EP0946697B1 - Mischungen von alkoxylaten mit schaumdämpfender und desinfizierender wirkung und deren verwendung in reinigungsmitteln - Google Patents

Mischungen von alkoxylaten mit schaumdämpfender und desinfizierender wirkung und deren verwendung in reinigungsmitteln Download PDF

Info

Publication number: EP0946697B1
Authority: EP; European Patent Office
Prior art keywords: weight; formula; radical; carbon atoms; fatty alcohol
Prior art date: 1996-12-18
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

EP97954395A

Other languages

German (de)

English (en)

French (fr)

Other versions

EP0946697A2 (de

Inventor

Norbert Schmitt

Manuela Hingerl

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Clariant Produkte Deutschland GmbH

Original Assignee

Clariant GmbH

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-12-18

Filing date

1997-12-12

Publication date

2002-10-30

1997-12-12 Application filed by Clariant GmbH filed Critical Clariant GmbH

1999-10-06 Publication of EP0946697A2 publication Critical patent/EP0946697A2/de

2002-10-30 Application granted granted Critical

2002-10-30 Publication of EP0946697B1 publication Critical patent/EP0946697B1/de

2017-12-12 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 36
238000004140 cleaning Methods 0.000 title claims abstract description 32
239000000645 desinfectant Substances 0.000 title description 10
230000000694 effects Effects 0.000 title description 8
230000003254 anti-foaming effect Effects 0.000 title 1
150000002191 fatty alcohols Chemical class 0.000 claims abstract description 24
125000000217 alkyl group Chemical group 0.000 claims abstract description 16
229920000768 polyamine Polymers 0.000 claims abstract description 8
230000000249 desinfective effect Effects 0.000 claims abstract 2
125000004432 carbon atom Chemical group C* 0.000 claims description 24
239000011521 glass Substances 0.000 claims description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
229920000728 polyester Polymers 0.000 claims 1
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
239000006260 foam Substances 0.000 description 13
239000000243 solution Substances 0.000 description 10
-1 n-octyl Chemical group 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
239000000654 additive Substances 0.000 description 6
244000005700 microbiome Species 0.000 description 6
229920000139 polyethylene terephthalate Polymers 0.000 description 6
239000005020 polyethylene terephthalate Substances 0.000 description 6
239000000725 suspension Substances 0.000 description 6
238000009472 formulation Methods 0.000 description 5
239000004094 surface-active agent Substances 0.000 description 5
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
239000001963 growth medium Substances 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000012459 cleaning agent Substances 0.000 description 3
239000008367 deionised water Substances 0.000 description 3
229910021641 deionized water Inorganic materials 0.000 description 3
238000009736 wetting Methods 0.000 description 3
IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
241001558165 Alternaria sp. Species 0.000 description 2
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
241001363490 Monilia Species 0.000 description 2
241000228168 Penicillium sp. Species 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
150000001447 alkali salts Chemical class 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
239000002585 base Substances 0.000 description 2
239000007374 caso agar Substances 0.000 description 2
230000000536 complexating effect Effects 0.000 description 2
230000007797 corrosion Effects 0.000 description 2
238000005260 corrosion Methods 0.000 description 2
239000003292 glue Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
230000002147 killing effect Effects 0.000 description 2
239000000787 lecithin Substances 0.000 description 2
235000010445 lecithin Nutrition 0.000 description 2
229940067606 lecithin Drugs 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
229920000151 polyglycol Polymers 0.000 description 2
239000010695 polyglycol Substances 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
102000014171 Milk Proteins Human genes 0.000 description 1
108010011756 Milk Proteins Proteins 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
240000004808 Saccharomyces cerevisiae Species 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
150000001241 acetals Chemical class 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000003973 alkyl amines Chemical class 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
238000010009 beating Methods 0.000 description 1
235000013405 beer Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000001735 carboxylic acids Chemical class 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000008139 complexing agent Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
230000006735 deficit Effects 0.000 description 1
238000004851 dishwashing Methods 0.000 description 1
JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
239000000975 dye Substances 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
229920005676 ethylene-propylene block copolymer Polymers 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
239000003205 fragrance Substances 0.000 description 1
239000013505 freshwater Substances 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
238000011086 high cleaning Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
239000000976 ink Substances 0.000 description 1
GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
235000015122 lemonade Nutrition 0.000 description 1
230000007257 malfunction Effects 0.000 description 1
239000000463 material Substances 0.000 description 1
239000002609 medium Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
NYNKJVPRTLBJNQ-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-dodecylpropane-1,3-diamine Chemical compound CCCCCCCCCCCCN(CCCN)CCCN NYNKJVPRTLBJNQ-UHFFFAOYSA-N 0.000 description 1
125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
235000019520 non-alcoholic beverage Nutrition 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
235000015097 nutrients Nutrition 0.000 description 1
125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
230000002572 peristaltic effect Effects 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
PTMHPRAIXMAOOB-UHFFFAOYSA-N phosphoramidic acid Chemical class NP(O)(O)=O PTMHPRAIXMAOOB-UHFFFAOYSA-N 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
102000004169 proteins and genes Human genes 0.000 description 1
108090000623 proteins and genes Proteins 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
230000001603 reducing effect Effects 0.000 description 1
239000000523 sample Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
235000011182 sodium carbonates Nutrition 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
239000007921 spray Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000004659 sterilization and disinfection Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
230000001629 suppression Effects 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
238000010998 test method Methods 0.000 description 1
239000012085 test solution Substances 0.000 description 1
239000001226 triphosphate Substances 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
- C11D1/8355—Mixtures of non-ionic with cationic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

