EP0854403A2 - Durchsichtiges und verschleissfestes Uhrenglas und ein mit diesem Glas versehenes Uhrengehäuse - Google Patents
Durchsichtiges und verschleissfestes Uhrenglas und ein mit diesem Glas versehenes Uhrengehäuse Download PDFInfo
- Publication number
- EP0854403A2 EP0854403A2 EP97100591A EP97100591A EP0854403A2 EP 0854403 A2 EP0854403 A2 EP 0854403A2 EP 97100591 A EP97100591 A EP 97100591A EP 97100591 A EP97100591 A EP 97100591A EP 0854403 A2 EP0854403 A2 EP 0854403A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- watch
- glass
- glasses
- same
- wear resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000013078 crystal Substances 0.000 title 1
- 239000011521 glass Substances 0.000 claims abstract description 62
- 239000010432 diamond Substances 0.000 claims abstract description 17
- 229910003460 diamond Inorganic materials 0.000 claims abstract description 16
- 230000003678 scratch resistant effect Effects 0.000 claims description 9
- 239000000758 substrate Substances 0.000 abstract description 7
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005234 chemical deposition Methods 0.000 abstract description 3
- 238000005498 polishing Methods 0.000 abstract description 3
- 229910010271 silicon carbide Inorganic materials 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000010439 graphite Substances 0.000 abstract description 2
- 229910002804 graphite Inorganic materials 0.000 abstract description 2
- 229910052594 sapphire Inorganic materials 0.000 description 10
- 239000010980 sapphire Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 5
- 241000220324 Pyrus Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 241001639412 Verres Species 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 235000021017 pears Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 210000000078 claw Anatomy 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005306 natural glass Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B39/00—Watch crystals; Fastening or sealing of crystals; Clock glasses
- G04B39/004—Watch crystals; Fastening or sealing of crystals; Clock glasses from a material other than glass
- G04B39/006—Watch crystals; Fastening or sealing of crystals; Clock glasses from a material other than glass out of wear resistant material, e.g. sapphire
Definitions
- the present invention relates to a watch glass transparent and scratch-resistant, and in particular a glass of watch with a low cost price regardless of the complexity of its shape, for example planar or spherical, while having a very high hardness, of the order of 10,000 HV.
- the present invention also relates to a box of watch fitted with such a glass.
- Watch glasses for the protection of dials and needles or the like are made most often either synthetic or mineral glass because of their relatively low cost price.
- the respective hardness of these material categories determines of course the scratch resistance of the glasses.
- a watch glass made of materials synthetic materials such as Plexiglas have a hardness Vickers of around 100 and mineral or natural glass has a Vickers hardness of around 900.
- Now experience showed that the glasses produced in these two categories of materials are poorly resistant to scratches by certain agents very hard such as the silica contained in dust, marble or sand constantly present in our environment, even if the mineral glass resists better against these attacks than synthetic materials. he therefore a relatively rapid alteration of the aesthetic appearance by scratches of these types of glasses or funds of watches.
- the object of the present invention is therefore precisely a scratch-resistant and transparent watch glass, characterized in that it is made of polycrystalline diamond.
- the hardness of the glasses watch according to the invention is of the order of 10'000 HV this which makes them almost scratchproof.
- Diamond glasses polycrystalline of the invention also exhibit the advantage of having excellent resistance to chemical attack.
- the present invention also relates to a watch case comprising a middle and a back, characterized in that it further comprises a glass which is made of polycrystalline diamond.
- the watch shown in Figures 1 and 2 includes a box 10, a movement 12 and display means 14, comprising in this case hands and a dial.
- the box 10 includes a middle part 16, a first and a second closing element of the box, respectively a glass 18 and a bottom 20, as well as a casing circle 22.
- the middle part 16 is provided with four horns 24 which are extend above the body of the middle and form claws 26 defining with the body of the middle one slide inside which the glass 18 is housed.
- the base 20 is fixed to the middle part 16 by means of screws not shown in the drawing. He also leans against the casing ring 22. The latter extends over the entire height of the middle part 16 and it bears against the glass 18.
- the casing ring 22 exerts pressure on the glass 18 which rests on the claws 26.
- the glass 18 is an element practically scratch-resistant made of polycrystalline diamond.
- Glass 18 can be obtained in the following manner. We first prepare a graphite substrate comprising an upper surface with the negative shape of the glass that we want to obtain. This negative form is flat in the case of glass 18 but can of course be not planar, for example cylindrical curved, spherical curved or a combination of these forms.
- the face top of the substrate is polished and then coated with a thin layer of silicon carbide (SiC).
- SiC silicon carbide
- a layer of polycrystalline diamond is then deposited on the layer of SiC by chemical vapor deposition. During this deposition operation a layer of polycrystalline diamond grows on the surface of the SiC to the desired thickness.
- the layer of polycrystalline diamond intended to form glass 18 is then polished and, if necessary, dimensioned final to form a watch glass such as glass 18. This dimensioning step is for example performed by laser machining.
- the polycrystalline diamond layer is finally detached from the substrate, for example by elimination chemical of the substrate.
- the glass thus produced is of course completely transparent in the visible spectrum after polishing and thus protects the display means while allowing their reading.
