EP0691397A2 - Antimikrobieller Reiniger für harte Oberflächen - Google Patents

Antimikrobieller Reiniger für harte Oberflächen Download PDF

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Publication number
EP0691397A2
EP0691397A2 EP95304637A EP95304637A EP0691397A2 EP 0691397 A2 EP0691397 A2 EP 0691397A2 EP 95304637 A EP95304637 A EP 95304637A EP 95304637 A EP95304637 A EP 95304637A EP 0691397 A2 EP0691397 A2 EP 0691397A2
Authority
EP
European Patent Office
Prior art keywords
hard surface
cleaner
effective amount
surface cleaner
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP95304637A
Other languages
English (en)
French (fr)
Other versions
EP0691397A3 (de
EP0691397B1 (de
Inventor
Boli Zhou
Anna G. Stanislowski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Clorox Co
Original Assignee
Clorox Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clorox Co filed Critical Clorox Co
Publication of EP0691397A2 publication Critical patent/EP0691397A2/de
Publication of EP0691397A3 publication Critical patent/EP0691397A3/de
Application granted granted Critical
Publication of EP0691397B1 publication Critical patent/EP0691397B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Definitions

  • the invention relates to a non-rinse, isotropic, antimicrobial hard surface cleaner especially adapted to be used on glossy or smooth, hard surfaces, which removes soils deposited thereon and disinfects same, while significantly reducing the amount of residue caused by unremoved soil, cleaner, or a combination thereof.
  • quaternary ammonium based liquid hard surface cleaners are in common use, typically as bathroom cleaners. Certain quaternary ammonium compounds can be effective as antimicrobial agents in small dosages in these cleaners. However, these types of cleaners typically are not effective on glossy, hard surfaces because they tend to leave a visible residue.
  • G.B. 2,160,887 describes a cleaning system in which a combination of nonionic and anionic surfactants (including an alkanolamine salt alkyl sulfate) is contended to enhance cleaning efficacy.
  • WO 91/11505 describes a glass cleaner containing a zwitterionic surfactant, monoethanolamine and/or beta-aminoalkanols as solvents/buffers for assertedly improving cleaning and reducing filming spotting.
  • the prior art hard surface cleaners fail to achieve the desired goals of reduced residue (streaking and/or filming) and antimicrobial action.
  • the invention provides an aqueous, antimicrobial hard surface cleaner with significantly improved residue removal and substantially reduced filming/streaking, said cleaner comprising:
  • the invention further comprises a method of cleaning soils from hard surfaces by applying said inventive cleaner to said soil, and removing both from said surface, while disinfecting said surface.
  • the invention is an improved cleaning, substantially non-streaking/filming, antimicrobial hard surface cleaner especially adapted to be used on glossy or smooth, hard surfaces.
  • the cleaner benefits from the presence of a quaternary ammonium surfactant which contributes unexpectedly to both antimicrobial efficacy as well as to the complete removal of soils and the cleaner from the surface being cleaned.
  • the cleaner itself has the following ingredients:
  • adjuncts in small amounts such as fragrance, dye and the like can be included to provide desirable attributes of such adjuncts.
  • the solvent is selected from C1 ⁇ 6 alkanol, C3 ⁇ 24 alkylene glycol ether, and mixtures thereof.
  • the alkanol can be selected from methanol, ethanol, n-propanol, isopropanol, butanol, pentanol, hexanol, their various positional isomers, and mixtures of the foregoing.
