EP0964410A2 - Substance à couche épaisse et procédé pour la fabrication d'une structure à couche épaisse - Google Patents
Substance à couche épaisse et procédé pour la fabrication d'une structure à couche épaisse Download PDFInfo
- Publication number
- EP0964410A2 EP0964410A2 EP99109459A EP99109459A EP0964410A2 EP 0964410 A2 EP0964410 A2 EP 0964410A2 EP 99109459 A EP99109459 A EP 99109459A EP 99109459 A EP99109459 A EP 99109459A EP 0964410 A2 EP0964410 A2 EP 0964410A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- thick
- substance
- film
- substrate
- film substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000126 substance Substances 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000000758 substrate Substances 0.000 claims abstract description 40
- 238000000034 method Methods 0.000 claims abstract description 23
- 230000004907 flux Effects 0.000 claims abstract description 5
- 239000000470 constituent Substances 0.000 claims abstract description 3
- 230000005855 radiation Effects 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 238000007650 screen-printing Methods 0.000 abstract description 3
- 239000004020 conductor Substances 0.000 description 19
- 238000010438 heat treatment Methods 0.000 description 18
- 238000005516 engineering process Methods 0.000 description 7
- 238000009413 insulation Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000010292 electrical insulation Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- -1 ferrous metals Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000006855 networking Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
- 230000009189 diving Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 238000012690 ionic polymerization Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000012811 non-conductive material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- SJLOMQIUPFZJAN-UHFFFAOYSA-N oxorhodium Chemical compound [Rh]=O SJLOMQIUPFZJAN-UHFFFAOYSA-N 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910003450 rhodium oxide Inorganic materials 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C7/00—Stoves or ranges heated by electric energy
- F24C7/06—Arrangement or mounting of electric heating elements
Definitions
- the present invention relates to a thick film substance, in particular a thick film paste, from an active component, in particular to define the substance properties serves, and a flux that connects to one to be coated Causes substrate. Furthermore, it relates to a manufacturing method a structure from a thick-film substance on a substrate.
- Such a paste and such a method are known for household appliances the publication DE 33 02 794 A1, with resistance elements on a baking muffle of an electric cooker are printed in thick-film technology for heating the muffle.
- the heating element consists of a known resistance paste from the outside is printed on the muffle wall.
- thick-film structures on any base material or subtract generally known e.g. from Peter Hauptmann: sensors, principles and applications; Carl Hanser publishing house.
- a screen printing process is used Thick film paste applied to the substrate, which is then at 100 ° C to 200 ° C dried and then baked at temperatures above 500 ° C.
- Thin steel or nylon screens are used to print the stencils and through which the pastes are pressed.
- a substrate material Usually ceramic, enamelled steel, glass or flexible plastic substrates are used.
- the thick film paste generally consists of an active component, e.g. Metal, metal oxide or ceramic, a flux, for example glass frit or bismuth oxide, and organic solvents and binders.
- the pastes in their physical-technical properties, such as toughness, coefficient of thermal expansion or temperature coefficient of resistance can be varied.
- passive components and Circuit protection today are commercially available conductor, masking, resistance and Dielectric pastes available.
- Resistance pastes contain frit material and binders predominantly metal oxides e.g. Rothenium and / or rhodium oxide.
- Thick film pastes are increasingly used on thick film powder.
- the object of the present invention is to create the free layout when creating to improve thick-film structures on substrates.
- this is a thick-film substance according to the preamble of Claim 1 achieved in that the thick-film substance at least one organic Contains reactive substance with a chemically reactive component by suitable energy input limited to the locations of the energy input with the substrate and can be crosslinked with the remaining constituents of the thick-film substance.
- the Corresponding method according to the invention is characterized in that initially the substrate is coated over a large area with the thick-film substance, then selectively attaching the thick-film substance to the substrate according to the desired substance structure by locally limited to the structure suitable energy input and finally by removing the unattached Thick film substance from the substrate.
