EP0960251A1 - Obturation d'ouverture a l'epreuve du feu - Google Patents
Obturation d'ouverture a l'epreuve du feuInfo
- Publication number
- EP0960251A1 EP0960251A1 EP98908030A EP98908030A EP0960251A1 EP 0960251 A1 EP0960251 A1 EP 0960251A1 EP 98908030 A EP98908030 A EP 98908030A EP 98908030 A EP98908030 A EP 98908030A EP 0960251 A1 EP0960251 A1 EP 0960251A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- opening closure
- closure according
- heat
- composite body
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000009970 fire resistant effect Effects 0.000 title claims abstract description 7
- 239000002131 composite material Substances 0.000 claims abstract description 33
- 239000002245 particle Substances 0.000 claims abstract description 27
- 239000011230 binding agent Substances 0.000 claims abstract description 20
- 230000001070 adhesive effect Effects 0.000 claims abstract description 12
- 239000000853 adhesive Substances 0.000 claims abstract description 11
- 125000005442 diisocyanate group Chemical group 0.000 claims abstract description 3
- 239000004604 Blowing Agent Substances 0.000 claims description 17
- 239000006260 foam Substances 0.000 claims description 11
- 239000008187 granular material Substances 0.000 claims description 8
- 229920001169 thermoplastic Polymers 0.000 claims description 7
- 239000004416 thermosoftening plastic Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000011521 glass Substances 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 5
- 238000007906 compression Methods 0.000 claims description 5
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 3
- 239000004831 Hot glue Substances 0.000 claims description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 229910001562 pearlite Inorganic materials 0.000 claims description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 2
- 239000010455 vermiculite Substances 0.000 claims description 2
- 229910052902 vermiculite Inorganic materials 0.000 claims description 2
- 235000019354 vermiculite Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 239000000758 substrate Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 description 16
- 239000000463 material Substances 0.000 description 7
- 229920002689 polyvinyl acetate Polymers 0.000 description 5
- 239000011118 polyvinyl acetate Substances 0.000 description 5
- 229920005830 Polyurethane Foam Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000011496 polyurethane foam Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000011805 ball Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 239000002557 mineral fiber Substances 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 206010000060 Abdominal distension Diseases 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 208000024330 bloating Diseases 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 229920001821 foam rubber Polymers 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011806 microball Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C3/00—Fire prevention, containment or extinguishing specially adapted for particular objects or places
- A62C3/16—Fire prevention, containment or extinguishing specially adapted for particular objects or places in electrical installations, e.g. cableways
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/913—Material designed to be responsive to temperature, light, moisture
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
- Y10S428/921—Fire or flameproofing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/699—Including particulate material other than strand or fiber material
Definitions
- the invention relates to a fire-resistant, elastic opening closure in the form of a preformed composite body.
- Openings are not permitted in components classified as fire protection (walls, ceilings), since in the event of a fire, fire and smoke can spread through the openings into the adjacent rooms.
- fire protection walls, ceilings
- a fire and smoke-tight closure for wall openings is known from the German utility model G 87 16 908.6.
- This closure is produced in the form of a conical stopper by foaming a fine-pored two-component foam in a suitable raw form.
- conical plugs are difficult to handle, which is is reinforced by the sticky outer skin.
- numerous hollow molds must be kept in order to obtain plugs of different sizes.
- DE 35 42 326 C1 describes a flame-retardant composite foam made of polyurethane foam flakes. This is produced by mixing the foam flakes with intumescent materials which can be inflated in the event of fire as binders and / or additives and then pressing them together. Intumescent materials in the form of expanded graphite can be used as the additive and intumescent materials in the form of an epoxy resin with a melamine hydrohalide can be used as the binder.
- the composite foam obtained in this way is suitable as a composite foam panel for laying on surfaces to be protected.
- the invention relates to a fire-resistant, elastic opening closure in the form of a preformed composite body
- the opening closure according to the invention can be produced in a simple manner, to a large extent or completely using recycled material.
- the opening closure according to the invention has excellent mechanical properties, in particular with regard to strength, abrasion resistance and elasticity.
