EP0812140A1 - Explosions und zersetzungsbeständige polyurethanstifelsohle für sicherheitsschuhe - Google Patents

Explosions und zersetzungsbeständige polyurethanstifelsohle für sicherheitsschuhe

Info

Publication number
EP0812140A1
EP0812140A1 EP96907854A EP96907854A EP0812140A1 EP 0812140 A1 EP0812140 A1 EP 0812140A1 EP 96907854 A EP96907854 A EP 96907854A EP 96907854 A EP96907854 A EP 96907854A EP 0812140 A1 EP0812140 A1 EP 0812140A1
Authority
EP
European Patent Office
Prior art keywords
polyaramid
fibres
sole
layer
kevlar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96907854A
Other languages
English (en)
French (fr)
Other versions
EP0812140B1 (de
Inventor
Guy Andrew Vaz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BFR Holdings Ltd
Original Assignee
Vaz Guy Andrew
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vaz Guy Andrew filed Critical Vaz Guy Andrew
Publication of EP0812140A1 publication Critical patent/EP0812140A1/de
Application granted granted Critical
Publication of EP0812140B1 publication Critical patent/EP0812140B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B7/00Footwear with health or hygienic arrangements
    • A43B7/32Footwear with health or hygienic arrangements with shock-absorbing means
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/12Soles with several layers of different materials
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/42Filling materials located between the insole and outer sole; Stiffening materials
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B3/00Footwear characterised by the shape or the use