the invention relates to mixtures of alkoxylates with foam-suppressing and disinfectant effect and their use in aqueous cleaning liquors for hard surfaces.
Cleaning hard surfaces such as plastic or glass bottles, Porcelain, ceramic, glass or plastic dishes and other items from such materials or from metal
Commercial and industrial Cleaning equipment is generally with an aqueous solution of Alkali metal hydroxides, preferably sodium hydroxide solution (alkaline cleaning liquor) or with aqueous acid solutions (acid cleaning liquor).
This Cleaning systems work with high throughput and with high Fleet movements and spray intensities to ensure quick detachment and To ensure emulsification of the adhering impurities. Because of the high mechanical liquor movements, the system must be as low-foam as possible or be foam-free, since excessive foaming leads to malfunctions in the system can lead.
Bottle cleaning also applies to the labels to be removed the glue residues and residues of printing inks including those in the latter containing surfactant aids are introduced into the cleaning liquor.
nonionic surfactants as foam suppressants Agent in alkaline or acidic aqueous base solutions for the cleaning of hard surfaces.
nonionic surfactants are, in particular, investment products from Ethylene oxide and / or propylene oxide over amines, fatty alcohols or alkylphenols, Polyglycol ether formals or acetals or block copolymers of ethylene and Propylene oxide.
DE-A-25 23 588 (GB-A-1 488 108) describes polyglycol ether mixed formals in EP-B-322 781 end-capped fatty alcohol alkoxylates and in EP-A-694 606 Mixtures of a fatty alcohol ethoxylate propoxylate and a fatty amine or Fatty amine ethoxylate is described as a foam-suppressing additive to cleaning agents.
WO-A-96/10069 in which disinfectant cleaning agents for hard surfaces are described. In detail, it is about the use a mixture of an alkyl and / or alkenyl oligoglycoside and one Fatty alcohol alkoxylate to enhance the germ reducing effect of Cleaning agents containing disinfectants for hard surfaces.
Disinfectant the effect of which is increased by adding the mixture mentioned should be, among other things, fatty alkyl polyamines such as N, N-bis (3-aminopropyl) dodecylamine called.
DE-A-3048642 describes surfactant mixtures for cleaning hard surfaces, in particular Bottles containing alkoxylates and quaternary ammonium salts.
the alkyl and alkenyl radicals can be straight or branched, with preference being given to this.
the alkenyl radicals preferably have 1 to 3 double bonds.
the numbers given for x, y, z, a and b are statistical averages (average values), which means that these indices can each be an integer or fractional number.
the propylene oxide units can be of the type -CH 2 -CH (CH 3 ) O- or -CH (CH 3 ) -CH 2 O-, the former being preferred.
alkyl and alkenyl radicals are n-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, iso-nonyl, n-decyl, iso-decyl, n-dodecyl, stearyl, n-eikosyl, oleyl, cocoalkyl and Tallow alkyl as well as alkyl or alkenyl mixtures, for example a mixture of C 12 alkyl to C 14 alkyl (C 12/14 ).
Components A1, A2 and A3 in the preferred mixture described can each be used alone or together, the mixing ratio being able to vary within wide limits.
R 5 is an alkyl radical or alkenyl radical having 6 to 22 C atoms, preferably 8 to 18 C atoms
R 6 is the radical mentioned - (CH 2 ) m -NH 2 , where m is n, that is, m and n are each an integer from 2 to 6, preferably 3.
the particularly preferred amines of the formula IV are therefore fatty alkyl dipropylenetriamines. All components to be used according to the invention are known from the publications mentioned at the outset and are commercially available.
the agents according to the invention are simply manufactured by Mixing the components together and, if appropriate, more appropriately Additives and additives at a temperature of 15 to 50 ° C, preferably 20 to 30 ° C, and advantageously with stirring.
the mixtures according to the invention can be used in undiluted form, ie as such or, for example, for better meterability in the form of aqueous Concentrates are used, optionally with the addition of an organic Solvent.
