EP0804625B1 - Verfahren zur erhöhung der oxidations- und temperaturwechselbeständigkeit von diffusen aluminidbeschichtungen - Google Patents

Verfahren zur erhöhung der oxidations- und temperaturwechselbeständigkeit von diffusen aluminidbeschichtungen Download PDF

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Publication number
EP0804625B1
EP0804625B1 EP95918905A EP95918905A EP0804625B1 EP 0804625 B1 EP0804625 B1 EP 0804625B1 EP 95918905 A EP95918905 A EP 95918905A EP 95918905 A EP95918905 A EP 95918905A EP 0804625 B1 EP0804625 B1 EP 0804625B1
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Prior art keywords
percent
substrate
coating
diffusion aluminide
additive
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EP95918905A
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French (fr)
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EP0804625A1 (de
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Abdus S. Khan
Richard J. Fenton
Kenneth S. Murphy
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RTX Corp
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United Technologies Corp
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C10/00—Solid state diffusion of only metal elements or silicon into metallic material surfaces
    • C23C10/28—Solid state diffusion of only metal elements or silicon into metallic material surfaces using solids, e.g. powders, pastes
    • C23C10/34—Embedding in a powder mixture, i.e. pack cementation
    • C23C10/36—Embedding in a powder mixture, i.e. pack cementation only one element being diffused
    • C23C10/48—Aluminising
    • C23C10/50—Aluminising of ferrous surfaces
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/057—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being less 10%

