EP0700985A1 - Combustibles, pour moteurs à allumage par etincelles, contenant des polyetheramines - Google Patents

Combustibles, pour moteurs à allumage par etincelles, contenant des polyetheramines Download PDF

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Publication number
EP0700985A1
EP0700985A1 EP95113660A EP95113660A EP0700985A1 EP 0700985 A1 EP0700985 A1 EP 0700985A1 EP 95113660 A EP95113660 A EP 95113660A EP 95113660 A EP95113660 A EP 95113660A EP 0700985 A1 EP0700985 A1 EP 0700985A1
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Prior art keywords
fuels
alkyl
polyetheramines
radical
denotes
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EP0700985B1 (fr
Inventor
Knut Dr. Oppenländer
Wolfgang Dr. Günther
Andreas Dr. Henne
Volkmar Dr. Menger
Rainer Dr. Becker
Wolfgang Dr. Reif
Jürgen Dr. Thomas
Harald Dr. Schwahn
Erhard Dr. Henkes
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BASF SE
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BASF SE
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/06—Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1625—Hydrocarbons macromolecular compounds
    • C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
    • C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
    • C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/188—Carboxylic acids; metal salts thereof
    • C10L1/1881—Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C10L1/1905—Esters ester radical containing compounds; ester ethers; carbonic acid esters of di- or polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/232—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring
    • C10L1/233—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles
    • C10L1/2335—Organic compounds containing nitrogen containing nitrogen in a heterocyclic ring containing nitrogen and oxygen in the ring, e.g. oxazoles morpholino, and derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)

Definitions

  • EP-A 310 875 discloses polyetheramines of the above type with alkylene radicals derived from propylene oxide or butylene oxide as valve-cleaning additives for petrol.
  • the degree of alkorylation is indicated there with 5 to 100, preferably 5 to 30.
  • Example B describes an iso-tridecanol of molecular weight 730 which has been reacted with butylene oxide and then aminated with ammonia, from which a degree of butoxylation of about 7.5 can be calculated.
  • the radical R1 preferably denotes C8 to C20 alkyl, in particular C9 to C15 alkyl, especially C11 to C14 alkyl; C13-alkyl is very particularly preferred.
  • the mostly long-chain radical R 1 can be linear or preferably branched.
  • radicals R2 and R3 or one of the radicals R2 or R3 do not represent the (poly) aminoalkylene radicals II or III, they mean or preferably means C1 to C4 alkyl, e.g. Methyl or ethyl, or especially hydrogen.
  • the bridge member R4 is preferably linear or branched C2 to C4 alkylene, especially 1,2-ethylene or 1,3-propylene.
  • the number m is an integer and preferably denotes a number from 2 to 6, especially from 2 to 4.
  • the radicals R5 and R6 are preferably C1 to C4 alkyl, e.g. Methyl or ethyl, or especially hydrogen.
  • both radicals R2 and R3 are hydrogen or one of the radicals is hydrogen and the other is 2-aminoethyl, 3-aminopropyl or 3- (N, N-dimethylamino) propyl.
  • the latter radicals are derived from the diamines 1,2-ethylenediamine, 1,3-propylenediamine and 3- (N, N-dimethylamino) propylamine.
  • the degree of butoxylation n is preferably 18 to 25, in particular 20 to 23, especially 22.
  • n represents an average value for a statistical distribution of butoxylation products.
  • polyetheramines I are expediently - as described in EP-A 310 875 - by reacting alcohols of the formula R.sup.1 OH with butylene oxide, where 1,2-butylene oxide, 2,3-butylene oxide, isobutylene oxide or mixtures thereof can be used , and subsequent amination with ammonia or amines of the formula NHR2R3.
  • the gasolines can also contain components other than hydrocarbons, e.g. Alcohols such as methanol, ethanol or tert-butanol as well as ethers, e.g. Methyl tert-butyl ether.
  • the fuels generally also contain additives such as corrosion inhibitors, stabilizers, antioxidants or other detergents.
  • Corrosion inhibitors are usually ammonium salts of organic carboxylic acids, which tend to form films due to the structure of the starting compounds. Amines to increase the pH are also often found in corrosion inhibitors. Heterocyclic aromatics are mostly used as non-ferrous metal corrosion protection.
  • Antioxidants or stabilizers include, in particular, amines such as para-phenylenediamine, dicyclohexylamine, morpholine or derivatives of these amines.
  • Phenolic antioxidants such as 2,4-di-tert-butylphenol or 3,5-di-tert-butyl-4-hydroxyphenylpropionic acid and their derivatives are also added to fuels.
  • the gasifiers, injector and valve detergents may also contain amides and imides of polyisobutylene succinic anhydride, poly (iso) butenamines, poly (iso) butenepolyamines and long-chain carboxamides and imides in the fuels.
  • Mineral oils of the viscosity range SN 500-900, but also Brightstock and synthetic oils such as polyalphaolefin, trimellitic acid ester or polyether can be used as carrier oils for concentrates of the polyetheramines I to be used according to the invention.
  • the esters should contain long-chain, branched alcohols with more than 8 carbon atoms, the polyethers preferably long-chain starters and high propylene oxide or butylene oxide contents in the molecule.
  • the fuels generally contain the polyetheramines I in amounts of 10 to 2000 ppm, based on the pure polyetheramine. Usually, however, 20 to 1000 ppm, preferably 40 to 400 ppm, are sufficient.
  • the polyetheramines I to be used according to the invention serve mainly in the fuels as valve-cleaning additives, i.e. as detergents. However, they can also partially function as carrier oils for other detergents.
  • the fuels described can contain a specific polyetheramine I or a mixture of several polyetheramines I.
  • the engine test was carried out on an Opel Kadett 1.2 liter engine using the cyclic test program CEC-F-04-A-87. The total test duration was 40 hours.
  • the petrol used was standard unleaded premium petrol and the motor oil used was the reference oil RL-139.
  • the intake valves were evaluated gravimetrically.
  • the inlet valves on the underside were carefully mechanically cleaned of deposits from the combustion chamber. Thereafter, surface-adhering, easily soluble parts on the valves were removed by immersion in cyclohexane and the valves were dried by swirling in air. This treatment was done twice in total.
  • the intake valves were then weighed. From the weight difference between the valve weight before and after the experiment, the amount of deposits per intake valve was obtained. The results of these tests are shown in the following tables. table Testing the inlet valve load with an Opel Kadett 1.2 l engine on the test bench with 100 mg polyetheramine per kg unleaded super fuel according to DIN EN 228, 150 l, engine oil RL-139, test duration 40 hours

