Classifications

• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
  • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
  • C07C219/04—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
  • C07C219/06—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/03—Non-macromolecular organic compounds
  • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
  • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/03—Non-macromolecular organic compounds
  • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
  • D21H17/07—Nitrogen-containing compounds
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/03—Non-macromolecular organic compounds
  • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
  • D21H17/14—Carboxylic acids; Derivatives thereof

Definitions

• This invention relates to tissue paper webs. More particularly, it relates to soft, absorbent tissue paper webs which can be used in sanitary tissue, facial tissue products, and paper napkins.
• Paper webs or sheets sometimes called tissue or paper tissue webs or sheets, find extensive use in modern society. Such items as paper towels, napkins, and facial tissues are staple items of commerce. It has long been recognized that three important physical attributes of these products are their softness; their absorbency, particularly their absorbency for aqueous systems; and their strength, particularly their strength when wet. Research and development efforts have been directed to the improvement of each of these attributes without deleteriously affecting the others as well as to the improvement of two or three attributes simultaneously.
• Absorbency is the measure of the ability of a product, and its constituent webs, to absorb quantities of liquid, particularly aqueous solutions or dispersions. Overall absorbency as perceived by the human consumer is generally considered to be a combination of the total quantity of liquid a given mass of tissue paper will absorb at saturation as well as the rate at which the mass absorbs the liquid.
• Chemical debonding agents have been disclosed in various references such as U.S. Pat. No. 3,554,862, issued to Hervey et al . on January 12, 197K These materials include quaternary ammonium salts such as trimethylcocoammonium chloride, tri ethyloleylammonium chloride, di(hydrogenated-tallow)dimethylammonium chloride and trimethylstearyl- am ⁇ onium chloride.
• each R substituent is a Cj-C ⁇ alky! or hydroxyalkyl group, or mixtures thereof;
• R- is
• R 2 is a
• tissue paper web, paper web, web, and paper sheet all refer to sheets of paper made by a process comprising the steps of forming an aqueous papermaking furnish, depositing this furnish on a foraminous surface, such as a Fourdrinier wire, and removing the water from the furnish as by gravity or vacuum-assisted drainage, with or without pressing, and by evaporation.
• the first step in the process of this invention is the forming of an aqueous papermaking furnish.
• the furnish comprises papermaking fibers (hereinafter sometimes referred to as wood pulp), at least one wet strength resin, at least one quaternary ammonium and at least one wetting agent, all of which will be hereinafter described.
• Wood pulp in all its varieties will normally comprise the papermaking fibers used in this invention. However, other cellulosic fibrous pulps, such as cotton 1inters, bagasse, rayon, etc., can be used and none are disclaimed.
• Wood pulps useful herein include chemical pulps such as Kraft, sulfite and sulfate pulps as well as mechanical pulps including for example, ground wood, thermomechanica pulps and chemically modified thermomechanical pulp (CTMP). Pulp derived from both deciduous (e.g., Eucalyptus pulp) and coniferous tree (e.g., spruce) can be used.
• the papermaking fibers used in this invention comprise Kraft pulp derive from northern softwoods. Wet Strength Resins
• Wet strength resins are generally believed to undergo cross-linking or other curing reactions after they have been deposit on, within, or among the papermaking fibers. Cross-linking or curi does not normally occur so long as substantial amounts of water a present.
• temporary wet strength resin refe to a resin that allows the tissue paper, when placed in an aqueo medium, to lose a majority of its initial wet strength in a short peri of time, e.g., two minutes or less, more preferably, 30 seconds or less
• X is —0—, —NCH3—, and R is a substituted or unsubstitute aliphatic groups
• Yi and Y2 are independently —H, —CH3 or halogen
• W is a nonnucleophilic, water-soluble nitrogen heterocycli moiety
• C is a cationic monomeric unit
• the mole percent of a i from about 30% to about 70%
• the mole percent of b is from about 30 to about 70%
• the mole percent of c is from about 1% to abou 40%
• said polymer has an average molecular weight of betwee about 30,000 and about 200,000.
• R 1 is (CH2)2"0-C-R Z or a long chain C13-C19 hydrocarb substituent, preferably Ci6-Cj8 alkyl, most preferably straight-chain C alkyl
• R 2 is a long chain C13-C21 hydrocarbyl substituent, preferab C13-C17 alkyl, most preferably C15 straight chain alkyl.
• the counteri X" is not critical herein, and can be any softener-compatible anion, su as an halide (e.g., chloride or bromide), or methylsulfate.
• Preferabl X" is methyl sulfate or chloride.
• R, R 1 and R may optionally be substituted with vario groups such as alkoxyl, hydroxyl, or can be branched, but such materia are not preferred herein.
• the preferred compounds can be considered be mono- and di- ester variations of the well-known dialkyldimeth ammonium salts such as ditallowdi ethylammonium chlorid ditallowdimethylammonium methylsulfate, di(hydrogenated tallow) methylammonium chloride, with the di-ester variations di(hydrogenatedtallow)dimethylammonium methylsulfate or di(hydrogenat tallow)dimethylammonium chloride being preferred.
• the purpose of this example is to illustrate one method that can be used to make soft, absorbent and high temporary wet strength tissue fibrous structure treated with a mixture of Diester Dihydrogenated Tallow Dimethyl Ammonium Chloride (DEDTDMAC) and a linear alkylphenoxy ⁇ poly(ethyleneoxy) alcohol (Igepal RC-520) in the presence of a temporary wet strength resin in accordance with the present invention.
• DEDTDMAC Diester Dihydrogenated Tallow Dimethyl Ammonium Chloride
• Igepal RC-520 linear alkylphenoxy ⁇ poly(ethyleneoxy) alcohol

