EP0724623A1 - Compositions detergentes granulaires pour la lessive, contenant une lipase et un sulfonate de nonanoyloxybenzene de sodium - Google Patents

Compositions detergentes granulaires pour la lessive, contenant une lipase et un sulfonate de nonanoyloxybenzene de sodium

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Publication number
EP0724623A1
EP0724623A1 EP94921928A EP94921928A EP0724623A1 EP 0724623 A1 EP0724623 A1 EP 0724623A1 EP 94921928 A EP94921928 A EP 94921928A EP 94921928 A EP94921928 A EP 94921928A EP 0724623 A1 EP0724623 A1 EP 0724623A1
Authority
EP
European Patent Office
Prior art keywords
composition
weight
sodium
laundry detergent
granular laundry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94921928A
Other languages
German (de)
English (en)
Inventor
Ann Margaret Wolff
Manuel Garcia Venegas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP0724623A1 publication Critical patent/EP0724623A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3907—Organic compounds
    • C11D3/3915—Sulfur-containing compounds

Definitions

  • TECHNICAL FIELD This relates to a granular laundry detergent composition containing lipase produced by Pseudomonas alcaligenes, certain levels of alkyl alkoxy sulfate or polyhydroxy fatty acid amide, and sodium nonanoyloxybenzene sulfonate and sodium perborate in a specified ratio for good stain removal and bleaching action.
  • lipase in laundry detergent compositions for improved cleaning performance is known.
  • an activated bleach-containing granular laundry detergent composition the inclusion of lipase can result in compromised bleach effectiveness.
  • a granular laundry detergent composition with both good stain removal and good bleaching action has now been found.
  • the present composition contains lipase produced by Pseudomonas alcaligenes. certain levels of alkyl alkoxy sulfate or polyhydroxy fatty acid amide, and certain levels of sodium nonanoyloxybenzene sulfonate and sodium perborate in a specified ratio.
  • This relates to a granular laundry detergent composition, comprising: (a) from about 0.00025 to about 0.015 grams of active enzyme per 100 grams of composition of lipase produced by Pseudomonas alcaligenes;
  • composition from about 1 to about 20%, by weight of the composition, of sodium nonanoyloxybenzene sulfonate and from about 0.5 to about 20%, by weight of the composition, of sodium perborate; in a ratio of sodium nonanoyloxybenzene sulfonate to sodium perborate of between about 0.5:1 and about 10:1; and wherein the composition has a pH in water at about 20 ⁇ C of between about 7 and about 11.
  • Granular laundry detergent compositions of the present invention include from about 0.00025 to about 0.015, preferably from about 0.0025 to about 0.01, grams of active enzyme per 100 grams of composition of lipase produced by Pseudomonas alcaligenes. Genetically engineered variants and mutants thereof are also included in this lipase definition, as is lipase obtained from Pseudomonas pseudoalcaligenes (which is believed to be the old name for Pseudomonas alcaligenes).
  • a lipase unit is defined as the amount of lipase which produces 1 umol of titratable butyric acid per minute in a pH stat, where pH is 7.0, temperature is
  • substrate is an emulsion of tributyrin and gum arabic in the presence of Ca++ and NaCl in phosphate buffer.
  • Granular laundry detergent compositions of the present invention further include from about 0.5 to about 30%, preferably from about 1 to about 10%, most preferably from about 1 to about 3%, by weight of the composition, of alkyl alkoxy sulfate or polyhydroxy fatty acid. Mixtures of the two are included herein.
  • Preferred is from about 1 to about 10%, most preferably from about 1 to about 3%, by weight of the composition, of C10-24, preferably C12-18, alkyl sulfate which has been ethoxylated with an average of from about 0.5 to about 6, preferably from about 1 to about 3, moles of ethylene oxide per mole of sulfate.
  • Alkyl alkoxy(lated) sulfate surfactants are water soluble salts or acids typically of the formula RO(A) m S03M wherein R is an unsubstituted c 10 _c 24 alkyl or hydroxyalkyl group having a C10-C24 alkyl component, preferably a C12-C20 alkyl or hydroxyalkyl, more preferably C12-C18 alkyl or hydroxyalkyl, A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 6, more preferably between about 0.5 and about 3, and M is H or a cation which can be, for example, a metal cation (e.g., sodium, potassium, lithium, calcium, magnesium), ammonium or substituted-ammonium cation.