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Polyethers (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP95113660A 1994-09-09 1995-08-31 Combustibles, pour moteurs à allumage par etincelles, contenant des polyetheramines Expired - Lifetime EP0700985B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4432038A DE4432038A1 (de) 1994-09-09 1994-09-09 Polyetheramine enthaltende Kraftstoffe für Ottomotoren
DE4432038 1994-09-09

Publications (2)

Publication Number Publication Date
EP0700985A1 true EP0700985A1 (fr) 1996-03-13
EP0700985B1 EP0700985B1 (fr) 1999-03-03

Family

ID=6527739

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95113660A Expired - Lifetime EP0700985B1 (fr) 1994-09-09 1995-08-31 Combustibles, pour moteurs à allumage par etincelles, contenant des polyetheramines

Country Status (5)

Country Link
US (1) US5660601A (fr)
EP (1) EP0700985B1 (fr)
JP (1) JP3725588B2 (fr)
DE (2) DE4432038A1 (fr)
ES (1) ES2127976T3 (fr)

Cited By (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1122295A4 (fr) * 1998-10-06 2002-02-06 Nippon Mitsubishi Oil Corp Additif pour essence destinee a un moteur a essence a injection directe
WO2009050287A1 (fr) 2007-10-19 2009-04-23 Shell Internationale Research Maatschappij B.V. Fluides fonctionnels pour moteurs à combustion interne
DE102008037662A1 (de) 2007-08-17 2009-04-23 Basf Se Öllösliches Detergens und Verfahren zur Herstellung funktionalisierter Polyalkene
WO2009095443A1 (fr) 2008-02-01 2009-08-06 Basf Se Polyisobutène-amines spécifiques, et leur utilisation comme détergents dans des carburants
US7601185B2 (en) 2002-03-06 2009-10-13 Basf Aktiengesellschaft Fuel additive mixtures for gasolines with synergistic IVD performance
US7753970B2 (en) 2003-04-01 2010-07-13 Basf Aktiengesellschaft Polyalkene amines with improved applicational properties
DE102010001408A1 (de) 2009-02-06 2010-08-12 Basf Se Verwendung von Ketonen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauches von Dieselmotoren
EP2267104A2 (fr) 2006-02-27 2010-12-29 Basf Se Utilisation de composés phénoliques polynucléaires comme dispersants
EP2270119A1 (fr) 2003-04-11 2011-01-05 Basf Se Composition de carburant
DE102010039039A1 (de) 2009-08-24 2011-03-03 Basf Se Verwendung von organischen Verbindungen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauchs von Dieselmotoren
WO2011134923A1 (fr) 2010-04-27 2011-11-03 Basf Se Terpolymère quaternisé
WO2011151207A1 (fr) 2010-06-01 2011-12-08 Basf Se Amines à substitution polyisobutyle, de faible masse moléculaire, servant de renforçateurs de détergents
WO2011161149A1 (fr) 2010-06-25 2011-12-29 Basf Se Copolymère quaternisé
WO2012004300A1 (fr) 2010-07-06 2012-01-12 Basf Se Composés azotés quaternisés exempts d'acide et utilisation desdits composés comme additifs pour carburants ou pour lubrifiants
WO2012072723A2 (fr) 2010-12-02 2012-06-07 Basf Se Utilisation du produit réactionnel d'un acide dicarbonique à substitution hydrocarbyle et d'un composé azote pour réduire la consommation de carburant
WO2012072643A2 (fr) 2010-11-30 2012-06-07 Basf Se Préparation de dérivés d'homopolymères ou de copolymères d'isobutène
WO2012076428A1 (fr) 2010-12-09 2012-06-14 Basf Se Polytetrahydrobenzoxazines et bistetrahydrobenzoxazines et leur utilisation comme additif pour carburant ou additif pour lubrifiant
WO2012163935A2 (fr) 2011-05-30 2012-12-06 Shell Internationale Research Maatschappij B.V. Compositions de carburants liquides
EP2540808A1 (fr) 2011-06-28 2013-01-02 Basf Se Composés d'azote quaternisés et leur utilisation en tant qu'additifs dans des carburants et des lubrifiants
EP2589647A1 (fr) 2011-11-04 2013-05-08 Basf Se Polyétheramines quaternisées et leur utilisation en tant qu'additifs dans des carburants et des lubrifiants
EP2604674A1 (fr) 2011-12-12 2013-06-19 Basf Se Utilisation d'alkylamine quaternisé comme additif dans des carburants et des lubrifiants
WO2013117616A1 (fr) 2012-02-10 2013-08-15 Basf Se Sels d'imidazolium en tant qu'additifs pour carburants et combustibles
US8551365B2 (en) 2007-03-02 2013-10-08 Basf Se Additive formulation suitable for antistatic modification and improving the electrical conductivity of inanimate organic material
WO2013174619A1 (fr) 2012-05-25 2013-11-28 Basf Se Amines tertiaires pour la réduction de l'encrassement d'injecteurs dans des moteurs à allumage par étincelles et à injection directe
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WO2014064151A1 (fr) 2012-10-23 2014-05-01 Basf Se Sels d'ammonium quaternisés d'époxydes hydrocarbyliques et utilisation desdits sels d'ammonium quaternisés d'époxydes hydrocarbyliques comme additifs de carburants et de lubrifiants
US8790426B2 (en) 2010-04-27 2014-07-29 Basf Se Quaternized terpolymer
WO2014184066A1 (fr) 2013-05-14 2014-11-20 Basf Se Polyalcénylsuccinimides pour réduire l'encrassement d'injecteurs dans des moteurs à allumage commandé et injection directe
EP2811007A1 (fr) 2013-06-07 2014-12-10 Basf Se Utilisation avec de l'oxyde d'alkylène et de l'acide polycarbonique à substitution hydrocarbyle d'alkylamines quaternisés comme additifs dans les carburants et lubrifiants
US8911516B2 (en) 2010-06-25 2014-12-16 Basf Se Quaternized copolymer
WO2015003961A1 (fr) 2013-07-12 2015-01-15 Basf Se Utilisation d'un acide dicarboxylique à substitution hydrocarbyle pour améliorer ou augmenter la séparation de l'eau du fioul et de l'essence
WO2015007553A1 (fr) 2013-07-17 2015-01-22 Basf Se Polyisobutylène à réactivité élevée et à haute teneur en doubles liaisons vinylidène dans les chaînes latérales
US9006158B2 (en) 2010-12-09 2015-04-14 Basf Se Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines and use thereof as a fuel additive or lubricant additive
WO2015058992A1 (fr) 2013-10-24 2015-04-30 Basf Se Utilisation d'un polytétrahydrofurane alcoxylé en tant qu'additif dans un carburant
WO2015058993A2 (fr) 2013-10-24 2015-04-30 Basf Se Utilisation d'un polyalkylène glycol pour réduire la consommation de carburant
EP2883944A1 (fr) 2013-12-13 2015-06-17 Shell Internationale Research Maatschappij B.V. Nouvelles utilisations
US9062266B2 (en) 2012-02-10 2015-06-23 Basf Se Imidazolium salts as additives for fuels
WO2015091458A1 (fr) 2013-12-16 2015-06-25 Shell Internationale Research Maatschappij B.V. Compositions de carburant liquide
EP2891699A1 (fr) 2013-12-31 2015-07-08 Shell Internationale Research Maatschappij B.V. Compositions de carburant sans plomb
WO2015113681A1 (fr) 2014-01-29 2015-08-06 Basf Se Additifs à base d'acide polycarbonique, destinés à des carburants et à des lubrifiants
WO2015148361A1 (fr) * 2014-03-27 2015-10-01 The Procter & Gamble Company Compositions de nettoyage contenant une polyétheramine
