EP0825902A1 - Films pour le revetement d'ebauches de pieces fa onnees et leur utilisation dans la construction automobile - Google Patents

Films pour le revetement d'ebauches de pieces fa onnees et leur utilisation dans la construction automobile

Info

Publication number
EP0825902A1
EP0825902A1 EP96919735A EP96919735A EP0825902A1 EP 0825902 A1 EP0825902 A1 EP 0825902A1 EP 96919735 A EP96919735 A EP 96919735A EP 96919735 A EP96919735 A EP 96919735A EP 0825902 A1 EP0825902 A1 EP 0825902A1
Authority
EP
European Patent Office
Prior art keywords
film
transparent
coated
layer
plastic film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96919735A
Other languages
German (de)
English (en)
Inventor
Leonidas Kiriazis
Egon Wegner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Coatings GmbH
Original Assignee
BASF Lacke und Farben AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Lacke und Farben AG filed Critical BASF Lacke und Farben AG
Publication of EP0825902A1 publication Critical patent/EP0825902A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/53—Base coat plus clear coat type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/36—Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02—Homopolymers or copolymers of hydrocarbons
    • C08J2425/04—Homopolymers or copolymers of styrene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/261—In terms of molecular thickness or light wave length
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31554—Next to second layer of polyamidoester
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers
    • Y10T428/31928—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31935—Ester, halide or nitrile of addition polymer