Definitions

  • the present invention relates to the construction of a boot sole, and more particularly pertains to a new and improved safety boot sole construction to prevent puncturing of the sole by high energy and high velocity projectiles thus affording greater protection to an individual's foot without over-restricting movement.
  • U.S. Patent no. 5,237,758 to Zachman this uses semi-elliptical sections intersecting at loops with adjacent webs of adjacent loops intersecting with flexible rods directed through the intersecting loops to minimise lateral displacement of adjacent webs.
  • U.S. Patent no. 5,285,583 to Aleven this uses a protective layer composed of plastic and including a flexible forepart portion having an insole board bonded to its bottom surface and a fabric liner bonded to its top surface during the process of moulding the protective plastic layer. The plastic used by Aleven is molten plastic injected in the final bonding process.
  • UHL GMBH KARL A multi-layer boot sole having a walking surface, a damping intermediate sole, and an upper insole.
  • the base is a thermo-plastic moulding, or is made of metal, ceramic or graphite, in which multi-filament organic or inorganic reinforcing fibres are embedded in the form of a mat, or woven or knitted into the structure.
  • the elastic profiled portions are formed on the underside of the base by injection moulding or pressing.
  • the base can contain only a single layer of woven fibres, its total thickness being approximately 0.5 mm.
  • the present invention provides a blast and fragment resistant polyester and/or polyether-based polyurethane boot sole comprising embedded protective material in which the material is embedded throughout the entire sole and is composed of at least one woven polyaramid (Kevlar) layer, the density of which is less than or equal to 15 oz per square yard. Increasing density and additional layers of woven polyaramid fibres increases the blast and fragment resistance.
  • woven polyaramid Kevlar
  • polyaramid (Kevlar) and/or graphite fibres can be coated thinly with polyester or polyether based polyurethane before they are woven into the required mat form, this will greatly improve adhesion between the polyaramid and polyurethane material.
  • polyester fibres preferably poly(ethylene terephthalate) (PET) fibres
  • PET poly(ethylene terephthalate)
  • Kevlar poly(ethylene terephthalate)
  • carbon graphite fibres can be interwoven with or between the polyaramid (Kevlar) layers to further strengthen and to stiffen the sole.
  • a woven layer of mineral fibres notably ceramic fibres or S-glass fibres, can be included into the boot sole to act as a fire wall for protection against hot gasses with temperatures of between 815 and 1 ,650 degrees
  • Figure 1 is a vertical cross-sectional view of a boot having a first embodiment of the sole construction according to the present invention
  • Figure 1-A is an enlarged view of the sole construction of Figure 1;
  • Figure 2 is a vertical cross-sectional view of a boot having a second embodiment of the sole construction according to the present invention
  • Figure 2- A is an enlarged view of the sole construction of Figure 2;
  • Figure 3 is a vertical cross-sectional view of a boot having a third embodiment of the sole construction according to the present invention;
  • Figure 3-A is an enlarged view of the sole construction of Figure 3;
  • Figure 3-B is an enlarged view of an alternative sole construction to that depicted in Figure 3-A;
  • Figure 4 is a vertical cross-sectional view of a boot having a fourth embodiment of the sole construction according to the present invention.
  • Figure 4- A is an enlarged view of the sole construction of Figure 4; and Figure 4-B is an enlarged view of an alternative sole construction to that depicted in Figure 4- A.
  • a boot having a first embodiment of the sole construction according to the present invention is generally depicted as 10 in Figures 1 and 1-A.
  • the boot 10 has a standard shaped upper portion 11 and a composite sole 13.
  • the composite sole 13 comprises an outer polyurethane sole 14 having a tread 17, an intermediate sole 15 into which is embedded a layer of polyaramid fibres 18, and optionally, an upper sole 16.
  • the composite safety boot sole is made in a traditional multi-stage mould which is commonly used in the polyurethane shoe soling industry.
  • polyester and/or polyether-based polyurethane is first injected into a composite sole mould cavity to form the outer (lower) sole 14 such that its density is typically in the range of 500 to 2000 kg/m 3 .
  • one thick layer of polyaramid (Kevlar) woven fibre material 18 is placed onto the outer (lower) sole 14 which remains in the mould cavity.
  • the polyaramid (Kevlar) fibre material can be precoated with polyester and/or polyether-based polyurethane prior to weaving.
  • the coat of polyurethane serves to facilitate good adhesion with and penetration by polyurethane which is injected into the mould cavity.
  • the density of the polyaramid layer 18 is at least 5 oz per square yard, preferably 15 oz per square yard, for each ply of woven polyaramid material.
  • This thick polyaramid layer 18 preferably consists of bundles of polyaramid in crowfoot or leno weave with 70% to 90% in the X to Y direction (that is perpendicular to toe-to-heel), and 10 to 30% in the toe-to-heel direction.
  • the thickness of the layer of the polyaramid layer 18 is at least 0.07 inches, more typically 0.11 inches, using Kevlar 49 in 7100 dernier bundles with tensile strength of 43,000 PSI and modulus 19 million PSI with a 0.07 inch diameter polyaramid fibres.