  • R is an unsubstituted c 10 _c 24 alkyl or hydroxyalkyl group having a C10-C24 alkyl component, preferably a C12
  • Alkyl ethoxylated sulfates as well as alkyl propoxylated sulfates are contemplated herein.
  • Specific examples of substituted ammonium cations include methyl-, dimethyl-, tri ethyl-ammonium and quaternary ammonium cations, such as tetra ethyl-ammonium, dimethyl piperydinium and cations derived from al anolamines, e.g. monoethanolamine, diethanola ine, and triethanol mine, and mixtures thereof.
  • Exemplary surfactants are C 12 -C 18 alkyl polyethoxylate (1.0) sulfate, C12-C18 alkyl polyethoxylate (2.25) sulfate, C12-C18 alkyl polyethoxylate (3.0) sulfate, and Ci2 _c 18 alkyl polyethoxylate (4.0) sulfate wherein M is selected from sodium and potassium.
  • R 1 is H, C1-C4 hydrocarbyl, 2-hydroxy ethyl, 2-hydroxy propyl , or a mixture thereof, preferably C1-C4 alkyl, more preferably Ci or C2 alkyl, most preferably Ci alkyl (i.e., methyl); and R 2 is a C5-C31 hydrocarbyl, preferably straight chain C7-C19 alkyl or alkenyl, more preferably straight chain C9-C17 alkyl or alkenyl, most preferably straight chain C11-C15 alkyl or alkenyl, or mixtures thereof; and Z is a polyhydroxyhydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof.
  • Z preferably will be derived from a reducing sugar in a reductive amination reaction; more preferably Z will be a glycityl.
  • Suitable reducing sugars include glucose, fructose, maltose, lactose, galactose, annose, and xylose.
  • Z preferably will be selected from the group consisting of -CH2-(CHOH) n -CH2 ⁇ H, -CH(CH20H)-(CH0H) n -i-CH20H, -CH2-(CHOH)2(CHOR')(CHOH)-CH2 ⁇ H, and alkoxylated derivatives thereof, where n is an integer from 3 to 5, inclusive, and R' is H or a cyclic or aliphatic monosaccharide. Most preferred are glycityls wherein n is 4, particularly -CH2-(CHOH)4-CH2 ⁇ H.
  • the polyhydroxy fatty acid amide preferred herein is glucose amide, preferably C12-I8 N-acetyl glucamide.
  • Sodium nonanoyloxybenzene sulfonate and Sodium perborate Granular laundry detergent compositions of the present invention further include from about 1 to about 20%, preferably from about 2 to about 15%, most preferably from about 5 to about 10%, by weight of the composition, of sodium nonanoyloxybenzene sulfonate and from about 0.5 to about 20%, preferably from about 2 to about 15%, most preferably from about 4 to about 8%, by weight of the composition, of sodium perborate.
  • the ratio of sodium nonanoyloxybenzene sulfonate to sodium perborate is between about 0.5:1 and about 10:1, preferably between about 1:1 and about 5:1, most preferably between about 1:1 and about 2:1.
  • compositions herein optionally further comprise from about 2 to about 30%, preferably from about 10 to about 20%, by weight of the composition, of additional anionic or nonionic detergent surfactant.
  • Anionic surfactants useful for detersive purposes are preferably included in the compositions hereof. These can include salts (including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and triethanolamine salts) of soap, C9-C20 linear alkylbenzenesulphonates, C8-C22 primary or secondary alkanesulphonates, C8-C24 olefinsulphonates, sulphonated polycarboxylic acids prepared by sulphonation of the pyrolyzed product of alkaline earth metal citrates, e.g., as described in British Patent Specification No.
  • salts including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and triethanolamine salts
  • C9-C20 linear alkylbenzenesulphonates C8-C22 primary or secondary alkanesulphonates
  • C8-C24 olefinsulphonates C8-C
  • alkyl glycerol sulfonates 1,082,179, alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfates, alkyl phenol ethylene oxide ether sulfates, paraffin sulfonates, alkyl phosphates, isothionates such as the acyl isothionates, N-acyl taurates, fatty acid amides of methyl tauride, alkyl succinamates and sulfosuccinates, monoesters of sulfosuccinate (especially saturated and unsaturated C1 -C18 monoesters) diesters of sulfosuccinate (especially saturated and unsaturated C6-C14 diesters), N-acyl sarcosinates, sulfates of alkylpolysaccharides such as the sulfates of alkyl