- the opening closure according to the invention has excellent fire properties. It can easily be formulated so that its fire resistance is above F90 according to DIN 4102. His fire resistance is therefore the same as the fire resistance of concrete components, which is particularly advantageous.
- the blowing agent which becomes effective when the heat develops, increases the volume and ensures a particularly tight seal of the opening. Furthermore, additional cavities are created that increase the thermal insulation.
- the at least one heat-effective binder becomes sticky when exposed to heat and ensures that the individual components of the composite body hold together in the event of a fire and do not crumble.
- At least two heat-binding binders starting at different temperatures are advantageously provided.
- Organic thermoplastics that melt at low temperatures, inorganic hot-melt adhesives such as borates, ammonium polyphosphate, which softens over a wide temperature range and at the same time have flame-retardant properties, and glass, which develops their adhesive properties at higher temperatures, are particularly suitable as heat-binding binders.
- the glass is preferably in finely divided form, in particular in the form of fibers, hollow microspheres or glass powder.
- blowing agents which expand at different temperatures are provided as blowing agents. This also allows the blowing properties to be controlled over a wide temperature range. Expandable graphite is particularly suitable as a blowing agent and, if bloating is desired even at high temperatures, also unexpanded vermiculite and / or pearlite.
- the individual components can be premixed in finely divided form, after which the mixture is provided with the adhesive, preferably by spraying it onto the moving mixture.
- the mixture wetted with the adhesive is then preferably pressed into a block under the action of heat, the heat being able to be introduced evenly into the mixture, in particular with the aid of a steam jet.
- the at least one blowing agent and the at least one thermally active binder are in the form of a granulate containing both components. This will make it a very even one Distribution of the components in the opening closure obtained, which results in very uniform mechanical and fire properties.
- Particularly suitable granules of this type are described in DE 39 30 722 A1 as a swelling agent composition.
- the content of this publication is expressly referred to here.
- the composite bodies are composed of 10-50% by weight, in particular approximately 40% by weight, of elastically compressible particles, 20-70% by weight, in particular 40-60% by weight from the combination of heat-effective blowing agents and heat-binding binders, and 0.5 - 20% by weight, in particular approximately 10% by weight of adhesive.
- the combination of thermally active blowing agents and thermally active binders usually splits up to 40-80% by weight, in particular
- blowing agent in particular blowing agent mixture, and 60-20% by weight, especially binder mixture.
- the adhesive holding the components of the composite body together is a diisocyanate, in particular
- Diphenylmethane diisocyanate which is preferably set with water.
- the water from the steam jet or the aqueous medium with which the adhesive is added can be used for setting.
- the adhesive that holds the components of the composite body together is a thermoplastic, in particular a thermoplastic that can be applied in an aqueous medium, for example as a dispersion. This can also serve as a heat-effective binder.
- thermoplastics are polyvinyl acetate / ethylene copolymers and
- the opening closure according to the invention is preferably porous and in particular has a rough surface. This makes it particularly easy to compress. On the other hand, the rough surface ensures good adhesion in the openings to be closed.
- the opening closure according to the invention has the properties despite its heterogeneous composition of a homogeneous body.
- the elastically compressible particles can be essentially solid, such as rubber pieces or cork pieces. However, they are preferably porous.
- the composite body is a composite foam body, and the elastically compressible particles are foam particles.
- Balls of fiber are also suitable as compressible particles. Fibers and other compressible particles can also be present in combination with one another.
- the elastically compressible particles are open-pore, as is the case with fiber balls and open-pore foam particles.
- the particle size of the individual components can vary within wide limits. In the case of the compressible particles, it is generally between 1 and 20 mm, in particular 1 and 5 mm.
- the remaining constituents can be in the form of powders or particles with a particle size of 0.001-10 mm, preferably 0.1-5 mm, in particular 0.3-5 mm.
- the opening closures according to the invention are preferably made from larger blocks. Sheets of suitable thickness can be cut from these. This is possible in a simple manner, since the material of the composite body can be cut easily, for example with knives, scissors or hot wires. Punching is also possible. As a result, any sizes and shapes of opening closures can be produced without having to keep special shapes in stock.