the components described can also be added separately to the aqueous cleaning liquor.
the Application concentration in the aqueous liquors expediently at 0.05 to 10 g of the mixture according to the invention per liter Cleaning liquor, preferably at 0.1 to 2 g per liter.
the above Application concentrations are non-critical information since the amount in to a certain extent depending on the type of surfaces to be cleaned and on type and Scope of impurities.
the surfactant mixtures according to the invention can be further Additives and auxiliaries for the preparation of commercial formulations added become. These are, for example, dyes, fragrances, corrosion inhibitors and Disinfectant. Also worth mentioning here are the known builders, the optionally are complexing agents at the same time. These include the condensed ones Phosphates such as tripolyphosphate and pentasodium triphosphate that are complexing acting aminopolycarboxylic acids and their salts, for example the Alkali salts of nitrilotriacetic acid and ethylenediaminetetraacetic acid, and the complex-forming hydroxycarboxylic acids and polymeric carboxylic acids such as Citric acid, tartaric acid and the like.
Phosphates such as tripolyphosphate and pentasodium triphosphate
aminopolycarboxylic acids and their salts for example the Alkali salts of nitrilotriacetic acid and ethylenediaminetetraacetic acid
Another class of complexing builders are polyphosphonic acid salts, such as the alkali salts of aminophosphonic acid.
builders can also such as silicates, for example sodium metasilicate, carbonates, bicarbonates, borates and Citrate can be added.
the surfactant mixtures according to the invention optionally converted into powder form and are used in this form.
the mixtures according to the invention are distinguished by a high level of disinfectant and foam suppressing effect. They are extremely low Foam tendency and tendency to foam at low and at high Temperatures (for example in the range of 15 to 80 ° C) and also at strong ones Fleet movement and the presence of foam-promoting contaminants, such as Protein, milk, beer, lemonade, glue or other adhesives and the like.
foam-promoting contaminants such as Protein, milk, beer, lemonade, glue or other adhesives and the like.
the equally unexpectedly high germicidal property extends to all common Microorganisms.
the mixtures according to the invention also have a high Cleaning effect and a high dirt absorption capacity on what long Operating times allowed without affecting the cleaning effect. Your good Wetting capacity and drainage behavior enable dirt to be removed quickly and thus a high throughput of items to be cleaned.
the cleaned good is free of Stains and streaks and shows high gloss (that means no attack on that Appearance) and no damage (that means no impairment to the Example of mechanical stability).
the mixtures according to the invention are also resistant to alkali and acids and together with them for long periods storage stable.
the surfactant mixtures according to the invention are generally suitable for cleaning liquors. They are particularly suitable for alkaline fleets for the mechanical cleaning of hard surfaces, for example for fleets in household dishwashers and in commercial cleaning systems. They are particularly suitable in the case of industrial cleaning systems for hard surfaces such as dishwashing and bottle washing systems, which work with aqueous alkaline liquors with high mechanical liquor movements in continuous operation, where the pH values can be > 10 or > 12 (highly alkaline liquors). Another example is the cleaning of bottles made of glass or polyethylene terephthalate (PET) in breweries and in bottling plants for non-alcoholic beverages.
PET polyethylene terephthalate
alkaline cleaning liquors consist essentially of 95 to 99% by weight of water and 1 to 5% by weight of sodium and / or potassium hydroxide.
the agent according to the invention is also suitable for aqueous acidic cleaning liquors which are known to consist essentially of 50 to 80% by weight of water and 20 to 50% by weight of preferably phosphoric acid or sulfuric acid.
Component B is a compound having Component B:

