EP0711399A1 - Radiatorrohr, verfahren und vorrichtung zu dessen herstellung - Google Patents

Radiatorrohr, verfahren und vorrichtung zu dessen herstellung

Info

Publication number
EP0711399A1
EP0711399A1 EP94924586A EP94924586A EP0711399A1 EP 0711399 A1 EP0711399 A1 EP 0711399A1 EP 94924586 A EP94924586 A EP 94924586A EP 94924586 A EP94924586 A EP 94924586A EP 0711399 A1 EP0711399 A1 EP 0711399A1
Authority
EP
European Patent Office
Prior art keywords
roll
tube
dimples
heat transfer
rolls
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94924586A
Other languages
English (en)
French (fr)
Other versions
EP0711399A4 (de
Inventor
John D. Lamberth
Peter M. Watson
Francis Clark, Sr.
David L. Tomlin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
INSILCO Corp THERMAL COMPONENTS DIVISION
Insilco Corp
Original Assignee
INSILCO Corp THERMAL COMPONENTS DIVISION
Insilco Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by INSILCO Corp THERMAL COMPONENTS DIVISION, Insilco Corp filed Critical INSILCO Corp THERMAL COMPONENTS DIVISION
Publication of EP0711399A1 publication Critical patent/EP0711399A1/de
Publication of EP0711399A4 publication Critical patent/EP0711399A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/02Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
    • F28F3/04Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element
    • F28F3/042Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element in the form of local deformations of the element
    • F28F3/044Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element in the form of local deformations of the element the deformations being pontual, e.g. dimples
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D13/00Corrugating sheet metal, rods or profiles; Bending sheet metal, rods or profiles into wave form
    • B21D13/04Corrugating sheet metal, rods or profiles; Bending sheet metal, rods or profiles into wave form by rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D53/00Making other particular articles
    • B21D53/02Making other particular articles heat exchangers or parts thereof, e.g. radiators, condensers fins, headers
    • B21D53/04Making other particular articles heat exchangers or parts thereof, e.g. radiators, condensers fins, headers of sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
    • F28D1/02Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid
    • F28D1/03Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with plate-like or laminated conduits
    • F28D1/0391Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators with heat-exchange conduits immersed in the body of fluid with plate-like or laminated conduits a single plate being bent to form one or more conduits
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00Tubular elements; Assemblies of tubular elements
    • F28F1/02Tubular elements of cross-section which is non-circular
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F1/00Tubular elements; Assemblies of tubular elements
    • F28F1/02Tubular elements of cross-section which is non-circular
    • F28F2001/027Tubular elements of cross-section which is non-circular with dimples

