1) EP0631005A1 (fr)
JP (1) JPH0742658B2 (fr)
CA (1) CA2115184A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0693587A3 (fr) * 1994-07-21 1998-04-15 Canon Kabushiki Kaisha Tissu pour impression par jet d'encre, procédé d'impression par jet d'encre et procédé de production d'imprimés
WO2000003081A1 (fr) * 1998-07-08 2000-01-20 Ciba Specialty Chemicals Holding Inc. Procede d'impression de materiaux fibreux textiles selon le procede d'impression par jet d'encre
WO2000003082A1 (fr) * 1998-07-08 2000-01-20 Ciba Specialty Chemicals Holding Inc. Procede d'impression de materiaux fibreux textiles selon le procede d'impression par jet d'encre
WO2001008895A1 (fr) * 1999-07-30 2001-02-08 Seiko Epson Corporation Procede d'enregistrement comprenant des supports d'enregistrement et d'impression avec deux composes liquides
EP1122068A1 (fr) * 2000-01-28 2001-08-08 Seiren Co., Ltd. Procédé d'impression à jet d'encre et tissu imprimé par jet d'encre
US7040747B2 (en) 1999-07-30 2006-05-09 Seiko Epson Corporation Recording method for printing using two liquids on recording medium
EP3044363A4 (fr) * 2013-09-09 2018-04-04 Ltd Hangzhou Hongying Digital Technology Co. Procédé d'imagerie numérique pour matériau de revêtement de sol

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0742658B2 (ja) * 1991-12-27 1995-05-10 三洋化成工業株式会社 インクジェット染色用布帛および染色方法
JP3384874B2 (ja) * 1994-06-02 2003-03-10 三洋化成工業株式会社 インテリア基材およびプリント方法
JP3265136B2 (ja) * 1994-09-14 2002-03-11 三洋化成工業株式会社 インテリア基材およびプリント方法
US8252715B2 (en) * 2007-03-05 2012-08-28 Nippon Shokubai Co., Ltd. Water-absorbing agent and production method thereof
CN103253021A (zh) * 2012-02-17 2013-08-21 苏州市全佳涂布制品有限公司 一种用于含棉面料的数码印染纸及其制备方法
JP2019023373A (ja) * 2017-07-21 2019-02-14 有限会社フラッグ タナカ 染色物の製造方法及び染色物

Citations (2)

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Publication number Priority date Publication date Assignee Title
JPS6046290A (ja) * 1983-08-24 1985-03-13 Teijin Ltd 記録シ−ト
JPH05179577A (ja) * 1991-12-27 1993-07-20 Sanyo Chem Ind Ltd インクジェット染色用布帛および染色方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05148777A (ja) * 1991-11-26 1993-06-15 Kanebo Ltd 布帛の捺染方法

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
JPS6046290A (ja) * 1983-08-24 1985-03-13 Teijin Ltd 記録シ−ト
JPH05179577A (ja) * 1991-12-27 1993-07-20 Sanyo Chem Ind Ltd インクジェット染色用布帛および染色方法

Non-Patent Citations (2)

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Title
DATABASE WPI Week 8517, Derwent World Patents Index; AN 85-101549 *
DATABASE WPI Week 9333, Derwent World Patents Index; AN 93-262179 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0693587A3 (fr) * 1994-07-21 1998-04-15 Canon Kabushiki Kaisha Tissu pour impression par jet d'encre, procédé d'impression par jet d'encre et procédé de production d'imprimés
US5867197A (en) * 1994-07-21 1999-02-02 Canon Kabushiki Kaisha Ink-jet printing cloth, ink-jet printing process and production process of print
WO2000003081A1 (fr) * 1998-07-08 2000-01-20 Ciba Specialty Chemicals Holding Inc. Procede d'impression de materiaux fibreux textiles selon le procede d'impression par jet d'encre
WO2000003082A1 (fr) * 1998-07-08 2000-01-20 Ciba Specialty Chemicals Holding Inc. Procede d'impression de materiaux fibreux textiles selon le procede d'impression par jet d'encre
US6511535B1 (en) 1998-07-08 2003-01-28 Ciba Specialty Chemicals Corporation Method for printing fibrous textile materials using the ink jet technique
WO2001008895A1 (fr) * 1999-07-30 2001-02-08 Seiko Epson Corporation Procede d'enregistrement comprenant des supports d'enregistrement et d'impression avec deux composes liquides
US7040747B2 (en) 1999-07-30 2006-05-09 Seiko Epson Corporation Recording method for printing using two liquids on recording medium
EP1122068A1 (fr) * 2000-01-28 2001-08-08 Seiren Co., Ltd. Procédé d'impression à jet d'encre et tissu imprimé par jet d'encre
EP3044363A4 (fr) * 2013-09-09 2018-04-04 Ltd Hangzhou Hongying Digital Technology Co. Procédé d'imagerie numérique pour matériau de revêtement de sol
US10052889B2 (en) 2013-09-09 2018-08-21 Hangzhou Hongying Digital Technology Co., Ltd. Digital imaging process for flooring material

Also Published As

Publication number Publication date
JPH05179577A (ja) 1993-07-20
JPH0742658B2 (ja) 1995-05-10
CA2115184A1 (fr) 1995-08-09

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