EP0647993B1 - Balai en charbon et son procédé d'imprégnation - Google Patents
Balai en charbon et son procédé d'imprégnation Download PDFInfo
- Publication number
- EP0647993B1 EP0647993B1 EP94113830A EP94113830A EP0647993B1 EP 0647993 B1 EP0647993 B1 EP 0647993B1 EP 94113830 A EP94113830 A EP 94113830A EP 94113830 A EP94113830 A EP 94113830A EP 0647993 B1 EP0647993 B1 EP 0647993B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- carbon brush
- carbon
- polyether
- siloxane
- impregnating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims description 10
- 230000008569 process Effects 0.000 title claims description 6
- 238000005470 impregnation Methods 0.000 title description 11
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 12
- 229920000570 polyether Polymers 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 2
- -1 Polymethylsiloxan Polymers 0.000 description 12
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000003245 coal Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 240000007124 Brassica oleracea Species 0.000 description 1
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 1
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- IIGAELMXVLEZPM-GRVYQHKQSA-L cobalt(2+);(9z,12z)-octadeca-9,12-dienoate Chemical compound [Co+2].CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O.CCCCC\C=C/C\C=C/CCCCCCCC([O-])=O IIGAELMXVLEZPM-GRVYQHKQSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 231100000206 health hazard Toxicity 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000001367 organochlorosilanes Chemical class 0.000 description 1
- 125000005375 organosiloxane group Chemical class 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01R—ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS
- H01R39/00—Rotary current collectors, distributors or interrupters
- H01R39/02—Details for dynamo electric machines
- H01R39/18—Contacts for co-operation with commutator or slip-ring, e.g. contact brush
- H01R39/20—Contacts for co-operation with commutator or slip-ring, e.g. contact brush characterised by the material thereof
- H01R39/22—Contacts for co-operation with commutator or slip-ring, e.g. contact brush characterised by the material thereof incorporating lubricating or polishing ingredient
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/50—Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
Definitions
- the invention relates to a carbon brush with a polyethersiloxane or Polymethylsiloxan is impregnated as an impregnating agent, in particular carbon brush for heavily used tools.
- the invention further relates to a method for Impregnating a carbon brush or a carbon bar.
- Impregnated carbon brush for electrical machines an impregnating agent containing grease, wax or oil as a lubricant.
- the Impregnants are either liquid or solid at normal temperature and are in an impregnation bath in which the carbon brush is impregnated to a temperature brought equal to or above the melting point of the lubricant.
- Petroleum jelly When used as an impregnating agent, the impregnating temperature is raised to approximately 100 ° C set. After the impregnation process, the carbon brush is at a temperature aftertreated, which is at least as high as the maximum operating temperature.
- CH 262 391 describes a carbon brush, its mechanical properties should be improved in that an impregnation with e.g. a polysiloxane he follows. As with the state of the art already dealt with, this becomes Impregnant introduced under pressure into the pores of the carbon material. Herewith is however, the impregnation was not completed. Rather, it takes place at Temperatures e.g. in the range between 100 ° C and 150 ° C a polymerization of Impregnating agent to improve the strength of the carbon brush.
- a carbon brush for electrical machines contains chlorine-containing polymers which are formed by crosslinking at least one compound the group of chlorinated organochlorosilanes and chlorinated organosiloxanes are formed.
- An impregnated carbon brush is described in DE 26 09 834 C3, which is used as an impregnating agent a non-melting fat, a non-melting wax or a non-flowing Contains oil, the fat, wax or oil of the impregnating agent with a Gelling agent from montmorillonite scales, the surfaces of which are made with long-chain hydrocarbons are coated, intimately mixed and thus in the non-melting or not flowing, harder and abrasion-resistant condition. The impregnation takes place according to the vacuum pressure method.
- Impregnated carbon brushes according to DE 26 09 834 C3 have proven themselves and show advantages in use in terms of good commutation, less spark interference, long service life and possible application with high performance. Desirable it would be, however, if there were other advantages related to brush wear, collector wear or the collector temperatures that occur during operation or the running time the machine would be given, especially if it is used in machines with temperature-sensitive commutators that are asbestos-free.