Definitions

  • the present invention relates to films for coating molded part blanks, a method for producing these films and the use of the films in automobile construction.
  • EP-A-374 551 discloses coated substrates which are suitable for the production of add-on parts for automobile bodies.
  • the coated substrates described in EP-A-374 551 consist of metal sheets which are coated with at least one layer of paint or of composite materials, the surface layer of which consists of the coated metal sheets.
  • P4424290.9 discloses substrates coated with several layers. These are deformed and, if necessary, further processed with the aid of further materials. In this way, add-on parts for vehicle bodies can be produced.
  • the object of the present invention was to provide films for coating molded part blanks which, after the molded molded part blanks have been deformed, have improved properties compared to the coated substrates disclosed in EP-A-374 551 and only small amounts of solvents are emitted during their production and simple quality monitoring is possible.
  • foils which are characterized in that A. the films made of a pigmented plastic carrier film with a thickness of 10 to 500 ⁇ m,
  • the plastic film or the effect layer is coated with a transparent plastic film or a transparent lacquer layer, which may be provided with effect pigments.
  • a peelable film is applied to the non-coated side of the carrier film, the transparent plastic film or the clear lacquer layer.
  • the present invention also relates to a method for producing a film coated with a plurality of layers, in which the surface of a pigmented plastic film with a thickness of 10 to 500 ⁇ m is coated with a transparent plastic film or transparent lacquer layer, optionally before the transparent film or is applied An additional effect layer is applied to the lacquer layer, and the lacquer layer or the lacquer layers applied to the surface of the pigmented plastic film are cured.
  • a peelable film is applied to the non-coated side of the carrier film and / or the transparent plastic film or transparent lacquer layer.
  • Another object of the present invention is the use of the films according to the invention for coating molded part blanks for the production of automobile bodies and for the production of attachments for vehicle bodies. Therefore, according to the invention, suitable paints are preferably used for automobile bodies, which, however, must have the flexibility required for the purposes of the invention.
  • the pigmented film can first be laminated onto the non-deformed substrate, for example a metal sheet, and then deformed. This is how the effect layer is applied if necessary. Finally, the coating is carried out with the transparent lacquer or the transparent film.
  • the bodies coated with the films according to the invention are distinguished by a very high resistance to stone chips and corrosion. Further advantages of the coated films according to the invention consist in the fact that they can be produced in systems with a small space requirement, that only very small amounts of organic solvents are emitted in the manufacture of the coated bodies according to the invention by the use of the plastic films, and that the quality monitoring is carried out during manufacture the plastic film can use. On the other hand, in conventional painting of metal sheets, the quality of the coating can only be assessed after application of the paint layers to the substrate, so that in the event of quality defects, the painted substrate as a whole must be discarded.
  • Thermoplastic materials are predominantly used for producing the films according to the invention.
  • the carrier film can consist of a polyolefin, a polyamide, a polyurethane, a polyester, a polyacrylate, a polycarbonate or a mixture of different polymeric substances, have a thickness of 10-500, preferably 20-250 ⁇ m and contains dyes and / or pigments .
  • an effect layer may be applied to the surface of the pigmented plastic film before the transparent film or transparent lacquer layer is applied.
  • This can be another very low pigment film or a layer of lacquer.
  • the same materials are considered for the former as for the carrier film.
  • the Clear coat or transparent film containing the effect pigments so that they take over the function of the effect layer.
  • topcoat or basecoat suitable for the conventional painting of automobile bodies can be used as the coating layer, provided the flexibility and pigmentation required for the purposes of the invention are present.
  • They essentially contain a polymeric binder, possibly a crosslinking agent and coating aid.
  • the topcoat or basecoat used can contain, for example, a polyester resin, a polyurethane resin, an epoxy resin or a polyacrylate resin or a mixture of such binders.
  • the topcoat or basecoat may contain an aminoplast resin, a polyisocyanate resin, a carboxyl group-containing crosslinking agent or a mixture of such crosslinking agents.
  • paint auxiliaries include into consideration: anti-foam, anti-settling, flow and rheology aids such as Viscalex HV30 from Allied Colloid Ltd. or a layered silicate (Laponite RD from the company. Laporte).
  • Effect pigments are e.g. Pearlescent pigment from Merck, metal paint, etc.
  • the solids ratio of pigment to binder is ⁇ 0.01: 1, preferably ⁇ _0.006: 1, particularly preferably ⁇ 0.003: 1.