  • isopropanol usually in conjunction with a glycol ether.
  • the diols such as methylene, ethylene, propylene and butylene glycols, and mixtures thereof.
  • the alkylene glycol ether solvents can include ethylene glycol monobutyl ether, ethylene glycol monopropyl ether, propylene glycol n-propyl ether, propylene glycol monobutyl ether, dipropylene glycol methyl ether, and mixtures thereof.
  • Two preferred glycol ethers are ethylene glycol, monobutyl ether, also known as butoxyethanol, sold as butyl Cellosolve by Union Carbide, and propylene glycol n-propyl ether, available from a variety of sources..
  • Another preferred alkylene glycol ether is propylene glycol, t-butyl ether, which is commercially sold as Arcosolve PTB, by Arco Chemical Co. It has the structure: Other suppliers of preferred solvents include Union Carbide. If mixtures of solvents are used. the amounts and ratios of such solvents used are important to determine the optimum cleaning and streak/film performances of the inventive cleaner. It is preferred to limit the total amount of solvent to no more than 50%, more preferably no more than 25%, and most preferably, no more than 15%, of the cleaner. A preferred range is about 1-15%.
  • the surfactant is selected from nonionic and amphoteric surfactants, and mixtures thereof.
  • the nonionic surfactants are selected from alkoxylated alcohols, alkoxylated ether phenols, and other surfactants often referred to as semi-polar nonionics, such as the trialkyl amine oxides.
  • the alkoxylated alcohols include ethoxylated, and ethoxylated and propoxylated C6 ⁇ 16 alcohols, with about 2-10 moles of ethylene oxide, or 1-10 and 1-10 moles of ethylene and propylene oxide per mole of alcohol, respectively.
  • the semi-polar amine oxides are especially preferred, although, for the invention, a mixture of nonionic and amine oxide surfactants are most preferred.
  • R is C6 ⁇ 24 alkyl
  • R' and R'' are both C1 ⁇ 4 alkyl, although R' and R'' do not have to be equal.
  • These amine oxides can also be ethoxylated or propoxylated.
  • the preferred amine oxide is lauryl amine oxide, such as Barlox 12, from Lonza Chemical Company.
  • the ratio of amine oxide:EDTA must be carefully controlled in the invention.
  • the amount of amine oxide must exceed the amount of EDTA, more preferably exceeds 3:1 and most preferably is about 4:1 or greater.
  • the amphoteric surfactant is typically an alkylbetaine or a sulfobetaine.
  • alkylamidoalkyldialkylbetaines These have the structure: wherein R' is C6 ⁇ 20 alkyl, R and R3 are both C1 ⁇ 4 alkyl, although R and R3 do not have to be equal, and m can be 1-5, preferably 3, and n can be 1-5, preferably 1.
  • These alkylbetaines can also be ethoxylated or propoxylated.
  • the preferred alkylbetaine is a cocoamidopropyldimethyl betaine called Lonzaine CO, available from Lonza Chemical Co.
  • Other vendors are Henkel KGaA, which provides Velvetex AB, and Sherex Chemical Co., which offers Varion CADG, both of which products are cocobetaines.
  • the amounts of surfactants present are to be somewhat minimized, for purposes of cost-savings and to generally restrict the dissolved actives which could contribute to leaving behind residues when the cleaner is applied to a surface.
  • the amounts added are generally about 0.001-5%, more preferably 0.002-2.00% surfactant.
  • the invention further requires a cationic surfactant, specifically, a quaternary ammonium surfactant.
  • a cationic surfactant specifically, a quaternary ammonium surfactant.