EP2949733A1 (fr) 2014-05-28 2015-12-02 Shell Internationale Research Maatschappij B.V. Compositions d'essence contenant d'absorbants uv de type oxanilide
US9296841B2 (en) 2010-11-30 2016-03-29 Basf Se Preparation of isobutene homo- or copolymer derivatives
US9315759B2 (en) 2007-07-16 2016-04-19 Basf Se Synergistic mixture
US9388354B2 (en) 2012-11-06 2016-07-12 Basf Se Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines
WO2016135036A1 (fr) 2015-02-27 2016-09-01 Shell Internationale Research Maatschappij B.V. Utilisation d'une composition de graissage
US9434900B2 (en) 2012-12-21 2016-09-06 Shell Oil Company Liquid fuel compositions
WO2017050777A1 (fr) 2015-09-22 2017-03-30 Shell Internationale Research Maatschappij B.V. Compositions de combustible
WO2017093203A1 (fr) 2015-11-30 2017-06-08 Shell Internationale Research Maatschappij B.V. Composition de carburant
EP3205705A1 (fr) 2013-06-07 2017-08-16 Basf Se Utilisation avec de l'oxyde d'alkylène et de l'acide polycarbonique à substitution hydrocarbyle d'alkylamines quaternisés comme additifs dans les carburants et lubrifiants
WO2017144378A1 (fr) 2016-02-23 2017-08-31 Basf Se Acides polycarboxyliques hydrophobes utilisés comme additifs réducteurs d'usure par frottement dans des carburants
DE212015000271U1 (de) 2014-11-25 2017-09-06 Basf Se Korrosionsinhibitoren für Kraft- und Schmierstoffe
WO2018007445A1 (fr) 2016-07-07 2018-01-11 Basf Se Inhibiteurs de corrosion pour carburants et lubrifiants
WO2018007192A1 (fr) 2016-07-05 2018-01-11 Basf Se Inhibiteurs de corrosion pour carburants et lubrifiants
WO2018007375A1 (fr) 2016-07-07 2018-01-11 Basf Se Copolymères utilisés en tant qu'additifs pour carburants et lubrifiants
WO2018007486A1 (fr) 2016-07-07 2018-01-11 Basf Se Polymères utilisés en tant qu'additifs pour carburants et lubrifiants
WO2018007191A1 (fr) 2016-07-05 2018-01-11 Basf Se Utilisation d'inhibiteurs de corrosion pour carburants et lubrifiants
DE212016000150U1 (de) 2015-07-24 2018-03-16 Basf Se Korrosionsinhibitoren für Kraft- und Schmierstoffe
US9951285B2 (en) 2011-06-28 2018-04-24 Basf Se Quaternized nitrogen compounds and use thereof as additives in fuels and lubricants
WO2018108534A1 (fr) 2016-12-15 2018-06-21 Basf Se Polymères comme additifs pour carburants
WO2018114348A1 (fr) 2016-12-19 2018-06-28 Basf Se Additifs pour améliorer la stabilité thermique des carburants
WO2018114350A1 (fr) 2016-12-20 2018-06-28 Basf Se Utilisation d'un mélange d'un ester complexe avec un acide monocarboxylique pour réduire un frottement
US10030206B2 (en) 2013-10-24 2018-07-24 Basf Se Use of a complex ester to reduce fuel consumption
WO2018188986A1 (fr) 2017-04-13 2018-10-18 Basf Se Polymères utilisés en tant qu'additifs pour carburants et lubrifiants
WO2018188982A1 (fr) 2017-04-11 2018-10-18 Basf Se Amines alcoxylées utilisées comme additifs pour carburants
US10240100B2 (en) 2014-01-29 2019-03-26 Basf Se Corrosion inhibitors for fuels and lubricants
EP3483234A1 (fr) 2013-09-20 2019-05-15 Basf Se Utilisation de dérivés spéciaux de composés azotés quaternisés en tant qu'additifs dans des carburants et des lubrifiants
US10294436B2 (en) 2014-11-12 2019-05-21 Shell Oil Company Fuel composition
WO2020007790A1 (fr) 2018-07-02 2020-01-09 Shell Internationale Research Maatschappij B.V. Compositions de carburant liquide
WO2020260062A1 (fr) 2019-06-26 2020-12-30 Basf Se Nouveaux packages d'additifs pour carburants à base d'essence
WO2021063733A1 (fr) 2019-09-30 2021-04-08 Basf Se Utilisation de composés azotés quaternisés avec de l'oxyde d'alkylène et de l'acide polycarboxylique à substitution hydrocarbyle en tant qu'additifs dans des carburants et des lubrifiants
WO2021078753A1 (fr) 2019-10-22 2021-04-29 Shell Internationale Research Maatschappij B.V. Procédé de réduction de dépôts de soupape d'admission
US11085001B2 (en) 2015-07-16 2021-08-10 Basf Se Copolymers as additives for fuels and lubricants
EP3933014A1 (fr) 2020-06-30 2022-01-05 Basf Se Additivation de carburants permettant de réduire les allumages non contrôlés dans des moteurs à combustion interne
EP3940043A1 (fr) 2020-07-14 2022-01-19 Basf Se Inhibiteurs de corrosion pour carburants et lubrifiants
WO2022017912A1 (fr) 2020-07-20 2022-01-27 Shell Internationale Research Maatschappij B.V. Composition de carburant
EP3945126A1 (fr) 2020-07-31 2022-02-02 Basf Se Compositions de débrumage pour carburants
WO2022106301A1 (fr) 2020-11-20 2022-05-27 Basf Se Mélanges pour améliorer ou renforcer la séparation de l'eau de carburants
WO2022128569A2 (fr) 2020-12-16 2022-06-23 Basf Se Nouveaux mélanges pour améliorer la stabilité d'ensembles d'additifs
WO2022161803A1 (fr) 2021-01-27 2022-08-04 Basf Se Amines d'alkyle primaires ramifiées en tant qu'additifs pour carburants de type essence
WO2022228990A1 (fr) 2021-04-26 2022-11-03 Shell Internationale Research Maatschappij B.V. Compositions de carburant
WO2022228989A1 (fr) 2021-04-26 2022-11-03 Shell Internationale Research Maatschappij B.V. Compositions de combustible
EP4105301A1 (fr) 2021-06-15 2022-12-21 Basf Se Nouveaux paquets d'additifs pour l'essence
WO2022263244A1 (fr) 2021-06-16 2022-12-22 Basf Se Bétaïnes quaternisées servant d'additifs dans des carburants
DE102022131356A1 (de) 2022-11-28 2023-01-12 Basf Se Formamidine als Kraftstoffadditive
DE102022132342A1 (de) 2022-12-06 2023-01-26 Basf Se Guanidiniumsalze als Kraftstoffadditive
DE102022131890A1 (de) 2022-12-01 2023-01-26 Basf Se Guanidinderivate als Kraftstoffadditive
WO2023052286A1 (fr) 2021-09-29 2023-04-06 Shell Internationale Research Maatschappij B.V. Compositions de carburant
EP4163353A1 (fr) 2021-10-06 2023-04-12 Basf Se Procédé de réduction de dépôts sur les soupapes d'admission
WO2023111550A1 (fr) 2021-12-14 2023-06-22 Innospec Limited Procédés et utilisations relatifs à des compositions de carburant
EP4269541A1 (fr) 2022-04-29 2023-11-01 Basf Se Nouveaux mélanges pour améliorer ou renforcer la séparation de l'eau à partir de carburants
WO2024017743A1 (fr) 2022-07-20 2024-01-25 Shell Internationale Research Maatschappij B.V. Compositions de carburant
WO2024083782A1 (fr) 2022-10-21 2024-04-25 Shell Internationale Research Maatschappij B.V. Compositions de carburant
EP4382588A1 (fr) 2022-12-06 2024-06-12 Basf Se Additifs pour améliorer la stabilité thermique de carburants
WO2024149635A1 (fr) 2023-01-12 2024-07-18 Basf Se Amines ramifiées en tant qu'additifs pour carburants à base d'essence
WO2024251585A1 (fr) 2023-06-08 2024-12-12 Shell Internationale Research Maatschappij B.V. Composition de carburant
EP4556456A1 (fr) 2023-10-31 2025-05-21 Basf Se Procédé de fabrication d'éthylène glycols et d'éthoxylates basés sur l'énergie non-fosil
WO2026046756A1 (fr) 2024-08-29 2026-03-05 Basf Se Procédé pour améliorer l'injection de moteurs à essence à injection directe

