EP0750732A1 - Zweizweckwärmeübertragungselement für isothermische räume, mit einem solchen element versehenener, isothermischer raum - Google Patents

Zweizweckwärmeübertragungselement für isothermische räume, mit einem solchen element versehenener, isothermischer raum

Info

Publication number
EP0750732A1
EP0750732A1 EP95913201A EP95913201A EP0750732A1 EP 0750732 A1 EP0750732 A1 EP 0750732A1 EP 95913201 A EP95913201 A EP 95913201A EP 95913201 A EP95913201 A EP 95913201A EP 0750732 A1 EP0750732 A1 EP 0750732A1
Authority
EP
European Patent Office
Prior art keywords
compartment
isothermal
enclosure
refrigerant
partition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP95913201A
Other languages
English (en)
French (fr)
Other versions
EP0750732B1 (de
Inventor
Jean-Pierre Grazon
Claude Gibot
Alain Bechennec
Gérard TIBY
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MONETTI FRANCE
Carboxyque Francaise SA
Premark FEG LLC
Original Assignee
MONETTI FRANCE
Carboxyque Francaise SA
Premark FEG Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MONETTI FRANCE, Carboxyque Francaise SA, Premark FEG Corp filed Critical MONETTI FRANCE
Publication of EP0750732A1 publication Critical patent/EP0750732A1/de
Application granted granted Critical
Publication of EP0750732B1 publication Critical patent/EP0750732B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00General constructional features
    • F25D23/06Walls
    • F25D23/069Cooling space dividing partitions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2331/00Details or arrangements of other cooling or freezing apparatus not provided for in other groups of this subclass
    • F25D2331/80Type of cooled receptacles
    • F25D2331/804Boxes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2400/00General features of, or devices for refrigerators, cold rooms, ice-boxes, or for cooling or freezing apparatus not covered by any other subclass
    • F25D2400/38Refrigerating devices characterised by wheels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D3/00Devices using other cold materials; Devices using cold-storage bodies
    • F25D3/10Devices using other cold materials; Devices using cold-storage bodies using liquefied gases, e.g. liquid air
    • F25D3/102Stationary cabinets