  • These types of surfactants are typically used in bathroom cleaners because they are generally considered "broad spectrum" antimicrobial compounds, having efficacy against both gram positive (e.g., Staphylococcus sp .) and gram negative (e.g., Escherischia coli ) microorganisms.
  • gram positive e.g., Staphylococcus sp .
  • gram negative e.g., Escherischia coli
  • the builder is selected from the group consisting of: ethylene diamine tetraacetates (EDTA), alkali metal carbonates, alkali metal silicates, and mixtures thereof.
  • EDTA ethylene diamine tetraacetates
  • alkali metal carbonates alkali metal silicates
  • mixtures thereof ethylene diamine tetraacetates
  • a co-builder selected from ammonium, alkali metal and alkaline earth metal hydroxides, may be desirable.
  • the builder is an important aspect of the invention. As mentioned above, there appears to be an interaction between the amine oxide surfactant and the builder, particularly EDTA. EDTA is known as a chelant, as well. The preferred builder is EDTA. Buffers, such as the above mentioned hydroxides, and such as ammonium carbamate, which has the structure NH2COO ⁇ NH+4, may also be desirable for inclusion.
  • guanidine derivatives such as diaminoguanidine and guanidine carbonate
  • alkoxylalkylamines such as isopropoxypropylamine, butoxypropylamine, ethoxypropylamine and methoxypropylamine
  • alkylamines such as ethyleneamine, ethylenediamine, ethylenetriamine, ethylenetetramine, diethylenetetramine, triethylenetetramine, tetraethylenepentamine, N,N-dimethylethylenediamine, N-methylenediamine, and other variations of the alkyl and amine substituents.
  • the amount of builder added should be in the range of 0.01-2%, more preferably 0.01-1%, by weight of the cleaner, while hydroxide, if present, should be added in the range of 0.001-1% by weight of the cleaner.
  • the cleaner is an aqueous cleaner with relatively low levels of actives
  • the principal ingredient is water, which should be present at a level of at least about 50%, more preferably at least about 80%, and most preferably, at least about 90%. Deionized water is most preferred.
  • adjuncts can be added for improving cleaning performance or aesthetic qualities of the cleaner.
  • Adjuncts for cleaning include additional surfactants, such as those described in Kirk-Othmer, Encyclopedia of Chemical Technology , 3rd Ed., Volume 22 pp. 332-432 (Marcel-Dekker. 1983), which are incorporated herein by reference.
  • Aesthetic adjuncts include fragrances, such as those available from Givaudan, IFF, Quest and others, and dyes and pigments which can be solubilized or suspended in the formulation, such as diaminoanthraquinones.
  • the amounts of these cleaning and aesthetic adjuncts should be in the range of 0-2%, more preferably 0-1%.
  • the two formulations 1 and 2 were compared against one another and against a number of commercially available cleaners for filming/streaking performance on glass mirror tiles.
  • a grading scale of 0 to 10 was used, with 0 being worst and 10 being best. The results are tabulated below:
  • Example 1 which had the preferred >3:1 ratio of amine oxide: EDTA, clearly outperformed Example 2, as well as the commercial product Lysol Antibacterial Kitchen Cleaner, as well as commercial products 1-4, all of which are bactericidal products. Additionally, its streaking/filming performance was comparable to that of Formula 409® all purpose cleaner and commercial product 1, both of which are hard surface cleaners without bactericides.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
EP95304637A 1994-07-07 1995-07-03 Antimikrobieller Reiniger für harte Oberflächen Expired - Lifetime EP0691397B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US27168194A 1994-07-07 1994-07-07
US271681 1994-07-07