  • Resin acids and hydrogenated resin acids are also suitable. Further examples are given in "Surface Active Agents and Detergents" (Vol. I and II by Schwartz, Perry and Berch). A variety of such surfactants are also generally disclosed in U.S. Patent 3,929,678, issued December 30, 1975 to Laugh!in, et al . at Column 23, line 58 through Column 29, line 23 (herein incorporated by reference).
  • C12-C20 alkyl sulfate, and/or C9-C20 linear alkylbenzene sulfonate preferably sodium salts. Preferred are from about 2 to about 10%, by weight of the composition, of sodium Cj2-20 alkyl sulfate and from about 5 to about 15%, by weight of the composition, of sodium C9-20 linear alkylbenzene sulfonate.
  • Suitable nonionic detergent surfactants are generally disclosed in U.S. Patent 3,929,678, Laughlin et al., issued December 30, 1975, at column 13, line 14 through column 16, line 6, incorporated herein by reference. Exemplary, non-limiting classes of useful nonionic surfactants are listed below. 1.
  • condensation products of ethylene oxide with a hydrophobic base formed by the condensation of propylene oxide with propylene glycol.
  • Semi-polar nonionic surfactants are a special category of nonionic surfactants which include water-soluble amine oxides containing one alkyl moiety of from about 10 to about 18 carbon atoms and 2 moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from about 1 to about 3 carbon atoms; water-soluble phosphine oxides containing one alkyl moiety of from about 10 to about 18 carbon atoms and 2 moieties selected from the group consisting of alkyl groups and hydroxyalkyl groups containing from about 1 to about 3 carbon atoms; and water-soluble sulfoxides containing one alkyl moiety of from about 10 to about 18 carbon atoms and a moiety selected from the group consisting of alkyl and hydroxyalkyl moieties of from about 1 to about 3 carbon atoms.
  • R 6 is an alkyl group containing from about 7 to about 21 (preferably from about 9 to about 17) carbon atoms and each R? is selected from the group consisting of hydrogen C1-C4 alkyl, C1-C4 hydroxyalkyl, and -(C2H4 ⁇ ) x H where x varies from about 1 to about 3.
  • Detergency Builder is an alkyl group containing from about 7 to about 21 (preferably from about 9 to about 17) carbon atoms and each R? is selected from the group consisting of hydrogen C1-C4 alkyl, C1-C4 hydroxyalkyl, and -(C2H4 ⁇ ) x H where x varies from about 1 to about 3.
  • inorganic detergency builders include, but are not limited to, the alkali metal, ammonium and alkanolammonium salts of polyphosphates (exemplified by the tripolyphosphates, pyrophosphates, and glassy polymeric meta-phosphates), phosphonates, phytic acid, silicates such as the alkali metal silicates and the layered sodium silicates described in U.S. Patent 4,664,839, carbonates (including bicarbonates and sesquicarbonates), borates, sulphates, and aluminosilicates.
  • carbonate builders are the alkaline earth and alkali metal carbonates, including sodium carbonate and sesqui arbonate and mixtures thereof with ultra-fine calcium carbonate as disclosed in German Patent Application No. 2,321,001 published on November 15, 1973.
  • Preferred aluminosilicates are zeolite builders which have the formula:
  • Preferred synthetic crystalline aluminosilicate ion exchange materials useful herein are available under the designations Zeolite A, Zeolite P (B), and Zeolite X.
  • polyphosphates are the alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta phosphate in which the degree of polymerization ranges from about 6 to about 21, and salts of phytic acid.
  • phosphonate builder salts are the water-soluble salts of ethane 1-hydroxy-l, 1-diphosphonate, the water-soluble salts- of methylene diphosphonic acid e.g. the trisodium and tripotassiu salts and the water-soluble salts of substituted methylene diphosphonic acids, such as the trisodium and tripotassium ethylidene, isopyropylidene benzylmethylidene and halo methylidene phosphonates.
  • Phosphonate builder salts of the aforementioned types are disclosed in U.S. Patents 3,159,581 and 3,213,030 issued December 1, 1964 and October 19, 1965, to Diehl; U.S. Patent 3,422,021 issued January 14, 1969, to Roy; and U.S. Patents 3,400,148 and 3,422,137 issued September 3, 1968, and January 14, 1969 to Quimby, each incorporated herein by reference.
  • ether polycarboxylate builders include the ether polycarboxylates.
  • useful ether polycarboxylates include oxydisuccinate, as disclosed in Berg, U.S. Patent