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6217624B1 (en) * 1999-02-18 2001-04-17 Chevron Chemical Company Llc Fuel compositions containing hydrocarbyl-substituted polyoxyalkylene amines
US6193767B1 (en) * 1999-09-28 2001-02-27 The Lubrizol Corporation Fuel additives and fuel compositions comprising said fuel additives
US6224642B1 (en) 1999-11-23 2001-05-01 The Lubrizol Corporation Additive composition
US6458172B1 (en) 2000-03-03 2002-10-01 The Lubrizol Corporation Fuel additive compositions and fuel compositions containing detergents and fluidizers
US7204863B2 (en) * 2001-12-11 2007-04-17 Exxonmobil Research And Engineering Company Gasoline additives for reducing the amount of internal combustion engine intake valve deposits and combustion chamber deposits
US7226489B2 (en) 2001-12-12 2007-06-05 Exxonmobil Research And Engineering Company Gasoline additives for reducing the amount of internal combustion engine intake valve deposits and combustion chamber deposits
DE10239841A1 (de) * 2002-08-29 2004-03-11 Basf Ag Additivgemische für Kraft- und Schmierstoffe
DE102004038113A1 (de) 2004-08-05 2006-03-16 Basf Ag Stickstoffhaltige heterocyclische Verbindungen als Reibverschleißvermindernder Zusatz zu Kraftstoffen
KR20070049178A (ko) * 2004-08-06 2007-05-10 바스프 악티엔게젤샤프트 연료 및 윤활유용 폴리아민 첨가제
US9650583B2 (en) 2004-10-19 2017-05-16 The Lubrizol Corporation Additive and fuel compositions containing detergent and fluidizer and method thereof
BRPI0720645A2 (pt) * 2006-12-28 2014-01-07 Lubrizol Corp Concentrado de aditivo para combustíveis, modificador de atrito, composição de combustível e método para abastecer um motor de combustão interna
JP7083310B2 (ja) 2015-12-03 2022-06-10 中国石油化工股▲ふん▼有限公司 アミン系ポリマー、その製造方法、およびその用途
GB202118103D0 (en) 2021-12-14 2022-01-26 Innospec Ltd Fuel compositions
GB202118104D0 (en) 2021-12-14 2022-01-26 Innospec Ltd Methods and uses relating to fuel compositions
GB202118107D0 (en) 2021-12-14 2022-01-26 Innospec Ltd Fuel compositions

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4247301A (en) * 1978-06-19 1981-01-27 Chevron Research Company Deposit control and dispersant additives
EP0100665A2 (fr) * 1982-07-30 1984-02-15 Chevron Research Company Additifs contrôlant des dépôts de carburants hydrocarbones et de lubrifiants utilisés dans des moteurs à combustion interne
EP0310875A1 (fr) 1987-09-30 1989-04-12 BASF Aktiengesellschaft Combustibles contenant une polyétheramine pour moteur à allumage par étincelle
EP0440248A1 (fr) * 1990-02-02 1991-08-07 Kao Corporation Composition d'essence
DE4309074A1 (de) * 1993-03-20 1994-09-22 Basf Ag Als Kraftstoffadditiv geeignete Mischungen