Definitions

  • the present invention relates to the conservation, in isothermal conditions independent of any external energy source, of all products such as for example food or pharmaceutical products for which a homogeneous temperature must be necessarily preserved between the time of their preparation and their use by an end user.
  • Each compartment must ensure a constant ambient temperature both in the volume of said compartment and in the autonomy time necessary to keep these speakers outside of any external refrigerant energy source, and in any event at least for a period between 0 and 4 hours.
  • constant temperature or “controlled temperature” a room temperature for which the variations are within a range of plus or minus 4 ° C around the temperature chosen in the fresh produce compartment and the temperature variation is between -18 "C and -26 ° C in the frozen product compartment; the meaning of maintaining a constant or practically constant temperature notwithstanding variations in the outside temperature also applies to variations in the time in an interval of 0 to 4 h during which the enclosure is dissociated from any source of external cold.
  • the object of the present invention is also to produce such an insulated enclosure comprising any number of compartments which can be maintained individually at different temperatures, not requiring the use, in this enclosure, of separating partitions made of inert insulating material, which would create a large dead volume inside the enclosure.
  • the invention which consists in the development of a removable double-sided partition element usable in particular in an isothermal enclosure, characterized in that it has in its thickness two compartments contiguous to each other, the first non-watertight compartment is capable of being filled with a solid and sublimable refrigerant element, for example dry ice, the other watertight compartment, which can be assimilated to a housing, has been filled with eutectic in the form of gel or mixture or air; the compartment contiguous to the sealed housing is provided with openings distributed in a substantially homogeneous manner on its external face so as to establish different directed temperatures on either side of this partition element, these directed temperatures being sufficiently different to be able to ensure compartments capable of simultaneously containing frozen products in one and fresh products in the other, without breaking the cold chain for all the products considered.
  • a solid and sublimable refrigerant element for example dry ice
  • the other watertight compartment which can be assimilated to a housing, has been filled with eutectic in the form of
  • eutectic in the present application any mixture of two or more bodies whose fusion takes place at constant temperature. Under these conditions, as long as the frigories are provided by the dry ice, the eutectic remains at a constant temperature which is its melting temperature, which can therefore be determined by the choice of the eutectic mixture considered, as a function of the ambient temperature. chosen in the compartment. The only condition is that the solidification temperature of the refrigerant (dry ice) is very significantly lower than the melting temperature of the gel or the eutectic mixture.
  • this refrigerant will consist of solid carbon dioxide in all its forms (wafers, sticks, pellets, snow) whose sublimation temperature is -78 ° C to atmospheric pressure, but other refrigerants can be considered in other applications.
  • this refrigerant may have the function of directing a temperature, even a very low one, in one of the volumes of the isothermal enclosure and of transferring the necessary refrigerants through the buffer housing described above in order to maintain a another different directed temperature in another volume of the isothermal enclosure, temperature determined as a function of the envisaged application, this temperature being for example close to 0 ° C. for keeping food fresh.
  • a partition element in accordance with the invention could thus constitute, in an isothermal enclosure, at least two compartments at different temperatures: on the side of the refrigerant space, a freezing compartment at temperature in principle notably below 0 ° C (up to -18 or -25 ° C if necessary) for the products to be kept at negative temperatures and on the side of the buffer housing containing for example the eutectic gel, a refrigeration compartment at a temperature close to 0 ° C for the products to be kept fresh.
  • the "buffer box” thus represents between these two refrigerator and freezer compartments, a “balance of impedance” mechanism avoiding the use of any inert insulating partition.
  • temperatures in the various compartments can be adjusted and maintained over time at the desired values as a function of the impedance of the buffer and that of the refrigerant, as well as heat losses to the outside (function of the outside temperature), the initial state of the buffer (eutectic) and the expected duration of transport.
  • a partition element according to the invention is also characterized in that the compartment contiguous to the sealed housing is delimited on one side by the latter and on the opposite side by a wall provided with one or more openings, or a grid, leaving transition to refrigerant gas from the sublimation of said refrigerant (perforated face).