- the resulting waste can be recycled in a simple manner by using it as an elastically compressible particle in the production of a new composite body. Since these particles then already contain the heat-effective binders and blowing agents, their amount can be reduced accordingly. It is also advantageously possible to prepare openings and recesses in the opening closures for the passage of lines, for example by partial punching.
- the opening closures contain 800-400, in particular 750-600 l gas / m 3 .
- the modulus of elasticity of the opening closures is generally from 1 • 10 3 to 1 ⁇ 10 5 N / m 2, preferably from 4 to 10 ⁇ 10 3 N / m 2, in particular about 7 • 10 3 N / m 2.
- the opening closures advantageously have a compression hardness (at 40% compression) of 1 • 10 2 to 7 • 10 3 N / mm 2 , preferably 1, 3 to 5 ⁇ 10 2 N / mm 2 , in particular approx. 1, 7 • 10 2 N / mm 2 .
- the Shore A hardness of the opening closures is preferably in the range of 10-40, preferably 12 to 20, in particular approximately 15. These mechanical properties can be varied in a suitable manner by controlling the production conditions.
- a dry mixture is made from the following ingredients:
- the cut surfaces were porous and not sticky. They had a uniform black-gray color, with individual expandable graphite particles being recognizable. Sheets were cut from the composite body, from which the desired shapes of the opening closures (cylinders, cuboids and the like) were punched out. For the formation of cable feedthroughs, holes of different sizes were pre-punched so that the respective hole cores could be pushed out by hand at the construction site without tools.
- the opening closures could be bent and pressed together without the risk of breakage. They are so firm that they can be hammered into openings and pulled out of the openings without risk of breakage or tearing.
- Cylindrical parts with a thickness of 6 cm can be cut from the composite bodies. These cylinders are suitable for sealing off holes in components through which electrical cables are led. If two of these cylinders are installed in a bore in a 120 mm thick concrete wall, through which electrical cables of up to 20 mm in diameter are passed, a fire resistance of more than 120 minutes according to DIN 3102, part 9 can be achieved.
- Example 1 was repeated, first of all producing a granulate containing blowing agent and heat-binding agent. For this purpose
- a dry mixture is produced from 45% by weight of a swelling agent granulate according to DE 39 30 722 A1, which already contains a heat-effective binder, and 50% by weight of a rubber foam ground to a size of 1-3 mm.
- This mixture is sprayed with 5% by weight diphenylmethane diisocyanate, which is diluted 1: 1 with water.
- This preliminary product is heated in a heated press mold with several bursts of steam to approx. 170 ° C., whereby it solidifies into a composite body with a density of 380 kg / m 2 .
- the composite body has a modulus of elasticity of 2 • 10 4 N / m 2 and a compression hardness (40%) of 2.5 ⁇ 10 2 N / mm 2 .
- the cross-section of the composite body is used to cut trapezoidal bodies which can be used to seal the trapezoidal sheet beads above walls inside buildings.
- the composite bodies with a thickness of 120 mm have a fire resistance duration of more than 2 hours.