  • polyester and/ or polyether-based polyurethane is injected into the mould cavity containing the outer (lower) sole 14 at the base of the sole to form the intermediate sole 15.
  • the polyurethane after injection into the mould has a typical density of ⁇ 1000 kg/m 3 .
  • the upper portion 11 can be directly attached to the polyurethane composite sole 13 comprising of the outer (lower) and intermediate soles 14, 15 or a third upper sole 16 can be added on top of the intermediate sole for enhanced comfort.
  • a shoe sole 13 made according to the above method with the preferred 15 oz per square yard polyaramid layer 18 is effective in providing blast and fragment resistance to 60 grain projectile with a velocity of 1350 fps. It also conserves good toe-to-heel flexion in order to enable running, jumping and to clear obstacles such as rope ladders, rope climbing and small steps, while avoiding delamination of the sole in subsequent use.
  • a boot having a second embodiment of the sole construction according to the present invention is depicted as 20 in Figures 2 and 2-A.
  • the sole 13 has further layers 18 of polyaramid fibre material incorporated therein.
  • the outer sole can have up to two layers of polyaramid fibre 18.
  • the intermediate sole 15 would typically have between 2 and
  • the polyaramid layers 18 consist preferably of polyaramid fibres being of 0.01 inch diameter.
  • the fibres are woven together to form a layer less than 0.06 inches thick and, more typically, about 0.04 inches thick.
  • a polyester and/or polyether-based polyurethane is then injected into a composite shoe sole mould cavity to form the outer (lower) sole 14 such that its density is typically in the range of 500 to 2000 kg/m 3 .
  • a polyester and/or polyether-based polyurethane is injected into the mould cavity to form the intermediate sole 15 such that the polyurethane has a typical density of ⁇ 1000 kg/m 3 .
  • the upper portion 11 can be directly attached to the polyurethane composite sole 13 comprising of the outer (lower) and intermediate soles 14, 15 or a third, upper polyurethane sole 16 can be included for enhanced comfort.
  • This is achieved by allowing the outer and intermediate soles (made by the process above) to remain in the mould cavity and by injecting polyester and/or polyether-based polyurethane onto the intermediate sole 15.
  • a shoe sole made according to the above method is even more effective in providing blast and fragment resistance than the first embodiment due to the multiple polyaramid layers.
  • polyaramid layers 18 as described in relation to soles depicted in Figures 1 and 2 are interwoven with polyester (PET) fibres and the boot sole is made in the same manner as described above.
  • interwoven polyaramid and polyester (PET) fibres has the advantage of further increasing the adhesion of the polyurethane material to the embedded layer(s) 18. This being due to the intrinsically superior adhesion between polyurethane and polyester.
  • the polyaramid layers 18 as described in the embodiments above are further interwoven with carbon graphite fibres having 12K TOW and a tensile strength of 470,000 PSI and modulus of 35 million PSI with the boot sole 13 being made in the same manner as described above.
  • the use of interwoven carbon graphite fibres has the advantage of further increasing strength and stiffness and of improving wear resistance.
  • boot sole 13 is made as described above except that, in addition, a layer of woven ceramic fibres of composite ceramic/polyaramid fibres 31 are included into the intermediate sole 15.
  • the woven ceramic fibre layer is preferably comprised of 0.05 inch diameter ceramic fibres with 70% to 90% of the ceramic fibres being woven into a crowfoot or leno weave in the X-Y direction (perpendicular to the toe-to-heel direction) and with 10% to 30% of ceramic fibres in the toe-to-heel direction.
  • This layer is embedded in the intermediate sole above the polyaramid (Kevlar) layer(s) 18 (see Figure 3- A).
  • a thin (0.025 inch) composite layer 32 of ceramic/polyaramid fibres preferably consisting of standard bidirectional weave can be embedded in the upper sole 16.
  • the boot sole incorporating this composite layer of ceramic/polyaramid fibres
  • a layer of composite S-Glass fibres can be added into the middle or upper sole 14, 15 (see Figures 4, 4-A and 4-B).
  • Glass fibres are woven into a crowfoot or leno weave in the X-Y direction (perpendicular to the toe-to-heel direction) and with 10% to 30% of S-Glass fibres in the toe-to-heel direction, is embedded in the intermediate sole above the polyaramid (Kevlar) layer(s) 18 ( Figure 4- A).
  • a thinner (0.025 inch) layer 42 of S-Glass fibres preferably having a standard bi-directional satin weave can be embedded in the upper sole 16 ( Figure 4-B).
  • the boot sole 13 incorporating the layer of S-Glass fibres 41 , 42 allows for protection against hot gasses with a temperature resistance of 815 degrees Celsius for the very brief duration of the blast.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Laminated Bodies (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP96907854A 1995-03-01 1996-02-28 Explosions und zersetzungsbeständige polyurethanstifelsohle für sicherheitsschuhe Expired - Lifetime EP0812140B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SG9500037 1995-03-01
SG1995000037A SG34208A1 (en) 1995-03-01 1995-03-01 Blast and fragment resistant polyurethane boot sole for safety footwear
PCT/SG1996/000001 WO1996026655A1 (en) 1995-03-01 1996-02-28 Blast and fragment resistant polyurethane boot sole for safety footwear