Definitions

  • the invention relates to a coated superalloy article having a substrate of a nickel-base composition, with an oxidation resistant diffusion aluminide coating thereupon having improved resistance to spalling.
  • Nickel-base superalloy articles are used in applications requiring strength and oxidation resistance at elevated temperatures. These applications include components for high temperature gas turbine engines, such as gas turbine engine blades.
  • aluminide coatings are produced by introducing aluminum into the surface of a nickel-base superalloy article to provide an aluminum-rich diffused surface layer that serves to improve the oxidation resistance of the article by providing sufficient aluminum to develop a protective alumina scale on the article surface, with sufficient aluminum also being present to reform this scale as it spalls from the surface of the article as a result of heat cycling during use thereof.
  • This nickel aluminide coating is also known to be highly resistant to diffusion of metal from the substrate to the surface, thus limiting loss of strengthening or otherwise beneficial elements in the substrate.
  • the diffusion zone i.e. the zone of diffusion of substrate materials into the aluminide coating, has been observed to be limited to about one third of the thickness of the coating, below the surface zone.
  • the effectiveness of diffusion aluminide coatings in improving surface oxidation resistance is materially affected by the resistance of the alumina scale to removal, such as by spalling. Hence, the adherence of the coating oxide scale to the article surface greatly influences the duration of the desired oxidation resistance upon cyclic high temperature exposure during typical applications.
  • Strangman et al in US 4,880,614, teach a ceramic thermal barrier coating system for superalloy components, which includes a high purity alumina interfacial layer between the metallic substrate and the ceramic overcoat to better resist spalling.
  • the reference teaches the use of a diffusion aluminide coating on a zirconium containing superalloy, but requires additional layers over said diffusion aluminide to achieve protection of the substrate.
  • Gostic et al on the other hand, in US 4,878,965, teach the addition of small amounts of zirconium to a single crystal alloy composition to improve oxidation resistance.
  • Gostic et al specifically teach the use of the alloy compositions in a uncoated manner, to avoid the additional costs and complexities of aluminide coatings.
  • US-A-4 885 216 is reprentative of some prior art which does foresee the addition of ZR and/or Y to the bulk of certain nickel based superalloys. It does not, however, dislose a superalloy substrate with compositions of the types claimed.
  • the present invention provides a method for improving the oxidation and spallation resistance of a diffusion aluminide coated superalloy substrate comprising 9.5 to 10.5 percent chromium, 4.5 to 5.5 percent cobalt, 3.75 to 4.25 percent tungsten, 1.25 to 1.75 percent titanium, 11.75 to 12.25 percent tantalum, and 4.75 to 5.25 percent aluminum, the balance nickel and unavoidable impurities, said method comprising adding to said substrate from 0.01 to 0.30 percent by weight of an additive selected from zirconium or yttrium, and applying directly to said substrate containing said additive a diffusion aluminide coating, with no intermediate coatings and with no further coating thereupon.
  • the present invention provides a method for improving the oxidation and spallation resistance of a diffusion aluminide coated superalloy substrate comprising 4.75 to 5.25 percent chromium, 9.5 to 10.5 percent cobalt, 1.70 to 2.10 percent molybdenum, 5.60 to 6.20 percent tungsten, 2.80 to 3.20 percent rhenium, 8.40 to 9.00 percent tantalum, 5.50 to 5.80 percent aluminum, and 0.05 to 0.15 percent hafnium, the balance nickel and unavoidable impurities, said method comprising adding to said substrate from 0.01 to 0.30 percent by weight of an additive selected from zirconium or yttrium, and applying directly to said substrate containing said additive a diffusion aluminide coating, with no intermediate coatings and with no further coating thereupon.
  • the present invention provides an oxidation resistant superalloy article comprising a substrate comprising 4.75 to 5.25 percent chromium, 9.5 to 10.5 percent cobalt, 1.70 to 2.10 percent molybdenum, 5.60 to 6.20 percent tungsten, 2.80 to 3.20 percent rhenium, 8.40 to 9.00 percent tantalum, 5.50 to 5.80 percent aluminum, and 0.05 to 0.15 percent hafnium, the balance nickel and unavoidable impurities, and from 0.01 to 0.30 percent by weight of an additive selected from zirconium or yttrium, said substrate having only a diffusion aluminide coating thereupon, and said additive is present in said diffusion aluminide coating as a solid solution.
  • the present invention provides an oxidation resistant superalloy article comprising a substrate comprising 9.5 to 10.5 percent chromium, 4.5 to 5.5 percent cobalt, 3.75 to 4.25 percent tungsten, 1.25 to 1.75 percent titanium, 11.75 to 12.25 percent tantalum, 4.75 to 5.25 percent aluminum, the balance nickel and unavoidable impurities, and from 0.01 to 0.30 percent by weight of an additive selected from zirconium or yttrium, said substrate having only a diffusion aluminide coating thereupon, and said additive is present in said diffusion aluminide coating as a solid solution.