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Building Environments (AREA)
- Sealing Material Composition (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Fire-Detection Mechanisms (AREA)
- Insulated Conductors (AREA)
- Control Of Combustion (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19704833A DE19704833A1 (de) | 1997-02-08 | 1997-02-08 | Feuerwiderstandsfähiger Öffnungsverschluß |
| DE19704833 | 1997-02-08 | ||
| PCT/EP1998/000517 WO1998035122A1 (fr) | 1997-02-08 | 1998-01-31 | Obturation d'ouverture a l'epreuve du feu |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0960251A1 true EP0960251A1 (fr) | 1999-12-01 |
| EP0960251B1 EP0960251B1 (fr) | 2003-04-02 |
Family
ID=7819713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98908030A Expired - Lifetime EP0960251B1 (fr) | 1997-02-08 | 1998-01-31 | Obturation d'ouverture a l'epreuve du feu |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6544445B1 (fr) |
| EP (1) | EP0960251B1 (fr) |
| AT (1) | ATE236337T1 (fr) |
| AU (1) | AU721890B2 (fr) |
| DE (2) | DE19704833A1 (fr) |
| DK (1) | DK0960251T3 (fr) |
| WO (1) | WO1998035122A1 (fr) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE20002828U1 (de) | 2000-02-17 | 2000-07-13 | MEBA GmbH, 82065 Baierbrunn | Kabel-Brandschotteinrichtung |
| US6751814B2 (en) * | 2001-11-02 | 2004-06-22 | Roy Mattson | Whirlpool bath filter and suction device |
| US6760931B1 (en) * | 2002-08-02 | 2004-07-13 | Roy W. Mattson, Jr. | Non-electric sanitation water vessel system |
| US7352034B2 (en) * | 2005-08-25 | 2008-04-01 | International Business Machines Corporation | Semiconductor structures integrating damascene-body FinFET's and planar devices on a common substrate and methods for forming such semiconductor structures |
| US8275635B2 (en) * | 2007-02-16 | 2012-09-25 | Bodymedia, Inc. | Integration of lifeotypes with devices and systems |
| US20100056660A1 (en) * | 2008-08-29 | 2010-03-04 | Bayer Materialscience Llc | Decorative molded foams with good fire retardant properties |
| US9670666B1 (en) | 2008-11-20 | 2017-06-06 | Emseal Joint Sytstems Ltd. | Fire and water resistant expansion joint system |
| US9739050B1 (en) | 2011-10-14 | 2017-08-22 | Emseal Joint Systems Ltd. | Flexible expansion joint seal system |
| US9631362B2 (en) | 2008-11-20 | 2017-04-25 | Emseal Joint Systems Ltd. | Precompressed water and/or fire resistant tunnel expansion joint systems, and transitions |
| US10316661B2 (en) | 2008-11-20 | 2019-06-11 | Emseal Joint Systems, Ltd. | Water and/or fire resistant tunnel expansion joint systems |
| US9637915B1 (en) | 2008-11-20 | 2017-05-02 | Emseal Joint Systems Ltd. | Factory fabricated precompressed water and/or fire resistant expansion joint system transition |
| US11180995B2 (en) | 2008-11-20 | 2021-11-23 | Emseal Joint Systems, Ltd. | Water and/or fire resistant tunnel expansion joint systems |
| US10851542B2 (en) | 2008-11-20 | 2020-12-01 | Emseal Joint Systems Ltd. | Fire and water resistant, integrated wall and roof expansion joint seal system |
| US8365495B1 (en) | 2008-11-20 | 2013-02-05 | Emseal Joint Systems Ltd. | Fire and water resistant expansion joint system |
| US8341908B1 (en) | 2009-03-24 | 2013-01-01 | Emseal Joint Systems Ltd. | Fire and water resistant expansion and seismic joint system |
| US8813450B1 (en) | 2009-03-24 | 2014-08-26 | Emseal Joint Systems Ltd. | Fire and water resistant expansion and seismic joint system |
| GB201201885D0 (en) * | 2012-02-03 | 2012-03-21 | Knauf Insulation Doo Skofa Loka | Composite fibre panel |
| US9068297B2 (en) | 2012-11-16 | 2015-06-30 | Emseal Joint Systems Ltd. | Expansion joint system |
| US10480654B2 (en) | 2014-02-28 | 2019-11-19 | Schul International Co., Llc | Joint seal system having internal barrier and external wings |