- the Adhesion of the thick-film substance structure thus produced is in the Difference from the prior art according to the invention due to the chemical bond the structure of the substance is particularly good.
- the reactive substance is advantageously formed by a resin.
- a resin When energy input With UV light, for example, acrylic resin is suitable, while with infrared radiation Epoxy resin is an inexpensive solution at low temperatures.
- the surfaces of the remaining components of the thick-film substance can also be special suitably matched to the properties of the reactive component or the substrate if they are manufactured or processed using the sol-gel technique are.
- the thick-film substance is advantageously removed after the unattached one has been removed Branded thick film substance.
- this can be the case with the manufacturing process be carried out by yourself or when commissioning the device, in which the thick-film substance structure is provided by an operator.
- the thick-film substance is replaced by a Thick film paste is formed and by means of dipping or spraying onto the substrate is applied.
- the large area Coating of the substrate can also be done electrostatically.
- the properties of the thick-film structure for example its resistance value or their adherence to the substrate to permanently define the reactive substance removed from or during the introduction of the thick-film substance.
- the muffle wall serves as a substrate, both made of suitable metal or other Materials such as Non-conductive materials can exist.
- a suitable electrical insulation layer is preferred using sol-gel technology deposited on the muffle wall or the substrate. This turns into a solution (Sol) a colloidal system on a ⁇ scale through controlled condensation methods (Gel) generated. This gel is made by drying due to solvent removal compressed and then cured by introducing a suitable energy.
- the sol gel layer is chemically attached to the substrate or the Muffle wall bound, which leads to a particularly good adhesion of the layer on the Leads substrate.
- the necessary Layer thicknesses are less than 10 ⁇ m, which causes the thermomechanical stresses in the insulation layer with operational temperature increases clearly be reduced.
- the heat transfer is due to the small layer thickness the insulation layer improved.
- the transparent or colored sol-gel insulation layer serves as an electrical insulation as well as the requirement functional surface for the wear side, i.e. the inside of the muffle.
- a thick-layer heating conductor substance is first used produced, which in their composition a proportion of a contains reactive organic or organosilicon components.
- This reactive component opens up the possibility of defining the thick-film structure and to fix that the proportions of the reactive component targeted each other be networked.
- the initially liquid, pasty or powdery thick-film substance defined structured and to a homogeneous, stable and am Solidified substrate or intermediate product adhering to the electrical insulation layer.
- the crosslinking itself can be effected by the action of initiators, e.g.
- the heating conductor structure is generated as follows:
- the thick-film paste is sprayed over a large area into the desired one Areas applied to the outside of the oven muffle. After that is done the selective connection of the desired heating conductor structure or the heating conductor layout on the substrate. With the help of a corresponding structure mask they will not shielded areas of the heating conductor paste.
- the thick-film paste becomes energy input, for example a UV or IR exposure process selectively pre-hardened in the non-masked areas and to the Chemically bound substrate.
- the reactive component of the heating conductor paste activated and networked by the energy input. Through this networking, the Heating conductor paste sufficient strength for the further process steps and Adhesion to the substrate or the electrical insulation layer.
- this is Process when using a focused energy source, e.g. a laser too possible without mask.
- a focused energy source e.g. a laser too possible without mask.
- the insulation layer bound portion of the thick layer paste For example done in a rinsing process. So that is also on a substrate with a not flat, but, for example, channel-shaped or groove-shaped profile a thick-film heating conductor structure possible. It just has to be structured Energy input and thus the structured networking of the thick-film substance ensured be.
- the final connection of the heating conductor to the substrate can then, for example in a baking oven, which is heated electrically by IR radiation or flash lamps becomes.
- a baking oven which is heated electrically by IR radiation or flash lamps becomes.
- the area of application of the heating conductor is below 250 ° C, the baking temperature should not exceed 250 ° C.
- This especially low process temperatures are particularly due to the sol technical Preparation of the reactive component and the other components of the thick-film substance possible.
