EP0691673A2 - Conducteur électrique dans des lampes - Google Patents
Conducteur électrique dans des lampes Download PDFInfo
- Publication number
- EP0691673A2 EP0691673A2 EP95201756A EP95201756A EP0691673A2 EP 0691673 A2 EP0691673 A2 EP 0691673A2 EP 95201756 A EP95201756 A EP 95201756A EP 95201756 A EP95201756 A EP 95201756A EP 0691673 A2 EP0691673 A2 EP 0691673A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- molybdenum
- lamps
- electrical conductor
- oxide
- cerium oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004020 conductor Substances 0.000 title claims abstract description 39
- 239000000463 material Substances 0.000 claims abstract description 38
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 12
- 239000011521 glass Substances 0.000 claims abstract description 12
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 12
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims abstract description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- OBOUWLBQUVHNJT-UHFFFAOYSA-N [O-2].[Y+3].[Mo+4] Chemical compound [O-2].[Y+3].[Mo+4] OBOUWLBQUVHNJT-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052681 coesite Inorganic materials 0.000 claims abstract 2
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract 2
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(III) oxide Inorganic materials O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 claims abstract 2
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 claims abstract 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum oxide Inorganic materials [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052682 stishovite Inorganic materials 0.000 claims abstract 2
- 229910052905 tridymite Inorganic materials 0.000 claims abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 19
- 229910052750 molybdenum Inorganic materials 0.000 claims description 19
- 239000011733 molybdenum Substances 0.000 claims description 19
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 2
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims 1
- 229910052593 corundum Inorganic materials 0.000 claims 1
- KTUFCUMIWABKDW-UHFFFAOYSA-N oxo(oxolanthaniooxy)lanthanum Chemical compound O=[La]O[La]=O KTUFCUMIWABKDW-UHFFFAOYSA-N 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 1
- 238000007789 sealing Methods 0.000 abstract description 3
- 230000005611 electricity Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 13
- 230000003647 oxidation Effects 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 239000011888 foil Substances 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002585 base Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- 229910001182 Mo alloy Inorganic materials 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000001953 recrystallisation Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- LENJPRSQISBMDN-UHFFFAOYSA-N [Y].[Ce] Chemical compound [Y].[Ce] LENJPRSQISBMDN-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910001507 metal halide Inorganic materials 0.000 description 2
- 150000005309 metal halides Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical class [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Chemical class 0.000 description 2
- 239000010937 tungsten Chemical class 0.000 description 2
- 229910052724 xenon Inorganic materials 0.000 description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- LGLOITKZTDVGOE-UHFFFAOYSA-N boranylidynemolybdenum Chemical compound [Mo]#B LGLOITKZTDVGOE-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000007723 die pressing method Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 238000005468 ion implantation Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000005341 toughened glass Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/36—Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/02—Electrodes; Screens; Mounting, supporting, spacing or insulating thereof
- H01J29/10—Screens on or from which an image or pattern is formed, picked up, converted or stored
- H01J29/18—Luminescent screens
- H01J29/28—Luminescent screens with protective, conductive or reflective layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/36—Seals between parts of vessels; Seals for leading-in conductors; Leading-in conductors
- H01J61/366—Seals for leading-in conductors
- H01J61/368—Pinched seals or analogous seals
Definitions
- the invention relates to an electrical conductor made of etched strip material based on molybdenum yttrium oxide as a power supply in lamps with a metal / glass seal.
- lamps includes in particular halogen incandescent lamps and discharge lamps, such as high-pressure mercury lamps, metal halide lamps and xenon HD discharge lamps.
- molybdenum conductor Further material requirements for the molybdenum conductor are ductility, good ductility, high mechanical strength, resistance to oxidation and corrosion, particularly with respect to halides, and weldability with other conductor components.
- DE-C-29 47 230 has the task of creating an electric lamp with a mechanically stronger current feedthrough and describes instead of using the molybdenum foil used up to that point in which in the molybdenum yttrium oxide particles in an amount of 0.25 to 1% of the molybdenum weight are dispersed.
- this material has inadequate corrosion, in particular oxidation properties.