| US9404581B1 (en) | 2014-02-28 | 2016-08-02 | Schul International Company, LLC | Joint seal system |
| KR101575989B1 (ko) * | 2014-12-24 | 2015-12-09 | 고영신 | 팽창흑연을 이용한 경량화된 흡음내화 단열재 및 그 제조방법 |
| US10060122B2 (en) | 2015-03-10 | 2018-08-28 | Schul International Company, LLC | Expansion joint seal system |
| US9206596B1 (en) | 2015-03-10 | 2015-12-08 | Schul International, Inc. | Expansion joint seal system |
| US10087621B1 (en) | 2015-03-10 | 2018-10-02 | Schul International Company, LLC | Expansion joint seal system with isolated temperature-activated fire retarding members |
| US9982428B2 (en) | 2015-12-30 | 2018-05-29 | Schul International Company, LLC | Expansion joint seal with surface load transfer, intumescent, and internal sensor |
| US10066386B2 (en) | 2015-12-30 | 2018-09-04 | Schul International Company, LLC | Expansion joint seal with surface load transfer and intumescent |
| US9745738B2 (en) | 2015-12-30 | 2017-08-29 | Schul International Company, LLC | Expansion joint for longitudinal load transfer |
| US10213962B2 (en) | 2015-12-30 | 2019-02-26 | Schul International Company, LLC | Expansion joint seal with load transfer and flexion |
| US9915038B2 (en) | 2016-03-07 | 2018-03-13 | Schul International Company, LLC | Durable joint seal system with detachable cover plate and rotatable ribs |
| US10352003B2 (en) | 2016-03-07 | 2019-07-16 | Schul International Company, LLC | Expansion joint seal system with spring centering |
| US10240302B2 (en) | 2016-03-07 | 2019-03-26 | Schul International Company, LLC | Durable joint seal system with detachable cover plate and rotatable ribs |
| US10352039B2 (en) | 2016-03-07 | 2019-07-16 | Schul International Company, LLC | Durable joint seal system with cover plate and ribs |
| US10125490B2 (en) | 2016-07-22 | 2018-11-13 | Schul International Company, LLC | Expansion joint seal system with internal intumescent springs providing fire retardancy |
| US10280610B1 (en) | 2016-07-22 | 2019-05-07 | Schul International Company, LLC | Vapor-permeable water and fire-resistant expansion joint seal |
| US10087619B1 (en) | 2016-07-22 | 2018-10-02 | Schul International Company, LLC | Fire retardant expansion joint seal system with elastically-compressible members and resilient members |
| US10280611B1 (en) | 2016-07-22 | 2019-05-07 | Schul International Company, LLC | Vapor permeable water and fire-resistant expansion joint seal |
| US10358813B2 (en) | 2016-07-22 | 2019-07-23 | Schul International Company, LLC | Fire retardant expansion joint seal system with elastically-compressible body members, internal spring members, and connector |
| US9803357B1 (en) | 2016-07-22 | 2017-10-31 | Schul International Company, LLC | Expansion joint seal system providing fire retardancy |
| US10087620B1 (en) | 2016-07-22 | 2018-10-02 | Schul International Company, LLC | Fire retardant expansion joint seal system with elastically-compressible body members, resilient members, and fire retardants |
| US10344471B1 (en) | 2016-07-22 | 2019-07-09 | Schull International Company, LLC | Durable water and fire-resistant expansion joint seal |
| US10323408B1 (en) | 2016-07-22 | 2019-06-18 | Schul International Company, LLC | Durable water and fire-resistant tunnel expansion joint seal |
| US10081939B1 (en) | 2016-07-22 | 2018-09-25 | Schul International Company, LLC | Fire retardant expansion joint seal system with internal resilient members and intumescent members |
| US10323407B1 (en) | 2016-07-22 | 2019-06-18 | Schul International Company, LLC | Water and fire-resistant expansion joint seal |
| US10227734B1 (en) | 2017-12-26 | 2019-03-12 | Veloxion, Inc. | Helically-packaged expansion joint seal system |
| US10851541B2 (en) | 2018-03-05 | 2020-12-01 | Schul International Co., Llc | Expansion joint seal for surface contact with offset rail |