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Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
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Organic Chemistry (AREA)
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EP97954395A 1996-12-18 1997-12-12 Mischungen von alkoxylaten mit schaumdämpfender und desinfizierender wirkung und deren verwendung in reinigungsmitteln Expired - Lifetime EP0946697B1 (de)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE19652680A DE19652680A1 (de)	1996-12-18	1996-12-18	Mischungen von Alkoxylaten mit schaumdämpfender und desinfizierender Wirkung und deren Verwendung in Reinigungsmitteln
DE19652680		1996-12-18
PCT/EP1997/006993 WO1998027188A2 (de)	1996-12-18	1997-12-12	Mischungen von alkoxylaten mit schaumdämpfender und desinfizierender wirkung und deren verwendung in reinigungsmitteln

Publications (2)

Publication Number	Publication Date
EP0946697A2 EP0946697A2 (de)	1999-10-06
EP0946697B1 true EP0946697B1 (de)	2002-10-30

Family

ID=7815131

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP97954395A Expired - Lifetime EP0946697B1 (de)	1996-12-18	1997-12-12	Mischungen von alkoxylaten mit schaumdämpfender und desinfizierender wirkung und deren verwendung in reinigungsmitteln

Country Status (8)

Country	Link
US (1)	US6001790A (da)
EP (1)	EP0946697B1 (da)
AT (1)	ATE226975T1 (da)
AU (1)	AU5856598A (da)
DE (2)	DE19652680A1 (da)
DK (1)	DK0946697T3 (da)
HU (1)	HUP0000595A3 (da)
WO (1)	WO1998027188A2 (da)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US10376901B2 (en)	2014-09-18	2019-08-13	Akzo Nobel Chemicals International B.V.	Use of branched alcohols and alkoxylates thereof as secondary collectors

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6806233B2 (en)	1996-08-02	2004-10-19	M-I Llc	Methods of using reversible phase oil based drilling fluid
AU1396601A (en) *	1999-12-14	2001-06-25	Unilever Plc	Antimicrobial solutions
US7572755B2 (en)	2000-12-29	2009-08-11	Halliburton Energy Services, Inc.	Drilling fluid comprising a vinyl neodecanoate polymer and method for enhanced suspension
US6887832B2 (en) *	2000-12-29	2005-05-03	Halliburton Energy Service,S Inc.	Method of formulating and using a drilling mud with fragile gels
US7456135B2 (en)	2000-12-29	2008-11-25	Halliburton Energy Services, Inc.	Methods of drilling using flat rheology drilling fluids
DE60044619D1 (de) *	2000-12-29	2010-08-12	Cognis Ip Man Gmbh	Verflüssiger für invert-emulsionen
MXPA03005918A (es)	2000-12-29	2005-02-14	Halliburton Energy Serv Inc	Diluyentes para emulsiones invertidas.
US20030036484A1 (en)	2001-08-14	2003-02-20	Jeff Kirsner	Blends of esters with isomerized olefins and other hydrocarbons as base oils for invert emulsion oil muds
US6620770B1 (en)	2001-10-31	2003-09-16	Halliburton Energy Services, Inc.	Additive for oil-based drilling fluids
US7534746B2 (en) *	2001-10-31	2009-05-19	Halliburton Energy Services, Inc.	Metallic soaps of modified tall oil acids
US7008907B2 (en) *	2001-10-31	2006-03-07	Halliburton Energy Services, Inc.	Additive for oil-based drilling fluids
US7271132B2 (en) *	2001-10-31	2007-09-18	Halliburton Energy Services, Inc.	Metallic soaps of modified fatty acids and rosin acids and methods of making and using same
DE10228656A1 (de) *	2002-06-27	2004-01-22	Ecolab Gmbh & Co. Ohg	Schaumdesinfektionsmittel
US20060019854A1 (en) *	2004-07-21	2006-01-26	Johnsondiversey. Inc.	Paper mill cleaner with taed
CN101578130A (zh) *	2007-01-11	2009-11-11	陶氏环球技术公司	烷氧基化物混合物表面活性剂
GB2458189B (en)	2008-03-13	2012-05-09	Amity Ltd	Cleaning composition
BRPI0917728B1 (pt) *	2008-12-18	2018-02-06	Akzo Nobel N.V.	Composição, uso da composição, e, método de prevenção da formação de espuma em uma composição
US11051510B2 (en) *	2014-01-30	2021-07-06	Basf Se	Asymmetric formales and acetales as adjuvants for crop protection
PL3359515T3 (pl) *	2015-10-07	2020-07-27	Elementis Specialties, Inc.	Środek zwilżający i przeciwpieniący
EP3542628A1 (de) *	2018-03-22	2019-09-25	Chemische Fabrik Dr. Weigert GmbH & Co. KG	Desinfektionsmittel und verwendung von n,n-bis(3-aminopropyl)alkylamin in desinfektionsmitteln
WO2026004578A1 (ja) *	2024-06-25	2026-01-02	花王株式会社	洗浄機用洗浄剤組成物