  • the invention results in a more adherent alumina scale formed at the surface of the aluminide coating.
  • the scale is formed at elevated temperatures such as those encountered during use of the article in conventional high-temperature applications.
  • Diffusion aluminide coatings formed on superalloy substrates including such an additive, preferably from about 0.02 to 0.15 percent zirconium, or from about 0.01 to 0.10 percent yttrium provide a significantly higher life than aluminide coatings on superalloy substrates having less of these elements. It is also noted that if hafnium is present in the alloy of the substrate, the effectiveness of the yttrium is enhanced.
  • Such diffusion aluminide coatings may be used without the addition of further surface coatings, and are highly resistant to spalling.
  • Articles prepared in accordance with the present invention comprise an oxidation resistant coated superalloy, wherein the nickel-base superalloy substrate has been modified by the addition of a small but critical amount of a specified additive element selected from the group consisting of zirconium, and yttrium.
  • the substrate is coated with a diffusion aluminide coating, whereby nickel diffuses from the substrate alloy into the applied coating, thereby forming a nickel aluminide, and improving the oxidation characteristics of the coated substrate.
  • the above cited elemental additives unexpectedly also diffuse from the substrate alloy through the aluminide coating to the surface thereof, and act to limit the flaking or spalling of the surface oxide during cyclic heating. This improvement in flaking or spalling is not observed in coated substrates in the absence of the additives of this invention, as demonstrated by Figure 1.
  • the present invention constitutes an enhancement of diffusion coating oxidation resistance as opposed to an improvement in inherent oxidation resistance.
  • This improvement to diffusion aluminide formation is particularly advantageous for superalloy substrates having lower levels of aluminum, e.g. those in which the aluminum content is insufficient to form an extensive alumina surface scale.
  • the invention is applicable to both single crystal materials and to polycrystalline substrates. It is also to be noted that the addition of these elements to the substrate alloys has been found to improve the oxidation characteristics of the substrate alloys per se slightly, but insufficiently to use the alloy uncoated at high temperatures.
  • the nickel-base superalloy substrates suitable for modification in accordance with this invention are defined in the claims.
  • Exemplary suitable substrate alloys are set forth in Table I.
  • COMPOSITIONS OF SUBSTRATE ALLOYS (PERCENT BY WEIGHT) Alloy A Alloy B Ingredients min max min max Chromium 9.50 10.50 4.75 5.25 Cobalt 4.50 5.50 9.50 10.50 Molybdenum -- -- 1.70 2.10 Tungsten 3.75 4.25 5.60 6.20 Titanium 1.25 1.75 -- -- Rhenium -- -- 2.80 3.20 Tantalum 11.75 12.25 8.40 9.00 Aluminum 4.75 5.25 5.50 5.80 Hafnium -- 0.0300 (300 ppm) 0.05 0.15 Carbon -- 0.0500 (500 ppm) -- 0.050 (500 ppm) Manganese -- 0.12 -- 0.12 Silicon -- 0.12 -- 0.12 Phosphorus -- 0.015 -- 0.015 Sulfur -- 0.015 -- 0.015 Boron -- 0.0030 (30 ppm) -- 0.0030 (30 pp
  • the diffusion nickel aluminide coating materials may be chosen from conventional high aluminum content diffusion coating materials.
  • Aluminum may be transferred to the substrate by various coating techniques, such as gas phase deposition, low temperature pack coating, or high temperature pack coating.
  • gas phase deposition gaseous aluminum trichloride may be passed over the heated substrate in a furnace at about 815-1150°C (1500- 2100°F).
  • pack coating techniques the substrate may be encased within a pack of particulate elemental aluminum or appropriate aluminum alloy, inert alumina, and an activator such as ammonium chloride, fluoride, or bifluoride, at about 760°C (1400°F) (low temperature pack) or about 1040°C (1900°F) (high temperature pack).
  • an aluminum-silicon compound may be advantageously used in the pack, or, alternatively, may be applied to the surface of the substrate in the form of a slurry, utilizing a binder component such as nitrocellulose, and then heated to remove the binder materials and diffusion bond the aluminum-silicon compound, preferably comprising 90 percent aluminum and 10 percent silicon, to the substrate.
  • Diffusion aluminide coatings may be categorized as either inward diffusion or outward diffusion.
  • inward diffusion coating aluminum diffuses inwardly from the coating into the substrate, whereas with the outward diffusion coating, nickel diffuses outwardly from the substrate into the coating. It is not uncommon to have both forms, i.e. both inward and outward diffusion, in the same coating.
  • a surface coating of nickel aluminide, NiAl is formed to a depth of about 25.4 ⁇ m to about 102 ⁇ m (about 1 to about 4 mils), The aluminum content of said coating layer is nominally from about 22 to about 32 weight percent, dependent upon coating method and/or temperature.
  • a post coating diffusion heat treatment at about 1080°C (1975°F) in an argon or hydrogen environment may also be employed.
  • Coating I designates a vapor deposition method for applying a diffusion aluminide coating in which the article to be coated is not in contact with a pack powder mixture.
  • Coating II designates a pack process.