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3440029A (en) * 1964-05-20 1969-04-22 Dow Chemical Co Gasoline containing anti-icing additive
GB1403248A (en) * 1972-10-27 1975-08-28 British Petroleum Co Amino ethers
US4332595A (en) * 1980-12-05 1982-06-01 Texaco Inc. Ether amine detergent and motor fuel composition containing same
US4392866A (en) * 1981-11-05 1983-07-12 Texaco Inc. Etheramine corrosion inhibitor for alcohols
US4604103A (en) * 1982-07-30 1986-08-05 Chevron Research Company Deposit control additives--polyether polyamine ethanes
EP0110665B1 (fr) * 1982-11-27 1987-06-10 Peak Pattern Co. Limited Appareil broyeur
US4526587A (en) * 1983-05-31 1985-07-02 Chevron Research Company Deposit control additives-methylol polyether amino ethanes
US4527996A (en) * 1983-10-31 1985-07-09 Chevron Research Company Deposit control additives - hydroxy polyether polyamines
DE3611230A1 (de) * 1986-04-04 1987-10-08 Basf Ag Polybutyl- und polyisobutylamine, verfahren zu deren herstellung und diese enthaltende kraft- und schmierstoffzusammensetzungen
DE3700363A1 (de) * 1987-01-08 1988-07-21 Basf Ag Kraft- oder schmierstoffzusammensetzung und verwendung von polybutyl- oder polyisobutylderivaten in denselben
DE3826608A1 (de) * 1988-08-05 1990-02-08 Basf Ag Polyetheramine oder polyetheraminderivate enthaltende kraftstoffe fuer ottomotoren
US4964879A (en) * 1989-03-27 1990-10-23 Texaco Inc. Middle distillate fuel containing deposit inhibitor
US5094667A (en) * 1990-03-20 1992-03-10 Exxon Research And Engineering Company Guerbet alkyl ether mono amines

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4247301A (en) * 1978-06-19 1981-01-27 Chevron Research Company Deposit control and dispersant additives
EP0100665A2 (fr) * 1982-07-30 1984-02-15 Chevron Research Company Additifs contrôlant des dépôts de carburants hydrocarbones et de lubrifiants utilisés dans des moteurs à combustion interne
EP0310875A1 (fr) 1987-09-30 1989-04-12 BASF Aktiengesellschaft Combustibles contenant une polyétheramine pour moteur à allumage par étincelle
EP0440248A1 (fr) * 1990-02-02 1991-08-07 Kao Corporation Composition d'essence
DE4309074A1 (de) * 1993-03-20 1994-09-22 Basf Ag Als Kraftstoffadditiv geeignete Mischungen