- the electrical conductor for carrying the current in the form of a molybdenum or tungsten foil with a second metal from a group consisting of tantalum, niobium, vanadium, chromium, zirconium, titanium, yttrium, Lanthanum, scandium and hafnium exist.
- the molybdenum or tungsten conductor can be encased by vapor deposition, sputtering, electrolysis and other processes.
- sheathing is a complex, cost-intensive process and, when carried out economically, does not ensure that the coating is so uniformly thick that the desired corrosion protection is ensured in all areas.
- sheathed current feedthroughs lack sufficient weldability. This is especially true for chrome as a coating material. If necessary, the base material must first be welded to another component and then coated or coated.
- US Pat. No. 5,021,711 also deals with the oxidation protection of molybdenum foils, which are used as electrical conductors in vacuum lamps, and proposes to finish the molybdenum foil with chromium, aluminum or combinations of these metals by means of ion implantation.
- the lack of insufficient weldability applies and this process is complex and expensive for this material. It increases the manufacturing cost of the quartz lamp mass product to an unsatisfactory extent.
- EP-B-0 309 749 is concerned with increasing the oxidation resistance of molybdenum, which is to be used as an electrical conductor in electrical lamps in the sealing area.
- the improved service life of the material, especially in an oxidizing environment at elevated temperatures of 250 to 600 ° C, is to be achieved by an alkali metal silicate coating over the molybdenum base material.
- EP-B-0 098 858 proposes to increase the oxidation resistance, but also the weldability and the resistance to hydrogen-containing media, to provide the coating of a current lead made of molybdenum with a rhenium layer. Rhenium is an expensive material. The known processes for the production of the coating are complex, so that the main disadvantage in this case is the lack of economy of electrical conductors treated in this way.
- a molybdenum alloy for an electrical conductor as a power supply for lamps, consisting of 0.01 to 5% by weight of one or more oxides of lanthanides, the remainder being Mo.
- this material has excellent weldability and high-temperature strength, but other application-specific material characteristics are less favorable than for individual ones of the previously known Mo alloys.
- the sum of all material properties recommends use as a wire-shaped power supply for tempered glass melts, but not as a tape or film for quartz glass melts.
- EP-A-0 311 308 discloses a special method by means of which the metal and glass are to melt together in a special way in the presence of a hydrogen / nitrogen gas mixture in the sealing area.
- this and other methods can in no way satisfactorily compensate for the known problems when using appropriate materials as electrical conductors.
- JP-B-85058296 describes a heat-resistant alloy composed of 10 to 70% by weight of yttrium oxide and / or cerium oxide, the rest being molybdenum, which is used for protective tubes for thermocouples. This prior publication does not indicate that this alloy is suitable for power supply in lamps.
- the above-mentioned object is surprisingly achieved by an electrical conductor in the embodiment according to claim 1.
- Lamps according to the present invention include various types of incandescent halogen lamps as well as discharge lamps such as e.g. B. high-pressure mercury lamps, high-pressure xenon lamps and metal halide lamps.
- the strip material is in the lamp in various dimensions, but especially as thin elliptically etched foil is used.
- the electrical conductors according to the invention can be used without restriction while maintaining the currently customary methods for lamp manufacture, in particular the metal / glass melting or squeezing technique. This also applies in particular to methods according to which the ends of the electrical current conductor according to the present invention are welded to further current-carrying components and, including the welded connections, melted or squeezed into quartz glass.
- the electrical conductor according to the invention compared to a molybdenum material doped only with yttrium oxide as a dispersoid, would lead to a sudden increase in the resistance to corrosion and, in particular, to oxidation, given an overall comparable oxide concentration. This allows e.g. a longer storage of lamps made with such conductors and at the same time causes a significantly longer service life in operation.
- etching agents and etching processes customary today for molybdenum strip material or molybdenum foils are used. This applies in particular to the widespread methods for thinning the lateral edge zones of a conductor strip.
- the following examples describe advantageous configurations of the electrical conductor according to the invention and its manufacture. The explanations are supplemented by comparative studies on the oxidation resistance of such electrical conductors.