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3048642A1 (de) *	1980-12-23	1982-07-15	Hoechst Ag, 6000 Frankfurt	"tensidgemisch zur reinigung harter oberlaechen"

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2523588C2 (de) *	1975-05-28	1983-11-10	Hoechst Ag, 6230 Frankfurt	Polyglykoläthermischformale und deren Verwendung als ätzalkalibeständige Netz-, Wasch- und Reinigungsmittel
DE3744525C1 (de) *	1987-12-30	1988-12-01	Henkel Kgaa	Verfahren zur Herstellung endgruppenverschlossener Polyglykolether
US5223162A (en) *	1988-07-14	1993-06-29	Diversey Corporation	Washing composition for inhibiting stress cracking in poly(alkylene terephthalate) articles and methods of use therefor
DE4201038C2 (de) *	1992-01-17	1996-03-28	Schuelke & Mayr Gmbh	Desinfektionsmittelkonzentrat und Desinfektionsmittel auf Amin- und Alkoholbasis und deren Verwendung
FR2701037B1 (fr) *	1993-01-29	1995-03-17	Hakawerk H Kunz Gmbh	Détergents pour articles textiles en fibres de polychlorure de vinyle.
US5415837A (en) *	1993-10-25	1995-05-16	Alcon Laboratories, Inc.	Use of diamines to disinfect and clean contact lenses
DE4426889A1 (de) *	1994-07-29	1996-02-01	Hoechst Ag	Mischungen von Alkoxylaten als schaumdämpfendes Mittel und deren Verwendung
US5576284A (en) *	1994-09-26	1996-11-19	Henkel Kommanditgesellschaft Auf Aktien	Disinfecting cleanser for hard surfaces
FR2727958A1 (fr) *	1994-12-08	1996-06-14	Vanlaer Antoine	Procede de traitement d'eau et des surfaces en contact avec ladite eau en vue d'empecher la fixation et/ou d'eliminer et/ou controler des macroorganismes, composition et peinture pour ledit traitement

1996
- 1996-12-18 DE DE19652680A patent/DE19652680A1/de not_active Withdrawn
1997
- 1997-12-12 DK DK97954395T patent/DK0946697T3/da active
- 1997-12-12 AU AU58565/98A patent/AU5856598A/en not_active Abandoned
- 1997-12-12 AT AT97954395T patent/ATE226975T1/de not_active IP Right Cessation
- 1997-12-12 DE DE59708635T patent/DE59708635D1/de not_active Expired - Fee Related
- 1997-12-12 EP EP97954395A patent/EP0946697B1/de not_active Expired - Lifetime
- 1997-12-12 HU HU0000595A patent/HUP0000595A3/hu unknown
- 1997-12-12 WO PCT/EP1997/006993 patent/WO1998027188A2/de not_active Ceased
- 1997-12-17 US US08/992,156 patent/US6001790A/en not_active Expired - Fee Related

