EP0837121A1 - Fester Brennstoff zur Zerstörung des Russ und der Teeren, Verfahren zu dessen Herstellung, und dessen Verwendung - Google Patents

Fester Brennstoff zur Zerstörung des Russ und der Teeren, Verfahren zu dessen Herstellung, und dessen Verwendung Download PDF

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Publication number
EP0837121A1
EP0837121A1 EP97402235A EP97402235A EP0837121A1 EP 0837121 A1 EP0837121 A1 EP 0837121A1 EP 97402235 A EP97402235 A EP 97402235A EP 97402235 A EP97402235 A EP 97402235A EP 0837121 A1 EP0837121 A1 EP 0837121A1
Authority
EP
European Patent Office
Prior art keywords
agent
soot
solid
ammonium
combustible
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97402235A
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English (en)
French (fr)
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EP0837121B1 (de
Inventor
Olivier Boinet
Thierry Farjon
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EUREXIM SECURIFLAME
Original Assignee
Eurexim
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Publication date
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Application filed by Eurexim filed Critical Eurexim
Publication of EP0837121A1 publication Critical patent/EP0837121A1/de
Application granted granted Critical
Publication of EP0837121B1 publication Critical patent/EP0837121B1/de
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/06Use of additives to fuels or fires for particular purposes for facilitating soot removal