Definitions

  • the present invention relates to water tubes for copper/brass or aluminum radiators. More specifically, the invention relates to radiator tubes having welded seams and mating turbulator dimples forming pillars between the interior surfaces of the tubes, and a method
  • the prior art has employed a welded joint which does not rely on tin/lead solder.
  • Roll forming techniques using forming rolls and side forming or helix guides are employed to take the strip from its original flat shape to a tubular shape of circular cross-section and precise diameter.
  • high temperature the melting point of the parent metal
  • This compression at high temperature yields a leak-free joint.
  • a normal material or wall thickness increase is developed due to the compression and welding of the edges.
  • the tube After welding, the tube is passed through reduction rolls or tooling and breakdown rolls to transform the cross-section of the tube from circular to flattened oval.
  • radiator cores Thicker or higher density radiator cores, and consequently smaller face area or frontal surface in heat exchangers, are becoming more prevalent to meet the needs of automotive body styling, vehicle weight reduction, engine cooling, and air conditioning.
  • one-row radiator cores which traditionally were made in geometries with a height dimension (i.e. , the dimension along the major axis of the flattened oval shape, measured from exterior surface to exterior surface) from 15 mm. up to 38 mm., will now have to be made in geometries with a height dimension greater than 38 mm. Therefore, the height dimension of the flattened oval aluminum welded water tube will have to be increased to greater than 38 mm.
  • the parallel walls lose their column strength at high temperatures, causing them to sag or collapse.
  • the resulting tube has a concave or "hour glass" cross-section, which decreases tube-to-fin surface contact.
  • vacuum brazing or flux brazing (referred to in the heat exchanger industry as NOCOLOX and/or "controlled atmosphere brazing"), as disclosed in U.S. patent No. 3,971,501 to Cooke and in U.S. patent No. 4,955,525 to Kudo et al. and the patents discussed therein.
  • a hollow flattened oval tubular shape of aluminum collapses toward the middle (i.e., into an "hour glass" shape) during high temperature brazing, preventing satisfactory contact at the tube-to- fin joints, both during and following brazing.
  • the flattened oval shape is prevented from collapsing during the brazing process.
  • the pillars increase the heat transfer surface on the water side of the tube, in comparison with turbulator indentations which do not make contact in the tube interior, as disclosed in U.S. patent No.
  • a radiator tube having a flattened oval shape, and which comprises opposed first and second generally planar, principal heat transfer surfaces, a first generally continuous curved surface interconnecting and integrally formed with the first and second principal heat transfer surfaces, and a second generally continuous curved surface interconnecting and integrally formed with the first and second principal heat transfer surfaces.
  • the first and second principal heat transfer surfaces have a plurality of pairs of opposed turbulator dimples formed
  • dimples extend inwardly and meet in the tube interior to define a plurality of pillars.
  • the second curved surface has a longitudinal, leak-free seam formed therein.
  • the tube surfaces have a thickness of less than 0.23 mm.
  • a method of forming a radiator tube having a flattened oval shape in this method, a generally planar strip or blank of a metal material is provided, the metal material comprising a parent metal and a second metal, and the strip or blank having opposed side edges and a longitudinal center line intermediate the side edges. Turbulator dimples are formed in the blank on either side of the longitudinal center line to define a pattern of dimples which is symmetric about the longitudinal center line. The blank is then subjected to roll forming techniques in order to form it into a tube of circular cross-section with the opposed side edges precisely aligned.
  • the side edges are simultaneously compressed at the apex and welded together by heating at the melting point of the parent metal using a high frequency induction current, to form a leak free joint.
  • Reduction and breakdown rolls are then used to transform the cross-section of the tube from circular to a flattened oval, to define opposed first and second generally planar, principal heat transfer surfaces, a first generally continuous curved surface having the longitudinal center line approximately at its apex and interconnecting and
  • the step of forming the turbulator dimples comprises passing the blank between a pair of rotatable cylindrical rolls a predetermined distance apart, one of the rolls having male punches formed thereon and the other of the rolls having female sections formed therein in alignment with the male punches.
  • phasing gears are used to maintain alignment of the male punches with the female sections.
  • apparatus for forming a radiator tube having a flattened oval shape and interior pillars.
  • the apparatus includes first and second parallel, rotatable shafts, a first cylindrical roll mounted on the first shaft, and a second cylindrical roll mounted on the second shaft.
  • the first roll has male punches formed thereon, while the second roll has female sections formed therein in alignment with the male punches.