- the Substance to ensure that this is a continuous use temperature in height the desired later operating temperature, otherwise it would be due to the unintentional degradation of the reactive component to undesirable changes
- the electrical characteristics of the heating conductor can come.
- the curing can take place by applying a voltage to the thick-film heating conductor.
- the heat conductor heats up due to the current flow, causing it to reach the desired level Degree is cured.
- This curing can already take place during the The heating conductors are checked for functionality or only when the oven is started up by an operator.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Parts Printed On Printed Circuit Boards (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19822033 | 1998-05-15 | ||
| DE1998122033 DE19822033A1 (de) | 1998-05-15 | 1998-05-15 | Dickschichtsubstanz und Verfahren zum Herstellen einer Struktur aus einer Dickschichtsubstanz |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0964410A2 true EP0964410A2 (fr) | 1999-12-15 |
| EP0964410A3 EP0964410A3 (fr) | 2000-09-20 |
Family
ID=7868007
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99109459A Withdrawn EP0964410A3 (fr) | 1998-05-15 | 1999-05-11 | Substance à couche épaisse et procédé pour la fabrication d'une structure à couche épaisse |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0964410A3 (fr) |
| DE (1) | DE19822033A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1255083A1 (fr) * | 1998-03-27 | 2002-11-06 | BSH Bosch und Siemens Hausgeräte GmbH | Four à mouffle |
| WO2005115056A1 (fr) * | 2004-05-19 | 2005-12-01 | Koninklijke Philips Electronics N.V. | Pellicule pour appareil ménager |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2167267A1 (en) * | 1972-01-11 | 1973-08-24 | Klima Technik | Resistance compsn - for heating panels eg in muffles baking ovens and cooking appliances |
| JPH04305001A (ja) * | 1989-08-23 | 1992-10-28 | Fraunhofer Ges | 酸化物マトリックス中に金属小粒子または金属酸化物小粒子を含む複合材料の製造方法 |
| EP0434334B1 (fr) * | 1989-12-21 | 1994-02-02 | Minnesota Mining And Manufacturing Company | Compositions dentaires, procédé pour la préparation d'articles formés par une "polymérisation photoinifertée" de ces compositions dentaires et articles dentaires formés produits par ce procédé |
| GB9115154D0 (en) * | 1991-07-12 | 1991-08-28 | Patel Bipin C M | Sol-gel composition for producing glassy coatings |
| DE4442235C2 (de) * | 1993-12-01 | 2002-12-05 | Roland Man Druckmasch | Verfahren zur Herstellung einer Druckform für einen Formzylinder einer Druckmaschine und danach hergestellte Druckform |
| DE4406978C2 (de) * | 1994-03-03 | 1996-09-19 | Lohmann Gmbh & Co Kg | Verfahren zur Herstellung von selbstklebenden Hydrogelen und ihre medizinische Verwendung |
| GB9603050D0 (en) * | 1996-02-13 | 1996-04-10 | Electra Polymers & Chemicals L | Coating pattern formation |
-
1998
- 1998-05-15 DE DE1998122033 patent/DE19822033A1/de not_active Ceased
-
1999
- 1999-05-11 EP EP99109459A patent/EP0964410A3/fr not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1255083A1 (fr) * | 1998-03-27 | 2002-11-06 | BSH Bosch und Siemens Hausgeräte GmbH | Four à mouffle |
| WO2005115056A1 (fr) * | 2004-05-19 | 2005-12-01 | Koninklijke Philips Electronics N.V. | Pellicule pour appareil ménager |
| US7663075B2 (en) | 2004-05-19 | 2010-02-16 | Koninklijke Philips Electronics N.V. | Layer for use in a domestic appliance |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0964410A3 (fr) | 2000-09-20 |
| DE19822033A1 (de) | 1999-11-18 |
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| RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: SCHMIDMAYER, GERHARD DIPL.-ING. Inventor name: SCHUBERT, LARS |
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| STAA | Information on the status of an ep patent application or granted ep patent |
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| 18W | Application withdrawn |
Effective date: 20030701 |