EP0753048A1 - Waschmittelzusammensetzungen - Google Patents

Waschmittelzusammensetzungen

Info

Publication number: EP0753048A1
Authority: EP; European Patent Office
Prior art keywords: detergent composition; nonionic surfactant; surfactant; water; alcohol
Prior art date: 1994-03-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP95911339A

Other languages

English (en)

French (fr)

Other versions

EP0753048B1 (de

Inventor

Peter Robert Garrett

Dennis Giles

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Unilever NV

Original Assignee

Unilever PLC

Unilever NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-03-31

Filing date

1995-03-16

Publication date

1997-01-15

1994-03-31 Priority claimed from GB9406460A external-priority patent/GB9406460D0/en

1995-03-16 Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC

1997-01-15 Publication of EP0753048A1 publication Critical patent/EP0753048A1/de

1998-07-15 Application granted granted Critical

1998-07-15 Publication of EP0753048B1 publication Critical patent/EP0753048B1/de

2015-03-16 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 48
239000003599 detergent Substances 0.000 title claims abstract description 31
239000002736 nonionic surfactant Substances 0.000 claims abstract description 42
DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims abstract description 34
239000004530 micro-emulsion Substances 0.000 claims abstract description 34
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
239000000463 material Substances 0.000 claims abstract description 20
239000004094 surface-active agent Substances 0.000 claims abstract description 18
239000003125 aqueous solvent Substances 0.000 claims abstract description 8
239000004744 fabric Substances 0.000 claims abstract description 8
125000000217 alkyl group Chemical group 0.000 claims abstract description 7
238000005406 washing Methods 0.000 claims abstract description 6
239000002904 solvent Substances 0.000 claims description 14
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
235000019832 sodium triphosphate Nutrition 0.000 claims description 7
150000001298 alcohols Chemical class 0.000 claims description 6
150000001335 aliphatic alkanes Chemical class 0.000 claims description 6
239000004615 ingredient Substances 0.000 claims description 4
239000003945 anionic surfactant Substances 0.000 claims description 3
IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 30
239000002689 soil Substances 0.000 description 19
235000021314 Palmitic acid Nutrition 0.000 description 15
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 15
BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 13
PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 13
PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 13
229940117972 triolein Drugs 0.000 description 13
230000000052 comparative effect Effects 0.000 description 10
230000008901 benefit Effects 0.000 description 8
239000007788 liquid Substances 0.000 description 6
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 5
239000001509 sodium citrate Substances 0.000 description 5
239000004064 cosurfactant Substances 0.000 description 4
SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 3
229910021653 sulphate ion Inorganic materials 0.000 description 3
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
239000002253 acid Substances 0.000 description 2
-1 alkylbenzene sulphonate Chemical class 0.000 description 2
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
150000001860 citric acid derivatives Chemical class 0.000 description 2
235000014113 dietary fatty acids Nutrition 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000007046 ethoxylation reaction Methods 0.000 description 2
239000000194 fatty acid Substances 0.000 description 2
229930195729 fatty acid Natural products 0.000 description 2
150000004665 fatty acids Chemical class 0.000 description 2
238000000034 method Methods 0.000 description 2
229920005646 polycarboxylate Polymers 0.000 description 2
229920002689 polyvinyl acetate Polymers 0.000 description 2
239000011118 polyvinyl acetate Substances 0.000 description 2
239000000344 soap Substances 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
239000000126 substance Substances 0.000 description 2
239000004753 textile Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
YHGREDQDBYVEOS-UHFFFAOYSA-N [acetyloxy-[2-(diacetyloxyamino)ethyl]amino] acetate Chemical class CC(=O)ON(OC(C)=O)CCN(OC(C)=O)OC(C)=O YHGREDQDBYVEOS-UHFFFAOYSA-N 0.000 description 1
150000001253 acrylic acids Chemical class 0.000 description 1
229920006243 acrylic copolymer Polymers 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
238000010936 aqueous wash Methods 0.000 description 1
239000012612 commercial material Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000006184 cosolvent Substances 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000009472 formulation Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
150000002689 maleic acids Chemical class 0.000 description 1
239000000693 micelle Substances 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920001983 poloxamer Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
230000003389 potentiating effect Effects 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000019333 sodium laurylsulphate Nutrition 0.000 description 1
229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

EP95911339A 1994-03-31 1995-03-16 Waschmittelzusammensetzungen Expired - Lifetime EP0753048B1 (de)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
GB9406460		1994-03-31
GB9406460A GB9406460D0 (en)	1994-03-31	1994-03-31	Detergent compositions
GB9414323A GB9414323D0 (en)	1994-03-31	1994-07-15	Detergent compositions
GB9414323		1994-07-15
PCT/EP1995/000990 WO1995027034A1 (en)	1994-03-31	1995-03-16	Detergent compositions