  • First and second phasing gears are mounted to the first and second shafts, respectively, in meshing engagement with each other to maintain alignment of the male punches with the female sections.
  • Figure 1 is a partial perspective view of a tube blank with turbulator dimples formed thereon.
  • Figure 2 is a partial perspective view of a tube blank which has been formed into a tube of circular cross-section, with its side edges in precise alignment, prior to compression
  • FIG. 3 is a partial perspective view of a radiator tube in accordance with the present invention.
  • Figure 4 is a cross-sectional view taken along line 4-4 of Figure 3.
  • Figure 5 is a cross-sectional view taken along line 5-5 of Figure 3.
  • Figure 6 is a cross-sectional view taken along line 6-6 of Figure 3.
  • Figure 7 is a perspective view of apparatus in accordance with the present invention for maldng the radiator tube of Figure 3.
  • Figure 8 is a perspective exploded view of a dimple-forming roll of the apparatus of Figure 7.
  • Figure 9 is an enlarged, exploded view of a male dimple-forming disk and an spacer
  • Figure 10 is an enlarged, exploded view of a female dimple-forming disk and an spacer disk of the roll of Figure 8.
  • Radiator tube 10 comprises first and second opposed, generally planar principal heat transfer surfaces 12 and 14 and first and second opposed, continuous curved surfaces 16 and 18 interconnecting first and second principal heat transfer surfaces 12 and 14.
  • Curved surfaces 16 and 18 are substantially semi-circular; the diameters of the circles of which curved surface 16 and 18 form a part are referred to as the end diameters of tube 10.
  • a plurality of pairs of turbulator dimples 20 are formed in principal heat transfer surfaces 12 and 14 in opposed relation to each other and meet in the interior of tube 10 to define a plurality of pillars.
  • Tube 10 can be formed from strips or blanks of copper and brass, clad aluminum alloy, non-clad aluminum alloy, or any other metal material suitable for use in a heat exchanger which comprises a parent metal which can be welded by melting at a high temperature, and a secondary material.
  • the presence of the pillars permits the use of blanks having a thickness of less than 0.23 mm.
  • radiator tube 10 is made from a generally planar strip or blank 30 having opposed side edges 32 and a longitudinal line 36 intermediate side edges 32.
  • Turbulator dimples 20 are formed in rows 40 on either side of longitudinal line 36 in a pattern which is symmetric about longitudinal line 36.
  • Longitudinal line 36 can be centered between side edges 32, or it can be off-center, but in either case, turbulator dimples 20 must be formed in a pattern which is symmetric about the line.
  • Dimples 20 are formed with flattened upper faces 42 which are generally square or rectangular in configuration, with rounded corners.
  • each pair of dimples 20 are aligned with and contact each other, in order for the pillars so defined to support principal heat transfer surfaces 12 and 14 and prevent them from collapsing during high temperature brazing.
  • fracturing of the parent material lessens the strength of the flattened oval cross-section; it also accelerates silicon-aluminum diffusion or migration of the clad alloy from the aluminum brazing materials into the parent material at the fracture point of each pillar during high
  • strip 30 is subjected to roll forming in order to form it into continuous tubing 50 of circular cross-section with opposed side edges 32 precisely aligned to abut each other.
  • dimples 20 are formed in a pattern which is symmetric about a longitudinal line 36 which is centered between side edges 32, side edges
  • Second curved surface 18 is effectively integrally formed with first and second principal heat transfer surfaces 12 and 14.
  • reduction and breakdown rolls are used to transform the cross-section of tubing 50 from circular to a flattened oval, to define opposed first and second principal heat transfer surfaces 12 and 14, first curved surface 16 which incorporates longitudinal center line 36, and second curved surface 18 which incorporates
  • Leak free joint 52 is located approximately at the apex of second curved
  • tubing 50 Once leak free joint 52 has been formed and tubing 50 has been roll formed to achieve the desired flattened oval cross-section, lengths can be cut from tubing 50 to form a plurality of tubes 10. Tubes 10 can then be assembled to inlet and outlet header and tank assemblies (not shown) and brazed in a high temperature brazing furnace in accordance with conventional practice to achieve a leak-free joint between tubes 10 and the tank and header assembly.
  • each dimple 20 when formed i.e., the distance dimple 20 extends above the plane of strip 30 must be between 0.009 inch (0.250 mm) and 0.029 inch (0.760 mm).
  • each face 42 must have a length dimension (as measured in the direction of the longitudinal axis of tube 10) of between 0.30 mm and 1.90 mm and a width dimension (as measured in the direction perpendicular to the longitudinal axis of tube 10) of between 0.012 inch (0.30 mm) to 0.081 inch (2.05 mm) in order to provide sufficient contact between facing dimples 20, and in order to obtain the maximum scrubbing of the fluid to break or distort the laminar flow of the fluid on the inner surfaces of tube 10, and to prevent cavitation of the fluid at given fluid flows.
  • Apparatus 100 for forming the turbulator dimples 20 in a strip 30.
  • Apparatus 100 comprises a station 102 having an inboard (or front) stand 104, an outboard (or rear) stand 106, and a top or cover plate 108 attached to the upper edges of inboard and outboard stands 104 and 106.