- molybdenum powder with a very finely divided mixture of 0.55% by weight of yttrium-cerium mixed oxide with a ratio of cerium oxide to yttrium oxide of 0.25 was produced by means of liquid doping (oxide particle size ⁇ 0.1 ⁇ m), compacted by die pressing and then sintered at 1850 ° C / 5 h.
- the rolled plates thus produced were processed by means of hot and cold rolling into strips with a thickness of 0.045 mm, then cut and brought into the elliptical shape typical of the melting strip using an electrolytic pickling process and annealed at 800 ° C. under an H2 atmosphere.
- a strip material according to the invention made of molybdenum with 0.55% by weight cerium-yttrium mixed oxide with a ratio of cerium oxide to yttrium oxide of 0.43 was produced in accordance with the production conditions according to Example 1.
- Table 1 Tape material a) b) c) d) relative temperature resistance Oxidation rate ( ⁇ g / cm2h) Oxidation rate ( ⁇ g / cm2h) State of the art Mo with 0.55 wt.% Y2O3 120 160 + 1.0 according to the invention Mo with 0.55% by weight of mixed oxide according to Example 1 80 130 + 1.2 according to the invention Mo with 0.55% by weight of mixed oxide according to Example 2 85 115 + 1.2
Landscapes
- Glass Compositions (AREA)
- Vessels And Coating Films For Discharge Lamps (AREA)
- Common Detailed Techniques For Electron Tubes Or Discharge Tubes (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT132394 | 1994-07-05 | ||
| AT0132394A AT401124B (de) | 1994-07-05 | 1994-07-05 | Elektrischer leiter in lampen |
| AT1323/94 | 1994-07-05 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0691673A2 true EP0691673A2 (fr) | 1996-01-10 |
| EP0691673A3 EP0691673A3 (fr) | 1997-11-26 |
| EP0691673B1 EP0691673B1 (fr) | 2000-03-01 |
Family
ID=3511417
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP95201756A Expired - Lifetime EP0691673B1 (fr) | 1994-07-05 | 1995-06-28 | Conducteur électrique dans des lampes |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5606141A (fr) |
| EP (1) | EP0691673B1 (fr) |
| JP (1) | JP3459318B2 (fr) |
| AT (1) | AT401124B (fr) |
| DE (1) | DE59507870D1 (fr) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19837904A1 (de) * | 1997-08-21 | 1999-04-08 | Koito Mfg Co Ltd | Verbesserte Molybdänfolien innerhalb der Quetschdichtungen einer Metallhalogenidlampe |
| EP0818805B1 (fr) * | 1996-07-12 | 2002-05-29 | Koito Manufacturing Co., Ltd | Tube de lampe à décharge à arc et son procédé de fabrication |
| US6753650B2 (en) | 2000-05-18 | 2004-06-22 | Plansee Aktiengesellschaft | Method for producing an electric lamp and foil configuration |
| EP1538658A2 (fr) | 2003-10-16 | 2005-06-08 | A.L.M.T. Corp. | Alliage pour un membre de raccordement d'une lampe électrique, structure d'électrode pour une lampe électrique et ampoule lumineuse pour véhicule l'utilisant |
| WO2006123271A3 (fr) * | 2005-05-19 | 2007-08-30 | Koninkl Philips Electronics Nv | Lampe dotee d'elements de lampe constitues d'un alliage de molybdene |
| WO2007000006A3 (fr) * | 2005-06-29 | 2007-10-18 | Plansee Se | Lampe halogene a incandescence pourvue d'un cache anti-eblouissement en alliage de mo |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5868876A (en) * | 1996-05-17 | 1999-02-09 | The United States Of America As Represented By The United States Department Of Energy | High-strength, creep-resistant molybdenum alloy and process for producing the same |
