EP0677624A2 - Lès d'étanchéité en matière synthétique - Google Patents

Lès d'étanchéité en matière synthétique Download PDF

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Publication number
EP0677624A2
EP0677624A2 EP95108745A EP95108745A EP0677624A2 EP 0677624 A2 EP0677624 A2 EP 0677624A2 EP 95108745 A EP95108745 A EP 95108745A EP 95108745 A EP95108745 A EP 95108745A EP 0677624 A2 EP0677624 A2 EP 0677624A2
Authority
EP
European Patent Office
Prior art keywords
weight
plastic sheets
plastic
sheets according
web
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP95108745A
Other languages
German (de)
English (en)
Other versions
EP0677624A3 (fr
Inventor
Hans Georg Karl Dietschi
Jean-Luc Claude Schläpfer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sarna Patent und Lizenz AG
Original Assignee
Sarna Patent und Lizenz AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sarna Patent und Lizenz AG filed Critical Sarna Patent und Lizenz AG
Priority to EP95108745A priority Critical patent/EP0677624A3/fr
Publication of EP0677624A2 publication Critical patent/EP0677624A2/fr
Publication of EP0677624A3 publication Critical patent/EP0677624A3/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/15Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
    • B32B37/153Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state at least one layer is extruded and immediately laminated while in semi-molten state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/026Knitted fabric
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethylene-propylene or ethylene-propylene-diene copolymers
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/66Sealings
    • E04B1/665Sheets or foils impervious to water and water vapor
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D5/00Roof covering by making use of flexible material, e.g. supplied in roll form
    • E04D5/10Roof covering by making use of flexible material, e.g. supplied in roll form by making use of compounded or laminated materials, e.g. metal foils or plastic films coated with bitumen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00Resin or rubber layer containing a blend of at least two different polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/718Weight, e.g. weight per square meter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Definitions