Cited By (153)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1122295A4 (fr) * 1998-10-06 2002-02-06 Nippon Mitsubishi Oil Corp Additif pour essence destinee a un moteur a essence a injection directe
US7601185B2 (en) 2002-03-06 2009-10-13 Basf Aktiengesellschaft Fuel additive mixtures for gasolines with synergistic IVD performance
US7753970B2 (en) 2003-04-01 2010-07-13 Basf Aktiengesellschaft Polyalkene amines with improved applicational properties
EP2270119A1 (fr) 2003-04-11 2011-01-05 Basf Se Composition de carburant
EP2270119B1 (fr) 2003-04-11 2020-07-15 Basf Se Composition de carburant
EP3736317A1 (fr) 2003-04-11 2020-11-11 Basf Se Composition de carburant
EP2267104A2 (fr) 2006-02-27 2010-12-29 Basf Se Utilisation de composés phénoliques polynucléaires comme dispersants
EP2272821A2 (fr) 2006-02-27 2011-01-12 Basf Se Composés phénoliques trinucléaires
US10062471B2 (en) 2007-03-02 2018-08-28 Basf Se Additive formulation suitable for antistatic modification and improving the electrical conductivity of inanimate organic material
US8858838B2 (en) 2007-03-02 2014-10-14 Basf Se Additive formulation suitable for antistatic modification and improving the electrical conductivity of inanimate organic material
US8551365B2 (en) 2007-03-02 2013-10-08 Basf Se Additive formulation suitable for antistatic modification and improving the electrical conductivity of inanimate organic material
US9670430B2 (en) 2007-07-16 2017-06-06 Basf Se Synergistic mixture
US9562202B2 (en) 2007-07-16 2017-02-07 Basf Se Synergistic mixture
US9315759B2 (en) 2007-07-16 2016-04-19 Basf Se Synergistic mixture
DE102008037662A1 (de) 2007-08-17 2009-04-23 Basf Se Öllösliches Detergens und Verfahren zur Herstellung funktionalisierter Polyalkene
WO2009050287A1 (fr) 2007-10-19 2009-04-23 Shell Internationale Research Maatschappij B.V. Fluides fonctionnels pour moteurs à combustion interne
US8486876B2 (en) 2007-10-19 2013-07-16 Shell Oil Company Functional fluids for internal combustion engines
WO2009095443A1 (fr) 2008-02-01 2009-08-06 Basf Se Polyisobutène-amines spécifiques, et leur utilisation comme détergents dans des carburants
DE102010001408A1 (de) 2009-02-06 2010-08-12 Basf Se Verwendung von Ketonen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauches von Dieselmotoren
DE102010039039A1 (de) 2009-08-24 2011-03-03 Basf Se Verwendung von organischen Verbindungen als Kraftstoffzusatz zur Verringerung des Kraftstoffverbrauchs von Dieselmotoren
US8790426B2 (en) 2010-04-27 2014-07-29 Basf Se Quaternized terpolymer
WO2011134923A1 (fr) 2010-04-27 2011-11-03 Basf Se Terpolymère quaternisé
WO2011151207A1 (fr) 2010-06-01 2011-12-08 Basf Se Amines à substitution polyisobutyle, de faible masse moléculaire, servant de renforçateurs de détergents
US8911516B2 (en) 2010-06-25 2014-12-16 Basf Se Quaternized copolymer
WO2011161149A1 (fr) 2010-06-25 2011-12-29 Basf Se Copolymère quaternisé
EP3327044A1 (fr) 2010-07-06 2018-05-30 Basf Se Säurefreie quaternisierte stickstoffverbindungen und deren verwendung als additive in kraft- und schmierstoffen
EP2808350A1 (fr) 2010-07-06 2014-12-03 Basf Se Liaisons d'azote quaternisées sans acide et leur utilisation en tant qu'additifs dans des carburants et des lubrifiants
WO2012004300A1 (fr) 2010-07-06 2012-01-12 Basf Se Composés azotés quaternisés exempts d'acide et utilisation desdits composés comme additifs pour carburants ou pour lubrifiants
EP3747915A1 (fr) 2010-07-06 2020-12-09 Basf Se Utilisation de composés azotés quaternisés comme additifs pour carburants
WO2012072643A2 (fr) 2010-11-30 2012-06-07 Basf Se Préparation de dérivés d'homopolymères ou de copolymères d'isobutène
US10745496B2 (en) 2010-11-30 2020-08-18 Basf Se Preparation of isobutene homo- or copolymer derivatives
US9296841B2 (en) 2010-11-30 2016-03-29 Basf Se Preparation of isobutene homo- or copolymer derivatives
US11306161B2 (en) 2010-11-30 2022-04-19 Basf Se Preparation of isobutene homo- or copolymer derivatives
EP4406982A2 (fr) 2010-11-30 2024-07-31 Basf Se Production de dérivés d'homo ou de copolymères d'isobutène
WO2012072723A2 (fr) 2010-12-02 2012-06-07 Basf Se Utilisation du produit réactionnel d'un acide dicarbonique à substitution hydrocarbyle et d'un composé azote pour réduire la consommation de carburant
US9359570B2 (en) 2010-12-09 2016-06-07 Basf Se Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines and use thereof as a fuel additive or lubricant additive
WO2012076428A1 (fr) 2010-12-09 2012-06-14 Basf Se Polytetrahydrobenzoxazines et bistetrahydrobenzoxazines et leur utilisation comme additif pour carburant ou additif pour lubrifiant
US9006158B2 (en) 2010-12-09 2015-04-14 Basf Se Polytetrahydrobenzoxazines and bistetrahydrobenzoxazines and use thereof as a fuel additive or lubricant additive
EP3263563A1 (fr) 2010-12-09 2018-01-03 Basf Se Polytétrahydrobenzoxazine et bistétrahydrobenzoxazine et leur utilisation en tant qu'additif de carburant ou additif de lubrifiant
WO2012163935A2 (fr) 2011-05-30 2012-12-06 Shell Internationale Research Maatschappij B.V. Compositions de carburants liquides
EP2540808A1 (fr) 2011-06-28 2013-01-02 Basf Se Composés d'azote quaternisés et leur utilisation en tant qu'additifs dans des carburants et des lubrifiants
US10119085B2 (en) 2011-06-28 2018-11-06 Basf Se Quaternized nitrogen compounds and use thereof as additives in fuels and lubricants
WO2013000997A1 (fr) 2011-06-28 2013-01-03 Basf Se Composés azotés quaternisés et utilisation desdits composés comme additifs pour carburants ou pour lubrifiants
US9951285B2 (en) 2011-06-28 2018-04-24 Basf Se Quaternized nitrogen compounds and use thereof as additives in fuels and lubricants
US10550346B2 (en) 2011-06-28 2020-02-04 Basf Se Quaternized nitrogen compounds and use thereof as additives in fuels and lubricants
EP2589647A1 (fr) 2011-11-04 2013-05-08 Basf Se Polyétheramines quaternisées et leur utilisation en tant qu'additifs dans des carburants et des lubrifiants
WO2013064689A1 (fr) 2011-11-04 2013-05-10 Basf Se Polyétheramines quaternaires et leur utilisation en tant qu'additifs dans des carburants et des lubrifiants
WO2013087701A1 (fr) 2011-12-12 2013-06-20 Basf Se Utilisation d'alkylamines quaternisées en tant qu'additifs de carburants et de lubrifiants
EP4219667A2 (fr) 2011-12-12 2023-08-02 Basf Se Utilisation d'alkylamines quaternisées comme additifs dans des carburants et des lubrifiants
EP2604674A1 (fr) 2011-12-12 2013-06-19 Basf Se Utilisation d'alkylamine quaternisé comme additif dans des carburants et des lubrifiants
WO2013117616A1 (fr) 2012-02-10 2013-08-15 Basf Se Sels d'imidazolium en tant qu'additifs pour carburants et combustibles
US9062266B2 (en) 2012-02-10 2015-06-23 Basf Se Imidazolium salts as additives for fuels