  • a transparent lacquer layer is applied to the surface of the pigmented or colored plastic film or to the effect layer described. All transparent lacquers that can be used for conventional automotive painting can be used here. Powder clearcoats can also be used. These transparent lacquers also consist of a binder, a crosslinking agent and other common additives.
  • the layers of paint are usually cured by heating to temperatures of 60 to 230 ° C. There is a reaction between the binders and crosslinking agents contained in the paints, and three-dimensional polymer networks are formed which give the paint surface a particularly high resistance to mechanical or chemical attacks.
  • the lacquer layers can be applied, for example, by spraying, rolling or knife coating.
  • the films according to the invention described can be rolled up.
  • the products can therefore be offered and delivered in the form of rolls.
  • the varnishes that may be used must therefore have sufficient flexibility for this.
  • the foils can be applied to all molded parts that are used to manufacture vehicle bodies, attachments for vehicle bodies, household appliances, e.g. Refrigerators, washing machines and dishwashers are suitable to be applied.
  • the foils are mainly applied to pretreated metal sheets. These can be pretreated, for example, by phosphating and / or chromating.
  • a transparent plastic film can be applied to the pigmented film or the effect layer.
  • all materials can be used here that are also suitable for the carrier film.
  • the possibly coated plastic films described can be laminated to the surface of a molded part blank, preferably made of sheet metal.
  • either the sheet can be coated successively with a carrier film, if necessary an effect layer and a transparent plastic film or a transparent lacquer layer. From this sheet coated in this way, which as Rolls can be stored and delivered, automotive parts are cut and shaped.
  • the pigmented carrier film is first coated one after the other, if necessary with an effect layer and with a transparent lacquer or a transparent plastic film.
  • This layered structure is laminated onto the sheets from which automobile parts are produced by cutting and shaping. The requirements for the flexibility of the paints used must therefore also be based on the application process described.
  • Another manufacturing possibility is that
  • the pigmented carrier film is laminated to the substrate
  • Adhesion to the surface to be coated can be achieved in different ways.
  • One possibility is, for example, that foils containing adhesion-promoting groups, e.g. Have urethane groups, acid anhydride groups or carboxyl groups or films which have been provided with adhesion-promoting groups by coextrusion with a polymer having adhesion-promoting groups.
  • the adhesion between the film and the surface to be coated can also be achieved by using an adhesive.
  • Adhesives that are solid at room temperature and liquid at room temperature can be used.
  • the substrate When laminating foils with adhesion-promoting groups, the substrate is generally covered with the foil in such a way that the adhesion promoter layer touches the substrate surface.
  • Pressure and heat are then laminated onto the surface to be coated. Pressure and temperature are to be chosen so that a firm connection is created between the substrate and the film.
  • the procedure is similar when using adhesives that are solid at room temperature. If liquid adhesives are used, the procedure is generally that the liquid adhesive is applied to the substrate and the coated plastic film is laminated onto the heated substrate coated with the adhesive.
  • adhesion promoter layer with a 20 ⁇ m thick adhesion promoter layer made of a polyester based on butanediol-1, 4 and
  • Terephthalic acid / isophthalic acid (1: 1) white-pigmented, thermoplastic 60 ⁇ m thick polyurethane film (Elastollan® EL 1184A from Elastogran GmbH) is covered with a release paper. Then the uncovered side of the film is overpainted with a commercially available two-pack clear lacquer based on polyacrylate polyisocyanate (dry film thickness 40-50 ⁇ m) and then baked at 130 ° C for 30 minutes. The laminate obtained in this way is freed from the release paper and laminated onto a body panel (Bonder 2660 OC) at a temperature of 220 ° C. and a pressure of 50 bar.
  • a body panel Body panel
  • the adhesion promoter layer of a white pigmented, thermoplastic 60 ⁇ m thick polyurethane film (Elastollan® EL 1184A from Elastogran GmbH) provided with a 20 ⁇ m thick adhesion promoter layer made of a polyester based on 1,4-butanediol and terephthalic acid / isophthalic acid (1: 1) is added covered with a release paper.
  • a transparent polyester film (Meiinex, IG), which has been provided with a 20 ⁇ m thick adhesive layer made of a polyester based on 1,4-butanediol and terephthalic acid / isophthalic acid (1: 1), at a temperature of 150 ° C and a pressure of 25 bar.
  • IG transparent polyester film
  • the laminate obtained in this way is laminated onto a body panel (Bonder 2660 OC) at a temperature of 220 ° C. and a pressure of 50 bar.
  • the coated substrates were provided with a 10 cm long scratch, the depth of which extends to the metal sheet, and subjected to a salt spray test in accordance with DIN 50 021. After 6 weeks, there was no rust under the Ritz.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