Publications (2)

Publication Number Publication Date
EP0812140A1 true EP0812140A1 (de) 1997-12-17
EP0812140B1 EP0812140B1 (de) 2000-05-10

Family

ID=20429030

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96907854A Expired - Lifetime EP0812140B1 (de) 1995-03-01 1996-02-28 Explosions und zersetzungsbeständige polyurethanstifelsohle für sicherheitsschuhe

Country Status (12)

Country Link
EP (1) EP0812140B1 (de)
KR (1) KR100229887B1 (de)
CN (1) CN1121830C (de)
AT (1) ATE192631T1 (de)
AU (1) AU694636B2 (de)
CA (1) CA2213988C (de)
DE (1) DE69608258T2 (de)
NO (1) NO310541B1 (de)
NZ (1) NZ304186A (de)
SG (1) SG34208A1 (de)
TR (1) TR199700745T1 (de)
WO (1) WO1996026655A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0921736B1 (de) * 1996-05-21 2002-02-06 BfR Holdings Limited Explosionssicheres schuhwerk

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2315663A (en) * 1996-07-30 1998-02-11 Fii Footwear Management Ltd Footwear item
FR2770098B1 (fr) * 1997-10-23 1999-12-03 Etex De Rech Tech Soc Dispositif anti-perforation pour articles chaussants et articles chaussants utilisant un tel dispositif
SG126668A1 (en) 1998-12-29 2006-11-29 Bfr Holding Ltd Protective boot and sole structure
US6368989B1 (en) 1999-01-12 2002-04-09 E. I. Du Pont De Nemours And Company Puncture resistant composite
FR2815289B1 (fr) 2000-10-17 2003-07-04 Salomon Sa Stratifie composite de faible epaisseur et son utilisation dans la confection d'articles de sport, notamment de chaussures
KR100484227B1 (ko) * 2001-05-22 2005-05-23 이균희 대인지뢰 방호용 일체형 전투화
GB0329813D0 (en) 2003-12-23 2004-01-28 Terra Plana Internat Ltd Footwear
KR101291847B1 (ko) 2011-08-23 2013-07-31 한스산업 주식회사 디딤판이 장입된 안전화 중창 및 이의 제조방법
US9668539B2 (en) 2012-02-09 2017-06-06 Simon La Rochelle Footwear with sole protection
CN103284396A (zh) * 2013-05-14 2013-09-11 吴江市董鑫塑料包装厂 一种反光防刺穿劳保靴
CN103300534A (zh) * 2013-05-14 2013-09-18 吴江市董鑫塑料包装厂 一种自动按摩防刺穿劳保靴
CN103251169B (zh) * 2013-05-14 2016-03-16 吴江市风尚鞋厂 一种弹性气囊换气防刺穿劳保靴
CN103238977A (zh) * 2013-05-14 2013-08-14 吴江市董鑫塑料包装厂 一种通风透气的防刺穿劳保靴
CN103251168B (zh) * 2013-05-14 2016-03-16 吴江市风尚鞋厂 一种按摩防刺穿劳保靴
CN103704926A (zh) * 2013-05-14 2014-04-09 吴江市董鑫塑料包装厂 一种保暖防刺穿劳保靴
CN103393251A (zh) * 2013-05-14 2013-11-20 吴江市董鑫塑料包装厂 一种隔热防刺穿劳保靴
CN103404997A (zh) * 2013-05-14 2013-11-27 吴江市董鑫塑料包装厂 一种发光防刺穿劳保靴
CN103230122A (zh) * 2013-05-14 2013-08-07 吴江市董鑫塑料包装厂 一种自发电源发光防刺穿劳保靴
CN103704934A (zh) * 2013-05-14 2014-04-09 吴江市董鑫塑料包装厂 一种高舒适防静电防刺穿劳保靴
CN103251167A (zh) * 2013-05-14 2013-08-21 吴江市董鑫塑料包装厂 一种储物防刺穿劳保靴
CN103230121A (zh) * 2013-05-14 2013-08-07 吴江市董鑫塑料包装厂 一种加热保暖防刺穿劳保靴
CN103251165A (zh) * 2013-05-14 2013-08-21 吴江市董鑫塑料包装厂 一种防静电防刺穿劳保靴
CN103315442B (zh) * 2013-07-22 2015-08-05 青岛亨达股份有限公司 一种特警战训靴
CN107074780B (zh) 2014-08-06 2020-06-12 卫材R&D管理有限公司 用于生产嘧啶-1-醇化合物及其中间体的方法
CN106117504B (zh) * 2016-07-05 2018-07-06 晋江市池店镇娇鹏贸易有限公司 一种聚氨酯弹性体鞋底材料
CN114502167A (zh) 2019-09-13 2022-05-13 卫材R&D管理有限公司 用于治疗失眠的药物组合物
TWI888599B (zh) 2020-07-17 2025-07-01 日商衛材R&D企管股份有限公司 取代哌啶化合物及其用途
JPWO2023136279A1 (de) 2022-01-14 2023-07-20
SE547502C2 (en) * 2023-10-03 2025-04-04 Innovation Soles Ltd Sole part for a shoe

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DE2216439C3 (de) * 1972-04-05 1976-01-08 Dr.-Ing. Funck Kg, 8000 Muenchen Schuh, insbesondere Arbeits- oder Sportschuh
DE3027601C2 (de) * 1980-07-21 1982-06-24 Herbert Dr.-Ing. 8032 Lochham Funck Formsohle mit durchtrittssicherer Einlage
CA1180891A (en) * 1982-06-16 1985-01-15 Henry D. Sweeny Insulative mid-sole assembly
US4858338A (en) * 1988-05-18 1989-08-22 Orthopedic Design Kinetic energy returning shoe

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9626655A1 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0921736B1 (de) * 1996-05-21 2002-02-06 BfR Holdings Limited Explosionssicheres schuhwerk

Also Published As

Publication number Publication date
DE69608258T2 (de) 2000-12-21
KR100229887B1 (ko) 1999-11-15
CN1175888A (zh) 1998-03-11
WO1996026655A1 (en) 1996-09-06
KR19980702053A (ko) 1998-07-15
NO310541B1 (no) 2001-07-23
NZ304186A (en) 1999-04-29
CN1121830C (zh) 2003-09-24
AU694636B2 (en) 1998-07-23
CA2213988C (en) 2000-04-25
NO973905D0 (no) 1997-08-26
AU5131396A (en) 1996-09-18
DE69608258D1 (de) 2000-06-15
EP0812140B1 (de) 2000-05-10
SG34208A1 (en) 1996-12-06
CA2213988A1 (en) 1996-09-06
TR199700745T1 (xx) 1998-03-21
NO973905L (no) 1997-09-01
ATE192631T1 (de) 2000-05-15

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