Definitions

  • the present invention relates to chemical sweeping and / or catalytic of combustion devices and conduits smoke. It relates more particularly to a combustible agent solid chemical and / or catalytic destruction of the soot, its manufacturing process and its use.
  • “soot” in the present description means the deposits of all kinds that form in the devices of heating and more particularly in the flues. These deposits can be of various nature, in particular particles carbonaceous matter, entrained ashes and above all tars. These are mainly deposited in the lower part of the flues. Training and filing of these materials are particularly emphasized in the case from burning solid fuels such as coal and wood, especially with closed hearths or "inserts".
  • Chimney sweeping products are currently on the market called “chemical” or “catalytic”. Some of these products contain sulfur to decompose tar to facilitate their combustion with all the risks that this involves, in particular the risk of a chimney fire, because it is necessary heat the duct to the maximum to make the product effective, and the risk of deterioration of the conduits by caustic soda or its decomposition products.
  • Document FR-A-2 554 458 describes a combustible agent solid acting preventively or curatively on deposits and soot in the calorie generators.
  • This agent can understand, among others, a combustible cellulosic material particulate, an active preventive or curative agent for soot and tar deposits and optionally a binder.
  • the agglomerates obtained, for example in the form of briquettes, sticks or granules are introduced into an active hearth, about one kilogram per tonne of fuel, the agglomerate containing a few grams or tens of grams of anti-soot agent per kilogram of agglomerate.
  • paraffin wax as a binder for materials in the manufacture of fire starters and artificial logs is known from documents US-A-4 147 518 and US-A-3,297,419 respectively.
  • This last document provides incorporate organometallic additives into artificial logs, in proportion less than 0.1% and whose effect is improve the terminal combustion of logs, or nitrates at a rate of 5% by weight to simulate the crunches produced by an actual wooden log. There is no suggestion an effect on chimney sweeping.
  • the invention is based on the new concept of realizing a combustible solid mass incorporating a destructive agent soot and especially tar.
  • the combustion of this mass allows the soot-destroying agent to volatilize as it burns and come to contact with soot and tar.
  • the above components are found in substantially homogeneous mixture, although one can envisage, for example, the use of successive layers of elements (a) and (b) linked by element (c), or a surface coating final mixing by the only component (c) or (a) or the mixture (c + a), for example to accelerate inflammation.
  • Particulate solid cellulosic combustible material preferably consists of wood particles, for example in the form of sawdust, flour, chips, fibers or the like.
  • other combustible materials can be used cellulosic, for example grinding or chopping products cereal straw, crushed and dried residue from certain household waste (plant residues) or residues pulp mills.
  • the particle size is advantageously between 0.1 and 10 mm for sawdust and wood flour.
  • Other materials are longer (chips or fibers) but their thickness is then preferably understood between 0.1 and 2 mm.
  • the binder is any material capable of maintaining the cohesion of the mixture of elements (a) and (b).
  • the preference is given to a solid paraffin wax at room temperature.
  • paraffin is a combustible material by wicking and which, in the molten state, can permeate the elements (a) and (b) and, after cooling, maintains good cohesion between these elements in the solid obtained.
  • a natural, artificial or synthetic glue and for example a vinyl adhesive, a thermoplastic resin, a starchy material, stearic acid.
  • the relative proportions of the elements can vary widely depending in particular on the nature of each of the elements of the composition, their porosity, their combustibility and, for the soot-destroying agent, of its effectiveness.
  • the relative weight proportions will be 20 to 80% of (a), 10 to 40% of (b) and 10 to 70% of (c) per 100 parts of the mixture (a + b + c).
  • Subjects additional may be present, either as thinners, for example silica and silicates, either as combustion additives, either as aesthetic modifiers, for example a dye or a pigment, or to any other end.
  • Their weight proportion will not exceed half of the proportion of (a + b + c) and will preferably remain less than 10% and, better, less than 5% of this proportion.
  • the combustible agent for destroying soot according to the invention can be presented in any desired form, either regular, for example cubes, cylinders, any polygons, spheres, either in random form.
  • a log form or log both more aesthetic and more practical.
  • the dimensions of the log or log may be any and preferably will be approximately those of the logs of wood usually used in the hearth, corresponding to the more often at a length of 10 to 40 cm.
  • the method of manufacturing the aggregates of the invention may be of the same type as that conventionally used in the manufacture of a log in sawdust and paraffin or in making a simply compressed log, unlike close that the combustible material (a) is added anti-soot agent (b) before sizing or coating with the agent (c) or during it.
  • the mixture obtained (a + b + c) can be press molded or extruded, or cast in mussels. If the binder is used as a solution or dispersion in a solvent, this is removed by evaporation or drying.
  • the elements of the aggregate are distributed substantially homogeneously, although we can also arrange the agent (b) in the center or in successive layers.
  • the aggregate, for example the log, obtained can then, if desired, be wrapped in an envelope preferably fuel that will facilitate inflammation, for example paper, cardboard or waxed or treated paper or cardboard to facilitate its ignition.
  • an envelope preferably fuel that will facilitate inflammation, for example paper, cardboard or waxed or treated paper or cardboard to facilitate its ignition.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Catalysts (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Glass Compositions (AREA)
  • Shovels (AREA)
  • Carbon And Carbon Compounds (AREA)
EP97402235A 1996-10-10 1997-09-25 Fester Brennstoff zur Zerstörung des Russ und der Teeren, Verfahren zu dessen Herstellung, und dessen Verwendung Revoked EP0837121B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9612365 1996-10-10
FR9612365A FR2749855B1 (fr) 1996-10-10 1996-10-10 Agent combustible solide de destruction de la suie et des goudrons, son procede de fabrication et son utilisation

Publications (2)

Publication Number Publication Date
EP0837121A1 true EP0837121A1 (de) 1998-04-22
EP0837121B1 EP0837121B1 (de) 1999-08-04

Family

ID=9496537

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97402235A Revoked EP0837121B1 (de) 1996-10-10 1997-09-25 Fester Brennstoff zur Zerstörung des Russ und der Teeren, Verfahren zu dessen Herstellung, und dessen Verwendung

Country Status (9)