  • lower and upper cylindrical shafts 110 and 112 respectively mounted in lower bearing blocks 114 and upper bearing blocks 116.
  • An adjusting plate 118 is connected to upper bearing blocks 116 at their upper edges, for a purpose to be described hereinafter.
  • Rolls 120 and 122 are respectively supported on shafts 110 and 112 a fixed distance apart.
  • the alignment and shape of the pillars can be varied by varying the alignment and shape of male punches 140 and female dies 142.
  • rolls 120 and 122 preferably are modular in construction, so that the number of rows and columns of dimples and the surface area of the dimples can readily be varied.
  • each of rolls 120 and 122 comprises a central hub 150 keyed to shaft 110 or 112, a plurality of pillar disks 152 axially aligned on either side of hub 150, and one or more spacer disks 154 separating each of pillar disks 152.
  • Pillar disks 152 on roll 120 are provided with male punches 140, as shown in Figure 10, while pillar disks 152 on roll 122 are provided with female dies 142, as shown in Figure 9.
  • Hub 150 comprises a cylindrical main body portion 160 having an outer side wall 162 and opposite end walls 164, cylindrical necked-in portions 166 extending outwardly from end walls 164, and a central annular flange 166 extending outwardly from side wall 162. Pillar disks 152 and spacer disks 154 are assembled to central annular flange 168, for example by screws (not shown) inserted through aligned holes 158 through pillar disks 152, spacer disks 154, and flange 168.
  • the inner diameters of pillar disks 152 and spacer disks 154 are substantially equal to the outer diameter of side wall 162, and the outer diameters of pillar disks 152 and spacer disks 154 are substantially equal to the outer diameter of flange 168 to provide an integral structure when assembled.
  • Pillar disks 152 and spacer disks 154 are further held in place on hub 150 by front and back end caps 170 inserted over necked-in portions 166 and abutting against end walls 164.
  • End caps 170 are affixed to hub 150 by screws 172 inserted through aligned holes 174 through end walls 164 and end caps 170.
  • Front and back end caps 170 have inner diameters substantially equal to the outer diameters of necking-in portions 166 and outer diameters substantially equal to the outer diameters of pillar disks 152, spacer disks 154, and flange 168, further to provide an integral structure when assembled.
  • Apparatus 100 is positioned immediately upstream of a roll forming station (not shown), and rolls 120 and 122 are driven as strip 30 is pulled through the roll forming station by the vertical forming rolls. Pulling strip 30 through rolls 120 and 122 permits strip 30 to be in precise line speed with the roll forming and welding stations. Were rolls 120 and 122 driven, they would create a loop that has to be in synchronization with the mill strip speed to prevent drag which would cause high frequency welding problems. In order to ensure proper alignment of punches 140 and dies 142 as rolls 120 and 122 rotate, phasing gears 180 are journaled on the front ends of shafts 110 and 112 and are in meshing engagement with each other.
  • Phasing gears 180 are provided with phase adjusting screws 182, for adjusting their pitch diameter and enabling male punches 140 to align with female dies 142, in a manner which will be appreciated by those of skill in the art. As a result, the finish radius within each dimple 20 is uniform, and fracturing of the parent material as previously described is prevented.
  • male and female alignment gears 184 and 186 are journaled respectively on
  • Male and female alignment gears 184 and 186 horizontally align pillar disks 152 on roll 120 with their mating pillar disks 152 on roll 122.
  • the height of dimples 20 can be adjusted through a pillar height adjusting nut 190 rotatably mounted to top plate 108, a threaded rod 192 inserted through adjusting nut 190 and attached to adjusting plate 118, and a pair of positive stop pins 194 inserted into a pair of holes 196 extending horizontally into inboard and outboard stands 104 and 106 between lower and upper bearing blocks 114 and 116.
  • Counterclockwise rotation of adjusting nut 190 raises adjusting plate 118 and upper bearing blocks 116 attached thereto, to permit removal and insertion of stop pins 194; while clockwise rotation of adjusting nut 190 lowers adjusting plate 118 to cause upper bearing blocks 116 to rest on the inner portion 194a of stop pins 194.
  • the diameter of the inner portion 194a of positive stop pins 194 determines the height of dimples 20, in that the diameter of inner portion 194a is proportional to the distance between rolls 120 and 122. Decreasing the diameter of the inner portion 194a of positive stop pins 194 decreases the distance between bottom and top rolls 122, and thus increases the height of dimples 20.
  • stop pins 194 of one diameter can be exchanged for stop pins 194 of a different diameter to change the height of dimples 20.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Geometry (AREA)
  • Bending Of Plates, Rods, And Pipes (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
  • Making Paper Articles (AREA)
  • Press Drives And Press Lines (AREA)
EP94924586A 1993-08-04 1994-08-04 Radiatorrohr, verfahren und vorrichtung zu dessen herstellung Withdrawn EP0711399A4 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10173693A 1993-08-04 1993-08-04
US101736 1993-08-04
PCT/US1994/008851 WO1995005571A2 (en) 1993-08-04 1994-08-04 Radiator tube and method and apparatus for forming same