La présente invention concerne des films utilisés pour revêtir des ébauches de pièces façonnées, caractérisés par le fait que la surface d'un film porteur en plastique pigmenté, d'une épaisseur de 10-500 νm, éventuellement pourvue d'une couche à effet, est recouverte éventuellement une couche de laque transparente ou d'un film de plastique transparent.
EP96919735A 1995-05-10 1996-05-09 Films pour le revetement d'ebauches de pieces fa onnees et leur utilisation dans la construction automobile Withdrawn EP0825902A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19517069A DE19517069A1 (de) 1995-05-10 1995-05-10 Folien zur Beschichtung von Formteilrohlingen und deren Verwendung im Automobilbau
DE19517069 1995-05-10
PCT/EP1996/001958 WO1996035520A1 (fr) 1995-05-10 1996-05-09 Films pour le revetement d'ebauches de pieces façonnees et leur utilisation dans la construction automobile

Publications (1)

Publication Number Publication Date
EP0825902A1 true EP0825902A1 (fr) 1998-03-04

Family

ID=7761517

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96919735A Withdrawn EP0825902A1 (fr) 1995-05-10 1996-05-09 Films pour le revetement d'ebauches de pieces fa onnees et leur utilisation dans la construction automobile

Country Status (7)

Country Link
US (1) US6037053A (fr)
EP (1) EP0825902A1 (fr)
JP (1) JPH11504878A (fr)
KR (1) KR19990008448A (fr)
BR (1) BR9608258A (fr)
DE (1) DE19517069A1 (fr)
WO (1) WO1996035520A1 (fr)

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Publication number Priority date Publication date Assignee Title
JP3479757B2 (ja) * 1995-08-25 2003-12-15 豊田合成株式会社 熱可塑性樹脂成形品の加飾成形方法
DE19733312A1 (de) * 1997-08-01 1999-02-04 Herberts Gmbh Verfahren zur Aufbringung eines schützenden und dekorativen Schichtenverbundes
CA2279737C (fr) * 1998-08-06 2004-04-27 Naoya Haruta Pellicule decorative destinee au moulage des plastiques, son mode de preparation et piece moulee par injection employant cette pellicule
DE19908616A1 (de) * 1999-02-27 2000-08-31 Basf Ag Verbundschichtplatte oder -folie
DE10114468B4 (de) * 2001-03-24 2005-04-28 Thyssenkrupp Stahl Ag Verfahren zur Herstellung von beschichteten Formteilen und ihre Verwendung
DE10140205A1 (de) * 2001-08-16 2003-03-06 Basf Coatings Ag Farb- und/oder effektgebende Folien, Verfahren zu ihrer Herstellung und ihre Verwendung
AU2003226258A1 (en) * 2002-04-05 2003-10-27 Ppg Industries Ohio, Inc. Process for applying automotive quality effect coatings to metal substrates
DE10306358A1 (de) * 2003-02-15 2004-09-23 Basf Coatings Ag Farb- und/oder Effekt gebende, deckende Folien zur Beschichtung von dreidimensionalen Substraten, deren Herstellung und deren Verwendung
ES2304232B1 (es) * 2008-04-08 2011-01-03 Jose Parra Navarro Procedimiento de union de al menos dos cuerpos laminares, carroceria asi formada y producto final asi obtenido.
US20100035025A1 (en) * 2008-08-08 2010-02-11 Christian Kearney Color Matched Wood-Grained Component
CN103203922A (zh) * 2013-04-19 2013-07-17 无锡龙盈环保科技有限公司 一种环保汽车车体材料

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GB1466405A (en) * 1973-11-26 1977-03-09 Dainippon Printing Co Ltd Moulded articles of plastics having surface characteristics and process for producing the same
KR950000329B1 (ko) * 1987-03-27 1995-01-13 아베리 인터내쇼날 코오포레이숀 건식페인트 전이공정 및 제품
US4959189A (en) * 1988-09-26 1990-09-25 E. I. Du Pont De Nemours And Company Process for forming a composite structure of thermoplastic polymer and sheet molding compound
US5100732A (en) * 1988-12-22 1992-03-31 Basf Corporation Coil coating aluminum for use as automotive veneer
US4933237A (en) * 1989-02-17 1990-06-12 Eastman Kodak Company Paint coated sheet material with adhesion promoting composition
US5030514A (en) * 1989-04-27 1991-07-09 Ppg Industries, Inc. Paint composites
US5268215A (en) * 1989-08-31 1993-12-07 Eastman Kodak Company Basecoat-clearcoat film
DE4424290C2 (de) * 1994-07-09 1996-05-15 Leuna Werke Gmbh Verfahren zur Herstellung bitumenverträglicher Polyolefincompounds und deren Verwendung

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Title
See references of WO9635520A1 *

Also Published As

Publication number Publication date
KR19990008448A (ko) 1999-01-25
WO1996035520A1 (fr) 1996-11-14
US6037053A (en) 2000-03-14
DE19517069A1 (de) 1996-11-14
BR9608258A (pt) 1999-02-02
JPH11504878A (ja) 1999-05-11

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