- the present invention addresses the problem of having a carbon brush is impregnated with an impregnating agent, especially a cabbage brush for heavily used items Tools and a method for impregnating a carbon brush or one Coal bar to develop so that further improvements in mechanical running behavior the carbon brush can be achieved and in particular an unproblematic one Use with asbestos-free commutators is possible.
- the impregnating agent used should be environmentally friendly.
- Appropriate carbon brushes impregnated according to the invention are used, so surprisingly managed to significantly lower the commutator temperature and an increase in the service life and a significant reduction in the commutator attack be determined.
- Corresponding carbon brushes are therefore particularly suitable for suitable for use in machines that have asbestos-free commutators.
- polymethylsiloxane by long-chain alkyl and / or Alkylaryl residues is modified.
- a reduction in brush collector wear and a reduction in Collector temperature could be reached especially when the impregnating agent the carbon brush is approximately 0.5 to 15 percent by weight.
- the problem is solved in that the carbon brush or Carbon bars in a polyethersiloxane or polymethylsiloxane as an impregnating agent containing emulsion is impregnated, the polyether siloxane and the polymethylsiloxane have the structures defined in claim 1.
- Impregnation agent does not have to be done using the vacuum pressure method, but that the carbon brush or the carbon bar only lasts for a certain period of time immerse the emulsion. The period is preferably between 0.5 and 5 hours, especially 1.5 to 2.5 hours. Then the carbon brush or the coal bar drained and then preferably by spinning at a Temperature between room temperature (20 ° C) and 90 ° C, especially around 80 ° C dried. The carbon brush is then immediately ready for use or the carbon bar could be machined directly to a carbon brush of the desired geometry.
- water is used as an emulsifier and an environmentally compatible one as an impregnating agent Substance used that can not be a health hazard. Furthermore, it is not necessary for the carbon brush to be rinsed hot after impregnation will, so that no unwanted vapors occur.
- a polymethylsiloxane modified by long-chain alkyl radicals was mixed with water stirred, the weight fraction of the impregnating agent was 5%. Homogenizing the emulsion was prepared at room temperature. After making the The carbon brush was then emulsified over a period of about 2 hours the emulsion heated to 80 ° C and then pulled out to the To drain the emulsion. The carbon brush was then spun dry at a temperature of 80 ° C without rinsing.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Motor Or Generator Current Collectors (AREA)
- Carbon And Carbon Compounds (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Pens And Brushes (AREA)
- Inert Electrodes (AREA)
- Ceramic Products (AREA)
Claims (7)
- Balai en charbon comportant, comme agent d'imprégnation, un polyéthersiloxane ou un polyméthylsiloxane, notamment balai en charbon pour des outils fortement sollicités,
caractérisé en ce que - Balai en charbon selon la revendication 1,
caractérisé en ce que
le polyméthylsiloxane est modifié par un radical à longue chaíne alkyl et/ou alkylaryl. - Balai en charbon selon au moins l'une des revendications précédentes,
caractérisé en ce que
le balai de charbon imprégné contient entre 0,5 et 15 % en poids d'agent d'imprégnation. - Procédé d'imprégnation d'un balai en charbon ou d'un verrou en charbon,
caractérisé en ce que
le balai en charbon ou le verrou en charbon est imprégné dans une émulsion contenant du polyéthersiloxane ou du polyméthylsiloxane comme agent d'imprégnation, le polyéthersiloxane et le polyméthylsiloxane ayant les structures définies dans la revendication 1. - Procédé selon la revendication 4,
caractérisé en ce que
l'émulsion contient de l'eau comme agent émulsifiant. - Procédé selon au moins l'une des revendications précédentes,