Publications (3)

Publication Number Publication Date
EP0691397A2 true EP0691397A2 (de) 1996-01-10
EP0691397A3 EP0691397A3 (de) 1997-03-05
EP0691397B1 EP0691397B1 (de) 2004-10-06

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP95304637A Expired - Lifetime EP0691397B1 (de) 1994-07-07 1995-07-03 Antimikrobieller Reiniger für harte Oberflächen

Country Status (6)

Country Link
EP (1) EP0691397B1 (de)
JP (1) JPH0827491A (de)
KR (1) KR100378903B1 (de)
AT (1) ATE278757T1 (de)
DE (1) DE69533603T2 (de)
ES (1) ES2229226T3 (de)

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997044427A1 (en) * 1996-05-24 1997-11-27 Reckitt & Colman Inc. Alkaline aqueous hard surface cleaning compositions
EP0826767A1 (de) * 1996-07-24 1998-03-04 Sunstar Inc. Waschmittelzusammensetzungen
WO1998017763A1 (en) * 1996-10-24 1998-04-30 Reckitt & Colman Inc. Low residue aqueous hard surface cleaning and desinfecting compositions
GB2319180A (en) * 1996-11-12 1998-05-20 Reckitt & Colman Inc Mycobactericidal compositions
WO1998024314A1 (en) * 1996-12-06 1998-06-11 Reckitt & Colman Inc. Aqueous disinfecting cleaning composition
GB2320927A (en) * 1997-01-06 1998-07-08 Reckitt & Colman Inc Germicidal hard surface cleaner
WO1998055578A1 (de) * 1997-06-06 1998-12-10 Henkel Kommanditgesellschaft Auf Aktien Schaumarmes reinigungsmittel
EP0937125A4 (de) * 1996-10-17 1999-12-29 Clorox Co Schwach riechendes reinigungsmittel für harte oberflächen mit verbesserter schmutzentfernung
US6017869A (en) * 1998-04-14 2000-01-25 Reckitt & Colman Inc. Aqueous cleaning and disinfecting compositions which include quaternary ammonium compounds, block copolymer surfactants and further mitigating compounds which compositions feature reduced irritation
WO2000005330A1 (en) * 1998-07-24 2000-02-03 Reckitt Benckiser Inc. Low residue aqueous hard surface cleaning and disinfecting compositions
US6090771A (en) * 1996-10-24 2000-07-18 Reckitt Benckiser Inc. Low residue aqueous hard surface cleaning and disinfecting compositions
ES2161169A1 (es) * 1998-10-09 2001-11-16 Dehon S A Mezcla para baño de preparacion para secado de una pieza mecanica, y procedimiento de secado de una pieza mecanica con ayuda de esta mezcla
WO2002048299A1 (en) * 2000-12-15 2002-06-20 Reckitt Benckiser Inc. Alkaline cleaning and sanitizing composition effective for soap scum removal
WO2002026268A3 (en) * 2000-09-29 2002-10-17 Reckitt Benckiser Inc Hard surface cleaning and disinfecting compositions
WO2003050229A1 (en) * 2001-12-10 2003-06-19 Colgate-Palmolive Company Antibacterial cleaning wipe
US6673761B2 (en) 2000-12-14 2004-01-06 The Clorox Company Bactericidal cleaning wipe
WO2004009754A1 (en) * 2002-07-24 2004-01-29 Reckitt Benckiser Inc Acidic hard surface cleaners
US6723692B2 (en) 2001-03-30 2004-04-20 The Procter & Gamble Company Cleaning composition
KR100493999B1 (ko) * 1996-07-24 2005-09-26 선스타 가부시키가이샤 세탁용세제조성물
US7576047B2 (en) 2000-12-14 2009-08-18 The Clorox Company Cleaning composition
US7741263B2 (en) 2000-12-14 2010-06-22 The Clorox Company Cleaning composition
US8071520B2 (en) 2009-11-06 2011-12-06 Ecolab Usa Inc. Sulfonated alkyl polyglucoside use for enhanced food soil removal
US8172953B2 (en) 2009-11-06 2012-05-08 Ecolab Usa Inc. Alkyl polyglucosides and a propoxylated-ethoxylated extended chain surfactant
US8216994B2 (en) 2009-11-09 2012-07-10 Ecolab Usa Inc. Phosphate functionalized alkyl polyglucosides used for enhanced food soil removal
US8389463B2 (en) 2009-11-09 2013-03-05 Ecolab Usa Inc. Enhanced dispensing of solid compositions
CN107835852A (zh) * 2015-07-14 2018-03-23 艺康美国股份有限公司 硬表面清洁剂中受控的泡沫破裂速度
EP3418368A1 (de) 2017-06-21 2018-12-26 The Procter & Gamble Company Lösungsmittel mit zusammensetzung zur reinigung harter oberflächen
EP3418361A1 (de) 2017-06-21 2018-12-26 The Procter & Gamble Company Lösungsmittel mit zusammensetzung zur reinigung harter oberflächen
EP3417709A1 (de) 2017-06-21 2018-12-26 The Procter & Gamble Company Lösungsmittel mit antimikrobiellen reinigungszusammensetzungen für harte oberflächen
US10647948B2 (en) 2017-06-21 2020-05-12 The Procter & Gamble Company Polymer containing antimicrobial hard surface cleaning compositions
WO2022106413A1 (en) * 2020-11-19 2022-05-27 Unilever Ip Holdings B.V. Hard surface cleaning composition
US11834624B2 (en) 2014-03-07 2023-12-05 Ecolab Usa Inc. Alkyl amides for enhanced food soil removal and asphalt dissolution

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3980514B2 (ja) * 2003-04-17 2007-09-26 花王株式会社 殺菌洗浄剤組成物
JP5481714B2 (ja) * 2007-09-20 2014-04-23 ライオン株式会社 液体洗浄剤組成物
US8455551B2 (en) * 2011-03-04 2013-06-04 American Sterilizer Company Broad spectrum disinfectant
DE102023121753A1 (de) 2023-08-15 2025-02-20 Zeller + Gmelin Gmbh & Co. Kg Reinigungslösung zur Entfernung von nicht ausgehärteten wasserbasierten Lackresten