  • a gap is formed between said housing and the lower part of said non-sealed wall or grid to allow the flow of said refrigerant gas downward, the latter being heavier than air in the case where it comes from the sublimation of solid carbon dioxide (C02).
  • the element can also be characterized in that the lower part of said housing is widened at its base to offer said buffer a sufficient volume of capacity, this housing advantageously being made of a material with high thermal conductivity, for example stainless steel or aluminum.
  • the refrigerant may be in any suitable form mentioned above and users will thus be able to obtain easily and at low cost the refrigerant, and introduce it into said space of the elements just before putting them in place. isothermal enclosure.
  • the invention also relates to an isothermal enclosure equipped with one or more partition elements as they have just been defined.
  • Such an enclosure will preferably have the form of a box or a conventional parallelepiped box with insulating walls, which can be hermetically closed using a cover which is also insulating, the partition elements then being established in this enclosure , as advantageously removable vertical walls, making it possible to form in this enclosure modular compartments capable of being maintained at different temperatures.
  • the height of the box or box representing the isothermal enclosure is substantially equal to the height of the double-sided partition element of the invention.
  • Such an enclosure may thus be characterized, in general, in that it contains at least one removable double-sided partition element, having in its thickness two compartments contiguous to each other, the first non-sealed compartment being susceptible to be filled with a solid and sublimable refrigerant element, in particular carbon dioxide or dry ice, the second sealed compartment or housing being filled with a eutectic type buffer substance; such a double-sided partition element delimits two compartments in the enclosure; it goes without saying that two partition elements determine three enclosures, etc.
  • a removable double-sided partition element having in its thickness two compartments contiguous to each other, the first non-sealed compartment being susceptible to be filled with a solid and sublimable refrigerant element, in particular carbon dioxide or dry ice, the second sealed compartment or housing being filled with a eutectic type buffer substance; such a double-sided partition element delimits two compartments in the enclosure; it goes without saying that two partition elements determine three enclosures, etc.
  • the compartment of the insulated enclosure adjoining the sealed housing part of the double-sided partition element maintains the ambient temperature of said compartment at a temperature close to the melting temperature of the eutectic, while the compartment adjoining the non-watertight part of the double-sided partition element containing a refrigerant element is maintained at an ambient temperature less than or equal to -18 "C, therefore much lower than the previous one.
  • such an enclosure has in its bottom grooves extending perpendicular to the plane of the cooling elements, these grooves allowing the circulation of the gas of sublimation of the refrigerant, this gas, in principle refrigerated CO 2 coming from the sublimation of the solid carbon dioxide constituting the refrigerant, being heavier than air.
  • the entire device comprising an isothermal enclosure provided with one or more removable double-sided partition elements as described above therefore allows a double directed temperature transfer with maintenance of a temperature which is: a) in the fresh produce compartment maintaining an ambient temperature of 4 ° C ⁇ 4 "C, said fresh product contained in such a compartment keeping a core temperature of 2 ° C ⁇ 2 ° C for a period of between 0 and 4 hours, being it being understood that the enclosure provided with the double-sided partition of the invention being loaded with a fresh product previously brought to a homogeneous temperature of 2 ° C; b) as regards the frozen food compartment, the ambient temperature is maintained at a temperature less than or equal to -18 ° C., knowing that the system of the invention allows natural convection allowing the maintenance of a temperature exhibiting no difference greater than 6 "C. between the top and bottom of the enclosure; the core temperature of products previously frozen and placed in such a compartment varies within a maximum range of -26 ° C to -18 ° C.
  • FIG. 1 shows in perspective a cooling and freezing element according to the invention, arranged as an intermediate partition in an isothermal enclosure, which is shown in perspective with cutaway;
  • FIG. 1 is a plan view of the cooling element
  • FIG. 3 shows schematically in section an isothermal enclosure according to the invention and divided by an element into a freezer compartment and a cooling compartment;
  • FIG. 4 shows schematically in section an isothermal refrigeration chamber according to the invention, in which the cold is maintained by two elements arranged so that their buffer housings are vis-à-vis;
  • FIG. 5 shows schematically in section an isothermal freezing enclosure according to the invention, in which the cold is maintained by two elements arranged so that their buffer housings are turned towards the end walls of the enclosure;