Landscapes

• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Paper (AREA)
• Biological Depolymerization Polymers (AREA)
• Polyamides (AREA)
• Sanitary Thin Papers (AREA)
• Absorbent Articles And Supports Therefor (AREA)

Applications Claiming Priority (3)

Publications (2)

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Family Applications (1)

Country Status (16)

Families Citing this family (106)

Family Cites Families (33)

• 1992
  • 1992-04-09 US US07/865,596 patent/US5262007A/en not_active Expired - Lifetime
• 1993
  • 1993-03-29 DE DE69312919T patent/DE69312919T2/de not_active Expired - Lifetime
  • 1993-03-29 JP JP51836193A patent/JP3193052B2/ja not_active Expired - Fee Related
  • 1993-03-29 FI FI944721A patent/FI944721A7/fi unknown
  • 1993-03-29 EP EP93908619A patent/EP0633963B1/de not_active Expired - Lifetime
  • 1993-03-29 AT AT93908619T patent/ATE156543T1/de not_active IP Right Cessation
  • 1993-03-29 WO PCT/US1993/002876 patent/WO1993021383A1/en not_active Ceased
  • 1993-03-29 DK DK93908619.5T patent/DK0633963T3/da active
  • 1993-03-29 ES ES93908619T patent/ES2107017T3/es not_active Expired - Lifetime
  • 1993-03-29 AU AU39378/93A patent/AU673521B2/en not_active Ceased
  • 1993-03-29 BR BR9306234A patent/BR9306234A/pt not_active IP Right Cessation
  • 1993-03-29 NZ NZ251623A patent/NZ251623A/en unknown
  • 1993-03-29 CA CA002133067A patent/CA2133067C/en not_active Expired - Lifetime
  • 1993-03-29 KR KR1019940703569A patent/KR100256982B1/ko not_active Expired - Fee Related
• 1994
  • 1994-10-07 NO NO943778A patent/NO302378B1/no unknown
• 1997
  • 1997-08-07 GR GR970401885T patent/GR3024374T3/el unknown

Non-Patent Citations (1)

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