- the thickness of the watch glass according to the invention is depending on the size of the desired glass and the effect obtain, it will generally be between 0.5 and 2 mm.
- the watch case has a upper shell 28 in the form of a spherical cap, of which at least one part is transparent and forms a first watch glass according to the invention.
- the box also has a lower shell 30, also in the shape of a spherical cap, and a middle part 32 arranged in the vicinity of the periphery of the shells 28 and 30, the lower shell 30 forming a second watch glass according to the invention. Glasses 28 and 30 therefore have non-planar shapes.
- the shells 28 and 30 define an interior space in which takes place a movement (not shown) and the middle part 32 is arranged to conform respectively to the shape of the faces lower and upper respectively upper 28 and lower 30 shells to serve them bearing surface. So when the box is assembled, the edges 34 and 36 of the upper and lower shells are joined around their entire periphery except for places 38 and 40 provided for the attachment of the strands of bracelet 42 and 44, and the middle no longer appears.
- the upper shell 28, i.e. the glass, and the lower shell 30, or the bottom, forming the glasses scratch-resistant transparencies are made like glass described in conjunction with Figures 1 and 2. Like the edges shells are joined, the box thus produced is completely scratch-resistant.
- the spherical cap of the glasses according to the invention normally very expensive when made in artificial sapphire - the case thus obtained has shock absorption characteristics it can undergo high because shocks are transmitted to the seat of shells located on the middle part on which they are fixed, thus benefiting from the arch effect.
- the two shells may have on the periphery of their inner face a masking layer such as metallization for hide some elements of the box like the middle.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Surface Treatment Of Glass (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Joining Of Glass To Other Materials (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT97100591T ATE298900T1 (de) | 1997-01-16 | 1997-01-16 | Durchsichtiges und kratzfestes uhrenglas und ein mit diesem glas versehenes uhrengehäuse |
| DE69733633T DE69733633T2 (de) | 1997-01-16 | 1997-01-16 | Durchsichtiges und kratzfestes Uhrenglas und ein mit diesem Glas versehenes Uhrengehäuse |
| EP97100591A EP0854403B1 (de) | 1997-01-16 | 1997-01-16 | Durchsichtiges und kratzfestes Uhrenglas und ein mit diesem Glas versehenes Uhrengehäuse |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97100591A EP0854403B1 (de) | 1997-01-16 | 1997-01-16 | Durchsichtiges und kratzfestes Uhrenglas und ein mit diesem Glas versehenes Uhrengehäuse |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0854403A2 true EP0854403A2 (de) | 1998-07-22 |
| EP0854403A3 EP0854403A3 (de) | 1999-12-01 |
| EP0854403B1 EP0854403B1 (de) | 2005-06-29 |
Family
ID=8226373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP97100591A Expired - Lifetime EP0854403B1 (de) | 1997-01-16 | 1997-01-16 | Durchsichtiges und kratzfestes Uhrenglas und ein mit diesem Glas versehenes Uhrengehäuse |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0854403B1 (de) |
| AT (1) | ATE298900T1 (de) |
| DE (1) | DE69733633T2 (de) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047989A3 (en) * | 2003-11-12 | 2005-06-23 | Cosetta Schiavolini | Horology crystal with three-dimensional decoration |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1238069A (fr) | 1959-10-15 | 1960-11-30 | Dalloz Freres Ets | Perfectionnement aux verres de montres |
| CH632891GA3 (en) | 1979-09-12 | 1982-11-15 | Process for producing a watch-glass | |
| EP0693573A1 (de) | 1994-07-18 | 1996-01-24 | Saint-Gobain/Norton Industrial Ceramics Corporation | Erzeugung eines Diamantfilmes |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH966570A4 (de) * | 1970-06-25 | 1974-04-11 | ||
| JPS4965864A (de) * | 1972-10-24 | 1974-06-26 | ||
| JPS5761644A (en) * | 1980-10-02 | 1982-04-14 | Seiko Epson Corp | Cover glass having diamond coating layer and its preparation |
| CH659168GA3 (de) * | 1985-04-16 | 1987-01-15 |
-
1997
- 1997-01-16 AT AT97100591T patent/ATE298900T1/de active
- 1997-01-16 DE DE69733633T patent/DE69733633T2/de not_active Expired - Lifetime
- 1997-01-16 EP EP97100591A patent/EP0854403B1/de not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1238069A (fr) | 1959-10-15 | 1960-11-30 | Dalloz Freres Ets | Perfectionnement aux verres de montres |
| CH632891GA3 (en) | 1979-09-12 | 1982-11-15 | Process for producing a watch-glass | |
| EP0693573A1 (de) | 1994-07-18 | 1996-01-24 | Saint-Gobain/Norton Industrial Ceramics Corporation | Erzeugung eines Diamantfilmes |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047989A3 (en) * | 2003-11-12 | 2005-06-23 | Cosetta Schiavolini | Horology crystal with three-dimensional decoration |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0854403B1 (de) | 2005-06-29 |
| DE69733633D1 (de) | 2005-08-04 |
| DE69733633T2 (de) | 2006-05-18 |
| EP0854403A3 (de) | 1999-12-01 |
| ATE298900T1 (de) | 2005-07-15 |
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