  • Suitable ether polycarboxylates also include cyclic compounds, particularly alicyclic compounds, such as those described in U.S. Patents 3,923,679; 3,835,163; 4,158,635; 4,120,874 and 4,102,903, all of which are incorporated herein by reference.
  • Other useful detergency builders include the ether hydroxypolycarboxylates and the copolymers of maleic anhydride with ethylene or vinyl methyl ether, 1, 3, 5-trihydroxy benzene-2, 4, 6-trisulphonic acid, and carboxymethyloxysuccinic acid.
  • Organic polycarboxylate builders also include the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids. Examples include the sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylenediamine tetraacetic acid, and nitrilotriacetic acid.
  • polycarboxylates such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1,3,5-tricarboxylic acid, and carboxymethyloxysuccinic acid, and soluble salts thereof.
  • Citrate builders e.g., citric acid and soluble salts thereof (particularly sodium salt) are polycarboxylate builders which can also be used in granular compositions.
  • Other carboxylate builders include the carboxylated carbohydrates disclosed in U.S. Patent 3,723 > 322, Diehl, issued March 28, 1973, incorporated herein by reference.
  • succinic acid builders include the C5-C20 alkyl succinic acids and salts thereof.
  • useful builders also include sodium and potassium carboxy ethyloxymalonate, carboxymethyloxysuccinate, cis-cyclo- hexane-hexacarboxylate, cis-cyclopentane-tetracarboxylate, water- soluble polyacrylates (these polyacrylates having molecular weights to above about 2,000 can also be effecitvly utilized as dispersants), and the copoly ers of maleic anhydride with vinyl methyl ether or ethylene.
  • polycarboxylates are the polyacetal carboxylates disclosed in U.S. Patent 4,144,226, Crutchfield et al., issued March 13, 1979, incorporated herein by reference.
  • Polycarboxylate builders are also disclosed in U.S. Patent 3,308,067, Diehl, issued March 7, 1967, incorporated herein by reference.
  • Other organic builders known in the art can also be used.
  • the detergency builder herein is selected from the group consisting of the salts, preferably the sodium salt, of carbonate, silicate, sulfate, phosphate, aluminosilicate, and citric acid and mixtures thereof. 4. Second Enzyme
  • ingredients include second enzymes, which include protease (most preferred), amylase, peroxidase, cellulase, and mixtures thereof.
  • second enzyme is meant detergent-compatible enzymes in addition to lipase which are also added to the composition. Second enzymes from chemically or genetically modified mutants, and from bacterial or fungal origin, are included herein. Additional lipases (from sources other than Pseudomonas alcaligenes) could be included herein, but preferably are not.
  • the amount of second enzyme used in the- composition varies according to the type of enzyme. In general, from about 0.0001 to about 1.0, more preferably about 0.001 to about 0.5, weight % on an active basis of these second enzymes are preferably used. Mixtures of enzymes from the same class (e.g. protease) or two or more classes (e.g. cellulase and protease) may be used.
  • same class e.g. protease
  • two or more classes e.g. cellulase and protease
  • Suitable cellulases are disclosed in U.S. Patent 4,435,307, Barbesgaard et al., issued March 6, 1984, incorporated herein by reference, which discloses fungal cellulase produced from Humicola insolens. Suitable cellulases are also disclosed in GB-A-2.075.028, GB-A-2.095.275 and DE-0S-2.247.832. Examples are cellulases produced by a strain of Humicola insolens (Humicola grisea var. thermoidea).
  • Suitable a ylases include, for example, ⁇ -amylases obtained from a special strain of B.licheniforms, described in more detail in British Patent Specification No. 1,296,839.
  • Amylolytic proteins include, for example, RapidaseTM, Maxamyl and TermamylTM.
  • Peroxidase enzymes are used in combination with oxygen sources, e.g., percarbonate, perborate, persulfate, hydrogen peroxide, etc. They are known in the art, and include, for example, horseradish peroxidase, ligninase, and haloperoxidase such as chloro-and bro o-peroxidase.
  • oxygen sources e.g., percarbonate, perborate, persulfate, hydrogen peroxide, etc.
  • oxygen sources e.g., percarbonate, perborate, persulfate, hydrogen peroxide, etc. They are known in the art, and include, for example, horseradish peroxidase, ligninase, and haloperoxidase such as chloro-and bro o-peroxidase.