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4065409A (en) 1975-08-01 1977-12-27 Corporate Brands, Inc. Hard surface detergent composition
US4174304A (en) 1975-08-01 1979-11-13 Bullen Chemical Company Midwest, Inc. Surfactant system
US4203872A (en) 1975-08-01 1980-05-20 Flanagan John J Surfactant system
US4264304A (en) 1978-09-06 1981-04-28 Siemens Aktiengesellschaft Apparatus for fixing images consisting of powder toner on a recording carrier with the aid of solvent vapor
GB2160887A (en) 1984-06-21 1986-01-02 Bristol Myers Co Hard surface cleaning composition
US4690779A (en) 1983-06-16 1987-09-01 The Clorox Company Hard surface cleaning composition
EP0393772A2 (de) 1989-04-21 1990-10-24 The Procter & Gamble Company Reinigungszusammensetzungen für harte Flächen
EP0428816A1 (de) 1989-11-23 1991-05-29 The Procter & Gamble Company Reinigungsmittel für harte Oberflächen
WO1991011505A1 (en) 1990-01-29 1991-08-08 The Procter & Gamble Company Liquid hard surface detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3694365A (en) * 1970-12-21 1972-09-26 Schuyler Dev Corp Compositions for cleaning and sterilizing milk equipment
FR2327310A1 (fr) * 1972-11-30 1977-05-06 Modokemi Ab Composition detergente liquide
GB2075043B (en) * 1980-04-23 1985-03-06 Flanagan J J Surfactant system
US4540505A (en) * 1981-05-22 1985-09-10 American Cyanamid Company Disinfectant spray cleanser containing glycol ethers
US5252245A (en) * 1992-02-07 1993-10-12 The Clorox Company Reduced residue hard surface cleaner
DE69422081T2 (de) * 1993-04-19 2000-07-20 Reckitt & Colman Inc., Wayne Allzweckreinigungsmittelzusammensetzung
CA2132274A1 (en) * 1993-11-01 1995-05-02 Janet G. Gardella Foaming antibacterial liquid formulation for cleaning kitchen surfaces

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4065409A (en) 1975-08-01 1977-12-27 Corporate Brands, Inc. Hard surface detergent composition
US4174304A (en) 1975-08-01 1979-11-13 Bullen Chemical Company Midwest, Inc. Surfactant system
US4203872A (en) 1975-08-01 1980-05-20 Flanagan John J Surfactant system
US4264304A (en) 1978-09-06 1981-04-28 Siemens Aktiengesellschaft Apparatus for fixing images consisting of powder toner on a recording carrier with the aid of solvent vapor
US4690779A (en) 1983-06-16 1987-09-01 The Clorox Company Hard surface cleaning composition
GB2160887A (en) 1984-06-21 1986-01-02 Bristol Myers Co Hard surface cleaning composition
EP0393772A2 (de) 1989-04-21 1990-10-24 The Procter & Gamble Company Reinigungszusammensetzungen für harte Flächen
EP0428816A1 (de) 1989-11-23 1991-05-29 The Procter & Gamble Company Reinigungsmittel für harte Oberflächen
WO1991011505A1 (en) 1990-01-29 1991-08-08 The Procter & Gamble Company Liquid hard surface detergent compositions containing zwitterionic detergent surfactant and monoethanolamine and/or beta-aminoalkanol

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"ASTM Standard Test Method", 1987, article "Efficacy of Sanitizers Recommended for Inanimate Non-Food Contact Surfaces", pages: E1135 - 87
MARCEL-DEKKER: "Kirk-Othmer, Encyclopedia of Chemical Technology, 3rd Ed.", vol. 22, 1983, pages: 332 - 432