| US6102979A (en) * | 1998-08-28 | 2000-08-15 | The United States Of America As Represented By The United States Department Of Energy | Oxide strengthened molybdenum-rhenium alloy |
| JP4927743B2 (ja) * | 2004-09-30 | 2012-05-09 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | シール薄膜を有する電気ランプ |
| CN1297485C (zh) * | 2004-12-16 | 2007-01-31 | 西安交通大学 | 稀土二钼酸铵制备工艺 |
| CN100370046C (zh) * | 2005-04-19 | 2008-02-20 | 泰州市万鑫钨钼制品有限公司 | 钇钼材料及生产方法 |
| CN100592452C (zh) * | 2005-07-29 | 2010-02-24 | 松下电器产业株式会社 | 荧光体悬浮液的制备方法、荧光灯、背光单元、直下方式的背光单元以及液晶显示装置 |
| US7476634B2 (en) * | 2005-08-16 | 2009-01-13 | Covalent Materials Corporation | Yttria sintered body and manufacturing method therefor |
| CN100417738C (zh) * | 2006-11-10 | 2008-09-10 | 金堆城钼业股份有限公司 | 耐高温、抗电弧侵蚀复合稀土钼合金及其制备方法 |
| AT11175U1 (de) | 2008-11-21 | 2010-05-15 | Plansee Metall Gmbh | Dichtungsfolie |
| CN104392892A (zh) * | 2013-11-15 | 2015-03-04 | 朱惠冲 | 一种汽车前照灯内配光屏及其制备材料 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2947230C2 (de) | 1978-11-29 | 1985-01-24 | N.V. Philips' Gloeilampenfabrieken, Eindhoven | Elektrische Lampe mit einer Elektrodenzuführung |
| JPS6058296B2 (ja) | 1977-06-13 | 1985-12-19 | 東芝セラミツクス株式会社 | 耐熱材料 |
| EP0098858B1 (fr) | 1982-01-28 | 1988-05-18 | TUNGSRAM Részvénytársaság | Conducteur d'alimentation en courant, principalement pour appareils a vide, et son procede de fabrication |
| DE3006846C2 (fr) | 1979-02-26 | 1988-09-22 | N.V. Philips' Gloeilampenfabrieken, Eindhoven, Nl | |
| EP0311308A2 (fr) | 1987-10-05 | 1989-04-12 | The BOC Group, Inc. | Procédé de liaison de verre à du métal |
| US5021711A (en) | 1990-10-29 | 1991-06-04 | Gte Products Corporation | Quartz lamp envelope with molybdenum foil having oxidation-resistant surface formed by ion implantation |
| EP0275580B1 (fr) | 1986-12-09 | 1991-08-14 | North American Philips Corporation | Alliage à base de molybdène et conducteur d'amenée de courant fabriqué avec cet alliage |
| AT395493B (de) | 1991-05-06 | 1993-01-25 | Plansee Metallwerk | Stromzufuehrung |
| EP0309749B1 (fr) | 1987-09-29 | 1993-02-10 | General Electric Company | Scellement de molybdène résistant à l'oxydation et son emploi dans des lampes |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US982751A (en) * | 1908-05-01 | 1911-01-24 | Orlando M Thowless | Glower for electrical incandescent lamps. |
| SE437257B (sv) * | 1983-08-10 | 1985-02-18 | Sca Development Ab | Sett att styra en anaerob process for rening av avloppsvatten |
| AT386612B (de) * | 1987-01-28 | 1988-09-26 | Plansee Metallwerk | Kriechfeste legierung aus hochschmelzendem metall und verfahren zu ihrer herstellung |
| US5077505A (en) * | 1989-07-24 | 1991-12-31 | U.S. Philips Corporation | Electric lamp and seal structure therefor |
-
1994
- 1994-07-05 AT AT0132394A patent/AT401124B/de not_active IP Right Cessation
-
1995
- 1995-06-19 US US08/491,637 patent/US5606141A/en not_active Expired - Lifetime
- 1995-06-28 DE DE59507870T patent/DE59507870D1/de not_active Expired - Lifetime
- 1995-06-28 EP EP95201756A patent/EP0691673B1/fr not_active Expired - Lifetime
- 1995-06-28 JP JP18328895A patent/JP3459318B2/ja not_active Expired - Lifetime
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6058296B2 (ja) | 1977-06-13 | 1985-12-19 | 東芝セラミツクス株式会社 | 耐熱材料 |