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3048642A1 (de) *	1980-12-23	1982-07-15	Hoechst Ag, 6000 Frankfurt	"tensidgemisch zur reinigung harter oberlaechen"

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US10376901B2 (en)	2014-09-18	2019-08-13	Akzo Nobel Chemicals International B.V.	Use of branched alcohols and alkoxylates thereof as secondary collectors

Also Published As

Publication number	Publication date
DE59708635D1 (de)	2002-12-05
HUP0000595A3 (en)	2002-07-29
DE19652680A1 (de)	1998-06-25
US6001790A (en)	1999-12-14
WO1998027188A3 (de)	1998-08-06
AU5856598A (en)	1998-07-15
DK0946697T3 (da)	2003-03-03
EP0946697A2 (de)	1999-10-06
ATE226975T1 (de)	2002-11-15
HUP0000595A2 (en)	2000-07-28
WO1998027188A2 (de)	1998-06-25

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Publication	Publication Date	Title
EP0946697B1 (de)	2002-10-30	Mischungen von alkoxylaten mit schaumdämpfender und desinfizierender wirkung und deren verwendung in reinigungsmitteln
EP0054895B1 (de)	1984-07-25	Tensidgemisch zur Reinigung harter Oberflächen
EP0977825B1 (de)	2002-10-09	Flüssige enzymzubereitung und ihre verwendung
DE3788895T2 (de)	1994-06-23	Antimikrobielle Zusammensetzungen.
EP0254208B1 (de)	1991-10-16	Schaumarme und/oder schaumdämpfende Tensidgemische und ihre Verwendung
DE69631436T2 (de)	2004-12-02	Keimtötende Geschirrspülmittelzusammensetzungen
EP0054894B1 (de)	1984-07-25	Tensidhaltiges Gemisch zur Reinigung harter Oberflächen
EP0161537A2 (de)	1985-11-21	Endgruppenverschlossene Fettalkoholalkoxylate für industrielle Reinigungsprozesse, insbesondere für die Flaschenwäsche und für die Metallreinigung
DE2106819A1 (de)	1972-09-14	Klarspulmittel fur die maschinelle Geschirreinigung
DE3603579A1 (de)	1987-08-13	Verwendung ethoxylierter fettamine als loesungsvermittler
EP0694606B1 (de)	1999-12-15	Mischungen von Alkoxylaten als schaumdämpfendes Mittel und deren Verwendung
DE69728303T2 (de)	2005-02-24	Reinigungsmittel
EP0728180B1 (de)	1998-08-26	Additiv für die glasflaschenreinigung und seine verwendung zur verringerung der glaskorrosion
DE60013191T2 (de)	2005-08-11	Tensidzusammensetzung und deren Verwendung
EP4232541B1 (de)	2024-11-27	Flüssiges reinigungsmittelkonzentrat, gebrauchsfertige anwendungslösung, deren verwendungen und reinigungsverfahren
EP0326795B1 (de)	1994-08-17	Verwendung von Polyglykolethern als schaumvermindernde Zusätze für Reinigungsmittel
DE69721552T2 (de)	2004-03-04	Entschäumerzusammensetzungen und verfahren zur herstellung
EP4232537B1 (de)	2024-11-27	Flüssiges reinigungsmittelkonzentrat, gebrauchsfertige anwendungslösung, deren verwendungen und reinigungsverfahren
DE19749964B4 (de)	2004-05-13	Waschlösung für die Getränke- und Lebensmittelindustrie
EP0652704B1 (de)	1997-01-29	Verwendung von ethercarbonsäuren als keimtötende substanzen
CH629846A5 (de)	1982-05-14	Klarspuelmittel fuer die maschinelle geschirreinigung.
CH676007A5 (da)	1990-11-30
WO1989011524A1 (fr)	1989-11-30	Ethers d'alkyle polyglycol antimousse pour detergents (ii)
DE2855778B2 (de)	1980-03-27	Flüssiges Reinigungsmittel
EP0095136B1 (de)	1988-11-17	Klarspülmittel für die maschinelle Geschirreinigung

EP0946697B1 - Mischungen von alkoxylaten mit schaumdämpfender und desinfizierender wirkung und deren verwendung in reinigungsmitteln - Google Patents

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