WO2013174619A1 (fr) 2012-05-25 2013-11-28 Basf Se Amines tertiaires pour la réduction de l'encrassement d'injecteurs dans des moteurs à allumage par étincelles et à injection directe
WO2014019911A1 (fr) 2012-08-01 2014-02-06 Basf Se Procédé d'amélioration de la thermostabilité d'huiles lubrifiantes dans des moteurs à combustion interne
WO2014064151A1 (fr) 2012-10-23 2014-05-01 Basf Se Sels d'ammonium quaternisés d'époxydes hydrocarbyliques et utilisation desdits sels d'ammonium quaternisés d'époxydes hydrocarbyliques comme additifs de carburants et de lubrifiants
US10173963B2 (en) 2012-10-23 2019-01-08 Basf Se Quaternized ammonium salts of hydrocarbyl epoxides and use thereof as additives in fuels and lubricants
US10689326B2 (en) 2012-10-23 2020-06-23 Basf Se Quaternized ammonium salts of hydrocarbyl epoxides and use thereof as additives in fuels and lubricants
WO2014023853A2 (fr) 2012-11-06 2014-02-13 Basf Se Amines tertiaires permettant de réduire l'encrassement des buses d'injecteur et de modifier le frottement dans les moteurs à allumage par étincelle avec injection directe
US9388354B2 (en) 2012-11-06 2016-07-12 Basf Se Tertiary amines for reducing injector nozzle fouling and modifying friction in direct injection spark ignition engines
US9434900B2 (en) 2012-12-21 2016-09-06 Shell Oil Company Liquid fuel compositions
WO2014184066A1 (fr) 2013-05-14 2014-11-20 Basf Se Polyalcénylsuccinimides pour réduire l'encrassement d'injecteurs dans des moteurs à allumage commandé et injection directe
EP2811007A1 (fr) 2013-06-07 2014-12-10 Basf Se Utilisation avec de l'oxyde d'alkylène et de l'acide polycarbonique à substitution hydrocarbyle d'alkylamines quaternisés comme additifs dans les carburants et lubrifiants
EP4190882A1 (fr) 2013-06-07 2023-06-07 Basf Se Utilisation avec de l'oxyde d'alkylène et de l'acide polycarboxylique substitué par un hydrocarbyle de composés azotés quaternisés comme additifs dans les carburants et lubrifiants
US11912950B2 (en) 2013-06-07 2024-02-27 Basf Se Use of nitrogen compounds quaternised with alkylene oxide and hydrocarbyl-substituted polycarboxylic acid as additives in fuels and lubricants
EP4442792A2 (fr) 2013-06-07 2024-10-09 Basf Se Utilisation avec de l'oxyde d'alkylène et de l'acide polycarboxylique substitué par un hydrocarbyle de composés azotés quaternisés comme additifs dans les carburants et lubrifiants
US10676685B2 (en) 2013-06-07 2020-06-09 Basf Se Use of nitrogen compounds quaternised with alkylene oxide and hydrocarbyl-substituted polycarboxylic acid as additives in fuels and lubricants
US11111449B2 (en) 2013-06-07 2021-09-07 Basf Se Use of nitrogen compounds quaternised with alkylene oxide and hydrocarbyl-substituted polycarboxylic acid as additives in fuels and lubricants
EP3653689A1 (fr) 2013-06-07 2020-05-20 Basf Se Utilisation d'acides polycarboxyliques substitués en oxyde d'alkylène et hydrocarbyle de composés azotés quaternisés en tant qu'additifs dans des carburants et des lubrifiants
EP3205705A1 (fr) 2013-06-07 2017-08-16 Basf Se Utilisation avec de l'oxyde d'alkylène et de l'acide polycarbonique à substitution hydrocarbyle d'alkylamines quaternisés comme additifs dans les carburants et lubrifiants
US10407634B2 (en) 2013-06-07 2019-09-10 Basf Se Use of nitrogen compounds quaternised with alkylene oxide and hydrocarbyl-substituted polycarboxylic acid as additives in fuels and lubricants
US10174269B2 (en) 2013-07-12 2019-01-08 Basf Se Use of a hydrocarbyl-substituted dicarboxylic acid for improving or boosting the separation of water from fuel oils and gasoline fuels
WO2015003961A1 (fr) 2013-07-12 2015-01-15 Basf Se Utilisation d'un acide dicarboxylique à substitution hydrocarbyle pour améliorer ou augmenter la séparation de l'eau du fioul et de l'essence
US10858608B2 (en) 2013-07-12 2020-12-08 Basf Se Use of a hydrocarbyl-substituted dicarboxylic acid for improving or boosting the separation of water from fuel oils and gasoline fuels
US9688791B2 (en) 2013-07-17 2017-06-27 Basf Se High-reactivity polyisobutylene having a high content of vinylidene double bonds in the side chains
WO2015007553A1 (fr) 2013-07-17 2015-01-22 Basf Se Polyisobutylène à réactivité élevée et à haute teneur en doubles liaisons vinylidène dans les chaînes latérales
EP3483234A1 (fr) 2013-09-20 2019-05-15 Basf Se Utilisation de dérivés spéciaux de composés azotés quaternisés en tant qu'additifs dans des carburants et des lubrifiants
US10815444B2 (en) 2013-09-20 2020-10-27 Basf Se Use of specific derivatives of quaternized nitrogen compounds as additives in fuels and lubricants
US10370610B2 (en) 2013-09-20 2019-08-06 Basf Se Use of specific derivatives of quaternized nitrogen compounds as additives in fuels and lubricants
US9957455B2 (en) 2013-10-24 2018-05-01 Basf Se Use of a polyalkylene glycol to reduce fuel consumption
US10030206B2 (en) 2013-10-24 2018-07-24 Basf Se Use of a complex ester to reduce fuel consumption
WO2015058992A1 (fr) 2013-10-24 2015-04-30 Basf Se Utilisation d'un polytétrahydrofurane alcoxylé en tant qu'additif dans un carburant
WO2015058993A2 (fr) 2013-10-24 2015-04-30 Basf Se Utilisation d'un polyalkylène glycol pour réduire la consommation de carburant
US9951288B2 (en) 2013-10-24 2018-04-24 Basf Se Use of an alkoxylated polytetrahydrofuran to reduce fuel consumption
EP3241882A1 (fr) 2013-10-24 2017-11-08 Basf Se Composition de carburant
US10465138B2 (en) 2013-10-24 2019-11-05 Basf Se Use of a complex ester to reduce fuel consumption
EP2883944A1 (fr) 2013-12-13 2015-06-17 Shell Internationale Research Maatschappij B.V. Nouvelles utilisations
US9587195B2 (en) 2013-12-16 2017-03-07 Shell Oil Company Liquid composition
WO2015091458A1 (fr) 2013-12-16 2015-06-25 Shell Internationale Research Maatschappij B.V. Compositions de carburant liquide
EP2891699A1 (fr) 2013-12-31 2015-07-08 Shell Internationale Research Maatschappij B.V. Compositions de carburant sans plomb
US11634654B2 (en) 2014-01-29 2023-04-25 Basf Se Polycarboxylic acid-based additives for fuels and lubricants
EP3363879A2 (fr) 2014-01-29 2018-08-22 Basf Se Carburants diesel contenant des additifs à base d'acide polycarboxique
US10377958B2 (en) 2014-01-29 2019-08-13 Basf Se Corrosion inhibitors for fuels and lubricants
WO2015113681A1 (fr) 2014-01-29 2015-08-06 Basf Se Additifs à base d'acide polycarbonique, destinés à des carburants et à des lubrifiants
US10240100B2 (en) 2014-01-29 2019-03-26 Basf Se Corrosion inhibitors for fuels and lubricants
US11168273B2 (en) 2014-01-29 2021-11-09 Basf Se Polycarboxylic acid-based additives for fuels and lubricants
WO2015148361A1 (fr) * 2014-03-27 2015-10-01 The Procter & Gamble Company Compositions de nettoyage contenant une polyétheramine
EP2949733A1 (fr) 2014-05-28 2015-12-02 Shell Internationale Research Maatschappij B.V. Compositions d'essence contenant d'absorbants uv de type oxanilide