  • articles to be coated were thoroughly cleaned and free of dirt, oil, grease, stains and other foreign materials after having been conditioned by grit blasting with No. 220 or finer aluminum oxide grit.
  • Articles subjected to Coating I were placed in a retort in such a manner that all surfaces thereof were out of contact with the source coating material.
  • the retort was covered and placed in a furnace, and heated to about 1080 ⁇ 28°C (1975 ⁇ 50°F), for sufficient time to produce the desired diffusion aluminide coating, to a depth of about 25.4 ⁇ m to about 50.8 ⁇ m (about 1 to about 2 mils), with a surface aluminum content of from about 25 to 28 weight percent.
  • Articles subjected to coating II were packed in a retort so as to surround all areas to be coated with at least 13mm (0.50 inch) of coating material.
  • the retort was covered and placed in a furnace at about 760 ⁇ 28°C (1400 ⁇ 50°F) for sufficient time to produce the desired coating thickness and aluminum content.
  • the articles were heated at 1080 ⁇ 14°C (1975 ⁇ 25°F) in an argon or hydrogen environment as diffusion heat treatment.
  • the aluminide coating was from about 50.8 ⁇ m to about 102 ⁇ m (about 2 to about 4 mils) thickness, with a surface aluminum content of from about 22 to 32 weight percent.
  • the pack material comprised about 15 weight percent aluminum silicon powder, about 2.5 weight percent ammonium chloride, and about 82.5 weight percent alumina.
  • the source of aluminum was cobalt aluminide, rather than aluminum silicon.
  • the addition of a small but significant amount of zirconium or yttrium to the nickel-base superalloy substrate results in the presence of a solid solution thereof at the surface of the nickel aluminide layer. While the mechanism is not fully understood at this time, a synergistic effect has been found in that more adherent coatings, which are more resistant to both erosion, e.g. spalling, and to oxidation, are formed when from about 0.01 to 0.30 percent zirconium or yttrium is present in the substrate. This synergy is more pronounced for the yttrium additive in those substrate alloys comprising a small amount of hafnium, such as from 0.02 to 0.30 percent.
  • the zirconium is preferably added in a concentration of from about 0.02 to 0.15 percent, most preferably from about 0.02 to 0.10 percent, and the yttrium is preferably added in a concentration of from about 0.01 to 0.10 percent, most preferably 0.01 to 0.04 percent by weight of the substrate alloy.
  • burner rig bars having a diameter of 11.9 mm (0 ⁇ 468 inch) with a length of 82.6 mm (3.25 inches) were fabricated as test specimens from both Alloy A and Alloy B. Additional test specimens were fabricated having zirconium additions in the range of from 0.10 to about 0.25 weight percent to each of Alloys A and B. Similarly, test specimens are fabricated having yttrium additions of from 0.01 to 0.05 percent to each of Alloys A and B. Diffusion aluminide coatings were applied to selected specimen bars in accordance with the methods set forth above for Coatings I and II.
  • coated specimens were subjected to burner rig oxidation testing at various temperatures to determine oxidation resistance, as measured by weight loss, and spalling resistance, as measured by diameter loss.
  • the temperature cycle during testing including heating to the indicated temperature for 57 minutes followed by forced air cooling for 3 minutes. Inspection for determining specific weight change, as a measure of oxidation, and specimen diameter, as a measure of spalling, were conducted at selected intervals after initiation of cyclic oxidation for the tests conducted at 1205°C (2200°F) and higher.
  • the weight of the specimens was measured on a Sartorius Type 1602 MP I Scale.
  • the oxidized surface area for all of the samples was estimated as 18 cm 2 .
  • Specific weight change per square centimeter was calculated and plotted versus time.
  • Minimum specimen bar diameters were measured with a flat blade dial vernier caliper at the hot spot center and plotted versus time. The tests were conducted to erode at least 0.76 ⁇ m (30 mils) from the base line Alloy B/Coating II bar specimen.
  • Figs. 1-3 show the specific weight change of selected samples having zirconium addition as a function of oxidation and spalling, which indicates the adherence characteristics of the alumina scale formation.
  • the diameter change of the specimens as a function of test time was also recorded and generally substantiated the specific wdight change behavior of test specimens at time-temperature intervals. Similar results are obtained for samples having yttrium additions.
  • Fig. 4 presents an indication of the shortest time to coating defeat or failure without regard to oxidation or spallation-erosion failure.
  • the overall life of a coated article with zirconium addition to Alloy B, depending on temperature, can be approximated as 2 to 3.5 times the life of a coated article of Alloy B with no zirconium addition.
  • Coating failure as reflected in Fig. 4 is a subjective observation, based upon the alumina (grey oxide) forming capability of the specimen surface. As the surfaces were depleted in aluminum during oxidation rig testing, other base metal atoms were incorporated into the surface scale, resulting in color changes to blue and green. Coating failure was designated as that point in time when 50 percent of the hot spot diameter no longer formed a grey alumina scale.