caractérisé en ce que
le balai en charbon ou le verrou en charbon est plongé dans l'émulsion contenant d'agent d'imprégnation pendant une durée (t), de préférence telle que 0,5 < t < 5 h à une température d'environ 50°C jusqu'à 90°C, de préférence de l'ordre de 80°C puis on enlève l'émulsion en excédent en laissant s'égoutter et, enfin, on sèche à une température (T), de préférence telle que 50° < T < 90°C. - Procédé selon au moins l'une des revendications précédentes,
caractérisé en ce que
le balai ou le verrou en charbon est centrifugé pendant le séchage.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4330547A DE4330547C2 (de) | 1993-09-09 | 1993-09-09 | Kohlebürste sowie Verfahren zum Imprägnieren einer solchen |
| DE4330547 | 1993-09-09 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0647993A2 EP0647993A2 (fr) | 1995-04-12 |
| EP0647993A3 EP0647993A3 (fr) | 1995-12-27 |
| EP0647993B1 true EP0647993B1 (fr) | 2000-03-15 |
Family
ID=6497260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94113830A Expired - Lifetime EP0647993B1 (fr) | 1993-09-09 | 1994-09-03 | Balai en charbon et son procédé d'imprégnation |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6068926A (fr) |
| EP (1) | EP0647993B1 (fr) |
| AT (1) | ATE190760T1 (fr) |
| DE (2) | DE4330547C2 (fr) |
| ES (1) | ES2144021T3 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10209199A1 (de) * | 2002-03-04 | 2003-10-02 | Schunk Kohlenstofftechnik Gmbh | Verfahren zur Herstellung einer Mehrschicht-Kohlebürste |
| CN100388600C (zh) * | 2003-09-04 | 2008-05-14 | 东炭化工株式会社 | 电动机械用碳刷 |
| JP4618484B2 (ja) * | 2004-08-26 | 2011-01-26 | アイシン精機株式会社 | 金属黒鉛質ブラシ及び金属黒鉛質ブラシを備えたモータ |
| DE102006050817A1 (de) * | 2006-10-27 | 2008-04-30 | Robert Bosch Gmbh | Elektrogerät sowie Zubehörteil für ein Elektrogerät |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US949988A (en) * | 1904-12-02 | 1910-02-22 | Gen Electric | Treated carbon and the method of producing it. |
| CH262391A (fr) * | 1946-02-09 | 1949-06-30 | Lorraine Carbone | Article contenant du carbone tel que, par exemple, pièce de machine et dispositif électrique, pièce de frein, etc. et procédé pour le fabriquer. |
| US2859139A (en) * | 1954-12-07 | 1958-11-04 | Union Carbide Corp | Method of making a silica containing carbon brush and resulting article |
| FR1137952A (fr) * | 1954-12-07 | 1957-06-06 | Union Carbide & Carbon Corp | Balai de contact électrique |
| US3088964A (en) * | 1958-09-29 | 1963-05-07 | Dow Corning | 2-phenylpropyl organosiloxanes |
| US3751294A (en) * | 1971-06-09 | 1973-08-07 | G Fridman | Brushes for electrical apparatus and methods for their manufacture |
| DE2609834C3 (de) * | 1976-03-10 | 1981-01-08 | Schunk & Ebe Gmbh, 6301 Heuchelheim | Imprägnierte Kohlebürste für elektrische Maschinen und Verfahren zur Herstellung der Kohlebürste |
| US4420409A (en) * | 1981-12-11 | 1983-12-13 | Toray Silicone Company, Ltd. | Hydraulic system and hydraulic fluid compositions comprising siloxane-oxyalkylene copolymers |
| DE3431533A1 (de) * | 1984-08-28 | 1986-03-06 | Ringsdorff-Werke GmbH, 5300 Bonn | Kohlebuerste fuer elektrische maschinen |
-
1993
- 1993-09-09 DE DE4330547A patent/DE4330547C2/de not_active Expired - Fee Related
-
1994
- 1994-09-03 EP EP94113830A patent/EP0647993B1/fr not_active Expired - Lifetime
- 1994-09-03 ES ES94113830T patent/ES2144021T3/es not_active Expired - Lifetime
- 1994-09-03 DE DE59409203T patent/DE59409203D1/de not_active Expired - Lifetime
- 1994-09-03 AT AT94113830T patent/ATE190760T1/de not_active IP Right Cessation
-
1997
- 1997-07-14 US US08/892,281 patent/US6068926A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2144021T3 (es) | 2000-06-01 |
| ATE190760T1 (de) | 2000-04-15 |
| EP0647993A3 (fr) | 1995-12-27 |
| DE4330547A1 (de) | 1995-03-16 |
| EP0647993A2 (fr) | 1995-04-12 |
| DE4330547C2 (de) | 2002-01-24 |
| DE59409203D1 (de) | 2000-04-20 |
| US6068926A (en) | 2000-05-30 |
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