Cited By (57)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5929007A (en) * 1996-05-24 1999-07-27 Reckitt & Colman Inc. Alkaline aqueous hard surface cleaning compositions
WO1997044427A1 (en) * 1996-05-24 1997-11-27 Reckitt & Colman Inc. Alkaline aqueous hard surface cleaning compositions
KR100493999B1 (ko) * 1996-07-24 2005-09-26 선스타 가부시키가이샤 세탁용세제조성물
EP0826767A1 (de) * 1996-07-24 1998-03-04 Sunstar Inc. Waschmittelzusammensetzungen
US5916864A (en) * 1996-07-24 1999-06-29 Sunstar Inc. Laundry detergent composition comprising a combination of a sparingly water soluble solvent and an easily water soluble solvent
EP0937125A4 (de) * 1996-10-17 1999-12-29 Clorox Co Schwach riechendes reinigungsmittel für harte oberflächen mit verbesserter schmutzentfernung
CN1308426C (zh) * 1996-10-24 2007-04-04 雷基特·本基泽尔有限公司 硬表面清洁和消毒用的低残留含水组合物
US5929016A (en) * 1996-10-24 1999-07-27 Reckitt & Colman Inc. Low residue aqueous hard surface cleaning and disinfecting compositions
WO1998017763A1 (en) * 1996-10-24 1998-04-30 Reckitt & Colman Inc. Low residue aqueous hard surface cleaning and desinfecting compositions
US6090771A (en) * 1996-10-24 2000-07-18 Reckitt Benckiser Inc. Low residue aqueous hard surface cleaning and disinfecting compositions
US5908854A (en) * 1996-11-12 1999-06-01 Reckitt & Colman Inc. Mycobacterial compositions and methods for their use
GB2319180A (en) * 1996-11-12 1998-05-20 Reckitt & Colman Inc Mycobactericidal compositions
GB2319180B (en) * 1996-11-12 2001-01-17 Reckitt & Colman Inc Mycobacterial compositions
WO1998024314A1 (en) * 1996-12-06 1998-06-11 Reckitt & Colman Inc. Aqueous disinfecting cleaning composition
US6030936A (en) * 1997-01-06 2000-02-29 Reckitt & Colman Inc. Blooming type disinfecting cleaning compositions
GB2320927B (en) * 1997-01-06 2001-04-18 Reckitt & Colman Inc Germicidal hard surface cleaner
GB2320927A (en) * 1997-01-06 1998-07-08 Reckitt & Colman Inc Germicidal hard surface cleaner
WO1998055578A1 (de) * 1997-06-06 1998-12-10 Henkel Kommanditgesellschaft Auf Aktien Schaumarmes reinigungsmittel
AU726452B2 (en) * 1997-06-06 2000-11-09 Henkel Kommanditgesellschaft Auf Aktien Low-foam cleaning agent
US6187737B1 (en) 1997-06-06 2001-02-13 Henkel Kommanditgesellschaft Auf Aktien Low-foam detergent comprising a cationic surfactant and a glycol ether
US6017869A (en) * 1998-04-14 2000-01-25 Reckitt & Colman Inc. Aqueous cleaning and disinfecting compositions which include quaternary ammonium compounds, block copolymer surfactants and further mitigating compounds which compositions feature reduced irritation
US6159924A (en) * 1998-07-24 2000-12-12 Reckitt Benckiser Inc. Low residue aqueous hard surface cleaning and disinfecting compositions
WO2000005330A1 (en) * 1998-07-24 2000-02-03 Reckitt Benckiser Inc. Low residue aqueous hard surface cleaning and disinfecting compositions
ES2161169A1 (es) * 1998-10-09 2001-11-16 Dehon S A Mezcla para baño de preparacion para secado de una pieza mecanica, y procedimiento de secado de una pieza mecanica con ayuda de esta mezcla
WO2002026268A3 (en) * 2000-09-29 2002-10-17 Reckitt Benckiser Inc Hard surface cleaning and disinfecting compositions
US7741263B2 (en) 2000-12-14 2010-06-22 The Clorox Company Cleaning composition
US6673761B2 (en) 2000-12-14 2004-01-06 The Clorox Company Bactericidal cleaning wipe
US7576047B2 (en) 2000-12-14 2009-08-18 The Clorox Company Cleaning composition
US7799751B2 (en) 2000-12-14 2010-09-21 The Clorox Company Cleaning composition
US6825158B2 (en) 2000-12-14 2004-11-30 The Clorox Company Bactericidal cleaning wipe comprising a cationic biocide