| DE2947230C2 (de) | 1978-11-29 | 1985-01-24 | N.V. Philips' Gloeilampenfabrieken, Eindhoven | Elektrische Lampe mit einer Elektrodenzuführung |
| DE3006846C2 (fr) | 1979-02-26 | 1988-09-22 | N.V. Philips' Gloeilampenfabrieken, Eindhoven, Nl | |
| EP0098858B1 (fr) | 1982-01-28 | 1988-05-18 | TUNGSRAM Részvénytársaság | Conducteur d'alimentation en courant, principalement pour appareils a vide, et son procede de fabrication |
| EP0275580B1 (fr) | 1986-12-09 | 1991-08-14 | North American Philips Corporation | Alliage à base de molybdène et conducteur d'amenée de courant fabriqué avec cet alliage |
| EP0309749B1 (fr) | 1987-09-29 | 1993-02-10 | General Electric Company | Scellement de molybdène résistant à l'oxydation et son emploi dans des lampes |
| EP0311308A2 (fr) | 1987-10-05 | 1989-04-12 | The BOC Group, Inc. | Procédé de liaison de verre à du métal |
| US5021711A (en) | 1990-10-29 | 1991-06-04 | Gte Products Corporation | Quartz lamp envelope with molybdenum foil having oxidation-resistant surface formed by ion implantation |
| AT395493B (de) | 1991-05-06 | 1993-01-25 | Plansee Metallwerk | Stromzufuehrung |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0818805B1 (fr) * | 1996-07-12 | 2002-05-29 | Koito Manufacturing Co., Ltd | Tube de lampe à décharge à arc et son procédé de fabrication |
| DE19837904A1 (de) * | 1997-08-21 | 1999-04-08 | Koito Mfg Co Ltd | Verbesserte Molybdänfolien innerhalb der Quetschdichtungen einer Metallhalogenidlampe |
| US5962976A (en) * | 1997-08-21 | 1999-10-05 | Koito Manufacturing Co., Ltd. | Molybdenum foils with yttrium oxide and recrystallization grains no more than 50 microns within the pinch seals of a metallic halide lamp |
| DE19837904B4 (de) * | 1997-08-21 | 2012-06-28 | Koito Mfg. Co., Ltd. | Verfahren zum Herstellen verbesserter Molybdänfolien innerhalb der Quetschdichtungen einer Metallhalogenidlampe |
| US6753650B2 (en) | 2000-05-18 | 2004-06-22 | Plansee Aktiengesellschaft | Method for producing an electric lamp and foil configuration |
| EP1538658A2 (fr) | 2003-10-16 | 2005-06-08 | A.L.M.T. Corp. | Alliage pour un membre de raccordement d'une lampe électrique, structure d'électrode pour une lampe électrique et ampoule lumineuse pour véhicule l'utilisant |
| EP1538658A3 (fr) * | 2003-10-16 | 2006-11-22 | A.L.M.T. Corp. | Alliage pour un membre de raccordement d'une lampe électrique, structure d'électrode pour une lampe électrique et ampoule lumineuse pour véhicule l'utilisant |
| US7345426B2 (en) | 2003-10-16 | 2008-03-18 | A.L.M.T. Corporation | Alloy for a lead member of an electric lamp and electrode structure of the electric lamp |
| WO2006123271A3 (fr) * | 2005-05-19 | 2007-08-30 | Koninkl Philips Electronics Nv | Lampe dotee d'elements de lampe constitues d'un alliage de molybdene |
| WO2007000006A3 (fr) * | 2005-06-29 | 2007-10-18 | Plansee Se | Lampe halogene a incandescence pourvue d'un cache anti-eblouissement en alliage de mo |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0855566A (ja) | 1996-02-27 |
| US5606141A (en) | 1997-02-25 |
| ATA132394A (de) | 1995-10-15 |
| JP3459318B2 (ja) | 2003-10-20 |
| EP0691673A3 (fr) | 1997-11-26 |
| EP0691673B1 (fr) | 2000-03-01 |
| DE59507870D1 (de) | 2000-04-06 |
| AT401124B (de) | 1996-06-25 |
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