US10294436B2 (en) 2014-11-12 2019-05-21 Shell Oil Company Fuel composition
DE212015000271U1 (de) 2014-11-25 2017-09-06 Basf Se Korrosionsinhibitoren für Kraft- und Schmierstoffe
WO2016135036A1 (fr) 2015-02-27 2016-09-01 Shell Internationale Research Maatschappij B.V. Utilisation d'une composition de graissage
US11085001B2 (en) 2015-07-16 2021-08-10 Basf Se Copolymers as additives for fuels and lubricants
DE212016000150U1 (de) 2015-07-24 2018-03-16 Basf Se Korrosionsinhibitoren für Kraft- und Schmierstoffe
US10808195B2 (en) 2015-09-22 2020-10-20 Shell Oil Company Fuel compositions
WO2017050777A1 (fr) 2015-09-22 2017-03-30 Shell Internationale Research Maatschappij B.V. Compositions de combustible
WO2017093203A1 (fr) 2015-11-30 2017-06-08 Shell Internationale Research Maatschappij B.V. Composition de carburant
WO2017144378A1 (fr) 2016-02-23 2017-08-31 Basf Se Acides polycarboxyliques hydrophobes utilisés comme additifs réducteurs d'usure par frottement dans des carburants
WO2018007192A1 (fr) 2016-07-05 2018-01-11 Basf Se Inhibiteurs de corrosion pour carburants et lubrifiants
US11078418B2 (en) 2016-07-05 2021-08-03 Basf Se Corrosion inhibitors for fuels and lubricants
US10844308B2 (en) 2016-07-05 2020-11-24 Basf Se Corrosion inhibitors for fuels and lubricants
WO2018007191A1 (fr) 2016-07-05 2018-01-11 Basf Se Utilisation d'inhibiteurs de corrosion pour carburants et lubrifiants
WO2018007486A1 (fr) 2016-07-07 2018-01-11 Basf Se Polymères utilisés en tant qu'additifs pour carburants et lubrifiants
WO2018007375A1 (fr) 2016-07-07 2018-01-11 Basf Se Copolymères utilisés en tant qu'additifs pour carburants et lubrifiants
WO2018007445A1 (fr) 2016-07-07 2018-01-11 Basf Se Inhibiteurs de corrosion pour carburants et lubrifiants
US10947467B2 (en) 2016-12-15 2021-03-16 Basf Se Polymers as additives for fuels
WO2018108534A1 (fr) 2016-12-15 2018-06-21 Basf Se Polymères comme additifs pour carburants
US11566196B2 (en) 2016-12-15 2023-01-31 Basf Se Polymers as additives for fuels
WO2018114348A1 (fr) 2016-12-19 2018-06-28 Basf Se Additifs pour améliorer la stabilité thermique des carburants
WO2018114350A1 (fr) 2016-12-20 2018-06-28 Basf Se Utilisation d'un mélange d'un ester complexe avec un acide monocarboxylique pour réduire un frottement
US10927319B2 (en) 2016-12-20 2021-02-23 Basf Se Use of a mixture of a complex ester with a monocarboxylic acid to reduce friction
US11130923B2 (en) 2017-04-11 2021-09-28 Basf Se Alkoxylated amines as fuel additives
WO2018188982A1 (fr) 2017-04-11 2018-10-18 Basf Se Amines alcoxylées utilisées comme additifs pour carburants
WO2018188986A1 (fr) 2017-04-13 2018-10-18 Basf Se Polymères utilisés en tant qu'additifs pour carburants et lubrifiants
US11499107B2 (en) 2018-07-02 2022-11-15 Shell Usa, Inc. Liquid fuel compositions
WO2020007790A1 (fr) 2018-07-02 2020-01-09 Shell Internationale Research Maatschappij B.V. Compositions de carburant liquide
WO2020260062A1 (fr) 2019-06-26 2020-12-30 Basf Se Nouveaux packages d'additifs pour carburants à base d'essence
WO2021063733A1 (fr) 2019-09-30 2021-04-08 Basf Se Utilisation de composés azotés quaternisés avec de l'oxyde d'alkylène et de l'acide polycarboxylique à substitution hydrocarbyle en tant qu'additifs dans des carburants et des lubrifiants
WO2021078753A1 (fr) 2019-10-22 2021-04-29 Shell Internationale Research Maatschappij B.V. Procédé de réduction de dépôts de soupape d'admission
EP3933014A1 (fr) 2020-06-30 2022-01-05 Basf Se Additivation de carburants permettant de réduire les allumages non contrôlés dans des moteurs à combustion interne
EP3940043A1 (fr) 2020-07-14 2022-01-19 Basf Se Inhibiteurs de corrosion pour carburants et lubrifiants
WO2022017912A1 (fr) 2020-07-20 2022-01-27 Shell Internationale Research Maatschappij B.V. Composition de carburant
EP3945126A1 (fr) 2020-07-31 2022-02-02 Basf Se Compositions de débrumage pour carburants
WO2022106301A1 (fr) 2020-11-20 2022-05-27 Basf Se Mélanges pour améliorer ou renforcer la séparation de l'eau de carburants
WO2022128569A2 (fr) 2020-12-16 2022-06-23 Basf Se Nouveaux mélanges pour améliorer la stabilité d'ensembles d'additifs
WO2022161803A1 (fr) 2021-01-27 2022-08-04 Basf Se Amines d'alkyle primaires ramifiées en tant qu'additifs pour carburants de type essence
WO2022228989A1 (fr) 2021-04-26 2022-11-03 Shell Internationale Research Maatschappij B.V. Compositions de combustible
WO2022228990A1 (fr) 2021-04-26 2022-11-03 Shell Internationale Research Maatschappij B.V. Compositions de carburant
EP4105301A1 (fr) 2021-06-15 2022-12-21 Basf Se Nouveaux paquets d'additifs pour l'essence
WO2022263254A1 (fr) 2021-06-15 2022-12-22 Basf Se Nouveaux ensembles d'additifs d'essence
WO2022263244A1 (fr) 2021-06-16 2022-12-22 Basf Se Bétaïnes quaternisées servant d'additifs dans des carburants
WO2023052286A1 (fr) 2021-09-29 2023-04-06 Shell Internationale Research Maatschappij B.V. Compositions de carburant
EP4163353A1 (fr) 2021-10-06 2023-04-12 Basf Se Procédé de réduction de dépôts sur les soupapes d'admission
WO2023111550A1 (fr) 2021-12-14 2023-06-22 Innospec Limited Procédés et utilisations relatifs à des compositions de carburant
EP4269541A1 (fr) 2022-04-29 2023-11-01 Basf Se Nouveaux mélanges pour améliorer ou renforcer la séparation de l'eau à partir de carburants
WO2024017743A1 (fr) 2022-07-20 2024-01-25 Shell Internationale Research Maatschappij B.V. Compositions de carburant
WO2024083782A1 (fr) 2022-10-21 2024-04-25 Shell Internationale Research Maatschappij B.V. Compositions de carburant
DE102022131356A1 (de) 2022-11-28 2023-01-12 Basf Se Formamidine als Kraftstoffadditive
DE102022131890A1 (de) 2022-12-01 2023-01-26 Basf Se Guanidinderivate als Kraftstoffadditive
EP4382588A1 (fr) 2022-12-06 2024-06-12 Basf Se Additifs pour améliorer la stabilité thermique de carburants
DE102022132342A1 (de) 2022-12-06 2023-01-26 Basf Se Guanidiniumsalze als Kraftstoffadditive
WO2024149635A1 (fr) 2023-01-12 2024-07-18 Basf Se Amines ramifiées en tant qu'additifs pour carburants à base d'essence
WO2024251585A1 (fr) 2023-06-08 2024-12-12 Shell Internationale Research Maatschappij B.V. Composition de carburant
EP4556456A1 (fr) 2023-10-31 2025-05-21 Basf Se Procédé de fabrication d'éthylène glycols et d'éthoxylates basés sur l'énergie non-fosil
WO2026046756A1 (fr) 2024-08-29 2026-03-05 Basf Se Procédé pour améliorer l'injection de moteurs à essence à injection directe

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DE59505179D1 (de) 1999-04-08
US5660601A (en) 1997-08-26
EP0700985B1 (fr) 1999-03-03
DE4432038A1 (de) 1996-03-14
JP3725588B2 (ja) 2005-12-14
JPH0892574A (ja) 1996-04-09
ES2127976T3 (es) 1999-05-01

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