  • the present invention relates to plastic sheets, processes for their production and their use for sealing buildings.
  • EP 0 428 851 describes plastic sealing sheets which are made up of flexible polyolefins.
  • plastic sealing sheets At elevated temperatures, for example in summer when there is strong solar radiation, these plastic sealing sheets have the disadvantage that they can be damaged, in particular perforated, during extreme mechanical loads during processing.
  • plastic sealing sheets also have a relatively large linear coefficient of thermal expansion, which, depending on the temperature differences, for example day / night, summer / winter, can lead to the formation of waves in the surface of the plastic sealing sheets when the plastic sealing sheets are laid.
  • EP 0 428 851 also describes the further prior art, which with this reference is also considered to be disclosed herein.
  • a new material is to be made available which has the requirements mentioned in EP 0 428 851 and additionally has improved mechanical properties, in particular in the heat, and a reduced linear mechanical expansion coefficient.
  • the new plastic sheets with reactor blends which are made up of inexpensive starting materials (monomers), are to be produced. These raw materials should also have a more favorable energy and eco-balance.
  • the new plastic sheets are said to have an even better price / performance ratio than EP 0 428 851.
  • reactor blends selected from the group consisting of polypropylene copolymers and ethylene- ⁇ -olefin copolymers can be used for the production of plastic webs with an upper layer, a lower layer and an intermediate substrate, the upper layer and penetrate the underlayer in such a way that they are welded together.
  • connection and finishing work such as borders, corner formations, roof edge closures, etc.
  • the thickness of the web can be reduced, which leads to an improved price / performance ratio and a saving in raw materials (resources).
  • the upper layer in multiple layers. Only the top part of the top layer can be pigmented, and the rest of the top layer can contain a less expensive filler.
  • This plastic sealing membrane has the following properties:
  • a premix was made from the following components for the bottom layer in a vertical universal mixer: Component sub-layer % By weight Polypropylene copolymer (Hifax CA 10 A, Himont) 92.0 Pigments: titanium dioxide, soot 1.0 Stabilizers: light stabilizers, antioxidants 0.2 Filler: chalk 6.8
  • This premix was plasticized in a co-rotating twin-screw extruder, mixed homogeneously and extruded through a slot die (working width 0.3 m).
  • the material was dosed into the extruder using a differential dosing scale.
  • the temperature of the sheet-like mass emerging from the slot die was 240 ° C to 250 ° C.
  • the output was 14 kg per hour.
  • This web-like mass was introduced from above into the lower nip of a 3-roll calender.
  • the carrier material a glass fleece with a basis weight, ran from below over the lower roller of 50 g / m2, at a speed of 0.9 m / minute.
  • a material template was used.
  • the temperature of the lower roller was 120 ° C, that of the middle roller 90 ° C.
  • the thickness of the web was set at 1.0 mm over the gap between the lower and middle roll.
  • the web was then cooled to room temperature via cooling rolls and wound up.
  • Component top layer % By weight Polypropylene copolymer (Hifax CA 10 A, Himont) 92.0 Pigments: titanium dioxide, soot 3.5 Stabilizers: light stabilizers, antioxidants 1.0 Filler: chalk 3.5
  • the second layer with the components for the top layer was inseparably welded to the web produced in the first step.
  • the premixing, plasticizing, homogenizing and extruding were carried out in the same manner as described above.
  • the sheet-like mass emerging from the slot die was placed in the lower nip of a 3-roll smoothing unit introduced.
  • the web from the first operation ran in from below via the lower roller, the carrier material being directed to the side with the material template.
  • the temperature of the lower roller was 90 ° C, that of the middle roller 90 ° C.
  • the thickness of the web was set at 1.8 mm over the gap of the lower and middle roll. This web was then cooled to room temperature via chill rolls, the edges were cut and the web was rolled up.
  • the web thus obtained had the following properties:
  • Example 2 (reactor blend, terpolymer)
  • a premix was made from the following components for the bottom layer in a vertical universal mixer:
  • This premix was plasticized in a co-rotating twin-screw extruder, mixed homogeneously and extruded through a slot die (working width 0.3 m).
  • the material was dosed into the extruder using a differential dosing scale.
  • the temperature of the sheet-like mass emerging from the slot die was 230 ° C.
  • the output was 16 kg per hour.
  • This web-like mass was introduced from above into the lower nip of a 3-roll calender.
  • the base material a glass fleece with a basis weight of 50 g / m2, ran in from the bottom at a speed of 1 m / minute.
  • Component top layer % By weight Polypropylene copolymer (Hifax CA 60 A, Himont) 75.0 Ethylene-propylene-diene terpolymer with 72% by weight of ethylene, 22% by weight of propylene, 6% by weight of diene 17.0 Pigments: titanium dioxide, soot 3.5 Stabilizers: light stabilizers, antioxidants 1.0 Filler: chalk 3.5
  • the second layer with the components for the top layer was inseparably welded to the web produced in the first step.
  • the premixing, plasticizing, homogenizing and extruding were carried out in the same manner as described above.
  • the web-like mass emerging from the slot die was introduced into the lower nip of a 3-roll smoothing unit.
  • the web from the first operation ran in from below via the lower roller, the carrier material being directed to the side with the material template.
  • the temperature of the lower roller was 70 ° C, that of the middle roller 70 ° C.
  • the thickness of the web was set at 1.8 mm over the gap of the lower and middle roll. This web was then cooled to room temperature via chill rolls, the edges were cut and the web was rolled up.
  • the web thus obtained had the following properties:
  • a premix was made from the following components for the bottom layer in a vertical universal mixer: Component sub-layer % By weight Polypropylene copolymer (Hifax CA 10 A, Himont) 57.0 Polypropylene copolymer (Hifax CA 40 A, Himont) 18.0 Ethylene-propylene-diene terpolymer with 72% by weight of ethylene, 22% by weight of propylene, 6% by weight of diene 17.0 Pigments: titanium dioxide, soot 1.0 Stabilizers: light stabilizers, antioxidants 0.2 Filler: chalk 6.8
  • This premix was plasticized in a co-rotating twin-screw extruder and mixed homogeneously and extruded via a slot die (working width 0.3 m).
  • the material was dosed into the extruder using a differential dosing scale.
  • the temperature of the sheet-like mass emerging from the slot die was 240 ° C to 250 ° C.
  • the output was 14 kg per hour.
  • This web-like mass was introduced from above into the lower nip of a 3-roll calender.
  • the carrier material a glass fleece with a basis weight of 50 g / m2, ran in from below at a speed of 0.9 m / minute.
  • a material template was used.
  • the temperature of the lower roller was 120 ° C, that of the middle roller 90 ° C.
  • the thickness of the web was set at 1.0 mm over the gap between the lower and middle roll. The web was then cooled to room temperature via cooling rolls and wound up.
  • the second layer with the components for the top layer was inseparably welded to the web produced in the first step.
  • the premixing, plasticizing, homogenizing and extruding were carried out in the same manner as described above.
  • the web-like mass emerging from the slot die was introduced into the lower nip of a 3-roll smoothing unit.
  • the web from the first operation ran in from below via the lower roller, the carrier material being directed to the side with the material template.
  • the temperature of the lower roller was 90 ° C, that of the middle roller 90 ° C.
  • the thickness of the web was set at 1.8 mm over the gap of the lower and middle roll. This web was then cooled to room temperature via chill rolls, the edges were cut and the web was rolled up.
  • the web thus obtained had the following properties:

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Architecture (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP95108745A 1995-06-07 1995-06-07 Feuilles d'étanchéité en matière synthétique. Withdrawn EP0677624A3 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP95108745A EP0677624A3 (fr) 1995-06-07 1995-06-07 Feuilles d'étanchéité en matière synthétique.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP95108745A EP0677624A3 (fr) 1995-06-07 1995-06-07 Feuilles d'étanchéité en matière synthétique.

Publications (2)

Publication Number Publication Date
EP0677624A2 true EP0677624A2 (fr) 1995-10-18
EP0677624A3 EP0677624A3 (fr) 1996-11-13

Family

ID=8219336

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95108745A Withdrawn EP0677624A3 (fr) 1995-06-07 1995-06-07 Feuilles d'étanchéité en matière synthétique.

Country Status (1)

Country Link
EP (1) EP0677624A3 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0821098A3 (fr) * 1996-07-26 1998-05-13 Kolon Industries Inc. Procédé de fabrication de bâches en oléfine

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0428851A1 (fr) 1989-10-02 1991-05-29 Sarna Patent- Und Lizenz-Ag Lés d'étanchéité

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2628741C3 (de) * 1976-06-25 1979-02-15 Fa. Carl Freudenberg, 6940 Weinheim Gegen Wassereinwirkung und Witterungseinflüsse widerstandsfähige Abdeckung und Verfahren zum Verlegen einer solchen Abdeckung
DE3150021C1 (de) * 1981-12-17 1987-11-12 Dynamit Nobel Ag, 5210 Troisdorf Mehrschichtige Dichtungsbahn aus elastomeren Kunststoffen und einer Verstaerkungseinlage
IT1243430B (it) * 1990-09-28 1994-06-10 Himont Inc Composizioni di polimeri cristallini del propilene aventi bassa temperatura
IT1250731B (it) * 1991-07-31 1995-04-21 Himont Inc Procedimento per la preparazione di polietilene lineare a bassa densita'
DE69311782T2 (de) * 1992-07-27 1997-11-13 Bridgestone Corp Polymerzusammensetzungen für verschweissbare Dachbahnen und Verfahren zur Dachabdeckung
IT1256663B (it) * 1992-12-15 1995-12-12 Himont Inc Composizioni polipropileniche aventi buona trasparenza e migliorata resistenza all'urto.

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0428851A1 (fr) 1989-10-02 1991-05-29 Sarna Patent- Und Lizenz-Ag Lés d'étanchéité

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0821098A3 (fr) * 1996-07-26 1998-05-13 Kolon Industries Inc. Procédé de fabrication de bâches en oléfine

Also Published As

Publication number Publication date
EP0677624A3 (fr) 1996-11-13

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