  • FIG. 6 shows an application of the invention to an isothermal enclosure in the form of a refrigerated cabinet comprising two compartments which can be modulated at different temperatures.
  • the insulated enclosure partially shown in perspective has been referenced in 1 and is in the form of a box with lateral insulating walls 2 and ends 3, produced for example by molding of synthetic material, and comprising a foam of insulating material 4 between two shells, exterior 5 and interior 6; it can be closed with a tight cover (fig. 3).
  • the shell 6 On its lateral faces, the shell 6 has pairs of opposite vertical grooves 7, spaced apart according to a determined module.
  • the bottom 8 of the box and the end walls 3 they have longitudinal ribs 9.
  • the double-sided partition element having a double thermal transfer function, made for example of stainless steel, is generally referenced at 10. It comprises a buffer housing made up of a flat (or ribbed) part 11 enlarged at its base at 12 and constituting a reservoir for a eutectic gel, water, air, an expanded insulating material, etc.
  • the element 10 has a profile 13 allowing the element 10 to be guided vertically by the lateral grooves 7 of the enclosure 1 when it is placed in the latter.
  • the element 10 further comprises a free space contiguous to the face 11, extending above the enlarged part 12 and delimited by a perforated sheet, grid or the like, referenced 14 in parallel to the flat part 11.
  • the fixing of the grid 14 on the buffer tank is ensured by any suitable means, for example welding spots 17 between the grid and the corresponding part of the buffer tank.
  • a refrigerant 15 for example solid carbon dioxide
  • the sublimation carbon dioxide can thus escape into the isothermal enclosure 1, on the side opposite to the flat part 11, by passing through the grid 14.
  • a freezing temperature for example of the order of -25 "C (negative temperature)
  • a refrigeration temperature generally greater than 0 ° C ( Figure 3) (positive temperature).
  • a slight space 16 (FIG. 2) is provided between the lower part of the grid 14 and the enlarged part 12 of the buffer tank.
  • the ribs 9 of the bottom 8 and of the extreme walls of the enclosure contribute to ensuring this good circulation.
  • FIG. 4 shows an arrangement making it possible to obtain a refrigeration temperature, for example of the order of + 3 ° C., in the whole of the isothermal enclosure 1. It suffices for this to have the elements 10 , with the desired charge of refrigerant 15 so that their smooth faces 10 are arranged opposite one another, the grids 14 of these elements then being applied against the end walls 3 of the pregnant.
  • the reverse arrangement of the elements 10 will make it possible to obtain, throughout the enclosure, a freezing temperature, for example of the order of -25 "C.
  • FIG. 6 Another mode of implementation is shown in FIG. 6 and relates to an insulated cabinet in the form of a refrigerated cabinet.
  • Two partition elements according to the invention 10 ′ arranged as horizontal partitions in an insulated cabinet 1 ′, for example mounted on wheels 19.
  • One of the elements 10 ′ will always be arranged at the top, the other element 10 'can be arranged at different heights, resting on projecting lugs 20 or of configuration similar to the previous example (groove 7 and conjugate profile 13), provided on the side walls 21 of the cabinet, or be of design similar to the refrigerator and freezer described above.
  • the refrigerating and freezing element 10 ′ may consist of a reservoir 22 for the eutectic gel or the buffer reservoir, and of a tank 23 in thermal contact with this reservoir and intended to contain the refrigerant 24, again consisting, for example, of solid carbon dioxide.
  • the tray 23 being closed by a grid 14 ′, it will be possible to have there food or other products to be kept frozen, for example at a temperature of the order of -25 ° C. as in the case of the previous application, while the lower part of the enclosure may be maintained at a refrigeration temperature of the order of, for example, 3 ° C. for the products to be kept cool, and this for the duration of the transport of the cabinet.
  • the cabinet l is provided with insulating walls 25 to 27 comprising grooves 9 * (or grooves 7 ') ensuring good circulation of cold gases and can be closed by a hermetic door 28, also insulating and also comprising grooves or grooves performing the same function as above.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Radiation Pyrometers (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Electromechanical Clocks (AREA)
  • Battery Mounting, Suspending (AREA)
  • Devices For Use In Laboratory Experiments (AREA)
EP95913201A 1994-03-15 1995-03-15 Zweizweckwärmeübertragungselement für isothermische räume, mit einem solchen element versehener, isothermischer raum Expired - Lifetime EP0750732B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9402998 1994-03-15
FR9402998A FR2717565B1 (fr) 1994-03-15 1994-03-15 Elément à double fonction de transfert thermique pour enceintes isothermes; enceinte isothermique équipée d'un tel élément.
PCT/FR1995/000315 WO1995025253A1 (fr) 1994-03-15 1995-03-15 Element a double fonction de transfert thermique pour enceintes isothermes; enceinte isothermique equipee d'un tel element