US6750190B2 (en) 2000-12-15 2004-06-15 Andrew Francis Colurciello Alkaline cleaning and sanitizing composition effective for soap scum removal
WO2002048299A1 (en) * 2000-12-15 2002-06-20 Reckitt Benckiser Inc. Alkaline cleaning and sanitizing composition effective for soap scum removal
US6933267B2 (en) 2000-12-15 2005-08-23 Rockitt Benckiser Inc. Alkaline cleaning and sanitizing composition effective for soap scum removal
US6723692B2 (en) 2001-03-30 2004-04-20 The Procter & Gamble Company Cleaning composition
WO2003050229A1 (en) * 2001-12-10 2003-06-19 Colgate-Palmolive Company Antibacterial cleaning wipe
AU2003281521B2 (en) * 2002-07-24 2009-05-21 Reckitt Benckiser Llc Acidic hard surface cleaners
WO2004009754A1 (en) * 2002-07-24 2004-01-29 Reckitt Benckiser Inc Acidic hard surface cleaners
US8071520B2 (en) 2009-11-06 2011-12-06 Ecolab Usa Inc. Sulfonated alkyl polyglucoside use for enhanced food soil removal
US8172953B2 (en) 2009-11-06 2012-05-08 Ecolab Usa Inc. Alkyl polyglucosides and a propoxylated-ethoxylated extended chain surfactant
US8216994B2 (en) 2009-11-09 2012-07-10 Ecolab Usa Inc. Phosphate functionalized alkyl polyglucosides used for enhanced food soil removal
US8389463B2 (en) 2009-11-09 2013-03-05 Ecolab Usa Inc. Enhanced dispensing of solid compositions
US12180439B2 (en) 2014-03-07 2024-12-31 Ecolab Usa Inc. Alkyl amides for enhanced food soil removal and asphalt dissolution
US11834624B2 (en) 2014-03-07 2023-12-05 Ecolab Usa Inc. Alkyl amides for enhanced food soil removal and asphalt dissolution
US12270011B2 (en) 2015-07-14 2025-04-08 Ecolab Usa Inc. Controlled rate of foam breakage in hard surface cleaners
CN107835852A (zh) * 2015-07-14 2018-03-23 艺康美国股份有限公司 硬表面清洁剂中受控的泡沫破裂速度
US10975333B2 (en) 2015-07-14 2021-04-13 Ecolab Usa Inc. Controlled rate of foam breakage in hard surface cleaners
CN107835852B (zh) * 2015-07-14 2024-02-23 艺康美国股份有限公司 硬表面清洁剂中受控的泡沫破裂速度
EP3322790A4 (de) * 2015-07-14 2019-04-03 Ecolab USA Inc. Kontrollierte rate des schaumbruchs in hartflächenreinigern
EP4219671A3 (de) * 2015-07-14 2023-08-16 Ecolab USA Inc. Kontrollierte rate des schaumbruchs in reinigern für harte oberflächen
EP3418361A1 (de) 2017-06-21 2018-12-26 The Procter & Gamble Company Lösungsmittel mit zusammensetzung zur reinigung harter oberflächen
US10696930B2 (en) 2017-06-21 2020-06-30 The Procter & Gamble Company Solvent containing anitmicrobial hard surface cleaning compositions
US10647948B2 (en) 2017-06-21 2020-05-12 The Procter & Gamble Company Polymer containing antimicrobial hard surface cleaning compositions
WO2018237126A1 (en) 2017-06-21 2018-12-27 The Procter & Gamble Company ANTIMICROBIAL CLEANING COMPOSITIONS FOR HARD SURFACES CONTAINING A SOLVENT
WO2018237129A1 (en) 2017-06-21 2018-12-27 The Procter & Gamble Company CLEANING COMPOSITIONS FOR HARD SURFACES CONTAINING A SOLVENT
EP3417709A1 (de) 2017-06-21 2018-12-26 The Procter & Gamble Company Lösungsmittel mit antimikrobiellen reinigungszusammensetzungen für harte oberflächen
EP3418368A1 (de) 2017-06-21 2018-12-26 The Procter & Gamble Company Lösungsmittel mit zusammensetzung zur reinigung harter oberflächen
WO2022106413A1 (en) * 2020-11-19 2022-05-27 Unilever Ip Holdings B.V. Hard surface cleaning composition

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ES2229226T3 (es) 2005-04-16
JPH0827491A (ja) 1996-01-30
EP0691397A3 (de) 1997-03-05
ATE278757T1 (de) 2004-10-15
KR100378903B1 (ko) 2003-05-23
DE69533603T2 (de) 2006-02-09
DE69533603D1 (de) 2004-11-11
EP0691397B1 (de) 2004-10-06

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