Country Link
US (1) US5882365A (de)
EP (1) EP0837121B1 (de)
AT (1) ATE182921T1 (de)
CA (1) CA2216012C (de)
DE (1) DE69700378T2 (de)
DK (1) DK0837121T3 (de)
ES (1) ES2134671T3 (de)
FR (1) FR2749855B1 (de)
GR (1) GR3030942T3 (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2800745A1 (fr) * 1999-11-10 2001-05-11 Philippe Madamour Agent solide de destruction de la suie et notamment des goudrons, et son procede de fabrication et ses utilisations
WO2002046337A1 (fr) * 2000-12-07 2002-06-13 Philippe Madamour Agent solide de destruction de la suie et notamment des goudrons, et son procede de fabrication et ses utilisations
FR2823759A1 (fr) * 2001-04-19 2002-10-25 Crea Produit de ramonage chimique
EP2434003A1 (de) * 2010-09-23 2012-03-28 Chembo S.A. Feste Zusammensetzung eines chemischen Schornsteinreinigungsmittels

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1013007C2 (nl) * 1999-09-09 2001-03-12 Dsm Nv Werkwijze voor het vervaardigen van brandstofkorrels.
BE1013395A5 (nl) * 2000-04-17 2001-12-04 Behoko Nv Vast brandbaar element voor het afbreken van een verbrandings-afzetlaag en werkwijze voor de productie van een dergelijk element.
US7540890B2 (en) * 2003-02-28 2009-06-02 Clark Schaefer Creosote and soot destroying fire log
US7857873B2 (en) * 2004-04-09 2010-12-28 Peter Leonard Hutchison Flue cleaner
US20090071068A1 (en) * 2007-09-14 2009-03-19 John Cook Method for reducing flammable creosote and other organic deposits in fireboxes
US20090107036A1 (en) * 2007-10-29 2009-04-30 Harmondsworth Holdings Limited Combustible log
US20130283676A1 (en) * 2012-04-30 2013-10-31 Aditivos Y Proyectos Energéticos E Industriales, S.A. De C.V. Additive for liquid hydrocarbon fuel fueled in fired burners or open flames
CN105062603B (zh) * 2015-08-31 2017-10-20 郑宇松 一种防水煤粉及其制备方法
EP3306193A1 (de) * 2016-10-10 2018-04-11 Renommé V/allan Hansen Kombinierter feueranzünder und schornsteinreiniger
GR20190100532A (el) * 2019-11-26 2021-06-14 Φυσικο Προσαναμμα Μονοπροσωπη Ικε Kaπνοδοχοκαθαριστης- κουτσουρο καθαρισμου

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2777761A (en) * 1954-06-03 1957-01-15 Chemical & Engineering Company Composition for eliminating slag, soot, and fly ash
GB1001772A (en) * 1962-05-24 1965-08-18 Bejs Vaesteras Ab Improvements in and relating to the removal of soot
US3297419A (en) * 1965-08-17 1967-01-10 Fyr Tech Products Inc Synthetic fuel log and method of manufacture
US3637355A (en) * 1969-06-20 1972-01-25 William Hughes Brockbank Artificial fireplace logs which burn with colored flame
US4147518A (en) * 1977-03-02 1979-04-03 Pine Rest Christian Rehabilitation Services Extrusion apparatus for making fire kindling device
WO1982004065A1 (en) * 1981-05-20 1982-11-25 Johannesson Joe Inge Olgarth Process and device for loosening and removing solid coatings on the surfaces of enclosed spaces,e.g.the flue gas side of a furnace or boiler
US4428310A (en) * 1982-07-26 1984-01-31 Nalco Chemical Company Phosphated alumina as slag modifier
US4481010A (en) * 1983-09-22 1984-11-06 Hercules Chemical Company, Inc. Non-corrosive creosote and soot removing composition
GB2145731A (en) * 1983-09-01 1985-04-03 Spencer Stoves Limited Philip Improvements in or relating to fuel combustion
DE3429584A1 (de) * 1983-09-26 1985-04-11 Kiskun MGTSZ, Kiskunlacháza Verbrennungsverbessernde zusatzstoffkomposition zur reinigung von heizvorrichtungen, kaminen, rauchzuegen und waermeregeneratoren
FR2554458A1 (fr) * 1983-11-03 1985-05-10 Thibonnet Bernard Complexe combustible de nettoyage
US5034114A (en) * 1989-07-28 1991-07-23 Ira Kukin Acid neutralizing combustion additive with detergent builder
US5284636A (en) * 1992-03-25 1994-02-08 Air Products And Chemicals, Inc. Method of stabilizing heavy metals in ash residues from combustion devices by addition of elemental phosphorus