Publications (2)

Publication Number Publication Date
EP0750732A1 true EP0750732A1 (de) 1997-01-02
EP0750732B1 EP0750732B1 (de) 1999-08-25

Family

ID=9461052

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95913201A Expired - Lifetime EP0750732B1 (de) 1994-03-15 1995-03-15 Zweizweckwärmeübertragungselement für isothermische räume, mit einem solchen element versehener, isothermischer raum

Country Status (7)

Country Link
EP (1) EP0750732B1 (de)
AT (1) ATE183819T1 (de)
CA (1) CA2184073A1 (de)
DE (2) DE29580117U1 (de)
FI (1) FIU960472U0 (de)
FR (1) FR2717565B1 (de)
WO (1) WO1995025253A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019223893A1 (de) * 2018-05-25 2019-11-28 Mchef Gmbh & Co. Kg Transportbox insbesondere für teilzubereitete speisen

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FR2751623B1 (fr) * 1996-07-23 1998-09-04 Olivo Conteneur isotherme avec bac refrigerant
NO982971A (no) * 1998-06-26 1999-12-27 H&R Ind Inc Fremgangsmåte for transport og lagring av varer, samt container egnet for samme
IT1309890B1 (it) * 1999-07-30 2002-02-05 Saldogas S R L Contenitori isotermici per il trasporto di prodotti termodeperibilimuniti di appositi vani per ospitare ghiaccio secco ed altri elementi
WO2003073030A1 (en) * 2002-02-27 2003-09-04 Energy Storage Technologies, Inc. Temperature-controlled system including a thermal barrier
WO2014206941A1 (fr) * 2013-06-24 2014-12-31 Good Deal For You Concept Sprl Emballage thermiquement isolant a paroi(s) creuse(s) munie(s) d'au moins une ouverture a base de materiau isolant isotherme et son procédé de fabrication
BE1022570B1 (fr) * 2014-04-22 2016-06-08 Good Deal For You Concept Sprl Emballage thermiquement isolant a paroi(s) creuse(s) munie(s) d'au moins une ouverture a base de materiau isolant isotherme
EP2988080B1 (de) 2014-08-22 2018-04-04 DeltiLog GmbH Behälter
EP3090961B1 (de) * 2015-05-07 2019-02-27 Air Liquide Deutschland GmbH Kühlbox und verfahren zum transport von verderblichen oder wärmeempfindlichen produkten in einem transportfahrzeug und/oder zum verteilen von produkten an endkunden
NL2014865B1 (nl) * 2015-05-27 2017-01-31 Cramer Holding B V Afsluitbare houder voor het op temperatuur houden van goederen, in het bijzonder levensmiddelen, en samenstel.
DE102016107813B3 (de) * 2016-04-27 2017-05-04 Verein zur Förderung innovativer Verfahren in der Logistik, VVL e.V. Mehrwegfähige Transportbox
DE102017006670A1 (de) * 2017-07-14 2019-01-17 MChef GmbH & Co.KG Transportbox insbesondere für teilzubereitete Speisen
CN107270604B (zh) * 2017-07-31 2018-06-01 深圳市袋鼠社区跨境电商有限公司 一种物流快递箱
CA3103275A1 (en) 2018-06-15 2019-12-19 Cold Chain Technologies, Llc Shipping system for storing and/or transporting temperature-sensitive materials
US11634266B2 (en) 2019-01-17 2023-04-25 Cold Chain Technologies, Llc Thermally insulated shipping system for parcel-sized payload
US12140367B2 (en) 2020-08-31 2024-11-12 Keter Home And Garden Products Ltd Cooler container
WO2024211855A2 (en) * 2023-04-06 2024-10-10 Cold Chain Technologies, Llc System suitable for storing and/or transporting temperature-sensitive materials

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Publication number Priority date Publication date Assignee Title
WO2019223893A1 (de) * 2018-05-25 2019-11-28 Mchef Gmbh & Co. Kg Transportbox insbesondere für teilzubereitete speisen

Also Published As

Publication number Publication date
DE69511685T2 (de) 2000-03-02
FR2717565A1 (fr) 1995-09-22
FIU960472U0 (fi) 1996-09-16
ATE183819T1 (de) 1999-09-15
WO1995025253A1 (fr) 1995-09-21
FR2717565B1 (fr) 1996-08-14
DE69511685D1 (de) 1999-09-30
DE29580117U1 (de) 1996-12-05
CA2184073A1 (fr) 1995-09-21
EP0750732B1 (de) 1999-08-25

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