Publications (2)

Publication Number Publication Date
EP0711399A1 true EP0711399A1 (de) 1996-05-15
EP0711399A4 EP0711399A4 (de) 1997-07-02

Family

ID=22286134

Family Applications (1)

Application Number Title Priority Date Filing Date
EP94924586A Withdrawn EP0711399A4 (de) 1993-08-04 1994-08-04 Radiatorrohr, verfahren und vorrichtung zu dessen herstellung

Country Status (6)

Country Link
EP (1) EP0711399A4 (de)
JP (1) JPH09506161A (de)
CN (1) CN1132552A (de)
AU (1) AU7481694A (de)
CA (1) CA2168746A1 (de)
WO (1) WO1995005571A2 (de)

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US6904677B2 (en) 2003-04-10 2005-06-14 Denso Corporation Method of manufacturing tube and apparatus for manufacturing the same
JP4459962B2 (ja) * 2003-05-13 2010-04-28 ヘス エンジニアリング インク 触媒コンバータを製造する方法及び装置
EP1644682A1 (de) * 2003-07-15 2006-04-12 Outokumpu Copper Products Oy DRUCK STANDHALTENDES WûRME BERTRAGUNGSROHR UNDHERSTELLUNGSVERFAHREN DAF R
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CN101096066B (zh) * 2006-06-30 2010-09-01 黄义洪 空气清新机上积尘片的加工方法
CN100460800C (zh) * 2006-07-07 2009-02-11 北京美联桥科技发展有限公司 扁平状换热管
KR101250771B1 (ko) * 2006-09-21 2013-04-04 한라공조주식회사 열교환기
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CN102069360B (zh) * 2011-01-11 2012-11-21 湖州腾云制冷设备有限公司 一种金属管的加工方法
CN102589337B (zh) * 2011-01-13 2016-02-03 摩丁制造公司 热交换管及使用该热交换管的方法
CN102313475A (zh) * 2011-08-19 2012-01-11 奇瑞汽车股份有限公司 一种散热管及其制造方法
CN102706199A (zh) * 2012-05-25 2012-10-03 锦州秀亭制管有限公司 刺凸式换热管及其制造工艺
CN104748599A (zh) * 2013-12-30 2015-07-01 泰安鼎鑫冷却器有限公司 一种高强度高性能散热管
CN106239170B (zh) * 2016-08-30 2018-04-03 嘉善天晟精密铸件有限公司 一种散热器生产的设备
CN106239171B (zh) * 2016-08-30 2018-06-01 嘉善天晟精密铸件有限公司 一种用于散热器生产的加工装置
CN106425510B (zh) * 2016-08-30 2018-08-07 嘉善天晟精密铸件有限公司 一种用于散热器生产的加工设备
EP3665428A4 (de) * 2017-08-07 2021-05-05 Modine Manufacturing Company Wärmetauscherröhre
CN109827456B (zh) * 2019-02-14 2020-12-22 合肥美的电冰箱有限公司 蒸发管、蒸发器和冰箱
CN112845938B (zh) * 2020-12-31 2023-06-23 南宁市安和机械设备有限公司 一种制作错位打点油冷器管的设备
CN112944972A (zh) * 2021-02-09 2021-06-11 广东鑫统仕集团有限公司 一种打点散热管
CN113638065B (zh) * 2021-09-02 2022-10-14 江苏中杰澳新材料有限公司 热管组件、包括热管组件的异型斜管式热辊及其加工方法
WO2023087957A1 (zh) * 2021-11-18 2023-05-25 格朗吉斯铝业(上海)有限公司 一种铝管、其制造方法及全铝换热器

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Also Published As

Publication number Publication date
CA2168746A1 (en) 1995-02-23
CN1132552A (zh) 1996-10-02
WO1995005571A3 (en) 1995-03-30
JPH09506161A (ja) 1997-06-17
AU7481694A (en) 1995-03-14
EP0711399A4 (de) 1997-07-02
WO1995005571A2 (en) 1995-02-23

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