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  • Other Surface Treatments For Metallic Materials (AREA)
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Claims (8)

  1. Verfahren zur Verbesserung der Beständigkeit gegen Oxidation und Abplatzen eines Aluminid-diffusionsbeschichteten Substrats aus Superlegierung, das 9,5 bis 10,5 Prozent Chrom, 4,5 bis 5,5 Prozent Cobalt, 3,75 bis 4,25 Prozent Wolfram, 1,25 bis 1,75 Prozent Titan, 11,75 bis 12,25 Prozent Tantal und 4,75 bis 5,25 Prozent Aluminium, Rest Nickel und unvermeidbare Verunreinigungen enthält, wobei das Verfahren aufweist das Zugeben von 0,01 bis 0,30 Gewichtsprozent eines aus Zirkonium oder Yttrium ausgewählten Zusatzstoffes zu dem Substrat, und das Aufbringen einer Aluminid-Diffusionsbeschichtung direkt auf das den Zusatzstoff enthaltende Substrat ohne Zwischenbeschichtungen und ohne weitere Beschichtung darauf.
  2. Verfahren zur Verbesserung der Beständigkeit gegen Oxidation und Abplatzen eines Aluminid-diffusionsbeschichteten Substrats aus Superlegierung, das 4,75 bis 5,25 Prozent Chrom, 9,5 bis 10,5 Prozent Cobalt, 1,70 bis 2,10 Prozent Molybdän, 5,60 bis 6,20 Prozent Wolfram, 2,80 bis 3,20 Prozent Rhenium, 8,40 bis 9,00 Prozent Tantal, 5,50 bis 5,80 Prozent Aluminium und 0,05 bis 0,15 Prozent Hafnium, Rest Nickel und unvermeidbare Verunreinigungen enthält, wobei das Verfahren aufweist das Zugeben von 0,01 bis 0,30 Gewichtsprozent eines aus Zirkonium oder Yttrium ausgewählten Zusatzstoffes zu dem Substrat, und das Aufbringen einer Aluminid-Diffusionsbeschichtung direkt auf das Substrat ohne Zwischenbeschichtungen und ohne weitere Beschichtung darauf.
  3. Oxidationsbeständiger Gegenstand aus Superlegierung, aufweisend ein Substrat, das 4,75 bis 5,25 Prozent Chrom, 9,5 bis 10,5 Prozent Cobalt, 1,70 bis 2,10 Prozent Molybdän, 5,60 bis 6,20 Prozent Wolfram, 2,80 bis 3,20 Prozent Rhenium, 8,40 bis 9,00 Prozent Tantal, 5,50 bis 5,80 Prozent Aluminium und 0,05 bis 0,15 Prozent Hafnium, Rest Nickel und unvermeidbare Verunreinigungen, und 0,01 bis 0,30 Gewichtsprozent eines aus Zirkonium oder Yttrium ausgewählten Zusatzstoffes enthält, wobei sich auf dem Substrat nur eine Aluminid-Diffusionsbeschichtung befindet und der Zusatzstoff in der Aluminid-Diffusionsbeschichtung als eine feste Lösung vorliegt.
  4. Oxidationsbeständiger Gegenstand aus Superlegierung, aufweisend ein Substrat, das 9,5 bis 10,5 Prozent Chrom, 4,5 bis 5,5 Prozent Cobalt, 3,75 bis 4,25 Prozent Wolfram, 1,25 bis 1,75 Prozent Titan, 11,75 bis 12,25 Prozent Tantal, 4,75 bis 5,25 Prozent Aluminium, Rest Nickel und unvermeidbare Verunreinigungen, und 0,01 bis 0,30 Gewichtsprozent eines aus Zirkonium oder Yttrium ausgewählten Zusatzstoffes enthält, wobei sich auf dem Substrat nur eine Aluminid-Diffusionsbeschichtung befindet und der Zusatzstoff in der Aluminid-Diffusionsbeschichtung als eine feste Lösung vorliegt.
  5. Verfahren nach Anspruch 1 oder 2, oder Gegenstand nach Anspruch 3 oder 4, bei dem der Zusatzstoff 0,02 bis 0,15 Prozent Zirkonium aufweist.
  6. Verfahren oder Gegenstand nach Anspruch 5, bei dem der Zusatzstoff 0,02 bis 0,10 Prozent Zirkonium aufweist.
  7. Verfahren nach Anspruch 1 oder 2, oder Gegenstand nach Anspruch 3 oder 4, bei dem der Zusatzstoff 0,01 bis 0,10 Prozent Yttrium aufweist.
  8. Verfahren oder Gegenstand nach Anspruch 7, bei dem der Zusatzstoff 0,01 bis 0,04 Prozent Yttrium aufweist.
EP95918905A 1994-05-10 1995-05-05 Verfahren zur erhöhung der oxidations- und temperaturwechselbeständigkeit von diffusen aluminidbeschichtungen Expired - Lifetime EP0804625B1 (de)