  • Peroxidase-containing detergent compositions are disclosed, for example, in PCT International Application WO 89/099813, published October 19, 1989, by 0. Kirk
  • protease enzymes can be of animal, vegetable or microorganism (preferred) origin. More preferred is serine protease enzyme of bacterial origin. Purified or nonpurified forms of this, enzyme may be used. Proteases produced by chemically or genetically modified mutants are included by definition, as are close structural enzyme variants. Particularly preferred is bacterial serine protease enzyme obtained from Bacillus subtilis and/or Bacillus licheniformis.
  • Suitable proteases include Alcalase ® , Esperase®, Savinase ® (preferred); Maxatase ® , Maxacal® (preferred), and Maxapem 15® (protein engineered Maxacal ® ); and subtilisin BPN and BPN' (preferred); which are commercially available.
  • Preferred proteases are also modified bacterial serine proteases, such as those described in European Patent Application Serial Number 87 303761.8, filed April 28, 1987 (particularly pages 17, 24 and 98), and which is called herein "Protease B", and in European Patent Application 199,404, Venegas, published October 29, 1986, which refers to a modified bacterial serine proteolytic enzyme which is called "Protease A” herein.
  • Protease B and genetically engineered variants and mutants thereof, are most preferred for use herein. 5.
  • ingredients suitable for use in the present compositions such as water, perfume, brightener, conditioners such as fumed silica, polyethylene glycol, dyes and colorants, and peroxyacids, can be included.
  • Preferred ingredients are from about 0.5 to about 5%, by weight of the composition, of 12 -
  • polyethylene glycol preferably with molecular weight between 5,000 and 10,000, most preferably 8,000
  • polyethylene glycol preferably with molecular weight between 5,000 and 10,000, most preferably 8,000
  • fluorescent whitening and/or brightening agents from about 0.01 to about 1.0 wt.% of perfume.
  • composition from about 1 to about 20%, preferably from about 2 to about 15%, by weight of the composition, of sodium nonanoyloxybenzene sulfonate, and from about 0.5 to about 20%, preferably from about 2 to about 15%, by o weight of the composition, of sodium perborate; in a ratio of sodium nonanoyloxybenzene sulfonate to sodium perborate of between about 0.5:1 and about 10:1, preferably between about 1:1 and about 5:1; and wherein the composition has a pH in water at about 20 * C of 5 between about 7 and about 11.
  • the granular detergent composition is added to the wash, usually at levels of 1/8 to 1 cup. Agitation is preferably provided in the washing machine for good cleaning. Washing is preferably followed by drying the wet fabric in a conventional 0 clothes dryer.
  • An effective amount of a granular detergent composition is preferably from about 500 to about 7000 ppm, more preferably from about 1000 to about 3000 ppm.
  • a composition of the present invention is as follows, detergent base having the following composition is spray dried.
  • Polyethylene glycol (molecular weight 8000) 1.05
  • Lipase produced by Pseudomonas alcaligenes (M-l from Gist-brocades, Delft, Holland) at 200,000 Lipase Units per gram.
  • the pH of the composition in water at about 20 ⁇ C is 9.5.
  • C12-18 N-acetyl glucosamide can be substituted for or added to the alkyl ethoxy sulfate.
  • Variants or mutants of the lipase produced by Ei alcaligenes can be substituted for or used with the lipase produced by J ⁇ . alcaligenes.
  • composition of the present invention is as follows, detergent base having the following formula is spray dried.
  • Component Weight % is as follows, detergent base having the following formula is spray dried.
  • C12-18 N-acetyl glucosamide can be substituted for or added to the alkyl ethoxy sulfate.
  • Variants or mutants of the lipase produced by Ei alcaligenes can be substituted for or used with the lipase produced by E- s . alcaligenes.
  • a composition of the present invention is as follows, detergent base having the following formula is spray dried.
  • C12-18 N-acetyl glucosamide can be substituted for or added to the alkyl ethoxy sulfate.
  • Variants or mutants of the lipase produced by E a . alcaligenes can be substituted for or used with the lipase produced by E-. alcaligenes.