| US10323409B1 (en) | 2018-07-12 | 2019-06-18 | Schul International Company, LLC | Expansion joint system with flexible sheeting |
| CN113248815B (zh) * | 2021-06-05 | 2022-03-29 | 台州菲尼科斯电气科技有限公司 | 一种插头用的阻燃抗老化塑料 |
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| DE3217816A1 (de) * | 1982-05-12 | 1983-11-17 | Hoechst Ag, 6230 Frankfurt | Teilchenfoermiges mittel zur verminderung der entzuendlichkeit von brennbaren stoffen |
| US4529467A (en) * | 1983-10-25 | 1985-07-16 | Ppg Industries, Inc. | Fire protective intumescent mastic composition and method employing same |
| US4588523A (en) * | 1984-05-29 | 1986-05-13 | Alva-Tech, Inc. | Intumescent fire retardant compositions |
| DE3542326C1 (en) * | 1985-11-29 | 1987-01-02 | Metzeler Schaum Gmbh | Flame-retardant composite foam |
| DE3609696C1 (de) * | 1986-03-19 | 1987-07-30 | Mankiewicz Gebr & Co | Formmasse |
| GB8922930D0 (en) * | 1989-10-11 | 1989-11-29 | Ici Plc | Fire retardant compositions |
| GB9002256D0 (en) * | 1990-02-01 | 1990-03-28 | Rendel Scient Services Limited | Fire protection |
| US5098778A (en) * | 1990-04-24 | 1992-03-24 | General Electric Company | Plastic based laminates comprising outer fiber-reinforced thermoset sheets, lofted fiber-reinforced thermoplastic sheets and a foam core layer |
| DE4034046A1 (de) * | 1990-10-26 | 1992-04-30 | Basf Ag | Verfahren zur herstellung von flammwidrigen polyurethan-weichschaumstoffen mit verminderter rauchgasdichte und melamin-blaehgraphit-polyether-polyol-dispersionen hierfuer |
| GB9107466D0 (en) * | 1991-04-09 | 1991-05-22 | Environmental Seals Ltd | Improvements in and relating to intumescent fire seals and their method of manufacture |
| DE4231342C1 (de) * | 1992-09-18 | 1994-05-26 | Bostik Gmbh | Intumeszierende Einkomponenten-Dichtmasse auf Polyurethanbasis |
| US5384188A (en) * | 1992-11-17 | 1995-01-24 | The Carborundum Company | Intumescent sheet |
| DE4311794A1 (de) * | 1993-04-09 | 1994-10-13 | Gruenau Gmbh Chem Fab | Brandschutzmaterial |
| US5942561A (en) * | 1995-03-03 | 1999-08-24 | Tosoh Corporation | Fire-retardant polymer composition |
| US5760115A (en) * | 1995-03-03 | 1998-06-02 | Tosoh Corporation | Fire-retardant polymer composition |
| US5523059A (en) * | 1995-06-30 | 1996-06-04 | Minnesota Mining And Manufacturing Company | Intumescent sheet material with glass fibers |
| DE19631813B4 (de) * | 1996-08-07 | 2006-03-09 | B & F Formulier- und Abfüll GmbH & Co. KG | Feuerhemmender Werkstoff und Verfahren zur Herstellung eines solchen Werkstoffes |
| US6130207A (en) * | 1997-11-05 | 2000-10-10 | South Alabama Medical Science Foundation | Cell-specific molecule and method for importing DNA into a nucleus |
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1997
- 1997-02-08 DE DE19704833A patent/DE19704833A1/de not_active Withdrawn
-
1998
- 1998-01-31 WO PCT/EP1998/000517 patent/WO1998035122A1/fr not_active Ceased
- 1998-01-31 DE DE59807738T patent/DE59807738D1/de not_active Expired - Lifetime
- 1998-01-31 AU AU66182/98A patent/AU721890B2/en not_active Expired
- 1998-01-31 AT AT98908030T patent/ATE236337T1/de active
- 1998-01-31 EP EP98908030A patent/EP0960251B1/fr not_active Expired - Lifetime
- 1998-01-31 DK DK98908030T patent/DK0960251T3/da active
- 1998-01-31 US US09/367,092 patent/US6544445B1/en not_active Expired - Fee Related
Non-Patent Citations (1)
| Title |
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Also Published As
| Publication number | Publication date |
|---|---|
| US6544445B1 (en) | 2003-04-08 |
| DE59807738D1 (de) | 2003-05-08 |
| DK0960251T3 (da) | 2003-07-28 |
| ATE236337T1 (de) | 2003-04-15 |
| DE19704833A1 (de) | 1998-08-13 |
| AU6618298A (en) | 1998-08-26 |
| WO1998035122A1 (fr) | 1998-08-13 |
| EP0960251B1 (fr) | 2003-04-02 |
| AU721890B2 (en) | 2000-07-13 |
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