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US24131094A 1994-05-10 1994-05-10
US241310 1994-05-10
PCT/US1995/005429 WO1995030779A1 (en) 1994-05-10 1995-05-05 Method for improving oxidation and spalling resistance of diffusion aluminide coatings

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EP0804625A1 EP0804625A1 (de) 1997-11-05
EP0804625B1 true EP0804625B1 (de) 1998-12-23

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JP (1) JPH09512060A (de)
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Publication number Priority date Publication date Assignee Title
GB2322869A (en) * 1997-03-04 1998-09-09 Rolls Royce Plc A coated superalloy article
US6190471B1 (en) * 1999-05-26 2001-02-20 General Electric Company Fabrication of superalloy articles having hafnium- or zirconium-enriched protective layer
US6444057B1 (en) * 1999-05-26 2002-09-03 General Electric Company Compositions and single-crystal articles of hafnium-modified and/or zirconium-modified nickel-base superalloys
US20070134418A1 (en) * 2005-12-14 2007-06-14 General Electric Company Method for depositing an aluminum-containing layer onto an article
JP5439822B2 (ja) * 2009-01-15 2014-03-12 独立行政法人物質・材料研究機構 Ｎｉ基単結晶超合金
US20240066493A1 (en) * 2022-08-25 2024-02-29 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Hydrogen production facility having equipment with a nitridation protective layer
CN118773601B (zh) * 2024-06-18 2026-02-06 西安热工研究院有限公司 一种提升铝化物熔覆涂层抗氧化性能的改性方法

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ZA828522B (en) * 1981-11-27 1983-09-28 United Technologies Corp Nickel base superalloy
US4885216A (en) * 1987-04-03 1989-12-05 Avco Corporation High strength nickel base single crystal alloys
DE3571149D1 (en) * 1985-03-13 1989-07-27 Gen Electric Yttrium and yttrium-silicon bearing nickel-base superalloys especially useful as compatible coatings for advanced superalloys
GB2191505B (en) * 1986-06-09 1991-02-13 Gen Electric Dispersion strengthened single crystal alloys
US5262245A (en) * 1988-08-12 1993-11-16 United Technologies Corporation Advanced thermal barrier coated superalloy components

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DE69506917D1 (de) 1999-02-04
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JPH09512060A (ja) 1997-12-02
EP0804625A1 (de) 1997-11-05

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