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  • Wood Science & Technology (AREA)
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Abstract

L'invention concerne une composition détergente granulaire pour la lessive, contenant une lipase produite par Pseudomonas alcaligenes, une certaine quantité de sulfate d'alkylalcoxy ou d'amide d'acide gras polyhydroxy, et de sulfonate de nonanoyloxybenzène de sodium et de perborate de sodium, dans un rapport spécifié pour un bon blanchiment et une bonne élimination des taches.
EP94921928A 1993-06-25 1994-06-06 Compositions detergentes granulaires pour la lessive, contenant une lipase et un sulfonate de nonanoyloxybenzene de sodium Withdrawn EP0724623A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US83114 1987-08-10
US8311493A 1993-06-25 1993-06-25
PCT/US1994/006305 WO1995000625A1 (fr) 1993-06-25 1994-06-06 Compositions detergentes granulaires pour la lessive, contenant une lipase et un sulfonate de nonanoyloxybenzene de sodium

Publications (1)

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EP0724623A1 true EP0724623A1 (fr) 1996-08-07

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EP94921928A Withdrawn EP0724623A1 (fr) 1993-06-25 1994-06-06 Compositions detergentes granulaires pour la lessive, contenant une lipase et un sulfonate de nonanoyloxybenzene de sodium

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Country Link
EP (1) EP0724623A1 (fr)
JP (1) JPH08511826A (fr)
AU (1) AU7244594A (fr)
MA (1) MA23232A1 (fr)
WO (1) WO1995000625A1 (fr)

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FR2954118B1 (fr) 2009-12-23 2012-04-13 Oreal Procede pour colorer les fibres keratiniques mettant en oeuvre au moins un derive d'orthodiphenol un oxyde metallique particulier, un agent alcalinisant sous photoirradiation
FR2954134A1 (fr) 2009-12-23 2011-06-24 Oreal Composition pour colorer les fibres keratiniques comprenant au moins un derive d'orthodiphenol, un agent oxydant chimique et un agent alcalinisant,
FR2954098A1 (fr) 2009-12-23 2011-06-24 Oreal Composition comprenant au moins un derive d'orthodiphenol un derive metallique particulier et un agent alcalinisant, pour colorer les fibres keratiniques
FR2961398B1 (fr) 2010-06-16 2013-02-15 Oreal Utilisation en cosmetique d'un extrait naturel issu de pelure de betterave rouge, composition comprenant l'extrait et un derive metallique, un agent oxydant et un agent alcalinisant
WO2012084472A1 (fr) 2010-12-20 2012-06-28 L'oreal Procédé pour la coloration de fibres de kératine utilisant des dérivés d'hydroxybenzaldéhyde, des agents oxydants et des agents alcalinisants en présence de chaleur
FR2968946B1 (fr) 2010-12-20 2013-04-19 Oreal Procede de coloration de fibres keratiniques a partir de derives du resorcinol, de sels de sulfate, d'agents oxydant et d'agent alcalinisant
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FR3047413B1 (fr) 2016-02-04 2018-01-26 L'oreal Utilisation de composes polyamines a linker aliphatique en presence d’oxydants pour traiter les fibres keratiniques
CA3067095C (fr) 2017-06-22 2023-02-14 Ecolab Usa Inc. Blanchiment a l'aide d'acide peroxyformique et d'un catalyseur a l'oxygene

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Also Published As

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JPH08511826A (ja) 1996-12-10
WO1995000625A1 (fr) 1995-01-05
MA23232A1 (fr) 1994-12-31
AU7244594A (en) 1995-01-17

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