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3951613A (en) * 1971-02-03 1976-04-20 Stewart Hall Chemical Co. Anti-pollution heating oil products and processes

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2777761A (en) * 1954-06-03 1957-01-15 Chemical & Engineering Company Composition for eliminating slag, soot, and fly ash
GB1001772A (en) * 1962-05-24 1965-08-18 Bejs Vaesteras Ab Improvements in and relating to the removal of soot
US3297419A (en) * 1965-08-17 1967-01-10 Fyr Tech Products Inc Synthetic fuel log and method of manufacture
US3637355A (en) * 1969-06-20 1972-01-25 William Hughes Brockbank Artificial fireplace logs which burn with colored flame
US4147518A (en) * 1977-03-02 1979-04-03 Pine Rest Christian Rehabilitation Services Extrusion apparatus for making fire kindling device
WO1982004065A1 (en) * 1981-05-20 1982-11-25 Johannesson Joe Inge Olgarth Process and device for loosening and removing solid coatings on the surfaces of enclosed spaces,e.g.the flue gas side of a furnace or boiler
US4428310A (en) * 1982-07-26 1984-01-31 Nalco Chemical Company Phosphated alumina as slag modifier
GB2145731A (en) * 1983-09-01 1985-04-03 Spencer Stoves Limited Philip Improvements in or relating to fuel combustion
US4481010A (en) * 1983-09-22 1984-11-06 Hercules Chemical Company, Inc. Non-corrosive creosote and soot removing composition
DE3429584A1 (de) * 1983-09-26 1985-04-11 Kiskun MGTSZ, Kiskunlacháza Verbrennungsverbessernde zusatzstoffkomposition zur reinigung von heizvorrichtungen, kaminen, rauchzuegen und waermeregeneratoren
FR2554458A1 (fr) * 1983-11-03 1985-05-10 Thibonnet Bernard Complexe combustible de nettoyage
US5034114A (en) * 1989-07-28 1991-07-23 Ira Kukin Acid neutralizing combustion additive with detergent builder
US5284636A (en) * 1992-03-25 1994-02-08 Air Products And Chemicals, Inc. Method of stabilizing heavy metals in ash residues from combustion devices by addition of elemental phosphorus

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2800745A1 (fr) * 1999-11-10 2001-05-11 Philippe Madamour Agent solide de destruction de la suie et notamment des goudrons, et son procede de fabrication et ses utilisations
WO2002046337A1 (fr) * 2000-12-07 2002-06-13 Philippe Madamour Agent solide de destruction de la suie et notamment des goudrons, et son procede de fabrication et ses utilisations
FR2823759A1 (fr) * 2001-04-19 2002-10-25 Crea Produit de ramonage chimique
EP1254946A1 (de) * 2001-04-19 2002-11-06 Crea Chemischer Russentferner
EP2434003A1 (de) * 2010-09-23 2012-03-28 Chembo S.A. Feste Zusammensetzung eines chemischen Schornsteinreinigungsmittels
BE1019873A3 (fr) * 2010-09-23 2013-02-05 Chembo S A Composition solide de ramonage chimique.

Also Published As

Publication number Publication date
ES2134671T3 (es) 1999-10-01
DK0837121T3 (da) 1999-12-06
US5882365A (en) 1999-03-16
GR3030942T3 (en) 1999-11-30
FR2749855B1 (fr) 1998-10-30
DE69700378D1 (de) 1999-09-09
ATE182921T1 (de) 1999-08-15
EP0837121B1 (de) 1999-08-04
FR2749855A1 (fr) 1997-12-19
CA2216012C (fr) 2000-07-18
CA2216012A1 (fr) 1998-04-10
DE69700378T2 (de) 2000-05-11

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