Publications (2)

Publication Number	Publication Date
EP0753048A1 true EP0753048A1 (de)	1997-01-15
EP0753048B1 EP0753048B1 (de)	1998-07-15

Family

ID=26304617

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP95911339A Expired - Lifetime EP0753048B1 (de)	1994-03-31	1995-03-16	Waschmittelzusammensetzungen

Country Status (7)

Country	Link
EP (1)	EP0753048B1 (de)
AU (1)	AU1894695A (de)
CA (1)	CA2173137A1 (de)
DE (1)	DE69503489T2 (de)
ES (1)	ES2119405T3 (de)
IN (1)	IN184051B (de)
WO (1)	WO1995027034A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP1129173A2 (de) *	1998-11-12	2001-09-05	Colgate-Palmolive Company	Kurzkettige amphiphile verbindungen enthaltende flüssige reinigungszusammensetzungen in form einer mikroemulsion
US6645929B2 (en) *	2001-12-10	2003-11-11	Colgate-Palmolive Company	Cleaning composition
ES2299717T5 (es)	2002-04-26	2017-05-03	Basf Se	C10-alcanolalcoxilatos y su empleo
WO2003091192A1 (de)	2002-04-26	2003-11-06	Basf Aktiengesellschaft	C10 -alkanolalkoxylat-gemische und ihre verwendung
CN101558033B (zh) *	2006-12-14	2013-10-23	巴斯夫欧洲公司	用于自发乳化的乳液浓缩物的非离子型乳化剂
TW201031743A (en)	2008-12-18	2010-09-01	Basf Se	Surfactant mixture comprising branched short-chain and branched long-chain components
WO2011003904A1 (de)	2009-07-10	2011-01-13	Basf Se	Tensidgemisch mit kurz- und langkettigen komponenten
EP2361963A1 (de)	2010-02-01	2011-08-31	Unilever N.V.	Bikontinuierliche Mikroemulsions-Waschmittelzusammensetzung
WO2011073062A1 (en)	2009-12-16	2011-06-23	Unilever Nv	Bi-continuous micro-emulsion detergent composition
ES2511465T3 (es)	2010-09-28	2014-10-22	Unilever N.V.	Composición detergente
EP3514207A1 (de) *	2018-01-18	2019-07-24	Henkel AG & Co. KGaA	Verfahren zum entlacken unter anwendung einer mikroemulsion mit niedrigem ölgehalt

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8409055D0 (en) *	1984-04-07	1984-05-16	Procter & Gamble	Cleaning compositions
MY101656A (en) *	1986-09-02	1991-12-31	Colgate Palmolive Co	Laundry pre-spotter composition providing improved oily soil removal.
US5108643A (en) *	1987-11-12	1992-04-28	Colgate-Palmolive Company	Stable microemulsion cleaning composition
CA2013431A1 (en) *	1989-03-30	1990-09-30	Arpad M. Magyar	Microemulsion engine cleaner and degreaser
US5035826A (en) *	1989-09-22	1991-07-30	Colgate-Palmolive Company	Liquid crystal detergent composition
GB2259518B (en) *	1991-09-05	1996-02-14	Shell Int Research	Micro-emulsion cleaner composition suitable for use in seawater

1995
- 1995-03-16 CA CA 2173137 patent/CA2173137A1/en not_active Abandoned
- 1995-03-16 ES ES95911339T patent/ES2119405T3/es not_active Expired - Lifetime
- 1995-03-16 DE DE69503489T patent/DE69503489T2/de not_active Expired - Lifetime
- 1995-03-16 EP EP95911339A patent/EP0753048B1/de not_active Expired - Lifetime
- 1995-03-16 AU AU18946/95A patent/AU1894695A/en not_active Abandoned
- 1995-03-16 WO PCT/EP1995/000990 patent/WO1995027034A1/en not_active Ceased
- 1995-03-29 IN IN132BO1995 patent/IN184051B/en unknown

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9527034A1 *

Also Published As

Publication number	Publication date
WO1995027034A1 (en)	1995-10-12
EP0753048B1 (de)	1998-07-15
DE69503489T2 (de)	1998-12-03
DE69503489D1 (de)	1998-08-20
IN184051B (de)	2000-06-03
AU1894695A (en)	1995-10-23
ES2119405T3 (es)	1998-10-01
CA2173137A1 (en)	1995-10-12

Legal Events

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Publication	Publication Date	Title
US5597507A (en)	1997-01-28	Microemulsion detergent composition containing specific ethoxylated alcohol based surfactant system
US5490948A (en)	1996-02-13	Translucent solid prespotting composition
AU691499B2 (en)	1998-05-21	Microemulsion all purpose liquid cleaning compositions
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